Articles | Volume 11, issue 3
https://doi.org/10.5194/essd-11-1109-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/essd-11-1109-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
A global monthly climatology of total alkalinity: a neural network approach
Daniel Broullón
CORRESPONDING AUTHOR
Instituto de Investigaciones Marinas, CSIC, Eduardo Cabello 6, 36208 Vigo, Spain
Fiz F. Pérez
Instituto de Investigaciones Marinas, CSIC, Eduardo Cabello 6, 36208 Vigo, Spain
Antón Velo
Instituto de Investigaciones Marinas, CSIC, Eduardo Cabello 6, 36208 Vigo, Spain
Mario Hoppema
Alfred Wegener Institute Helmholtz Centre for Polar and Marine
Research, Postfach 120161, 27515 Bremerhaven, Germany
Are Olsen
Geophysical Institute, University of Bergen and Bjerknes Centre for
Climate Research, Allégaten 70, 5007 Bergen, Norway
Taro Takahashi
Lamont-Doherty Earth Observatory of Columbia University, Palisades, NY 10964, USA
Robert M. Key
Atmospheric and Oceanic Sciences, Princeton University, 300 Forrestal Road, Sayre Hall, Princeton, NJ 08544, USA
Toste Tanhua
GEOMAR Helmholtz Centre for Ocean Research Kiel, Düsternbrooker
Weg 20, 24105 Kiel, Germany
Melchor González-Dávila
Instituto de Oceanografía y Cambio Global, IOCAG, Universidad de Las Palmas de Gran Canaria, Las Palmas de Gran Canaria, Spain
Emil Jeansson
Uni Research Climate, Bjerknes Centre for Climate Research,
Jahnebakken 5, 5007 Bergen, Norway
Alex Kozyr
NOAA National Centers for Environmental Information, 1315 East-West
Hwy Silver Spring, MD 20910, USA
Steven M. A. C. van Heuven
Faculty of Science and Engineering, Isotope Research – Energy and
Sustainability Research Institute Groningen, University of Groningen,
Nijenborgh 6, 9747 AG Groningen, the Netherlands
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Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Dorothee C. E. Bakker, Judith Hauck, Peter Landschützer, Corinne Le Quéré, Hongmei Li, Ingrid T. Luijkx, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Kjetil Aas, Simone R. Alin, Peter Anthoni, Leticia Barbero, Nicholas R. Bates, Nicolas Bellouin, Alice Benoit-Cattin, Carla F. Berghoff, Raffaele Bernardello, Laurent Bopp, Ida Bagus Mandhara Brasika, Matthew A. Chamberlain, Naveen Chandra, Frédéric Chevallier, Louise P. Chini, Nathan O. Collier, Thomas H. Colligan, Margot Cronin, Laique M. Djeutchouang, Xinyu Dou, Matt P. Enright, Kazutaka Enyo, Michael Erb, Wiley Evans, Richard A. Feely, Liang Feng, Daniel J. Ford, Adrianna Foster, Filippa Fransner, Thomas Gasser, Marion Gehlen, Thanos Gkritzalis, Jefferson Goncalves De Souza, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Bertrand Guenet, Özgür Gürses, Kirsty Harrington, Ian Harris, Jens Heinke, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Akihiko Ito, Andrew R. Jacobson, Atul K. Jain, Tereza Jarníková, Annika Jersild, Fei Jiang, Steve D. Jones, Etsushi Kato, Ralph F. Keeling, Kees Klein Goldewijk, Jürgen Knauer, Yawen Kong, Jan Ivar Korsbakken, Charles Koven, Taro Kunimitsu, Xin Lan, Junjie Liu, Zhiqiang Liu, Zhu Liu, Claire Lo Monaco, Lei Ma, Gregg Marland, Patrick C. McGuire, Galen A. McKinley, Joe R. Melton, Natalie Monacci, Erwan Monier, Eric J. Morgan, David R. Munro, Jens D. Müller, Shin-Ichiro Nakaoka, Lorna R. Nayagam, Yosuke Niwa, Tobias Nutzel, Are Olsen, Abdirahman M. Omar, Naiqing Pan, Sudhanshu Pandey, Denis Pierrot, Zhangcai Qin, Pierre Regnier, Gregor Rehder, Laure Resplandy, Alizée Roobaert, Thais M. Rosan, Christian Rödenbeck, Jörg Schwinger, Ingunn Skjelvan, T. Luke Smallman, Victoria Spada, Mohanan G. Sreeush, Qing Sun, Adrienne J. Sutton, Colm Sweeney, Didier Swingedouw, Roland Séférian, Shintaro Takao, Hiroaki Tatebe, Hanqin Tian, Xiangjun Tian, Bronte Tilbrook, Hiroyuki Tsujino, Francesco Tubiello, Erik van Ooijen, Guido R. van der Werf, Sebastiaan J. van de Velde, Anthony P. Walker, Rik Wanninkhof, Xiaojuan Yang, Wenping Yuan, Xu Yue, and Jiye Zeng
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Lennart Gerke, Toste Tanhua, William A. Nesbitt, Samuel W. Stevens, and Douglas W. R. Wallace
Ocean Sci., 22, 1391–1407, https://doi.org/10.5194/os-22-1391-2026, https://doi.org/10.5194/os-22-1391-2026, 2026
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Raphaël Bajon, Lidia I. Carracedo, Herlé Mercier, Rémy Asselot, and Fiz F. Pérez
Biogeosciences, 23, 2335–2363, https://doi.org/10.5194/bg-23-2335-2026, https://doi.org/10.5194/bg-23-2335-2026, 2026
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Alessandro Zanchetta, Steven van Heuven, Joram Hooghiem, Rigel Kivi, Thomas Laemmel, Michel Ramonet, Markus Leuenberger, Peter Nyfeler, Sophie L. Baartman, Maarten Krol, and Huilin Chen
Atmos. Meas. Tech., 19, 1465–1486, https://doi.org/10.5194/amt-19-1465-2026, https://doi.org/10.5194/amt-19-1465-2026, 2026
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Li-Qing Jiang, Amanda Fay, Jens Daniel Müller, Luke Gregor, Alizée Roobaert, Lydia Keppler, Dustin Carroll, Siv K. Lauvset, Tim DeVries, Judith Hauck, Christian Rödenbeck, Nicolas Metzl, Andrea J. Fassbender, Jean-Pierre Gattuso, Peter Landschützer, Rik Wanninkhof, Christopher Sabine, Simone R. Alin, Mario Hoppema, Are Olsen, Matthew P. Humphreys, Kunal Chakraborty, Ana C. Franco, Kumiko Azetsu-Scott, Dorothee C. E. Bakker, Leticia Barbero, Nicholas R. Bates, Nicole Besemer, Henry C. Bittig, Albert E. Boyd, Daniel Broullón, Wei-Jun Cai, Brendan R. Carter, Thi-Tuyet-Trang Chau, Chen-Tung Arthur Chen, Frédéric Cyr, John E. Dore, Ian Enochs, Richard A. Feely, Hernan E. Garcia, Marion Gehlen, Prasanna Kanti Ghoshal, Lucas Gloege, Melchor González-Dávila, Nicolas Gruber, Debby Ianson, Yosuke Iida, Masao Ishii, Apurva Padamnabh Joshi, Esther Kennedy, Alex Kozyr, Nico Lange, Claire Lo Monaco, Derek P. Manzello, Galen A. McKinley, Natalie M. Monacci, Xose A. Padin, Ana M. Palacio-Castro, Fiz F. Pérez, J. Magdalena Santana-Casiano, Jonathan Sharp, Adrienne Sutton, Jim Swift, Toste Tanhua, Maciej Telszewski, Jens Terhaar, Ruben van Hooidonk, Anton Velo, Andrew J. Watson, Angelicque E. White, Zelun Wu, Liang Xue, Hyelim Yoo, Jiye Zeng, and Guorong Zhong
Earth Syst. Sci. Data, 18, 1405–1462, https://doi.org/10.5194/essd-18-1405-2026, https://doi.org/10.5194/essd-18-1405-2026, 2026
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Irene Sánchez-Mendoza, Melchor González-Dávila, David González-Santana, David Curbelo-Hernández, David Estupiñán-Santana, Aridane G. González, and J. Magdalena Santana-Casiano
Ocean Sci., 22, 609–628, https://doi.org/10.5194/os-22-609-2026, https://doi.org/10.5194/os-22-609-2026, 2026
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Fiz F. Pérez, Marta López-Mozos, Marcos Fontela, Maribel I. García-Ibáñez, Noelia Fajar, Xosé Antonio Padín, Mónica Castaño-Carrera, Mercedes de la Paz, Lidia I. Carracedo, Marta Álvarez, Herlé Mercier, Pascale Lherminier, and Antón Velo
Earth Syst. Sci. Data, 18, 801–821, https://doi.org/10.5194/essd-18-801-2026, https://doi.org/10.5194/essd-18-801-2026, 2026
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Ocean acidification threatens marine ecosystems and the climate and is commonly assessed through ocean pH measurements. This study provides a new twenty-year dataset of pH measurements from the North Atlantic, derived from the correction and reevaluation of both historical and recent pH measurements affected by methodological bias. This revised dataset enables a more accurate reassessment of pH trends and carbon variables under novel and updated methodological standards.
Anne-Marie Wefing, Annabel Payne, Marcel Scheiwiller, Christof Vockenhuber, Marcus Christl, Toste Tanhua, and Núria Casacuberta
Ocean Sci., 21, 3311–3340, https://doi.org/10.5194/os-21-3311-2025, https://doi.org/10.5194/os-21-3311-2025, 2025
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Here we used the anthropogenic radionuclides I-129 and U-236 as tracers for Atlantic Water circulation in the Arctic Ocean. New data collected in 2021 allowed to assess the distribution of Atlantic Water and mixing with Pacific-origin water in the surface layer in that year. By using historical tracer data from 2011 to 2021, we looked into temporal changes of the circulation and found slightly older waters in the central Arctic Ocean in 2021 compared to 2015.
Sophie L. Baartman, Steven M. Driever, Maarten L. J. Wassenaar, Linda M. J. Kooijmans, Nerea Ubierna, Leon Mossink, Maria E. Popa, Ara Cho, Lisa Wingate, Thomas Röckmann, Steven M. A. C. van Heuven, and Maarten C. Krol
Biogeosciences, 22, 5683–5703, https://doi.org/10.5194/bg-22-5683-2025, https://doi.org/10.5194/bg-22-5683-2025, 2025
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Carbonyl sulfide (COS) is a proposed tracer for gross primary production. For the first time, COS and carbon dioxide (CO2) uptake fluxes and isotope discrimination were jointly measured in sunflower and papyrus plants, using a flow-through plant chamber approach and varying light availability. COS isotope discrimination did not differ significantly between the species, nor with changes in light. CO2 fluxes and isotope values provided additional valuable information for data interpretation.
William A. Nesbitt, Samuel W. Stevens, Alfonso O. Mucci, Lennart Gerke, Toste Tanhua, Gwénaëlle Chaillou, and Douglas W. R. Wallace
Ocean Sci., 21, 2179–2195, https://doi.org/10.5194/os-21-2179-2025, https://doi.org/10.5194/os-21-2179-2025, 2025
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We combine two decades of oxygen data with new carbon observations and a tracer-informed model to quantify oxygen loss and carbon buildup in the deep waters of the Gulf and Lower St. Lawrence Estuary. We then test a novel idea: reoxygenating these waters with the oxygen produced as a by-product from green-hydrogen production. Our results suggest this could significantly reduce hypoxia, though full recovery would require larger inputs.
Johannes C. Laube, Tanja J. Schuck, Sophie Baartman, Huilin Chen, Markus Geldenhuys, Steven van Heuven, Timo Keber, Maria Elena Popa, Elinor Tuffnell, Florian Voet, Bärbel Vogel, Thomas Wagenhäuser, Alessandro Zanchetta, and Andreas Engel
Atmos. Meas. Tech., 18, 4087–4102, https://doi.org/10.5194/amt-18-4087-2025, https://doi.org/10.5194/amt-18-4087-2025, 2025
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A large balloon was launched in summer 2021 in the Arctic to carry instruments for trace gas measurements up to 32 km, above the reach of aircraft. The main aims were to evaluate different techniques and atmospheric processes. We focus on halogenated greenhouse gases and ozone-depleting substances. For this, air was collected with the AirCore technique and a cryogenic air sampler and measured after the flight. A companion paper reports observations of major greenhouse gases.
Susana Flecha, Mercedes de la Paz, Fiz Fernández Pérez, Núria Marbà, Carlos Morell, Eva Alou-Font, Joaquín Tintoré, and Iris E. Hendriks
Ocean Sci., 21, 1515–1532, https://doi.org/10.5194/os-21-1515-2025, https://doi.org/10.5194/os-21-1515-2025, 2025
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Nitrous oxide (N2O), a potent greenhouse gas, is understudied in coastal zones. We present N2O concentrations and air–sea fluxes from the Balearic coast (2018–2023). Concentrations varied slightly across sites, with areas acting as weak sources or being near equilibrium. Temperature was the main driver of seasonal changes. These findings improve our understanding of coastal N2O emissions.
David Curbelo-Hernández, David González-Santana, Aridane G. González, J. Magdalena Santana-Casiano, and Melchor González-Dávila
Biogeosciences, 22, 3329–3356, https://doi.org/10.5194/bg-22-3329-2025, https://doi.org/10.5194/bg-22-3329-2025, 2025
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This study offers a unique high-resolution dataset (2019–2024) on surface physicochemical properties in the western Mediterranean Sea. It reveals accelerated surface warming, significantly altering CO2 levels and pH. Currently a net CO2 sink, the region may become a CO2 source by 2030 due to weakening in-gassing. The research highlights the value of VOS (volunteer observing ship) lines for monitoring climate impacts and emphasizes the need for ongoing observations to enhance long-term trend accuracy and future projections.
Tanja J. Schuck, Johannes Degen, Timo Keber, Katharina Meixner, Thomas Wagenhäuser, Mélanie Ghysels, Georges Durry, Nadir Amarouche, Alessandro Zanchetta, Steven van Heuven, Huilin Chen, Johannes C. Laube, Sophie L. Baartman, Carina van der Veen, Maria Elena Popa, and Andreas Engel
Atmos. Chem. Phys., 25, 4333–4348, https://doi.org/10.5194/acp-25-4333-2025, https://doi.org/10.5194/acp-25-4333-2025, 2025
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A balloon was launched in 2021 in the Arctic to carry instruments for trace gas measurements up to 32 km. One purpose was to compare measurement techniques. We focus on the major greenhouse gases. To measure these, air was sampled with the AirCore technique and with flask sampling, and samples were analysed after the flight. In flight, observations were done with an optical method. In a companion paper, we report on observations of chlorine and bromine containing trace gases.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Judith Hauck, Peter Landschützer, Corinne Le Quéré, Hongmei Li, Ingrid T. Luijkx, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Almut Arneth, Vivek Arora, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Carla F. Berghoff, Henry C. Bittig, Laurent Bopp, Patricia Cadule, Katie Campbell, Matthew A. Chamberlain, Naveen Chandra, Frédéric Chevallier, Louise P. Chini, Thomas Colligan, Jeanne Decayeux, Laique M. Djeutchouang, Xinyu Dou, Carolina Duran Rojas, Kazutaka Enyo, Wiley Evans, Amanda R. Fay, Richard A. Feely, Daniel J. Ford, Adrianna Foster, Thomas Gasser, Marion Gehlen, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Jens Heinke, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Andrew R. Jacobson, Atul K. Jain, Tereza Jarníková, Annika Jersild, Fei Jiang, Zhe Jin, Etsushi Kato, Ralph F. Keeling, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Xin Lan, Siv K. Lauvset, Nathalie Lefèvre, Zhu Liu, Junjie Liu, Lei Ma, Shamil Maksyutov, Gregg Marland, Nicolas Mayot, Patrick C. McGuire, Nicolas Metzl, Natalie M. Monacci, Eric J. Morgan, Shin-Ichiro Nakaoka, Craig Neill, Yosuke Niwa, Tobias Nützel, Lea Olivier, Tsuneo Ono, Paul I. Palmer, Denis Pierrot, Zhangcai Qin, Laure Resplandy, Alizée Roobaert, Thais M. Rosan, Christian Rödenbeck, Jörg Schwinger, T. Luke Smallman, Stephen M. Smith, Reinel Sospedra-Alfonso, Tobias Steinhoff, Qing Sun, Adrienne J. Sutton, Roland Séférian, Shintaro Takao, Hiroaki Tatebe, Hanqin Tian, Bronte Tilbrook, Olivier Torres, Etienne Tourigny, Hiroyuki Tsujino, Francesco Tubiello, Guido van der Werf, Rik Wanninkhof, Xuhui Wang, Dongxu Yang, Xiaojuan Yang, Zhen Yu, Wenping Yuan, Xu Yue, Sönke Zaehle, Ning Zeng, and Jiye Zeng
Earth Syst. Sci. Data, 17, 965–1039, https://doi.org/10.5194/essd-17-965-2025, https://doi.org/10.5194/essd-17-965-2025, 2025
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The Global Carbon Budget 2024 describes the methodology, main results, and datasets used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, land ecosystems, and the ocean over the historical period (1750–2024). These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
David Curbelo-Hernández, Fiz F. Pérez, Melchor González-Dávila, Sergey V. Gladyshev, Aridane G. González, David González-Santana, Antón Velo, Alexey Sokov, and J. Magdalena Santana-Casiano
Biogeosciences, 21, 5561–5589, https://doi.org/10.5194/bg-21-5561-2024, https://doi.org/10.5194/bg-21-5561-2024, 2024
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The study evaluated CO2–carbonate system dynamics in the North Atlantic subpolar gyre during 2009–2019. Significant ocean acidification, largely due to rising anthropogenic CO2 levels, was found. Cooling, freshening, and enhanced convective processes intensified this trend, affecting calcite and aragonite saturation. The findings contribute to a deeper understanding of ocean acidification and improve our knowledge about its impact on marine ecosystems.
Milagros Rico, Paula Santiago-Díaz, Guillermo Samperio-Ramos, Melchor González-Dávila, and Juana Magdalena Santana-Casiano
Biogeosciences, 21, 4381–4394, https://doi.org/10.5194/bg-21-4381-2024, https://doi.org/10.5194/bg-21-4381-2024, 2024
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Changes in pH generate stress conditions, either because high pH drastically decreases the availability of trace metals such as Fe(II), a restrictive element for primary productivity, or because reactive oxygen species are increased with low pH. The metabolic functions and composition of microalgae can be affected. These modifications in metabolites are potential factors leading to readjustments in phytoplankton community structure and diversity and possible alteration in marine ecosystems.
Nil Irvalı, Ulysses S. Ninnemann, Are Olsen, Neil L. Rose, David J. R. Thornalley, Tor L. Mjell, and François Counillon
Geochronology, 6, 449–463, https://doi.org/10.5194/gchron-6-449-2024, https://doi.org/10.5194/gchron-6-449-2024, 2024
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Marine sediments are excellent archives for reconstructing past changes in climate and ocean circulation. Yet, dating uncertainties, particularly during the 20th century, pose major challenges. Here we propose a novel chronostratigraphic approach that uses anthropogenic signals, such as the oceanic 13C Suess effect and spheroidal carbonaceous fly-ash particles, to reduce age model uncertainties in high-resolution marine archives over the 20th century.
Herlé Mercier, Damien Desbruyères, Pascale Lherminier, Antón Velo, Lidia Carracedo, Marcos Fontela, and Fiz F. Pérez
Ocean Sci., 20, 779–797, https://doi.org/10.5194/os-20-779-2024, https://doi.org/10.5194/os-20-779-2024, 2024
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We study the Atlantic Meridional Overturning Circulation (AMOC) measured between Greenland and Portugal between 1993–2021. We identify changes in AMOC limb volume and velocity as two major drivers of AMOC variability at subpolar latitudes. Volume variations dominate on the seasonal timescale, while velocity variations are more important on the decadal timescale. This decomposition proves useful for understanding the origin of the differences between AMOC time series from different analyses.
David González-Santana, María Segovia, Melchor González-Dávila, Librada Ramírez, Aridane G. González, Leonardo J. Pozzo-Pirotta, Veronica Arnone, Victor Vázquez, Ulf Riebesell, and J. Magdalena Santana-Casiano
Biogeosciences, 21, 2705–2715, https://doi.org/10.5194/bg-21-2705-2024, https://doi.org/10.5194/bg-21-2705-2024, 2024
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In a recent experiment off the coast of Gran Canaria (Spain), scientists explored a method called ocean alkalinization enhancement (OAE), where carbonate minerals were added to seawater. This process changed the levels of certain ions in the water, affecting its pH and buffering capacity. The researchers were particularly interested in how this could impact the levels of essential trace metals in the water.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Marta Álvarez, Kumiko Azetsu-Scott, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Akihiko Murata, Jens Daniel Müller, Fiz F. Pérez, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 16, 2047–2072, https://doi.org/10.5194/essd-16-2047-2024, https://doi.org/10.5194/essd-16-2047-2024, 2024
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GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2023 is the fifth update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality controlling, including systematic evaluation of measurement biases. This version contains data from 1108 hydrographic cruises covering the world's oceans from 1972 to 2021.
Nico Lange, Björn Fiedler, Marta Álvarez, Alice Benoit-Cattin, Heather Benway, Pier Luigi Buttigieg, Laurent Coppola, Kim Currie, Susana Flecha, Dana S. Gerlach, Makio Honda, I. Emma Huertas, Siv K. Lauvset, Frank Muller-Karger, Arne Körtzinger, Kevin M. O'Brien, Sólveig R. Ólafsdóttir, Fernando C. Pacheco, Digna Rueda-Roa, Ingunn Skjelvan, Masahide Wakita, Angelicque White, and Toste Tanhua
Earth Syst. Sci. Data, 16, 1901–1931, https://doi.org/10.5194/essd-16-1901-2024, https://doi.org/10.5194/essd-16-1901-2024, 2024
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The Synthesis Product for Ocean Time Series (SPOTS) is a novel achievement expanding and complementing the biogeochemical data landscape by providing consistent and high-quality biogeochemical time-series data from 12 ship-based fixed time-series programs. SPOTS covers multiple unique marine environments and time-series ranges, including data from 1983 to 2021. All in all, it facilitates a variety of applications that benefit from the collective value of biogeochemical time-series observations.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Dorothee C. E. Bakker, Judith Hauck, Peter Landschützer, Corinne Le Quéré, Ingrid T. Luijkx, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Peter Anthoni, Leticia Barbero, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Bertrand Decharme, Laurent Bopp, Ida Bagus Mandhara Brasika, Patricia Cadule, Matthew A. Chamberlain, Naveen Chandra, Thi-Tuyet-Trang Chau, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Xinyu Dou, Kazutaka Enyo, Wiley Evans, Stefanie Falk, Richard A. Feely, Liang Feng, Daniel J. Ford, Thomas Gasser, Josefine Ghattas, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Jens Heinke, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Andrew R. Jacobson, Atul Jain, Tereza Jarníková, Annika Jersild, Fei Jiang, Zhe Jin, Fortunat Joos, Etsushi Kato, Ralph F. Keeling, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Arne Körtzinger, Xin Lan, Nathalie Lefèvre, Hongmei Li, Junjie Liu, Zhiqiang Liu, Lei Ma, Greg Marland, Nicolas Mayot, Patrick C. McGuire, Galen A. McKinley, Gesa Meyer, Eric J. Morgan, David R. Munro, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin M. O'Brien, Are Olsen, Abdirahman M. Omar, Tsuneo Ono, Melf Paulsen, Denis Pierrot, Katie Pocock, Benjamin Poulter, Carter M. Powis, Gregor Rehder, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Thais M. Rosan, Jörg Schwinger, Roland Séférian, T. Luke Smallman, Stephen M. Smith, Reinel Sospedra-Alfonso, Qing Sun, Adrienne J. Sutton, Colm Sweeney, Shintaro Takao, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Hiroyuki Tsujino, Francesco Tubiello, Guido R. van der Werf, Erik van Ooijen, Rik Wanninkhof, Michio Watanabe, Cathy Wimart-Rousseau, Dongxu Yang, Xiaojuan Yang, Wenping Yuan, Xu Yue, Sönke Zaehle, Jiye Zeng, and Bo Zheng
Earth Syst. Sci. Data, 15, 5301–5369, https://doi.org/10.5194/essd-15-5301-2023, https://doi.org/10.5194/essd-15-5301-2023, 2023
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The Global Carbon Budget 2023 describes the methodology, main results, and data sets used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, land ecosystems, and the ocean over the historical period (1750–2023). These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Christoph Heinze, Thorsten Blenckner, Peter Brown, Friederike Fröb, Anne Morée, Adrian L. New, Cara Nissen, Stefanie Rynders, Isabel Seguro, Yevgeny Aksenov, Yuri Artioli, Timothée Bourgeois, Friedrich Burger, Jonathan Buzan, B. B. Cael, Veli Çağlar Yumruktepe, Melissa Chierici, Christopher Danek, Ulf Dieckmann, Agneta Fransson, Thomas Frölicher, Giovanni Galli, Marion Gehlen, Aridane G. González, Melchor Gonzalez-Davila, Nicolas Gruber, Örjan Gustafsson, Judith Hauck, Mikko Heino, Stephanie Henson, Jenny Hieronymus, I. Emma Huertas, Fatma Jebri, Aurich Jeltsch-Thömmes, Fortunat Joos, Jaideep Joshi, Stephen Kelly, Nandini Menon, Precious Mongwe, Laurent Oziel, Sólveig Ólafsdottir, Julien Palmieri, Fiz F. Pérez, Rajamohanan Pillai Ranith, Juliano Ramanantsoa, Tilla Roy, Dagmara Rusiecka, J. Magdalena Santana Casiano, Yeray Santana-Falcón, Jörg Schwinger, Roland Séférian, Miriam Seifert, Anna Shchiptsova, Bablu Sinha, Christopher Somes, Reiner Steinfeldt, Dandan Tao, Jerry Tjiputra, Adam Ulfsbo, Christoph Völker, Tsuyoshi Wakamatsu, and Ying Ye
Biogeosciences Discuss., https://doi.org/10.5194/bg-2023-182, https://doi.org/10.5194/bg-2023-182, 2023
Revised manuscript not accepted
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For assessing the consequences of human-induced climate change for the marine realm, it is necessary to not only look at gradual changes but also at abrupt changes of environmental conditions. We summarise abrupt changes in ocean warming, acidification, and oxygen concentration as the key environmental factors for ecosystems. Taking these abrupt changes into account requires greenhouse gas emissions to be reduced to a larger extent than previously thought to limit respective damage.
Foteini Stavropoulou, Katarina Vinković, Bert Kers, Marcel de Vries, Steven van Heuven, Piotr Korbeń, Martina Schmidt, Julia Wietzel, Pawel Jagoda, Jaroslav M. Necki, Jakub Bartyzel, Hossein Maazallahi, Malika Menoud, Carina van der Veen, Sylvia Walter, Béla Tuzson, Jonas Ravelid, Randulph Paulo Morales, Lukas Emmenegger, Dominik Brunner, Michael Steiner, Arjan Hensen, Ilona Velzeboer, Pim van den Bulk, Hugo Denier van der Gon, Antonio Delre, Maklawe Essonanawe Edjabou, Charlotte Scheutz, Marius Corbu, Sebastian Iancu, Denisa Moaca, Alin Scarlat, Alexandru Tudor, Ioana Vizireanu, Andreea Calcan, Magdalena Ardelean, Sorin Ghemulet, Alexandru Pana, Aurel Constantinescu, Lucian Cusa, Alexandru Nica, Calin Baciu, Cristian Pop, Andrei Radovici, Alexandru Mereuta, Horatiu Stefanie, Alexandru Dandocsi, Bas Hermans, Stefan Schwietzke, Daniel Zavala-Araiza, Huilin Chen, and Thomas Röckmann
Atmos. Chem. Phys., 23, 10399–10412, https://doi.org/10.5194/acp-23-10399-2023, https://doi.org/10.5194/acp-23-10399-2023, 2023
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In this study, we quantify CH4 emissions from onshore oil production sites in Romania at source and facility level using a combination of ground- and drone-based measurement techniques. We show that the total CH4 emissions in our studied areas are much higher than the emissions reported to UNFCCC, and up to three-quarters of the detected emissions are related to operational venting. Our results suggest that oil and gas production infrastructure in Romania holds a massive mitigation potential.
Alessandro Zanchetta, Linda M. J. Kooijmans, Steven van Heuven, Andrea Scifo, Hubertus A. Scheeren, Ivan Mammarella, Ute Karstens, Jin Ma, Maarten Krol, and Huilin Chen
Biogeosciences, 20, 3539–3553, https://doi.org/10.5194/bg-20-3539-2023, https://doi.org/10.5194/bg-20-3539-2023, 2023
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Carbonyl sulfide (COS) has been suggested as a tool to estimate carbon dioxide (CO2) uptake by plants during photosynthesis. However, understanding its sources and sinks is critical to preventing biases in this estimate. Combining observations and models, this study proves that regional sources occasionally influence the measurements at the 60 m tall Lutjewad tower (1 m a.s.l.; 53°24′ N, 6°21′ E) in the Netherlands. Moreover, it estimates nighttime COS fluxes to be −3.0 ± 2.6 pmol m−2 s−1.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Simone Alin, Marta Álvarez, Kumiko Azetsu-Scott, Leticia Barbero, Susan Becker, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Richard A. Feely, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Li-Qing Jiang, Steve D. Jones, Claire Lo Monaco, Akihiko Murata, Jens Daniel Müller, Fiz F. Pérez, Benjamin Pfeil, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Bronte Tilbrook, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 14, 5543–5572, https://doi.org/10.5194/essd-14-5543-2022, https://doi.org/10.5194/essd-14-5543-2022, 2022
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GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2022 is the fourth update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality controlling, including systematic evaluation of measurement biases. This version contains data from 1085 hydrographic cruises covering the world's oceans from 1972 to 2021.
Julian Gutt, Stefanie Arndt, David Keith Alan Barnes, Horst Bornemann, Thomas Brey, Olaf Eisen, Hauke Flores, Huw Griffiths, Christian Haas, Stefan Hain, Tore Hattermann, Christoph Held, Mario Hoppema, Enrique Isla, Markus Janout, Céline Le Bohec, Heike Link, Felix Christopher Mark, Sebastien Moreau, Scarlett Trimborn, Ilse van Opzeeland, Hans-Otto Pörtner, Fokje Schaafsma, Katharina Teschke, Sandra Tippenhauer, Anton Van de Putte, Mia Wege, Daniel Zitterbart, and Dieter Piepenburg
Biogeosciences, 19, 5313–5342, https://doi.org/10.5194/bg-19-5313-2022, https://doi.org/10.5194/bg-19-5313-2022, 2022
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Long-term ecological observations are key to assess, understand and predict impacts of environmental change on biotas. We present a multidisciplinary framework for such largely lacking investigations in the East Antarctic Southern Ocean, combined with case studies, experimental and modelling work. As climate change is still minor here but is projected to start soon, the timely implementation of this framework provides the unique opportunity to document its ecological impacts from the very onset.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Luke Gregor, Judith Hauck, Corinne Le Quéré, Ingrid T. Luijkx, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Ramdane Alkama, Almut Arneth, Vivek K. Arora, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Henry C. Bittig, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Wiley Evans, Stefanie Falk, Richard A. Feely, Thomas Gasser, Marion Gehlen, Thanos Gkritzalis, Lucas Gloege, Giacomo Grassi, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Atul K. Jain, Annika Jersild, Koji Kadono, Etsushi Kato, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Peter Landschützer, Nathalie Lefèvre, Keith Lindsay, Junjie Liu, Zhu Liu, Gregg Marland, Nicolas Mayot, Matthew J. McGrath, Nicolas Metzl, Natalie M. Monacci, David R. Munro, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin O'Brien, Tsuneo Ono, Paul I. Palmer, Naiqing Pan, Denis Pierrot, Katie Pocock, Benjamin Poulter, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Carmen Rodriguez, Thais M. Rosan, Jörg Schwinger, Roland Séférian, Jamie D. Shutler, Ingunn Skjelvan, Tobias Steinhoff, Qing Sun, Adrienne J. Sutton, Colm Sweeney, Shintaro Takao, Toste Tanhua, Pieter P. Tans, Xiangjun Tian, Hanqin Tian, Bronte Tilbrook, Hiroyuki Tsujino, Francesco Tubiello, Guido R. van der Werf, Anthony P. Walker, Rik Wanninkhof, Chris Whitehead, Anna Willstrand Wranne, Rebecca Wright, Wenping Yuan, Chao Yue, Xu Yue, Sönke Zaehle, Jiye Zeng, and Bo Zheng
Earth Syst. Sci. Data, 14, 4811–4900, https://doi.org/10.5194/essd-14-4811-2022, https://doi.org/10.5194/essd-14-4811-2022, 2022
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The Global Carbon Budget 2022 describes the datasets and methodology used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, the land ecosystems, and the ocean. These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Rainer Kiko, Marc Picheral, David Antoine, Marcel Babin, Léo Berline, Tristan Biard, Emmanuel Boss, Peter Brandt, Francois Carlotti, Svenja Christiansen, Laurent Coppola, Leandro de la Cruz, Emilie Diamond-Riquier, Xavier Durrieu de Madron, Amanda Elineau, Gabriel Gorsky, Lionel Guidi, Helena Hauss, Jean-Olivier Irisson, Lee Karp-Boss, Johannes Karstensen, Dong-gyun Kim, Rachel M. Lekanoff, Fabien Lombard, Rubens M. Lopes, Claudie Marec, Andrew M. P. McDonnell, Daniela Niemeyer, Margaux Noyon, Stephanie H. O'Daly, Mark D. Ohman, Jessica L. Pretty, Andreas Rogge, Sarah Searson, Masashi Shibata, Yuji Tanaka, Toste Tanhua, Jan Taucher, Emilia Trudnowska, Jessica S. Turner, Anya Waite, and Lars Stemmann
Earth Syst. Sci. Data, 14, 4315–4337, https://doi.org/10.5194/essd-14-4315-2022, https://doi.org/10.5194/essd-14-4315-2022, 2022
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The term
marine particlescomprises detrital aggregates; fecal pellets; bacterioplankton, phytoplankton and zooplankton; and even fish. Here, we present a global dataset that contains 8805 vertical particle size distribution profiles obtained with Underwater Vision Profiler 5 (UVP5) camera systems. These data are valuable to the scientific community, as they can be used to constrain important biogeochemical processes in the ocean, such as the flux of carbon to the deep sea.
Elise S. Droste, Mario Hoppema, Melchor González-Dávila, Juana Magdalena Santana-Casiano, Bastien Y. Queste, Giorgio Dall'Olmo, Hugh J. Venables, Gerd Rohardt, Sharyn Ossebaar, Daniel Schuller, Sunke Trace-Kleeberg, and Dorothee C. E. Bakker
Ocean Sci., 18, 1293–1320, https://doi.org/10.5194/os-18-1293-2022, https://doi.org/10.5194/os-18-1293-2022, 2022
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Tides affect the marine carbonate chemistry of a coastal polynya neighbouring the Ekström Ice Shelf by movement of seawater with different physical and biogeochemical properties. The result is that the coastal polynya in the summer can switch between being a sink or a source of CO2 multiple times a day. We encourage consideration of tides when collecting in polar coastal regions to account for tide-driven variability and to avoid overestimations or underestimations of air–sea CO2 exchange.
Hein J. W. de Baar, Mario Hoppema, and Elizabeth M. Jones
EGUsphere, https://doi.org/10.5194/egusphere-2022-676, https://doi.org/10.5194/egusphere-2022-676, 2022
Preprint archived
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There is confusion in the literature on interactions of dissolved phosphate and sulphate with the alkalinity of seawater. These do play a minor role in the titration to determine alkalinity. However, a perceived biological role of phosphate and sulphate has been suggested in the value of Oceanic Alkalinity. We think this is mistaken. Some other minor issues additionally have led to confusion on the exact description of Alkalinity. We treat those against a theoretical and empirical background.
Gilles Reverdin, Claire Waelbroeck, Catherine Pierre, Camille Akhoudas, Giovanni Aloisi, Marion Benetti, Bernard Bourlès, Magnus Danielsen, Jérôme Demange, Denis Diverrès, Jean-Claude Gascard, Marie-Noëlle Houssais, Hervé Le Goff, Pascale Lherminier, Claire Lo Monaco, Herlé Mercier, Nicolas Metzl, Simon Morisset, Aïcha Naamar, Thierry Reynaud, Jean-Baptiste Sallée, Virginie Thierry, Susan E. Hartman, Edward W. Mawji, Solveig Olafsdottir, Torsten Kanzow, Anton Velo, Antje Voelker, Igor Yashayaev, F. Alexander Haumann, Melanie J. Leng, Carol Arrowsmith, and Michael Meredith
Earth Syst. Sci. Data, 14, 2721–2735, https://doi.org/10.5194/essd-14-2721-2022, https://doi.org/10.5194/essd-14-2721-2022, 2022
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The CISE-LOCEAN seawater stable isotope dataset has close to 8000 data entries. The δ18O and δD isotopic data measured at LOCEAN have uncertainties of at most 0.05 ‰ and 0.25 ‰, respectively. Some data were adjusted to correct for evaporation. The internal consistency indicates that the data can be used to investigate time and space variability to within 0.03 ‰ and 0.15 ‰ in δ18O–δD17; comparisons with data analyzed in other institutions suggest larger differences with other datasets.
Pierre Friedlingstein, Matthew W. Jones, Michael O'Sullivan, Robbie M. Andrew, Dorothee C. E. Bakker, Judith Hauck, Corinne Le Quéré, Glen P. Peters, Wouter Peters, Julia Pongratz, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Rob B. Jackson, Simone R. Alin, Peter Anthoni, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Laurent Bopp, Thi Tuyet Trang Chau, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Kim I. Currie, Bertrand Decharme, Laique M. Djeutchouang, Xinyu Dou, Wiley Evans, Richard A. Feely, Liang Feng, Thomas Gasser, Dennis Gilfillan, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Ingrid T. Luijkx, Atul Jain, Steve D. Jones, Etsushi Kato, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Arne Körtzinger, Peter Landschützer, Siv K. Lauvset, Nathalie Lefèvre, Sebastian Lienert, Junjie Liu, Gregg Marland, Patrick C. McGuire, Joe R. Melton, David R. Munro, Julia E. M. S. Nabel, Shin-Ichiro Nakaoka, Yosuke Niwa, Tsuneo Ono, Denis Pierrot, Benjamin Poulter, Gregor Rehder, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Thais M. Rosan, Jörg Schwinger, Clemens Schwingshackl, Roland Séférian, Adrienne J. Sutton, Colm Sweeney, Toste Tanhua, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Francesco Tubiello, Guido R. van der Werf, Nicolas Vuichard, Chisato Wada, Rik Wanninkhof, Andrew J. Watson, David Willis, Andrew J. Wiltshire, Wenping Yuan, Chao Yue, Xu Yue, Sönke Zaehle, and Jiye Zeng
Earth Syst. Sci. Data, 14, 1917–2005, https://doi.org/10.5194/essd-14-1917-2022, https://doi.org/10.5194/essd-14-1917-2022, 2022
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The Global Carbon Budget 2021 describes the data sets and methodology used to quantify the emissions of carbon dioxide and their partitioning among the atmosphere, land, and ocean. These living data are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Filippa Fransner, Friederike Fröb, Jerry Tjiputra, Nadine Goris, Siv K. Lauvset, Ingunn Skjelvan, Emil Jeansson, Abdirahman Omar, Melissa Chierici, Elizabeth Jones, Agneta Fransson, Sólveig R. Ólafsdóttir, Truls Johannessen, and Are Olsen
Biogeosciences, 19, 979–1012, https://doi.org/10.5194/bg-19-979-2022, https://doi.org/10.5194/bg-19-979-2022, 2022
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Ocean acidification, a direct consequence of the CO2 release by human activities, is a serious threat to marine ecosystems. In this study, we conduct a detailed investigation of the acidification of the Nordic Seas, from 1850 to 2100, by using a large set of samples taken during research cruises together with numerical model simulations. We estimate the effects of changes in different environmental factors on the rate of acidification and its potential effects on cold-water corals.
Alice E. Webb, Didier M. de Bakker, Karline Soetaert, Tamara da Costa, Steven M. A. C. van Heuven, Fleur C. van Duyl, Gert-Jan Reichart, and Lennart J. de Nooijer
Biogeosciences, 18, 6501–6516, https://doi.org/10.5194/bg-18-6501-2021, https://doi.org/10.5194/bg-18-6501-2021, 2021
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The biogeochemical behaviour of shallow reef communities is quantified to better understand the impact of habitat degradation and species composition shifts on reef functioning. The reef communities investigated barely support reef functions that are usually ascribed to conventional coral reefs, and the overall biogeochemical behaviour is found to be similar regardless of substrate type. This suggests a decrease in functional diversity which may therefore limit services provided by this reef.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Marta Álvarez, Susan Becker, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Richard A. Feely, Steven van Heuven, Mario Hoppema, Masao Ishii, Emil Jeansson, Sara Jutterström, Steve D. Jones, Maren K. Karlsen, Claire Lo Monaco, Patrick Michaelis, Akihiko Murata, Fiz F. Pérez, Benjamin Pfeil, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Bronte Tilbrook, Anton Velo, Rik Wanninkhof, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 13, 5565–5589, https://doi.org/10.5194/essd-13-5565-2021, https://doi.org/10.5194/essd-13-5565-2021, 2021
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GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2021 is the third update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality control, including systematic evaluation of measurement biases. This version contains data from 989 hydrographic cruises covering the world's oceans from 1972 to 2020.
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Short summary
In this work, we are contributing to the knowledge of the consequences of climate change in the ocean. We have focused on a variable related to this process: total alkalinity. We have designed a monthly climatology of total alkalinity using artificial intelligence techniques, that is, a representation of the average capacity of the ocean in the last decades to decelerate the consequences of climate change. The climatology is especially useful to infer the evolution of the ocean through models.
In this work, we are contributing to the knowledge of the consequences of climate change in the...
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