Articles | Volume 16, issue 1
https://doi.org/10.5194/essd-16-89-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/essd-16-89-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
A synthesis of ocean total alkalinity and dissolved inorganic carbon measurements from 1993 to 2022: the SNAPO-CO2-v1 dataset
Nicolas Metzl
CORRESPONDING AUTHOR
Laboratoire LOCEAN/IPSL, Sorbonne Université-CNRS-IRD-MNHN, 75005 Paris, France
Jonathan Fin
Laboratoire LOCEAN/IPSL, Sorbonne Université-CNRS-IRD-MNHN, 75005 Paris, France
OSU Ecce Terra, Sorbonne Université-CNRS, 75005 Paris, France
Claire Lo Monaco
Laboratoire LOCEAN/IPSL, Sorbonne Université-CNRS-IRD-MNHN, 75005 Paris, France
Claude Mignon
Laboratoire LOCEAN/IPSL, Sorbonne Université-CNRS-IRD-MNHN, 75005 Paris, France
Samir Alliouane
CNRS, Laboratoire d'Océanographie de Villefranche, LOV, Sorbonne Université, 06230 Villefranche-sur-Mer, France
David Antoine
CNRS, Laboratoire d'Océanographie de Villefranche, LOV, Sorbonne Université, 06230 Villefranche-sur-Mer, France
Remote Sensing and Satellite Research Group, School of Earth and Planetary Sciences, Curtin University, Perth, WA 6845, Australia
Guillaume Bourdin
School of Marine Sciences, University of Maine, 04469 Orono, USA
Jacqueline Boutin
Laboratoire LOCEAN/IPSL, Sorbonne Université-CNRS-IRD-MNHN, 75005 Paris, France
Yann Bozec
Station Biologique de Roscoff, UMR 7144 – EDYCO-CHIMAR, 29680 Roscoff, France
Pascal Conan
CNRS, Laboratoire d'Océanographie Microbienne, LOMIC, Sorbonne Université, 66650 Banyuls-sur-Mer, France
CNRS, OSU Station Marines, STAMAR, Sorbonne Université, 75006 Paris, France
Laurent Coppola
CNRS, Laboratoire d'Océanographie de Villefranche, LOV, Sorbonne Université, 06230 Villefranche-sur-Mer, France
CNRS, OSU Station Marines, STAMAR, Sorbonne Université, 75006 Paris, France
Frédéric Diaz
Aix Marseille University, Université de Toulon, CNRS, IRD, MIO, 13288 Marseille, France
deceased, 14 March 2021
Eric Douville
Laboratoire des Sciences du Climat et de l'Environnement, LSCE/IPSL, UMR 8212 CEA-CNRS-UVSQ, Universiteì Paris-Saclay, 91191 Gif-sur-Yvette, France
Xavier Durrieu de Madron
CEFREM, CNRS-Université de Perpignan Via Domitia, 66860 Perpignan, France
Jean-Pierre Gattuso
CNRS, Laboratoire d'Océanographie de Villefranche, LOV, Sorbonne Université, 06230 Villefranche-sur-Mer, France
Institute for Sustainable Development and International Relations, Sciences Po, 75007 Paris, France
Frédéric Gazeau
CNRS, Laboratoire d'Océanographie de Villefranche, LOV, Sorbonne Université, 06230 Villefranche-sur-Mer, France
Melek Golbol
CNRS, OSU Station Marines, STAMAR, Sorbonne Université, 75006 Paris, France
CNRS, Institut de la Mer de Villefranche, IMEV, Sorbonne Université, 06230 Villefranche-sur-Mer, France
Bruno Lansard
Laboratoire des Sciences du Climat et de l'Environnement, LSCE/IPSL, UMR 8212 CEA-CNRS-UVSQ, Universiteì Paris-Saclay, 91191 Gif-sur-Yvette, France
Dominique Lefèvre
Aix Marseille University, Université de Toulon, CNRS, IRD, MIO, 13288 Marseille, France
Nathalie Lefèvre
Laboratoire LOCEAN/IPSL, Sorbonne Université-CNRS-IRD-MNHN, 75005 Paris, France
Fabien Lombard
CNRS, Laboratoire d'Océanographie de Villefranche, LOV, Sorbonne Université, 06230 Villefranche-sur-Mer, France
Research Federation for the study of Global Ocean Systems Ecology and Evolution, FR2022/Tara GOSEE, 75000 Paris, France
Férial Louanchi
CVRM: Laboratoire de Conservation et de Valorisation des Ressources Marines, Ecole Nationale Supérieure des Sciences de la Mer et de l'Aménagement du Littoral (ENSSMAL), Station de recherche de Sidi Fredj, 16320 Alger, Algeria
Liliane Merlivat
Laboratoire LOCEAN/IPSL, Sorbonne Université-CNRS-IRD-MNHN, 75005 Paris, France
Léa Olivier
Laboratoire LOCEAN/IPSL, Sorbonne Université-CNRS-IRD-MNHN, 75005 Paris, France
Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research, 27515 Bremerhaven, Germany
Anne Petrenko
Aix Marseille University, Université de Toulon, CNRS, IRD, MIO, 13288 Marseille, France
Sébastien Petton
Ifremer, Brest University, CNRS, IRD, LEMAR, 29840 Argenton, France
Mireille Pujo-Pay
CNRS, Laboratoire d'Océanographie Microbienne, LOMIC, Sorbonne Université, 66650 Banyuls-sur-Mer, France
Christophe Rabouille
Laboratoire des Sciences du Climat et de l'Environnement, LSCE/IPSL, UMR 8212 CEA-CNRS-UVSQ, Universiteì Paris-Saclay, 91191 Gif-sur-Yvette, France
Gilles Reverdin
Laboratoire LOCEAN/IPSL, Sorbonne Université-CNRS-IRD-MNHN, 75005 Paris, France
Céline Ridame
Laboratoire LOCEAN/IPSL, Sorbonne Université-CNRS-IRD-MNHN, 75005 Paris, France
Aline Tribollet
Laboratoire LOCEAN/IPSL, Sorbonne Université-CNRS-IRD-MNHN, 75005 Paris, France
Vincenzo Vellucci
CNRS, OSU Station Marines, STAMAR, Sorbonne Université, 75006 Paris, France
CNRS, Institut de la Mer de Villefranche, IMEV, Sorbonne Université, 06230 Villefranche-sur-Mer, France
Thibaut Wagener
Aix Marseille University, Université de Toulon, CNRS, IRD, MIO, 13288 Marseille, France
Cathy Wimart-Rousseau
Aix Marseille University, Université de Toulon, CNRS, IRD, MIO, 13288 Marseille, France
GEOMAR Helmholtz Center for Ocean Research Kiel, Helmholtz Association of German Research Centres, 24105 Kiel, Germany
Related authors
Nicolas Metzl, Claire Lo Monaco, Aline Tribollet, Jean-François Ternon, Frédéric Chevallier, and Marion Gehlen
EGUsphere, https://doi.org/10.5194/egusphere-2025-3469, https://doi.org/10.5194/egusphere-2025-3469, 2025
This preprint is open for discussion and under review for Biogeosciences (BG).
Short summary
Short summary
In the Mozambique Channel, observed acceleration of the ocean acidification in the recent decades is mainly driven by anthropogenic CO2 uptake. In this region the aragonite saturation state reached 3.2 in 2025 and could be as low as 3 in the next 10 years with potential impact on marine ecosystem including corals reefs areas.
Li-Qing Jiang, Amanda Fay, Jens Daniel Müller, Lydia Keppler, Dustin Carroll, Siv K. Lauvset, Tim DeVries, Judith Hauck, Christian Rödenbeck, Luke Gregor, Nicolas Metzl, Andrea J. Fassbender, Jean-Pierre Gattuso, Peter Landschützer, Rik Wanninkhof, Christopher Sabine, Simone R. Alin, Mario Hoppema, Are Olsen, Matthew P. Humphreys, Kumiko Azetsu-Scott, Dorothee C. E. Bakker, Leticia Barbero, Nicholas R. Bates, Nicole Besemer, Henry C. Bittig, Albert E. Boyd, Daniel Broullón, Wei-Jun Cai, Brendan R. Carter, Thi-Tuyet-Trang Chau, Chen-Tung Arthur Chen, Frédéric Cyr, John E. Dore, Ian Enochs, Richard A. Feely, Hernan E. Garcia, Marion Gehlen, Lucas Gloege, Melchor González-Dávila, Nicolas Gruber, Yosuke Iida, Masao Ishii, Esther Kennedy, Alex Kozyr, Nico Lange, Claire Lo Monaco, Derek P. Manzello, Galen A. McKinley, Natalie M. Monacci, Xose A. Padin, Ana M. Palacio-Castro, Fiz F. Pérez, Alizée Roobaert, J. Magdalena Santana-Casiano, Jonathan Sharp, Adrienne Sutton, Jim Swift, Toste Tanhua, Maciej Telszewski, Jens Terhaar, Ruben van Hooidonk, Anton Velo, Andrew J. Watson, Angelicque E. White, Zelun Wu, Hyelim Yoo, and Jiye Zeng
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2025-255, https://doi.org/10.5194/essd-2025-255, 2025
Preprint under review for ESSD
Short summary
Short summary
This review article provides an overview of 60 existing ocean carbonate chemistry data products, encompassing a broad range of types, including compilations of cruise datasets, gap-filled observational products, model simulations, and more. It is designed to help researchers identify and access the data products that best support their scientific objectives, thereby facilitating progress in understanding the ocean's changing carbonate chemistry.
Nicolas Metzl, Jonathan Fin, Claire Lo Monaco, Claude Mignon, Samir Alliouane, Bruno Bombled, Jacqueline Boutin, Yann Bozec, Steeve Comeau, Pascal Conan, Laurent Coppola, Pascale Cuet, Eva Ferreira, Jean-Pierre Gattuso, Frédéric Gazeau, Catherine Goyet, Emilie Grossteffan, Bruno Lansard, Dominique Lefèvre, Nathalie Lefèvre, Coraline Leseurre, Sébastien Petton, Mireille Pujo-Pay, Christophe Rabouille, Gilles Reverdin, Céline Ridame, Peggy Rimmelin-Maury, Jean-François Ternon, Franck Touratier, Aline Tribollet, Thibaut Wagener, and Cathy Wimart-Rousseau
Earth Syst. Sci. Data, 17, 1075–1100, https://doi.org/10.5194/essd-17-1075-2025, https://doi.org/10.5194/essd-17-1075-2025, 2025
Short summary
Short summary
This work presents a new synthesis of 67 000 total alkalinity and total dissolved inorganic carbon observations obtained between 1993 and 2023 in the global ocean, coastal zones, and the Mediterranean Sea. We describe the data assemblage and associated quality control and discuss some potential uses of this dataset. The dataset is provided in a single format and includes the quality flag for each sample.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Judith Hauck, Peter Landschützer, Corinne Le Quéré, Hongmei Li, Ingrid T. Luijkx, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Almut Arneth, Vivek Arora, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Carla F. Berghoff, Henry C. Bittig, Laurent Bopp, Patricia Cadule, Katie Campbell, Matthew A. Chamberlain, Naveen Chandra, Frédéric Chevallier, Louise P. Chini, Thomas Colligan, Jeanne Decayeux, Laique M. Djeutchouang, Xinyu Dou, Carolina Duran Rojas, Kazutaka Enyo, Wiley Evans, Amanda R. Fay, Richard A. Feely, Daniel J. Ford, Adrianna Foster, Thomas Gasser, Marion Gehlen, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Jens Heinke, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Andrew R. Jacobson, Atul K. Jain, Tereza Jarníková, Annika Jersild, Fei Jiang, Zhe Jin, Etsushi Kato, Ralph F. Keeling, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Xin Lan, Siv K. Lauvset, Nathalie Lefèvre, Zhu Liu, Junjie Liu, Lei Ma, Shamil Maksyutov, Gregg Marland, Nicolas Mayot, Patrick C. McGuire, Nicolas Metzl, Natalie M. Monacci, Eric J. Morgan, Shin-Ichiro Nakaoka, Craig Neill, Yosuke Niwa, Tobias Nützel, Lea Olivier, Tsuneo Ono, Paul I. Palmer, Denis Pierrot, Zhangcai Qin, Laure Resplandy, Alizée Roobaert, Thais M. Rosan, Christian Rödenbeck, Jörg Schwinger, T. Luke Smallman, Stephen M. Smith, Reinel Sospedra-Alfonso, Tobias Steinhoff, Qing Sun, Adrienne J. Sutton, Roland Séférian, Shintaro Takao, Hiroaki Tatebe, Hanqin Tian, Bronte Tilbrook, Olivier Torres, Etienne Tourigny, Hiroyuki Tsujino, Francesco Tubiello, Guido van der Werf, Rik Wanninkhof, Xuhui Wang, Dongxu Yang, Xiaojuan Yang, Zhen Yu, Wenping Yuan, Xu Yue, Sönke Zaehle, Ning Zeng, and Jiye Zeng
Earth Syst. Sci. Data, 17, 965–1039, https://doi.org/10.5194/essd-17-965-2025, https://doi.org/10.5194/essd-17-965-2025, 2025
Short summary
Short summary
The Global Carbon Budget 2024 describes the methodology, main results, and datasets used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, land ecosystems, and the ocean over the historical period (1750–2024). These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Nicolas Metzl, Claire Lo Monaco, Coraline Leseurre, Céline Ridame, Gilles Reverdin, Thi Tuyet Trang Chau, Frédéric Chevallier, and Marion Gehlen
Ocean Sci., 20, 725–758, https://doi.org/10.5194/os-20-725-2024, https://doi.org/10.5194/os-20-725-2024, 2024
Short summary
Short summary
In the southern Indian Ocean, south of the polar front, an observed increase of sea surface fCO2 and a decrease of pH over 1985–2021 are mainly driven by anthropogenic CO2 uptake, but in the last decade (2010–2020) fCO2 and pH were stable in summer, highlighting the competitive balance between anthropogenic CO2 and primary production. In the water column the increase of anthropogenic CO2 concentrations leads to migration of the aragonite saturation state from 600 m in 1985 up to 400 m in 2021.
Thi-Tuyet-Trang Chau, Marion Gehlen, Nicolas Metzl, and Frédéric Chevallier
Earth Syst. Sci. Data, 16, 121–160, https://doi.org/10.5194/essd-16-121-2024, https://doi.org/10.5194/essd-16-121-2024, 2024
Short summary
Short summary
CMEMS-LSCE leads as the first global observation-based reconstructions of six carbonate system variables for the years 1985–2021 at monthly and 0.25° resolutions. The high-resolution reconstructions outperform their 1° counterpart in reproducing horizontal and temporal gradients of observations over various oceanic regions to nearshore time series stations. New datasets can be exploited in numerous studies, including monitoring changes in ocean carbon uptake and ocean acidification.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Luke Gregor, Judith Hauck, Corinne Le Quéré, Ingrid T. Luijkx, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Ramdane Alkama, Almut Arneth, Vivek K. Arora, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Henry C. Bittig, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Wiley Evans, Stefanie Falk, Richard A. Feely, Thomas Gasser, Marion Gehlen, Thanos Gkritzalis, Lucas Gloege, Giacomo Grassi, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Atul K. Jain, Annika Jersild, Koji Kadono, Etsushi Kato, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Peter Landschützer, Nathalie Lefèvre, Keith Lindsay, Junjie Liu, Zhu Liu, Gregg Marland, Nicolas Mayot, Matthew J. McGrath, Nicolas Metzl, Natalie M. Monacci, David R. Munro, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin O'Brien, Tsuneo Ono, Paul I. Palmer, Naiqing Pan, Denis Pierrot, Katie Pocock, Benjamin Poulter, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Carmen Rodriguez, Thais M. Rosan, Jörg Schwinger, Roland Séférian, Jamie D. Shutler, Ingunn Skjelvan, Tobias Steinhoff, Qing Sun, Adrienne J. Sutton, Colm Sweeney, Shintaro Takao, Toste Tanhua, Pieter P. Tans, Xiangjun Tian, Hanqin Tian, Bronte Tilbrook, Hiroyuki Tsujino, Francesco Tubiello, Guido R. van der Werf, Anthony P. Walker, Rik Wanninkhof, Chris Whitehead, Anna Willstrand Wranne, Rebecca Wright, Wenping Yuan, Chao Yue, Xu Yue, Sönke Zaehle, Jiye Zeng, and Bo Zheng
Earth Syst. Sci. Data, 14, 4811–4900, https://doi.org/10.5194/essd-14-4811-2022, https://doi.org/10.5194/essd-14-4811-2022, 2022
Short summary
Short summary
The Global Carbon Budget 2022 describes the datasets and methodology used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, the land ecosystems, and the ocean. These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Gilles Reverdin, Claire Waelbroeck, Catherine Pierre, Camille Akhoudas, Giovanni Aloisi, Marion Benetti, Bernard Bourlès, Magnus Danielsen, Jérôme Demange, Denis Diverrès, Jean-Claude Gascard, Marie-Noëlle Houssais, Hervé Le Goff, Pascale Lherminier, Claire Lo Monaco, Herlé Mercier, Nicolas Metzl, Simon Morisset, Aïcha Naamar, Thierry Reynaud, Jean-Baptiste Sallée, Virginie Thierry, Susan E. Hartman, Edward W. Mawji, Solveig Olafsdottir, Torsten Kanzow, Anton Velo, Antje Voelker, Igor Yashayaev, F. Alexander Haumann, Melanie J. Leng, Carol Arrowsmith, and Michael Meredith
Earth Syst. Sci. Data, 14, 2721–2735, https://doi.org/10.5194/essd-14-2721-2022, https://doi.org/10.5194/essd-14-2721-2022, 2022
Short summary
Short summary
The CISE-LOCEAN seawater stable isotope dataset has close to 8000 data entries. The δ18O and δD isotopic data measured at LOCEAN have uncertainties of at most 0.05 ‰ and 0.25 ‰, respectively. Some data were adjusted to correct for evaporation. The internal consistency indicates that the data can be used to investigate time and space variability to within 0.03 ‰ and 0.15 ‰ in δ18O–δD17; comparisons with data analyzed in other institutions suggest larger differences with other datasets.
Coraline Leseurre, Claire Lo Monaco, Gilles Reverdin, Nicolas Metzl, Jonathan Fin, Claude Mignon, and Léa Benito
Biogeosciences, 19, 2599–2625, https://doi.org/10.5194/bg-19-2599-2022, https://doi.org/10.5194/bg-19-2599-2022, 2022
Short summary
Short summary
Decadal trends of fugacity of CO2 (fCO2), total alkalinity (AT), total carbon (CT) and pH in surface waters are investigated in different domains of the southern Indian Ocean (45°S–57°S) from ongoing and station observations regularly conducted in summer over the period 1998–2019. The fCO2 increase and pH decrease are mainly driven by anthropogenic CO2 estimated just below the summer mixed layer, as well as by a warming south of the polar front or in the fertilized waters near Kerguelen Island.
Nicolas Metzl, Claire Lo Monaco, Coraline Leseurre, Céline Ridame, Jonathan Fin, Claude Mignon, Marion Gehlen, and Thi Tuyet Trang Chau
Biogeosciences, 19, 1451–1468, https://doi.org/10.5194/bg-19-1451-2022, https://doi.org/10.5194/bg-19-1451-2022, 2022
Short summary
Short summary
During an oceanographic cruise conducted in January 2020 in the south-western Indian Ocean, we observed very low CO2 concentrations associated with a strong phytoplankton bloom that occurred south-east of Madagascar. This biological event led to a strong regional CO2 ocean sink not previously observed.
Ariadna Celina Nocera, Lars Stemmann, Marcel Babin, Tristan Biard, Julie Coustenoble, François Carlotti, Laurent Coppola, Lucas Courchet, Laetitia Drago, Amanda Elineau, Lionel Guidi, Helena Hauss, Laëtitia Jalabert, Lee Karp-Boss, Rainer Kiko, Manon Laget, Fabien Lombard, Andrew McDonnell, Camille Merland, Solène Motreuil, Thelma Panaïotis, Marc Picheral, Andreas Rogge, Anya Waite, and Jean-Olivier Irisson
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2025-522, https://doi.org/10.5194/essd-2025-522, 2025
Preprint under review for ESSD
Short summary
Short summary
Plankton and detritus play a key role in ocean health and climate regulation. We present a large global dataset of images and information collected from 2008 to 2018 using specialized underwater camera (UVP). This publicly available dataset will support more accurate ecological models and help train artificial intelligence tools, improving how scientists track ocean biodiversity and monitor environmental changes.
Gaëlle Capitaine, Samir Alliouane, Thierry Cariou, Jonathan Fin, Paola Fisicaro, and Thibaut Wagener
EGUsphere, https://doi.org/10.5194/egusphere-2025-3588, https://doi.org/10.5194/egusphere-2025-3588, 2025
This preprint is open for discussion and under review for Ocean Science (OS).
Short summary
Short summary
Measuring total alkalinity in seawater is essential for understanding and monitoring the ocean carbonate system. To improve the reliability of these measurements, we developed reference materials and tested them in an inter-laboratory comparison. We also thoroughly quantified, for the first time, the uncertainty of the standard measurement method. These results, as well as the key metrological tools developed, support more accurate long-term monitoring of the ocean carbonate system.
Léa Olivier, Jacqueline Boutin, Gilles Reverdin, Christopher Hunt, Thomas Linkowski, Alison Chase, Nils Haentjens, Pedro C. Junger, Stéphane Pesant, and Douglas Vandemark
Earth Syst. Sci. Data, 17, 3583–3598, https://doi.org/10.5194/essd-17-3583-2025, https://doi.org/10.5194/essd-17-3583-2025, 2025
Short summary
Short summary
The air–sea CO2 flux in coastal waters plays a key role in the global carbon budget but remains poorly understood. In 2021, the Tara schooner collected 14 000 km of CO2 fugacity (fCO2) data along the South American coast. This dataset improves our understanding of fCO2 in the under-sampled Brazilian coastal region and provides a unique insight into the complex biogeochemistry of the Amazon River–ocean continuum.
Nicolas Metzl, Claire Lo Monaco, Aline Tribollet, Jean-François Ternon, Frédéric Chevallier, and Marion Gehlen
EGUsphere, https://doi.org/10.5194/egusphere-2025-3469, https://doi.org/10.5194/egusphere-2025-3469, 2025
This preprint is open for discussion and under review for Biogeosciences (BG).
Short summary
Short summary
In the Mozambique Channel, observed acceleration of the ocean acidification in the recent decades is mainly driven by anthropogenic CO2 uptake. In this region the aragonite saturation state reached 3.2 in 2025 and could be as low as 3 in the next 10 years with potential impact on marine ecosystem including corals reefs areas.
Samantha Siedlecki, Stanley Nmor, Gennadi Lessin, Kelly Kearney, Subhadeep Rakshit, Colleen Petrik, Jessica Luo, Cristina Schultz, Dalton Sasaki, Kayla Gillen, Anh Pham, Christopher Somes, Damian Brady, Jeremy Testa, Christophe Rabouille, Isa Elegbede, and Olivier Sulpis
EGUsphere, https://doi.org/10.5194/egusphere-2025-1846, https://doi.org/10.5194/egusphere-2025-1846, 2025
This preprint is open for discussion and under review for Geoscientific Model Development (GMD).
Short summary
Short summary
Benthic biogeochemical models are essential for simulating seafloor carbon cycling and climate feedbacks, yet vary widely in structure and assumptions. This paper introduces SedBGC_MIP, a community initiative to compare existing models, refine key processes, and assess uncertainty. We highlight discrepancies through case studies and introduce needs including observational benchmarks. Ultimately, we seek to improve climate and resource projections.
Maxime Arnaud, Anne Petrenko, Jean-Luc Fuda, Caroline Comby, Anthony Bosse, Yann Ourmières, and Stéphanie Barrillon
EGUsphere, https://doi.org/10.5194/egusphere-2025-2757, https://doi.org/10.5194/egusphere-2025-2757, 2025
Short summary
Short summary
Measuring oceanic vertical velocities accurately is a challenge in today’s physical oceanography. Our work shows intense wind-induced coastal events involving upward or downward water movements that have been detected using an acoustic current profiler. These data has also been validated with other in situ and satellite observations. A brand new method to identify and filter out biological-induced velocities is also presented, giving an interdisciplinary point of view of such coastal processes.
Guillaume Bourdin, Lee Karp-Boss, Fabien Lombard, Gabriel Gorsky, and Emmanuel Boss
Biogeosciences, 22, 3207–3233, https://doi.org/10.5194/bg-22-3207-2025, https://doi.org/10.5194/bg-22-3207-2025, 2025
Short summary
Short summary
Remote islands and atolls create unique oceanic processes that affect the surrounding waters, known as the island mass effect (IME). These processes input nutrients to the ocean surface, leading to an increasing phytoplankton concentration near islands. We combine data from various satellites and modeled currents to better track these changes. This reveals a larger IME impact than previously estimated, suggesting that islands play a more significant role in ocean food chains in subtropical regions.
Zoé Mériguet, Guillaume Bourdin, Nathaniel Kristan, Laetitia Jalabert, Olivier Bun, Marc Picheral, Louis Caray-Counil, Juliette Maury, Maria-Luiza Pedrotti, Amanda Elineau, David A. Paz-Garcia, Lee Karp-Boss, Gaby Gorsky, Fabien Lombard, and the Tara Pacific Consortium Coordinators team
Earth Syst. Sci. Data, 17, 2761–2792, https://doi.org/10.5194/essd-17-2761-2025, https://doi.org/10.5194/essd-17-2761-2025, 2025
Short summary
Short summary
This study presents imaging datasets from the Tara Pacific expedition, covering multiple plankton sizes and a wide sampling area in Pacific waters. By sampling both open-ocean and island areas, these data can show how plankton size, diversity and abundance change with different environments. We also highlight the usefulness of high-speed plankton sampling when it is not possible to slow the boat during sailing as well as the value of this technique with respect to extending the sampling coverage and frequency.
Li-Qing Jiang, Amanda Fay, Jens Daniel Müller, Lydia Keppler, Dustin Carroll, Siv K. Lauvset, Tim DeVries, Judith Hauck, Christian Rödenbeck, Luke Gregor, Nicolas Metzl, Andrea J. Fassbender, Jean-Pierre Gattuso, Peter Landschützer, Rik Wanninkhof, Christopher Sabine, Simone R. Alin, Mario Hoppema, Are Olsen, Matthew P. Humphreys, Kumiko Azetsu-Scott, Dorothee C. E. Bakker, Leticia Barbero, Nicholas R. Bates, Nicole Besemer, Henry C. Bittig, Albert E. Boyd, Daniel Broullón, Wei-Jun Cai, Brendan R. Carter, Thi-Tuyet-Trang Chau, Chen-Tung Arthur Chen, Frédéric Cyr, John E. Dore, Ian Enochs, Richard A. Feely, Hernan E. Garcia, Marion Gehlen, Lucas Gloege, Melchor González-Dávila, Nicolas Gruber, Yosuke Iida, Masao Ishii, Esther Kennedy, Alex Kozyr, Nico Lange, Claire Lo Monaco, Derek P. Manzello, Galen A. McKinley, Natalie M. Monacci, Xose A. Padin, Ana M. Palacio-Castro, Fiz F. Pérez, Alizée Roobaert, J. Magdalena Santana-Casiano, Jonathan Sharp, Adrienne Sutton, Jim Swift, Toste Tanhua, Maciej Telszewski, Jens Terhaar, Ruben van Hooidonk, Anton Velo, Andrew J. Watson, Angelicque E. White, Zelun Wu, Hyelim Yoo, and Jiye Zeng
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2025-255, https://doi.org/10.5194/essd-2025-255, 2025
Preprint under review for ESSD
Short summary
Short summary
This review article provides an overview of 60 existing ocean carbonate chemistry data products, encompassing a broad range of types, including compilations of cruise datasets, gap-filled observational products, model simulations, and more. It is designed to help researchers identify and access the data products that best support their scientific objectives, thereby facilitating progress in understanding the ocean's changing carbonate chemistry.
Kirtana Naëck, Jacqueline Boutin, Sebastiaan Swart, Marcel du Plessis, Liliane Merlivat, Laurence Beaumont, Antonio Lourenco, Francesco d'Ovidio, Louise Rousselet, Brian Ward, and Jean-Baptiste Sallée
Biogeosciences, 22, 1947–1968, https://doi.org/10.5194/bg-22-1947-2025, https://doi.org/10.5194/bg-22-1947-2025, 2025
Short summary
Short summary
In summer 2022, a CARbon Interface OCean Atmosphere (CARIOCA) drifting buoy observed an anomalously strong ocean carbon sink in the subpolar Southern Ocean associated with large plumes of chlorophyll a. Lagrangian backward trajectories indicate that these waters originated from the sea ice edge in spring 2021. Our study highlights the northward migration of the CO2 sink associated with early sea ice retreat.
Helena Fos, Jesús Peña-Izquierdo, David Amblas, Marta Arjona-Camas, Laia Romero, Victor Estella-Pérez, Cristian Florindo-Lopez, Antoni Calafat-Frau, Marc Cerdà-Domènech, Pere Puig, Xavier Durrieu de Madron, and Anna Sanchez-Vidal
EGUsphere, https://doi.org/10.22541/essoar.174060515.57729804/v2, https://doi.org/10.22541/essoar.174060515.57729804/v2, 2025
Short summary
Short summary
Dense Shelf Water Cascading (DSWC) is an oceanographic process where dense shelf water rapidly spills over the shelf edge and cascades into the deep ocean. Using a high-resolution model that incorporates real observations from the water column and sea surface (MedSea Reanalysis), this study compares over 30 years of simulated intense DSWC with actual observations in the NW Mediterranean. We identified all the cascading events since 1987, with results closely matching the observations.
Marta Arjona-Camas, Xavier Durrieu de Madron, François Bourrin, Helena Fos, Anna Sanchez-Vidal, and David Amblas
EGUsphere, https://doi.org/10.5194/egusphere-2025-1310, https://doi.org/10.5194/egusphere-2025-1310, 2025
Short summary
Short summary
This study examines dense shelf-water and sediment transport in the Cap de Creus Canyon during the mild winter of 2021–2022, using multiplatform-observational data and the MedSea Reanalysis model. Results show dense shelf waters on the shelf and upper canyon, contributing to Western Intermediate Water. The canyon acts as a partial sink, with most dense water transport occurring along the coast. These events are expected to increase with climate change, favoring intermediate-water formation.
Nicolas Metzl, Jonathan Fin, Claire Lo Monaco, Claude Mignon, Samir Alliouane, Bruno Bombled, Jacqueline Boutin, Yann Bozec, Steeve Comeau, Pascal Conan, Laurent Coppola, Pascale Cuet, Eva Ferreira, Jean-Pierre Gattuso, Frédéric Gazeau, Catherine Goyet, Emilie Grossteffan, Bruno Lansard, Dominique Lefèvre, Nathalie Lefèvre, Coraline Leseurre, Sébastien Petton, Mireille Pujo-Pay, Christophe Rabouille, Gilles Reverdin, Céline Ridame, Peggy Rimmelin-Maury, Jean-François Ternon, Franck Touratier, Aline Tribollet, Thibaut Wagener, and Cathy Wimart-Rousseau
Earth Syst. Sci. Data, 17, 1075–1100, https://doi.org/10.5194/essd-17-1075-2025, https://doi.org/10.5194/essd-17-1075-2025, 2025
Short summary
Short summary
This work presents a new synthesis of 67 000 total alkalinity and total dissolved inorganic carbon observations obtained between 1993 and 2023 in the global ocean, coastal zones, and the Mediterranean Sea. We describe the data assemblage and associated quality control and discuss some potential uses of this dataset. The dataset is provided in a single format and includes the quality flag for each sample.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Judith Hauck, Peter Landschützer, Corinne Le Quéré, Hongmei Li, Ingrid T. Luijkx, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Almut Arneth, Vivek Arora, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Carla F. Berghoff, Henry C. Bittig, Laurent Bopp, Patricia Cadule, Katie Campbell, Matthew A. Chamberlain, Naveen Chandra, Frédéric Chevallier, Louise P. Chini, Thomas Colligan, Jeanne Decayeux, Laique M. Djeutchouang, Xinyu Dou, Carolina Duran Rojas, Kazutaka Enyo, Wiley Evans, Amanda R. Fay, Richard A. Feely, Daniel J. Ford, Adrianna Foster, Thomas Gasser, Marion Gehlen, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Jens Heinke, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Andrew R. Jacobson, Atul K. Jain, Tereza Jarníková, Annika Jersild, Fei Jiang, Zhe Jin, Etsushi Kato, Ralph F. Keeling, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Xin Lan, Siv K. Lauvset, Nathalie Lefèvre, Zhu Liu, Junjie Liu, Lei Ma, Shamil Maksyutov, Gregg Marland, Nicolas Mayot, Patrick C. McGuire, Nicolas Metzl, Natalie M. Monacci, Eric J. Morgan, Shin-Ichiro Nakaoka, Craig Neill, Yosuke Niwa, Tobias Nützel, Lea Olivier, Tsuneo Ono, Paul I. Palmer, Denis Pierrot, Zhangcai Qin, Laure Resplandy, Alizée Roobaert, Thais M. Rosan, Christian Rödenbeck, Jörg Schwinger, T. Luke Smallman, Stephen M. Smith, Reinel Sospedra-Alfonso, Tobias Steinhoff, Qing Sun, Adrienne J. Sutton, Roland Séférian, Shintaro Takao, Hiroaki Tatebe, Hanqin Tian, Bronte Tilbrook, Olivier Torres, Etienne Tourigny, Hiroyuki Tsujino, Francesco Tubiello, Guido van der Werf, Rik Wanninkhof, Xuhui Wang, Dongxu Yang, Xiaojuan Yang, Zhen Yu, Wenping Yuan, Xu Yue, Sönke Zaehle, Ning Zeng, and Jiye Zeng
Earth Syst. Sci. Data, 17, 965–1039, https://doi.org/10.5194/essd-17-965-2025, https://doi.org/10.5194/essd-17-965-2025, 2025
Short summary
Short summary
The Global Carbon Budget 2024 describes the methodology, main results, and datasets used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, land ecosystems, and the ocean over the historical period (1750–2024). These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Gilles Reverdin, Claire Waelbroeck, Antje H. L. Voelker, and Hanno Meyer
Ocean Sci., 21, 567–575, https://doi.org/10.5194/os-21-567-2025, https://doi.org/10.5194/os-21-567-2025, 2025
Short summary
Short summary
Water isotopes in the ocean trace the freshwater exchanges between the ocean, the atmosphere, and the cryosphere and are used to investigate processes of the hydrological cycle. We illustrate offsets in seawater isotopic composition between different datasets that are larger than the expected variability that one often wants to explore. This highlights the need to share seawater isotopic composition samples dedicated to specific intercomparison of data produced in different laboratories.
Clovis Thouvenin-Masson, Jacqueline Boutin, Vincent Échevin, Alban Lazar, and Jean-Luc Vergely
Ocean Sci., 20, 1547–1566, https://doi.org/10.5194/os-20-1547-2024, https://doi.org/10.5194/os-20-1547-2024, 2024
Short summary
Short summary
We focus on understanding the impact of river runoff and precipitation on sea surface salinity (SSS) in the eastern North Tropical Atlantic (e-NTA) region off northwestern Africa. By analyzing regional simulations and observational data, we find that river flows significantly influence SSS variability, particularly after the rainy season. Our findings underscore that a main source of uncertainty representing SSS variability in this region is from river runoff estimates.
Riccardo Martellucci, Michele Giani, Elena Mauri, Laurent Coppola, Melf Paulsen, Marine Fourrier, Sara Pensieri, Vanessa Cardin, Carlotta Dentico, Roberto Bozzano, Carolina Cantoni, Anna Lucchetta, Alfredo Izquierdo, Miguel Bruno, and Ingunn Skjelvan
Earth Syst. Sci. Data, 16, 5333–5356, https://doi.org/10.5194/essd-16-5333-2024, https://doi.org/10.5194/essd-16-5333-2024, 2024
Short summary
Short summary
As part of the ATL2MED demonstration experiment, two autonomous surface vehicles undertook a 9-month mission from the northeastern Atlantic to the Adriatic Sea. Biofouling affected the measurement of variables such as conductivity and dissolved oxygen. COVID-19 limited the availability of discrete samples for validation. We present correction methods for salinity and dissolved oxygen. We use model products to correct salinity and apply the Argo floats in-air correction method for oxygen
Xavier Durrieu de Madron, Paul Blin, Mireille Pujo-Pay, Vincent Taillandier, and Pascal Conan
EGUsphere, https://doi.org/10.5194/egusphere-2024-3436, https://doi.org/10.5194/egusphere-2024-3436, 2024
Short summary
Short summary
This study investigated the effects of salt fingering on particle and solute distribution in the Tyrrhenian Sea. Density interfaces associated with thermohaline staircases slow the settling of suspended particles and promote aggregation. This affects particle size distribution and creates nutrient and oxygen gradients, affecting microbial activity and nutrient cycling. The research highlights the potential role of salt fingers in deep ocean biogeochemical processes.
Anaïs Lebrun, Cale A. Miller, Marc Meynadier, Steeve Comeau, Pierre Urrutti, Samir Alliouane, Robert Schlegel, Jean-Pierre Gattuso, and Frédéric Gazeau
Biogeosciences, 21, 4605–4620, https://doi.org/10.5194/bg-21-4605-2024, https://doi.org/10.5194/bg-21-4605-2024, 2024
Short summary
Short summary
We tested the effects of warming, low salinity, and low irradiance on Arctic kelps. We show that growth rates were similar across species and treatments. Alaria esculenta is adapted to low-light conditions. Saccharina latissima exhibited nitrogen limitation, suggesting coastal erosion and permafrost thawing could be beneficial. Laminaria digitata did not respond to the treatments. Gene expression of Hedophyllum nigripes and S. latissima indicated acclimation to the experimental treatments.
Sophie Hage, Megan L. Baker, Nathalie Babonneau, Guillaume Soulet, Bernard Dennielou, Ricardo Silva Jacinto, Robert G. Hilton, Valier Galy, François Baudin, Christophe Rabouille, Clément Vic, Sefa Sahin, Sanem Açikalin, and Peter J. Talling
Biogeosciences, 21, 4251–4272, https://doi.org/10.5194/bg-21-4251-2024, https://doi.org/10.5194/bg-21-4251-2024, 2024
Short summary
Short summary
The land-to-ocean flux of particulate organic carbon (POC) is difficult to measure, inhibiting accurate modeling of the global carbon cycle. Here, we quantify the POC flux between one of the largest rivers on Earth (Congo) and the ocean. POC in the form of vegetation and soil is transported by episodic submarine avalanches in a 1000 km long canyon at up to 5 km water depth. The POC flux induced by avalanches is at least 3 times greater than that induced by the background flow related to tides.
Yan Yang, Patrick Brockmann, Carolina Galdino, Uwe Schindler, and Frédéric Gazeau
Earth Syst. Sci. Data, 16, 3771–3780, https://doi.org/10.5194/essd-16-3771-2024, https://doi.org/10.5194/essd-16-3771-2024, 2024
Short summary
Short summary
Studies investigating the effects of ocean acidification on marine organisms and communities have been steadily increasing. To facilitate data comparison, a data compilation hosted by the PANGAEA Data Publisher was initiated in 2008 and is updated on a regular basis. By November 2023, a total of 1501 datasets (~25 million data points) from 1554 papers have been archived. To filter and access relevant biological response data from this compilation, a user-friendly portal was launched in 2018.
Lucille Barré, Frédéric Diaz, Thibaut Wagener, Camille Mazoyer, Christophe Yohia, and Christel Pinazo
Geosci. Model Dev., 17, 5851–5882, https://doi.org/10.5194/gmd-17-5851-2024, https://doi.org/10.5194/gmd-17-5851-2024, 2024
Short summary
Short summary
The carbonate system is typically studied using measurements, but modeling can contribute valuable insights. Using a biogeochemical model, we propose a new representation of total alkalinity, dissolved inorganic carbon, pCO2, and pH in a highly dynamic Mediterranean coastal area, the Bay of Marseille, a useful addition to measurements. Through a detailed analysis of pCO2 and air–sea CO2 fluxes, we show that variations are strongly impacted by the hydrodynamic processes that affect the bay.
Mathilde Dugenne, Marco Corrales-Ugalde, Jessica Y. Luo, Rainer Kiko, Todd D. O'Brien, Jean-Olivier Irisson, Fabien Lombard, Lars Stemmann, Charles Stock, Clarissa R. Anderson, Marcel Babin, Nagib Bhairy, Sophie Bonnet, Francois Carlotti, Astrid Cornils, E. Taylor Crockford, Patrick Daniel, Corinne Desnos, Laetitia Drago, Amanda Elineau, Alexis Fischer, Nina Grandrémy, Pierre-Luc Grondin, Lionel Guidi, Cecile Guieu, Helena Hauss, Kendra Hayashi, Jenny A. Huggett, Laetitia Jalabert, Lee Karp-Boss, Kasia M. Kenitz, Raphael M. Kudela, Magali Lescot, Claudie Marec, Andrew McDonnell, Zoe Mériguet, Barbara Niehoff, Margaux Noyon, Thelma Panaïotis, Emily Peacock, Marc Picheral, Emilie Riquier, Collin Roesler, Jean-Baptiste Romagnan, Heidi M. Sosik, Gretchen Spencer, Jan Taucher, Chloé Tilliette, and Marion Vilain
Earth Syst. Sci. Data, 16, 2971–2999, https://doi.org/10.5194/essd-16-2971-2024, https://doi.org/10.5194/essd-16-2971-2024, 2024
Short summary
Short summary
Plankton and particles influence carbon cycling and energy flow in marine ecosystems. We used three types of novel plankton imaging systems to obtain size measurements from a range of plankton and particle sizes and across all major oceans. Data were compiled and cross-calibrated from many thousands of images, showing seasonal and spatial changes in particle size structure in different ocean basins. These datasets form the first release of the Pelagic Size Structure database (PSSdb).
Robert W. Schlegel, Rakesh Kumar Singh, Bernard Gentili, Simon Bélanger, Laura Castro de la Guardia, Dorte Krause-Jensen, Cale A. Miller, Mikael Sejr, and Jean-Pierre Gattuso
Earth Syst. Sci. Data, 16, 2773–2788, https://doi.org/10.5194/essd-16-2773-2024, https://doi.org/10.5194/essd-16-2773-2024, 2024
Short summary
Short summary
Fjords play a vital role in the Arctic ecosystems and human communities. It is therefore important to have as clear of an understanding of the processes within these systems as possible. While temperature and salinity tend to be well measured, light is usually not. The dataset described in this paper uses remotely sensed data from 2003 to 2022 to address this problem by providing high-spatial-resolution surface, water column, and seafloor light data for several well-studied Arctic fjords.
Nicolas Metzl, Claire Lo Monaco, Coraline Leseurre, Céline Ridame, Gilles Reverdin, Thi Tuyet Trang Chau, Frédéric Chevallier, and Marion Gehlen
Ocean Sci., 20, 725–758, https://doi.org/10.5194/os-20-725-2024, https://doi.org/10.5194/os-20-725-2024, 2024
Short summary
Short summary
In the southern Indian Ocean, south of the polar front, an observed increase of sea surface fCO2 and a decrease of pH over 1985–2021 are mainly driven by anthropogenic CO2 uptake, but in the last decade (2010–2020) fCO2 and pH were stable in summer, highlighting the competitive balance between anthropogenic CO2 and primary production. In the water column the increase of anthropogenic CO2 concentrations leads to migration of the aragonite saturation state from 600 m in 1985 up to 400 m in 2021.
France Van Wambeke, Pascal Conan, Mireille Pujo-Pay, Vincent Taillandier, Olivier Crispi, Alexandra Pavlidou, Sandra Nunige, Morgane Didry, Christophe Salmeron, and Elvira Pulido-Villena
Biogeosciences, 21, 2621–2640, https://doi.org/10.5194/bg-21-2621-2024, https://doi.org/10.5194/bg-21-2621-2024, 2024
Short summary
Short summary
Phosphomonoesterase (PME) and phosphodiesterase (PDE) activities over the epipelagic zone are described in the eastern Mediterranean Sea in winter and autumn. The types of concentration kinetics obtained for PDE (saturation at 50 µM, high Km, high turnover times) compared to those of PME (saturation at 1 µM, low Km, low turnover times) are discussed in regard to the possible inequal distribution of PDE and PME in the size continuum of organic material and accessibility to phosphodiesters.
Nico Lange, Björn Fiedler, Marta Álvarez, Alice Benoit-Cattin, Heather Benway, Pier Luigi Buttigieg, Laurent Coppola, Kim Currie, Susana Flecha, Dana S. Gerlach, Makio Honda, I. Emma Huertas, Siv K. Lauvset, Frank Muller-Karger, Arne Körtzinger, Kevin M. O'Brien, Sólveig R. Ólafsdóttir, Fernando C. Pacheco, Digna Rueda-Roa, Ingunn Skjelvan, Masahide Wakita, Angelicque White, and Toste Tanhua
Earth Syst. Sci. Data, 16, 1901–1931, https://doi.org/10.5194/essd-16-1901-2024, https://doi.org/10.5194/essd-16-1901-2024, 2024
Short summary
Short summary
The Synthesis Product for Ocean Time Series (SPOTS) is a novel achievement expanding and complementing the biogeochemical data landscape by providing consistent and high-quality biogeochemical time-series data from 12 ship-based fixed time-series programs. SPOTS covers multiple unique marine environments and time-series ranges, including data from 1983 to 2021. All in all, it facilitates a variety of applications that benefit from the collective value of biogeochemical time-series observations.
Sébastien Petton, Fabrice Pernet, Valérian Le Roy, Matthias Huber, Sophie Martin, Éric Macé, Yann Bozec, Stéphane Loisel, Peggy Rimmelin-Maury, Émilie Grossteffan, Michel Repecaud, Loïc Quemener, Michael Retho, Soazig Manac'h, Mathias Papin, Philippe Pineau, Thomas Lacoue-Labarthe, Jonathan Deborde, Louis Costes, Pierre Polsenaere, Loïc Rigouin, Jérémy Benhamou, Laure Gouriou, Joséphine Lequeux, Nathalie Labourdette, Nicolas Savoye, Grégory Messiaen, Elodie Foucault, Vincent Ouisse, Marion Richard, Franck Lagarde, Florian Voron, Valentin Kempf, Sébastien Mas, Léa Giannecchini, Francesca Vidussi, Behzad Mostajir, Yann Leredde, Samir Alliouane, Jean-Pierre Gattuso, and Frédéric Gazeau
Earth Syst. Sci. Data, 16, 1667–1688, https://doi.org/10.5194/essd-16-1667-2024, https://doi.org/10.5194/essd-16-1667-2024, 2024
Short summary
Short summary
Our research highlights the concerning impact of rising carbon dioxide levels on coastal areas. To better understand these changes, we've established an observation network in France. By deploying pH sensors and other monitoring equipment at key coastal sites, we're gaining valuable insights into how various factors, such as freshwater inputs, tides, temperature, and biological processes, influence ocean pH.
Cathy Wimart-Rousseau, Tobias Steinhoff, Birgit Klein, Henry Bittig, and Arne Körtzinger
Biogeosciences, 21, 1191–1211, https://doi.org/10.5194/bg-21-1191-2024, https://doi.org/10.5194/bg-21-1191-2024, 2024
Short summary
Short summary
The marine CO2 system can be measured independently and continuously by BGC-Argo floats since numerous pH sensors have been developed to suit these autonomous measurements platforms. By applying the Argo correction routines to float pH data acquired in the subpolar North Atlantic Ocean, we report the uncertainty and lack of objective criteria associated with the choice of the reference method as well the reference depth for the pH correction.
Eva Ferreira, Stanley Nmor, Eric Viollier, Bruno Lansard, Bruno Bombled, Edouard Regnier, Gaël Monvoisin, Christian Grenz, Pieter van Beek, and Christophe Rabouille
Biogeosciences, 21, 711–729, https://doi.org/10.5194/bg-21-711-2024, https://doi.org/10.5194/bg-21-711-2024, 2024
Short summary
Short summary
The study provides new insights by examining the short-term impact of winter floods on biogeochemical sediment processes near the Rhône River (NW Mediterranean Sea). This is the first winter monitoring of sediment and porewater in deltaic areas. The coupling of these data with a new model enables us to quantify the evolution of biogeochemical processes. It also provides new perspectives on the benthic carbon cycle in river deltas considering climate change, whereby flooding should intensify.
Cale A. Miller, Pierre Urrutti, Jean-Pierre Gattuso, Steeve Comeau, Anaïs Lebrun, Samir Alliouane, Robert W. Schlegel, and Frédéric Gazeau
Biogeosciences, 21, 315–333, https://doi.org/10.5194/bg-21-315-2024, https://doi.org/10.5194/bg-21-315-2024, 2024
Short summary
Short summary
This work describes an experimental system that can replicate and manipulate environmental conditions in marine or aquatic systems. Here, we show how the temperature and salinity of seawater delivered from a fjord is manipulated to experimental tanks on land. By constantly monitoring temperature and salinity in each tank via a computer program, the system continuously adjusts automated flow valves to ensure the seawater in each tank matches the targeted experimental conditions.
Thi-Tuyet-Trang Chau, Marion Gehlen, Nicolas Metzl, and Frédéric Chevallier
Earth Syst. Sci. Data, 16, 121–160, https://doi.org/10.5194/essd-16-121-2024, https://doi.org/10.5194/essd-16-121-2024, 2024
Short summary
Short summary
CMEMS-LSCE leads as the first global observation-based reconstructions of six carbonate system variables for the years 1985–2021 at monthly and 0.25° resolutions. The high-resolution reconstructions outperform their 1° counterpart in reproducing horizontal and temporal gradients of observations over various oceanic regions to nearshore time series stations. New datasets can be exploited in numerous studies, including monitoring changes in ocean carbon uptake and ocean acidification.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Dorothee C. E. Bakker, Judith Hauck, Peter Landschützer, Corinne Le Quéré, Ingrid T. Luijkx, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Peter Anthoni, Leticia Barbero, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Bertrand Decharme, Laurent Bopp, Ida Bagus Mandhara Brasika, Patricia Cadule, Matthew A. Chamberlain, Naveen Chandra, Thi-Tuyet-Trang Chau, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Xinyu Dou, Kazutaka Enyo, Wiley Evans, Stefanie Falk, Richard A. Feely, Liang Feng, Daniel J. Ford, Thomas Gasser, Josefine Ghattas, Thanos Gkritzalis, Giacomo Grassi, Luke Gregor, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Jens Heinke, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Andrew R. Jacobson, Atul Jain, Tereza Jarníková, Annika Jersild, Fei Jiang, Zhe Jin, Fortunat Joos, Etsushi Kato, Ralph F. Keeling, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Arne Körtzinger, Xin Lan, Nathalie Lefèvre, Hongmei Li, Junjie Liu, Zhiqiang Liu, Lei Ma, Greg Marland, Nicolas Mayot, Patrick C. McGuire, Galen A. McKinley, Gesa Meyer, Eric J. Morgan, David R. Munro, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin M. O'Brien, Are Olsen, Abdirahman M. Omar, Tsuneo Ono, Melf Paulsen, Denis Pierrot, Katie Pocock, Benjamin Poulter, Carter M. Powis, Gregor Rehder, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Thais M. Rosan, Jörg Schwinger, Roland Séférian, T. Luke Smallman, Stephen M. Smith, Reinel Sospedra-Alfonso, Qing Sun, Adrienne J. Sutton, Colm Sweeney, Shintaro Takao, Pieter P. Tans, Hanqin Tian, Bronte Tilbrook, Hiroyuki Tsujino, Francesco Tubiello, Guido R. van der Werf, Erik van Ooijen, Rik Wanninkhof, Michio Watanabe, Cathy Wimart-Rousseau, Dongxu Yang, Xiaojuan Yang, Wenping Yuan, Xu Yue, Sönke Zaehle, Jiye Zeng, and Bo Zheng
Earth Syst. Sci. Data, 15, 5301–5369, https://doi.org/10.5194/essd-15-5301-2023, https://doi.org/10.5194/essd-15-5301-2023, 2023
Short summary
Short summary
The Global Carbon Budget 2023 describes the methodology, main results, and data sets used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, land ecosystems, and the ocean over the historical period (1750–2023). These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Caroline Ulses, Claude Estournel, Patrick Marsaleix, Karline Soetaert, Marine Fourrier, Laurent Coppola, Dominique Lefèvre, Franck Touratier, Catherine Goyet, Véronique Guglielmi, Fayçal Kessouri, Pierre Testor, and Xavier Durrieu de Madron
Biogeosciences, 20, 4683–4710, https://doi.org/10.5194/bg-20-4683-2023, https://doi.org/10.5194/bg-20-4683-2023, 2023
Short summary
Short summary
Deep convection plays a key role in the circulation, thermodynamics, and biogeochemical cycles in the Mediterranean Sea, considered to be a hotspot of biodiversity and climate change. In this study, we investigate the seasonal and annual budget of dissolved inorganic carbon in the deep-convection area of the northwestern Mediterranean Sea.
Li-Qing Jiang, Adam V. Subhas, Daniela Basso, Katja Fennel, and Jean-Pierre Gattuso
State Planet, 2-oae2023, 13, https://doi.org/10.5194/sp-2-oae2023-13-2023, https://doi.org/10.5194/sp-2-oae2023-13-2023, 2023
Short summary
Short summary
This paper provides comprehensive guidelines for ocean alkalinity enhancement (OAE) researchers on archiving their metadata and data. It includes data standards for various OAE studies and a universal metadata template. Controlled vocabularies for terms like alkalinization methods are included. These guidelines also apply to ocean acidification data.
Andreas Oschlies, Lennart T. Bach, Rosalind E. M. Rickaby, Terre Satterfield, Romany Webb, and Jean-Pierre Gattuso
State Planet, 2-oae2023, 1, https://doi.org/10.5194/sp-2-oae2023-1-2023, https://doi.org/10.5194/sp-2-oae2023-1-2023, 2023
Short summary
Short summary
Reaching promised climate targets will require the deployment of carbon dioxide removal (CDR). Marine CDR options receive more and more interest. Based on idealized theoretical studies, ocean alkalinity enhancement (OAE) appears as a promising marine CDR method. We provide an overview on the current situation of developing OAE as a marine CDR method and describe the history that has led to the creation of the OAE research best practice guide.
Eva Álvarez, Gianpiero Cossarini, Anna Teruzzi, Jorn Bruggeman, Karsten Bolding, Stefano Ciavatta, Vincenzo Vellucci, Fabrizio D'Ortenzio, David Antoine, and Paolo Lazzari
Biogeosciences, 20, 4591–4624, https://doi.org/10.5194/bg-20-4591-2023, https://doi.org/10.5194/bg-20-4591-2023, 2023
Short summary
Short summary
Chromophoric dissolved organic matter (CDOM) interacts with the ambient light and gives the waters of the Mediterranean Sea their colour. We propose a novel parameterization of the CDOM cycle, whose parameter values have been optimized by using the data of the monitoring site BOUSSOLE. Nutrient and light limitations for locally produced CDOM caused aCDOM(λ) to covary with chlorophyll, while the above-average CDOM concentrations observed at this site were maintained by allochthonous sources.
Lucille Barré, Frédéric Diaz, Thibaut Wagener, France Van Wambeke, Camille Mazoyer, Christophe Yohia, and Christel Pinazo
Geosci. Model Dev., 16, 6701–6739, https://doi.org/10.5194/gmd-16-6701-2023, https://doi.org/10.5194/gmd-16-6701-2023, 2023
Short summary
Short summary
While several studies have shown that mixotrophs play a crucial role in the carbon cycle, the impact of environmental forcings on their dynamics remains poorly investigated. Using a biogeochemical model that considers mixotrophs, we study the impact of light and nutrient concentration on the ecosystem composition in a highly dynamic Mediterranean coastal area: the Bay of Marseille. We show that mixotrophs cope better with oligotrophic conditions compared to strict auto- and heterotrophs.
Roxane Tzortzis, Andrea M. Doglioli, Monique Messié, Stéphanie Barrillon, Anne A. Petrenko, Lloyd Izard, Yuan Zhao, Francesco d'Ovidio, Franck Dumas, and Gérald Gregori
Biogeosciences, 20, 3491–3508, https://doi.org/10.5194/bg-20-3491-2023, https://doi.org/10.5194/bg-20-3491-2023, 2023
Short summary
Short summary
We studied a finescale frontal structure in order to highlight its influence on the dynamics and distribution of phytoplankton communities. We computed the growth rates of several phytoplankton groups identified by flow cytometry in two water masses separated by the front. We found contrasted phytoplankton dynamics on the two sides of the front, consistent with the distribution of their abundances. Our study gives new insights into the physical and biological coupling on a finescale front.
Robert W. Schlegel and Jean-Pierre Gattuso
Earth Syst. Sci. Data, 15, 3733–3746, https://doi.org/10.5194/essd-15-3733-2023, https://doi.org/10.5194/essd-15-3733-2023, 2023
Short summary
Short summary
A single dataset was created for investigations of changes in the socio-ecological systems within seven Arctic fjords by amalgamating roughly 1400 datasets from a number of sources. The many variables in these data were organised into five distinct categories and classified into 14 key drivers. Data for seawater temperature and salinity are available from the late 19th century, with some other drivers having data available from the 1950s and 1960s and the others starting from the 1990s onward.
Joelle Habib, Caroline Ulses, Claude Estournel, Milad Fakhri, Patrick Marsaleix, Mireille Pujo-Pay, Marine Fourrier, Laurent Coppola, Alexandre Mignot, Laurent Mortier, and Pascal Conan
Biogeosciences, 20, 3203–3228, https://doi.org/10.5194/bg-20-3203-2023, https://doi.org/10.5194/bg-20-3203-2023, 2023
Short summary
Short summary
The Rhodes Gyre, eastern Mediterranean Sea, is the main Levantine Intermediate Water formation site. In this study, we use a 3D physical–biogeochemical model to investigate the seasonal and interannual variability of organic carbon dynamics in the gyre. Our results show its autotrophic nature and its high interannual variability, with enhanced primary production, downward exports, and onward exports to the surrounding regions during years marked by intense heat losses and deep mixed layers.
Jean-Pierre Gattuso, Samir Alliouane, and Philipp Fischer
Earth Syst. Sci. Data, 15, 2809–2825, https://doi.org/10.5194/essd-15-2809-2023, https://doi.org/10.5194/essd-15-2809-2023, 2023
Short summary
Short summary
The Arctic Ocean is subject to high rates of ocean warming and acidification, with critical implications for marine organisms, ecosystems and the services they provide. We report here on the first high-frequency (1 h), multi-year (5 years) dataset of the carbonate system at a coastal site in a high-Arctic fjord (Kongsfjorden, Svalbard). This site is a significant sink for CO2 every month of the year (9 to 17 mol m-2 yr-1). The saturation state of aragonite can be as low as 1.3.
Anna Denvil-Sommer, Erik T. Buitenhuis, Rainer Kiko, Fabien Lombard, Lionel Guidi, and Corinne Le Quéré
Geosci. Model Dev., 16, 2995–3012, https://doi.org/10.5194/gmd-16-2995-2023, https://doi.org/10.5194/gmd-16-2995-2023, 2023
Short summary
Short summary
Using outputs of global biogeochemical ocean model and machine learning methods, we demonstrate that it will be possible to identify linkages between surface environmental and ecosystem structure and the export of carbon to depth by sinking organic particles using real observations. It will be possible to use this knowledge to improve both our understanding of ecosystem dynamics and of their functional representation within models.
Pierre L'Hégaret, Florian Schütte, Sabrina Speich, Gilles Reverdin, Dariusz B. Baranowski, Rena Czeschel, Tim Fischer, Gregory R. Foltz, Karen J. Heywood, Gerd Krahmann, Rémi Laxenaire, Caroline Le Bihan, Philippe Le Bot, Stéphane Leizour, Callum Rollo, Michael Schlundt, Elizabeth Siddle, Corentin Subirade, Dongxiao Zhang, and Johannes Karstensen
Earth Syst. Sci. Data, 15, 1801–1830, https://doi.org/10.5194/essd-15-1801-2023, https://doi.org/10.5194/essd-15-1801-2023, 2023
Short summary
Short summary
In early 2020, the EUREC4A-OA/ATOMIC experiment took place in the northwestern Tropical Atlantic Ocean, a dynamical region where different water masses interact. Four oceanographic vessels and a fleet of autonomous devices were deployed to study the processes at play and sample the upper ocean, each with its own observing capability. The article first describes the data calibration and validation and second their cross-validation, using a hierarchy of instruments and estimating the uncertainty.
Thibauld M. Béjard, Andrés S. Rigual-Hernández, José A. Flores, Javier P. Tarruella, Xavier Durrieu de Madron, Isabel Cacho, Neghar Haghipour, Aidan Hunter, and Francisco J. Sierro
Biogeosciences, 20, 1505–1528, https://doi.org/10.5194/bg-20-1505-2023, https://doi.org/10.5194/bg-20-1505-2023, 2023
Short summary
Short summary
The Mediterranean Sea is undergoing a rapid and unprecedented environmental change. Planktic foraminifera calcification is affected on different timescales. On seasonal and interannual scales, calcification trends differ according to the species and are linked mainly to sea surface temperatures and carbonate system parameters, while comparison with pre/post-industrial assemblages shows that all three species have reduced their calcification between 10 % to 35 % according to the species.
Sébastien Petton, Valérie Garnier, Matthieu Caillaud, Laurent Debreu, and Franck Dumas
Geosci. Model Dev., 16, 1191–1211, https://doi.org/10.5194/gmd-16-1191-2023, https://doi.org/10.5194/gmd-16-1191-2023, 2023
Short summary
Short summary
The nesting AGRIF library is implemented in the MARS3D hydrodynamic model, a semi-implicit, free-surface numerical model which uses a time scheme as an alternating-direction implicit (ADI) algorithm. Two applications at the regional and coastal scale are introduced. We compare the two-nesting approach to the classic offline one-way approach, based on an in situ dataset. This method is an efficient means to significantly improve the physical hydrodynamics and unravel ecological challenges.
Adriana Bailey, Franziska Aemisegger, Leonie Villiger, Sebastian A. Los, Gilles Reverdin, Estefanía Quiñones Meléndez, Claudia Acquistapace, Dariusz B. Baranowski, Tobias Böck, Sandrine Bony, Tobias Bordsdorff, Derek Coffman, Simon P. de Szoeke, Christopher J. Diekmann, Marina Dütsch, Benjamin Ertl, Joseph Galewsky, Dean Henze, Przemyslaw Makuch, David Noone, Patricia K. Quinn, Michael Rösch, Andreas Schneider, Matthias Schneider, Sabrina Speich, Bjorn Stevens, and Elizabeth J. Thompson
Earth Syst. Sci. Data, 15, 465–495, https://doi.org/10.5194/essd-15-465-2023, https://doi.org/10.5194/essd-15-465-2023, 2023
Short summary
Short summary
One of the novel ways EUREC4A set out to investigate trade wind clouds and their coupling to the large-scale circulation was through an extensive network of isotopic measurements in water vapor, precipitation, and seawater. Samples were taken from the island of Barbados, from aboard two aircraft, and from aboard four ships. This paper describes the full collection of EUREC4A isotopic in situ data and guides readers to complementary remotely sensed water vapor isotope ratios.
Stéphanie Barrillon, Robin Fuchs, Anne A. Petrenko, Caroline Comby, Anthony Bosse, Christophe Yohia, Jean-Luc Fuda, Nagib Bhairy, Frédéric Cyr, Andrea M. Doglioli, Gérald Grégori, Roxane Tzortzis, Francesco d'Ovidio, and Melilotus Thyssen
Biogeosciences, 20, 141–161, https://doi.org/10.5194/bg-20-141-2023, https://doi.org/10.5194/bg-20-141-2023, 2023
Short summary
Short summary
Extreme weather events can have a major impact on ocean physics and biogeochemistry, but their study is challenging. In May 2019, an intense storm occurred in the north-western Mediterranean Sea, during which in situ multi-platform measurements were performed. The results show a strong impact on the surface phytoplankton, highlighting the need for high-resolution measurements coupling physics and biology during these violent events that may become more common in the context of global change.
André Valente, Shubha Sathyendranath, Vanda Brotas, Steve Groom, Michael Grant, Thomas Jackson, Andrei Chuprin, Malcolm Taberner, Ruth Airs, David Antoine, Robert Arnone, William M. Balch, Kathryn Barker, Ray Barlow, Simon Bélanger, Jean-François Berthon, Şükrü Beşiktepe, Yngve Borsheim, Astrid Bracher, Vittorio Brando, Robert J. W. Brewin, Elisabetta Canuti, Francisco P. Chavez, Andrés Cianca, Hervé Claustre, Lesley Clementson, Richard Crout, Afonso Ferreira, Scott Freeman, Robert Frouin, Carlos García-Soto, Stuart W. Gibb, Ralf Goericke, Richard Gould, Nathalie Guillocheau, Stanford B. Hooker, Chuamin Hu, Mati Kahru, Milton Kampel, Holger Klein, Susanne Kratzer, Raphael Kudela, Jesus Ledesma, Steven Lohrenz, Hubert Loisel, Antonio Mannino, Victor Martinez-Vicente, Patricia Matrai, David McKee, Brian G. Mitchell, Tiffany Moisan, Enrique Montes, Frank Muller-Karger, Aimee Neeley, Michael Novak, Leonie O'Dowd, Michael Ondrusek, Trevor Platt, Alex J. Poulton, Michel Repecaud, Rüdiger Röttgers, Thomas Schroeder, Timothy Smyth, Denise Smythe-Wright, Heidi M. Sosik, Crystal Thomas, Rob Thomas, Gavin Tilstone, Andreia Tracana, Michael Twardowski, Vincenzo Vellucci, Kenneth Voss, Jeremy Werdell, Marcel Wernand, Bozena Wojtasiewicz, Simon Wright, and Giuseppe Zibordi
Earth Syst. Sci. Data, 14, 5737–5770, https://doi.org/10.5194/essd-14-5737-2022, https://doi.org/10.5194/essd-14-5737-2022, 2022
Short summary
Short summary
A compiled set of in situ data is vital to evaluate the quality of ocean-colour satellite data records. Here we describe the global compilation of bio-optical in situ data (spanning from 1997 to 2021) used for the validation of the ocean-colour products from the ESA Ocean Colour Climate Change Initiative (OC-CCI). The compilation merges and harmonizes several in situ data sources into a simple format that could be used directly for the evaluation of satellite-derived ocean-colour data.
Oriane Bruyère, Benoit Soulard, Hugues Lemonnier, Thierry Laugier, Morgane Hubert, Sébastien Petton, Térence Desclaux, Simon Van Wynsberge, Eric Le Tesson, Jérôme Lefèvre, Franck Dumas, Jean-François Kayara, Emmanuel Bourassin, Noémie Lalau, Florence Antypas, and Romain Le Gendre
Earth Syst. Sci. Data, 14, 5439–5462, https://doi.org/10.5194/essd-14-5439-2022, https://doi.org/10.5194/essd-14-5439-2022, 2022
Short summary
Short summary
From 2014 to 2021, extensive monitoring of hydrodynamics was deployed within five contrasted lagoons of New Caledonia during austral summers. These coastal physical observations encompassed unmonitored lagoons and captured eight major atmospheric events ranging from tropical depression to category 4 cyclone. The main objectives were to characterize the processes controlling hydrodynamics of these lagoons and record the signature of extreme events on land–lagoon–ocean continuum functioning.
Pierre Friedlingstein, Michael O'Sullivan, Matthew W. Jones, Robbie M. Andrew, Luke Gregor, Judith Hauck, Corinne Le Quéré, Ingrid T. Luijkx, Are Olsen, Glen P. Peters, Wouter Peters, Julia Pongratz, Clemens Schwingshackl, Stephen Sitch, Josep G. Canadell, Philippe Ciais, Robert B. Jackson, Simone R. Alin, Ramdane Alkama, Almut Arneth, Vivek K. Arora, Nicholas R. Bates, Meike Becker, Nicolas Bellouin, Henry C. Bittig, Laurent Bopp, Frédéric Chevallier, Louise P. Chini, Margot Cronin, Wiley Evans, Stefanie Falk, Richard A. Feely, Thomas Gasser, Marion Gehlen, Thanos Gkritzalis, Lucas Gloege, Giacomo Grassi, Nicolas Gruber, Özgür Gürses, Ian Harris, Matthew Hefner, Richard A. Houghton, George C. Hurtt, Yosuke Iida, Tatiana Ilyina, Atul K. Jain, Annika Jersild, Koji Kadono, Etsushi Kato, Daniel Kennedy, Kees Klein Goldewijk, Jürgen Knauer, Jan Ivar Korsbakken, Peter Landschützer, Nathalie Lefèvre, Keith Lindsay, Junjie Liu, Zhu Liu, Gregg Marland, Nicolas Mayot, Matthew J. McGrath, Nicolas Metzl, Natalie M. Monacci, David R. Munro, Shin-Ichiro Nakaoka, Yosuke Niwa, Kevin O'Brien, Tsuneo Ono, Paul I. Palmer, Naiqing Pan, Denis Pierrot, Katie Pocock, Benjamin Poulter, Laure Resplandy, Eddy Robertson, Christian Rödenbeck, Carmen Rodriguez, Thais M. Rosan, Jörg Schwinger, Roland Séférian, Jamie D. Shutler, Ingunn Skjelvan, Tobias Steinhoff, Qing Sun, Adrienne J. Sutton, Colm Sweeney, Shintaro Takao, Toste Tanhua, Pieter P. Tans, Xiangjun Tian, Hanqin Tian, Bronte Tilbrook, Hiroyuki Tsujino, Francesco Tubiello, Guido R. van der Werf, Anthony P. Walker, Rik Wanninkhof, Chris Whitehead, Anna Willstrand Wranne, Rebecca Wright, Wenping Yuan, Chao Yue, Xu Yue, Sönke Zaehle, Jiye Zeng, and Bo Zheng
Earth Syst. Sci. Data, 14, 4811–4900, https://doi.org/10.5194/essd-14-4811-2022, https://doi.org/10.5194/essd-14-4811-2022, 2022
Short summary
Short summary
The Global Carbon Budget 2022 describes the datasets and methodology used to quantify the anthropogenic emissions of carbon dioxide (CO2) and their partitioning among the atmosphere, the land ecosystems, and the ocean. These living datasets are updated every year to provide the highest transparency and traceability in the reporting of CO2, the key driver of climate change.
Chloe Carbonne, Steeve Comeau, Phoebe T. W. Chan, Keyla Plichon, Jean-Pierre Gattuso, and Núria Teixidó
Biogeosciences, 19, 4767–4777, https://doi.org/10.5194/bg-19-4767-2022, https://doi.org/10.5194/bg-19-4767-2022, 2022
Short summary
Short summary
For the first time, our study highlights the synergistic effects of a 9-month warming and acidification combined stress on the early life stages of a Mediterranean azooxanthellate coral, Astroides calycularis. Our results predict a decrease in dispersion, settlement, post-settlement linear extention, budding and survival under future global change and that larvae and recruits of A. calycularis are stages of interest for this Mediterranean coral resistance, resilience and conservation.
Stanley I. Nmor, Eric Viollier, Lucie Pastor, Bruno Lansard, Christophe Rabouille, and Karline Soetaert
Geosci. Model Dev., 15, 7325–7351, https://doi.org/10.5194/gmd-15-7325-2022, https://doi.org/10.5194/gmd-15-7325-2022, 2022
Short summary
Short summary
The coastal marine environment serves as a transition zone in the land–ocean continuum and is susceptible to episodic phenomena such as flash floods, which cause massive organic matter deposition. Here, we present a model of sediment early diagenesis that explicitly describes this type of deposition while also incorporating unique flood deposit characteristics. This model can be used to investigate the temporal evolution of marine sediments following abrupt changes in environmental conditions.
Rainer Kiko, Marc Picheral, David Antoine, Marcel Babin, Léo Berline, Tristan Biard, Emmanuel Boss, Peter Brandt, Francois Carlotti, Svenja Christiansen, Laurent Coppola, Leandro de la Cruz, Emilie Diamond-Riquier, Xavier Durrieu de Madron, Amanda Elineau, Gabriel Gorsky, Lionel Guidi, Helena Hauss, Jean-Olivier Irisson, Lee Karp-Boss, Johannes Karstensen, Dong-gyun Kim, Rachel M. Lekanoff, Fabien Lombard, Rubens M. Lopes, Claudie Marec, Andrew M. P. McDonnell, Daniela Niemeyer, Margaux Noyon, Stephanie H. O'Daly, Mark D. Ohman, Jessica L. Pretty, Andreas Rogge, Sarah Searson, Masashi Shibata, Yuji Tanaka, Toste Tanhua, Jan Taucher, Emilia Trudnowska, Jessica S. Turner, Anya Waite, and Lars Stemmann
Earth Syst. Sci. Data, 14, 4315–4337, https://doi.org/10.5194/essd-14-4315-2022, https://doi.org/10.5194/essd-14-4315-2022, 2022
Short summary
Short summary
The term
marine particlescomprises detrital aggregates; fecal pellets; bacterioplankton, phytoplankton and zooplankton; and even fish. Here, we present a global dataset that contains 8805 vertical particle size distribution profiles obtained with Underwater Vision Profiler 5 (UVP5) camera systems. These data are valuable to the scientific community, as they can be used to constrain important biogeochemical processes in the ocean, such as the flux of carbon to the deep sea.
Liliane Merlivat, Michael Hemming, Jacqueline Boutin, David Antoine, Vincenzo Vellucci, Melek Golbol, Gareth A. Lee, and Laurence Beaumont
Biogeosciences, 19, 3911–3920, https://doi.org/10.5194/bg-19-3911-2022, https://doi.org/10.5194/bg-19-3911-2022, 2022
Short summary
Short summary
We use in situ high-temporal-resolution measurements of dissolved inorganic carbon and atmospheric parameters at the air–sea interface to analyse phytoplankton bloom initiation identified as the net rate of biological carbon uptake in the Mediterranean Sea. The shift from wind-driven to buoyancy-driven mixing creates conditions for blooms to begin. Active mixing at the air–sea interface leads to the onset of the surface phytoplankton bloom due to the relaxation of wind speed following storms.
Michael P. Hemming, Jan Kaiser, Jacqueline Boutin, Liliane Merlivat, Karen J. Heywood, Dorothee C. E. Bakker, Gareth A. Lee, Marcos Cobas García, David Antoine, and Kiminori Shitashima
Ocean Sci., 18, 1245–1262, https://doi.org/10.5194/os-18-1245-2022, https://doi.org/10.5194/os-18-1245-2022, 2022
Short summary
Short summary
An underwater glider mission was carried out in spring 2016 near a mooring in the northwestern Mediterranean Sea. The glider deployment served as a test of a prototype ion-sensitive field-effect transistor pH sensor. Mean net community production rates were estimated from glider and buoy measurements of dissolved oxygen and inorganic carbon concentrations before and during the spring bloom. Incorporating advection is important for accurate mass budgets. Unexpected metabolic quotients were found.
Katia Mallil, Pierre Testor, Anthony Bosse, Félix Margirier, Loic Houpert, Hervé Le Goff, Laurent Mortier, and Ferial Louanchi
Ocean Sci., 18, 937–952, https://doi.org/10.5194/os-18-937-2022, https://doi.org/10.5194/os-18-937-2022, 2022
Short summary
Short summary
Our study documents the circulation in the Algerian Basin of the western Mediterranean Sea using in situ data. It shows that the Algerian Gyres have an impact on the distribution at intermediate depth of Levantine Intermediate Water. They allow a westward transport from the south of Sardinia toward the interior of the Algerian Basin. Temperature and salinity trends of this water mass are also investigated, confirming a recent acceleration of the warming and salinification during the last decade.
Léa Olivier, Jacqueline Boutin, Gilles Reverdin, Nathalie Lefèvre, Peter Landschützer, Sabrina Speich, Johannes Karstensen, Matthieu Labaste, Christophe Noisel, Markus Ritschel, Tobias Steinhoff, and Rik Wanninkhof
Biogeosciences, 19, 2969–2988, https://doi.org/10.5194/bg-19-2969-2022, https://doi.org/10.5194/bg-19-2969-2022, 2022
Short summary
Short summary
We investigate the impact of the interactions between eddies and the Amazon River plume on the CO2 air–sea fluxes to better characterize the ocean carbon sink in winter 2020. The region is a strong CO2 sink, previously underestimated by a factor of 10 due to a lack of data and understanding of the processes responsible for the variability in ocean carbon parameters. The CO2 absorption is mainly driven by freshwater from the Amazon entrained by eddies and by the winter seasonal cooling.
Gilles Reverdin, Claire Waelbroeck, Catherine Pierre, Camille Akhoudas, Giovanni Aloisi, Marion Benetti, Bernard Bourlès, Magnus Danielsen, Jérôme Demange, Denis Diverrès, Jean-Claude Gascard, Marie-Noëlle Houssais, Hervé Le Goff, Pascale Lherminier, Claire Lo Monaco, Herlé Mercier, Nicolas Metzl, Simon Morisset, Aïcha Naamar, Thierry Reynaud, Jean-Baptiste Sallée, Virginie Thierry, Susan E. Hartman, Edward W. Mawji, Solveig Olafsdottir, Torsten Kanzow, Anton Velo, Antje Voelker, Igor Yashayaev, F. Alexander Haumann, Melanie J. Leng, Carol Arrowsmith, and Michael Meredith
Earth Syst. Sci. Data, 14, 2721–2735, https://doi.org/10.5194/essd-14-2721-2022, https://doi.org/10.5194/essd-14-2721-2022, 2022
Short summary
Short summary
The CISE-LOCEAN seawater stable isotope dataset has close to 8000 data entries. The δ18O and δD isotopic data measured at LOCEAN have uncertainties of at most 0.05 ‰ and 0.25 ‰, respectively. Some data were adjusted to correct for evaporation. The internal consistency indicates that the data can be used to investigate time and space variability to within 0.03 ‰ and 0.15 ‰ in δ18O–δD17; comparisons with data analyzed in other institutions suggest larger differences with other datasets.
Coraline Leseurre, Claire Lo Monaco, Gilles Reverdin, Nicolas Metzl, Jonathan Fin, Claude Mignon, and Léa Benito
Biogeosciences, 19, 2599–2625, https://doi.org/10.5194/bg-19-2599-2022, https://doi.org/10.5194/bg-19-2599-2022, 2022
Short summary
Short summary
Decadal trends of fugacity of CO2 (fCO2), total alkalinity (AT), total carbon (CT) and pH in surface waters are investigated in different domains of the southern Indian Ocean (45°S–57°S) from ongoing and station observations regularly conducted in summer over the period 1998–2019. The fCO2 increase and pH decrease are mainly driven by anthropogenic CO2 estimated just below the summer mixed layer, as well as by a warming south of the polar front or in the fertilized waters near Kerguelen Island.
Nicolas Metzl, Claire Lo Monaco, Coraline Leseurre, Céline Ridame, Jonathan Fin, Claude Mignon, Marion Gehlen, and Thi Tuyet Trang Chau
Biogeosciences, 19, 1451–1468, https://doi.org/10.5194/bg-19-1451-2022, https://doi.org/10.5194/bg-19-1451-2022, 2022
Short summary
Short summary
During an oceanographic cruise conducted in January 2020 in the south-western Indian Ocean, we observed very low CO2 concentrations associated with a strong phytoplankton bloom that occurred south-east of Madagascar. This biological event led to a strong regional CO2 ocean sink not previously observed.
Julie Dinasquet, Estelle Bigeard, Frédéric Gazeau, Farooq Azam, Cécile Guieu, Emilio Marañón, Céline Ridame, France Van Wambeke, Ingrid Obernosterer, and Anne-Claire Baudoux
Biogeosciences, 19, 1303–1319, https://doi.org/10.5194/bg-19-1303-2022, https://doi.org/10.5194/bg-19-1303-2022, 2022
Short summary
Short summary
Saharan dust deposition of nutrients and trace metals is crucial to microbes in the Mediterranean Sea. Here, we tested the response of microbial and viral communities to simulated dust deposition under present and future conditions of temperature and pH. Overall, the effect of the deposition was dependent on the initial microbial assemblage, and future conditions will intensify microbial responses. We observed effects on trophic interactions, cascading all the way down to viral processes.
Céline Ridame, Julie Dinasquet, Søren Hallstrøm, Estelle Bigeard, Lasse Riemann, France Van Wambeke, Matthieu Bressac, Elvira Pulido-Villena, Vincent Taillandier, Fréderic Gazeau, Antonio Tovar-Sanchez, Anne-Claire Baudoux, and Cécile Guieu
Biogeosciences, 19, 415–435, https://doi.org/10.5194/bg-19-415-2022, https://doi.org/10.5194/bg-19-415-2022, 2022
Short summary
Short summary
We show that in the Mediterranean Sea spatial variability in N2 fixation is related to the diazotrophic community composition reflecting different nutrient requirements among species. Nutrient supply by Saharan dust is of great importance to diazotrophs, as shown by the strong stimulation of N2 fixation after a simulated dust event under present and future climate conditions; the magnitude of stimulation depends on the degree of limitation related to the diazotrophic community composition.
Roxane Tzortzis, Andrea M. Doglioli, Stéphanie Barrillon, Anne A. Petrenko, Francesco d'Ovidio, Lloyd Izard, Melilotus Thyssen, Ananda Pascual, Bàrbara Barceló-Llull, Frédéric Cyr, Marc Tedetti, Nagib Bhairy, Pierre Garreau, Franck Dumas, and Gérald Gregori
Biogeosciences, 18, 6455–6477, https://doi.org/10.5194/bg-18-6455-2021, https://doi.org/10.5194/bg-18-6455-2021, 2021
Short summary
Short summary
This work analyzes an original high-resolution data set collected in the Mediterranean Sea. The major result is the impact of a fine-scale frontal structure on the distribution of phytoplankton groups, in an area of moderate energy with oligotrophic conditions. Our results provide an in situ confirmation of the findings obtained by previous modeling studies and remote sensing about the structuring effect of the fine-scale ocean dynamics on the structure of the phytoplankton community.
Matthieu Bressac, Thibaut Wagener, Nathalie Leblond, Antonio Tovar-Sánchez, Céline Ridame, Vincent Taillandier, Samuel Albani, Sophie Guasco, Aurélie Dufour, Stéphanie H. M. Jacquet, François Dulac, Karine Desboeufs, and Cécile Guieu
Biogeosciences, 18, 6435–6453, https://doi.org/10.5194/bg-18-6435-2021, https://doi.org/10.5194/bg-18-6435-2021, 2021
Short summary
Short summary
Phytoplankton growth is limited by the availability of iron in about 50 % of the ocean. Atmospheric deposition of desert dust represents a key source of iron. Here, we present direct observations of dust deposition in the Mediterranean Sea. A key finding is that the input of iron from dust primarily occurred in the deep ocean, while previous studies mainly focused on the ocean surface. This new insight will enable us to better represent controls on global marine productivity in models.
Léo Berline, Andrea Michelangelo Doglioli, Anne Petrenko, Stéphanie Barrillon, Boris Espinasse, Frederic A. C. Le Moigne, François Simon-Bot, Melilotus Thyssen, and François Carlotti
Biogeosciences, 18, 6377–6392, https://doi.org/10.5194/bg-18-6377-2021, https://doi.org/10.5194/bg-18-6377-2021, 2021
Short summary
Short summary
While the Ionian Sea is considered a nutrient-depleted and low-phytoplankton biomass area, it is a crossroad for water mass circulation. In the central Ionian Sea, we observed a strong contrast in particle distribution across a ~100 km long transect. Using remote sensing and Lagrangian simulations, we suggest that this contrast finds its origin in the long-distance transport of particles from the north, west and east of the Ionian Sea, where phytoplankton production was more intense.
Elvira Pulido-Villena, Karine Desboeufs, Kahina Djaoudi, France Van Wambeke, Stéphanie Barrillon, Andrea Doglioli, Anne Petrenko, Vincent Taillandier, Franck Fu, Tiphanie Gaillard, Sophie Guasco, Sandra Nunige, Sylvain Triquet, and Cécile Guieu
Biogeosciences, 18, 5871–5889, https://doi.org/10.5194/bg-18-5871-2021, https://doi.org/10.5194/bg-18-5871-2021, 2021
Short summary
Short summary
We report on phosphorus dynamics in the surface layer of the Mediterranean Sea. Highly sensitive phosphate measurements revealed vertical gradients above the phosphacline. The relative contribution of diapycnal fluxes to total external supply of phosphate to the mixed layer decreased towards the east, where atmospheric deposition dominated. Taken together, external sources of phosphate contributed little to total supply, which was mainly sustained by enzymatic hydrolysis of organic phosphorus.
France Van Wambeke, Vincent Taillandier, Karine Desboeufs, Elvira Pulido-Villena, Julie Dinasquet, Anja Engel, Emilio Marañón, Céline Ridame, and Cécile Guieu
Biogeosciences, 18, 5699–5717, https://doi.org/10.5194/bg-18-5699-2021, https://doi.org/10.5194/bg-18-5699-2021, 2021
Short summary
Short summary
Simultaneous in situ measurements of (dry and wet) atmospheric deposition and biogeochemical stocks and fluxes in the sunlit waters of the open Mediterranean Sea revealed complex physical and biological processes occurring within the mixed layer. Nitrogen (N) budgets were computed to compare the sources and sinks of N in the mixed layer. The transitory effect observed after a wet dust deposition impacted the microbial food web down to the deep chlorophyll maximum.
Frédéric Gazeau, France Van Wambeke, Emilio Marañón, Maria Pérez-Lorenzo, Samir Alliouane, Christian Stolpe, Thierry Blasco, Nathalie Leblond, Birthe Zäncker, Anja Engel, Barbara Marie, Julie Dinasquet, and Cécile Guieu
Biogeosciences, 18, 5423–5446, https://doi.org/10.5194/bg-18-5423-2021, https://doi.org/10.5194/bg-18-5423-2021, 2021
Short summary
Short summary
Our study shows that the impact of dust deposition on primary production depends on the initial composition and metabolic state of the tested community and is constrained by the amount of nutrients added, to sustain both the fast response of heterotrophic prokaryotes and the delayed one of phytoplankton. Under future environmental conditions, heterotrophic metabolism will be more impacted than primary production, therefore reducing the capacity of surface waters to sequester anthropogenic CO2.
Frédéric Gazeau, Céline Ridame, France Van Wambeke, Samir Alliouane, Christian Stolpe, Jean-Olivier Irisson, Sophie Marro, Jean-Michel Grisoni, Guillaume De Liège, Sandra Nunige, Kahina Djaoudi, Elvira Pulido-Villena, Julie Dinasquet, Ingrid Obernosterer, Philippe Catala, and Cécile Guieu
Biogeosciences, 18, 5011–5034, https://doi.org/10.5194/bg-18-5011-2021, https://doi.org/10.5194/bg-18-5011-2021, 2021
Short summary
Short summary
This paper shows that the impacts of Saharan dust deposition in different Mediterranean basins are as strong as those observed in coastal waters but differed substantially between the three tested stations, differences attributed to variable initial metabolic states. A stronger impact of warming and acidification on mineralization suggests a decreased capacity of Mediterranean surface communities to sequester CO2 following the deposition of atmospheric particles in the coming decades.
Bjorn Stevens, Sandrine Bony, David Farrell, Felix Ament, Alan Blyth, Christopher Fairall, Johannes Karstensen, Patricia K. Quinn, Sabrina Speich, Claudia Acquistapace, Franziska Aemisegger, Anna Lea Albright, Hugo Bellenger, Eberhard Bodenschatz, Kathy-Ann Caesar, Rebecca Chewitt-Lucas, Gijs de Boer, Julien Delanoë, Leif Denby, Florian Ewald, Benjamin Fildier, Marvin Forde, Geet George, Silke Gross, Martin Hagen, Andrea Hausold, Karen J. Heywood, Lutz Hirsch, Marek Jacob, Friedhelm Jansen, Stefan Kinne, Daniel Klocke, Tobias Kölling, Heike Konow, Marie Lothon, Wiebke Mohr, Ann Kristin Naumann, Louise Nuijens, Léa Olivier, Robert Pincus, Mira Pöhlker, Gilles Reverdin, Gregory Roberts, Sabrina Schnitt, Hauke Schulz, A. Pier Siebesma, Claudia Christine Stephan, Peter Sullivan, Ludovic Touzé-Peiffer, Jessica Vial, Raphaela Vogel, Paquita Zuidema, Nicola Alexander, Lyndon Alves, Sophian Arixi, Hamish Asmath, Gholamhossein Bagheri, Katharina Baier, Adriana Bailey, Dariusz Baranowski, Alexandre Baron, Sébastien Barrau, Paul A. Barrett, Frédéric Batier, Andreas Behrendt, Arne Bendinger, Florent Beucher, Sebastien Bigorre, Edmund Blades, Peter Blossey, Olivier Bock, Steven Böing, Pierre Bosser, Denis Bourras, Pascale Bouruet-Aubertot, Keith Bower, Pierre Branellec, Hubert Branger, Michal Brennek, Alan Brewer, Pierre-Etienne Brilouet, Björn Brügmann, Stefan A. Buehler, Elmo Burke, Ralph Burton, Radiance Calmer, Jean-Christophe Canonici, Xavier Carton, Gregory Cato Jr., Jude Andre Charles, Patrick Chazette, Yanxu Chen, Michal T. Chilinski, Thomas Choularton, Patrick Chuang, Shamal Clarke, Hugh Coe, Céline Cornet, Pierre Coutris, Fleur Couvreux, Susanne Crewell, Timothy Cronin, Zhiqiang Cui, Yannis Cuypers, Alton Daley, Gillian M. Damerell, Thibaut Dauhut, Hartwig Deneke, Jean-Philippe Desbios, Steffen Dörner, Sebastian Donner, Vincent Douet, Kyla Drushka, Marina Dütsch, André Ehrlich, Kerry Emanuel, Alexandros Emmanouilidis, Jean-Claude Etienne, Sheryl Etienne-Leblanc, Ghislain Faure, Graham Feingold, Luca Ferrero, Andreas Fix, Cyrille Flamant, Piotr Jacek Flatau, Gregory R. Foltz, Linda Forster, Iulian Furtuna, Alan Gadian, Joseph Galewsky, Martin Gallagher, Peter Gallimore, Cassandra Gaston, Chelle Gentemann, Nicolas Geyskens, Andreas Giez, John Gollop, Isabelle Gouirand, Christophe Gourbeyre, Dörte de Graaf, Geiske E. de Groot, Robert Grosz, Johannes Güttler, Manuel Gutleben, Kashawn Hall, George Harris, Kevin C. Helfer, Dean Henze, Calvert Herbert, Bruna Holanda, Antonio Ibanez-Landeta, Janet Intrieri, Suneil Iyer, Fabrice Julien, Heike Kalesse, Jan Kazil, Alexander Kellman, Abiel T. Kidane, Ulrike Kirchner, Marcus Klingebiel, Mareike Körner, Leslie Ann Kremper, Jan Kretzschmar, Ovid Krüger, Wojciech Kumala, Armin Kurz, Pierre L'Hégaret, Matthieu Labaste, Tom Lachlan-Cope, Arlene Laing, Peter Landschützer, Theresa Lang, Diego Lange, Ingo Lange, Clément Laplace, Gauke Lavik, Rémi Laxenaire, Caroline Le Bihan, Mason Leandro, Nathalie Lefevre, Marius Lena, Donald Lenschow, Qiang Li, Gary Lloyd, Sebastian Los, Niccolò Losi, Oscar Lovell, Christopher Luneau, Przemyslaw Makuch, Szymon Malinowski, Gaston Manta, Eleni Marinou, Nicholas Marsden, Sebastien Masson, Nicolas Maury, Bernhard Mayer, Margarette Mayers-Als, Christophe Mazel, Wayne McGeary, James C. McWilliams, Mario Mech, Melina Mehlmann, Agostino Niyonkuru Meroni, Theresa Mieslinger, Andreas Minikin, Peter Minnett, Gregor Möller, Yanmichel Morfa Avalos, Caroline Muller, Ionela Musat, Anna Napoli, Almuth Neuberger, Christophe Noisel, David Noone, Freja Nordsiek, Jakub L. Nowak, Lothar Oswald, Douglas J. Parker, Carolyn Peck, Renaud Person, Miriam Philippi, Albert Plueddemann, Christopher Pöhlker, Veronika Pörtge, Ulrich Pöschl, Lawrence Pologne, Michał Posyniak, Marc Prange, Estefanía Quiñones Meléndez, Jule Radtke, Karim Ramage, Jens Reimann, Lionel Renault, Klaus Reus, Ashford Reyes, Joachim Ribbe, Maximilian Ringel, Markus Ritschel, Cesar B. Rocha, Nicolas Rochetin, Johannes Röttenbacher, Callum Rollo, Haley Royer, Pauline Sadoulet, Leo Saffin, Sanola Sandiford, Irina Sandu, Michael Schäfer, Vera Schemann, Imke Schirmacher, Oliver Schlenczek, Jerome Schmidt, Marcel Schröder, Alfons Schwarzenboeck, Andrea Sealy, Christoph J. Senff, Ilya Serikov, Samkeyat Shohan, Elizabeth Siddle, Alexander Smirnov, Florian Späth, Branden Spooner, M. Katharina Stolla, Wojciech Szkółka, Simon P. de Szoeke, Stéphane Tarot, Eleni Tetoni, Elizabeth Thompson, Jim Thomson, Lorenzo Tomassini, Julien Totems, Alma Anna Ubele, Leonie Villiger, Jan von Arx, Thomas Wagner, Andi Walther, Ben Webber, Manfred Wendisch, Shanice Whitehall, Anton Wiltshire, Allison A. Wing, Martin Wirth, Jonathan Wiskandt, Kevin Wolf, Ludwig Worbes, Ethan Wright, Volker Wulfmeyer, Shanea Young, Chidong Zhang, Dongxiao Zhang, Florian Ziemen, Tobias Zinner, and Martin Zöger
Earth Syst. Sci. Data, 13, 4067–4119, https://doi.org/10.5194/essd-13-4067-2021, https://doi.org/10.5194/essd-13-4067-2021, 2021
Short summary
Short summary
The EUREC4A field campaign, designed to test hypothesized mechanisms by which clouds respond to warming and benchmark next-generation Earth-system models, is presented. EUREC4A comprised roughly 5 weeks of measurements in the downstream winter trades of the North Atlantic – eastward and southeastward of Barbados. It was the first campaign that attempted to characterize the full range of processes and scales influencing trade wind clouds.
Felipe S. Freitas, Philip A. Pika, Sabine Kasten, Bo B. Jørgensen, Jens Rassmann, Christophe Rabouille, Shaun Thomas, Henrik Sass, Richard D. Pancost, and Sandra Arndt
Biogeosciences, 18, 4651–4679, https://doi.org/10.5194/bg-18-4651-2021, https://doi.org/10.5194/bg-18-4651-2021, 2021
Short summary
Short summary
It remains challenging to fully understand what controls carbon burial in marine sediments globally. Thus, we use a model–data approach to identify patterns of organic matter reactivity at the seafloor across distinct environmental conditions. Our findings support the notion that organic matter reactivity is a dynamic ecosystem property and strongly influences biogeochemical cycling and exchange. Our results are essential to improve predictions of future changes in carbon cycling and climate.
Paolo Lazzari, Stefano Salon, Elena Terzić, Watson W. Gregg, Fabrizio D'Ortenzio, Vincenzo Vellucci, Emanuele Organelli, and David Antoine
Ocean Sci., 17, 675–697, https://doi.org/10.5194/os-17-675-2021, https://doi.org/10.5194/os-17-675-2021, 2021
Short summary
Short summary
Multispectral optical sensors and models are increasingly adopted to study marine systems. In this work, bio-optical mooring and biogeochemical Argo float optical observations are combined with the Ocean-Atmosphere Spectral Irradiance Model (OASIM) to analyse the variability of sunlight at the sea surface. We show that the model skill in simulating data varies according to the wavelength of light and temporal scale considered and that it is significantly affected by cloud dynamics.
Matthieu Roy-Barman, Lorna Foliot, Eric Douville, Nathalie Leblond, Fréderic Gazeau, Matthieu Bressac, Thibaut Wagener, Céline Ridame, Karine Desboeufs, and Cécile Guieu
Biogeosciences, 18, 2663–2678, https://doi.org/10.5194/bg-18-2663-2021, https://doi.org/10.5194/bg-18-2663-2021, 2021
Short summary
Short summary
The release of insoluble elements such as aluminum (Al), iron (Fe), rare earth elements (REEs), thorium (Th) and protactinium (Pa) when Saharan dust falls over the Mediterranean Sea was studied during tank experiments under present and future climate conditions. Each element exhibited different dissolution kinetics and dissolution fractions (always lower than a few percent). Changes in temperature and/or pH under greenhouse conditions lead to a lower Th release and a higher light REE release.
Philippe Massicotte, Rainer M. W. Amon, David Antoine, Philippe Archambault, Sergio Balzano, Simon Bélanger, Ronald Benner, Dominique Boeuf, Annick Bricaud, Flavienne Bruyant, Gwenaëlle Chaillou, Malik Chami, Bruno Charrière, Jing Chen, Hervé Claustre, Pierre Coupel, Nicole Delsaut, David Doxaran, Jens Ehn, Cédric Fichot, Marie-Hélène Forget, Pingqing Fu, Jonathan Gagnon, Nicole Garcia, Beat Gasser, Jean-François Ghiglione, Gaby Gorsky, Michel Gosselin, Priscillia Gourvil, Yves Gratton, Pascal Guillot, Hermann J. Heipieper, Serge Heussner, Stanford B. Hooker, Yannick Huot, Christian Jeanthon, Wade Jeffrey, Fabien Joux, Kimitaka Kawamura, Bruno Lansard, Edouard Leymarie, Heike Link, Connie Lovejoy, Claudie Marec, Dominique Marie, Johannie Martin, Jacobo Martín, Guillaume Massé, Atsushi Matsuoka, Vanessa McKague, Alexandre Mignot, William L. Miller, Juan-Carlos Miquel, Alfonso Mucci, Kaori Ono, Eva Ortega-Retuerta, Christos Panagiotopoulos, Tim Papakyriakou, Marc Picheral, Louis Prieur, Patrick Raimbault, Joséphine Ras, Rick A. Reynolds, André Rochon, Jean-François Rontani, Catherine Schmechtig, Sabine Schmidt, Richard Sempéré, Yuan Shen, Guisheng Song, Dariusz Stramski, Eri Tachibana, Alexandre Thirouard, Imma Tolosa, Jean-Éric Tremblay, Mickael Vaïtilingom, Daniel Vaulot, Frédéric Vaultier, John K. Volkman, Huixiang Xie, Guangming Zheng, and Marcel Babin
Earth Syst. Sci. Data, 13, 1561–1592, https://doi.org/10.5194/essd-13-1561-2021, https://doi.org/10.5194/essd-13-1561-2021, 2021
Short summary
Short summary
The MALINA oceanographic expedition was conducted in the Mackenzie River and the Beaufort Sea systems. The sampling was performed across seven shelf–basin transects to capture the meridional gradient between the estuary and the open ocean. The main goal of this research program was to better understand how processes such as primary production are influencing the fate of organic matter originating from the surrounding terrestrial landscape during its transition toward the Arctic Ocean.
Stéphanie H. M. Jacquet, Dominique Lefèvre, Christian Tamburini, Marc Garel, Frédéric A. C. Le Moigne, Nagib Bhairy, and Sophie Guasco
Biogeosciences, 18, 2205–2212, https://doi.org/10.5194/bg-18-2205-2021, https://doi.org/10.5194/bg-18-2205-2021, 2021
Short summary
Short summary
We present new data concerning the relation between biogenic barium (Baxs, a tracer of carbon remineralization at mesopelagic depths), O2 consumption and prokaryotic heterotrophic production (PHP) in the Mediterranean Sea. The purpose of this paper is to improve our understanding of the relation between Baxs, PHP and O2 and to test the validity of the Dehairs transfer function in the Mediterranean Sea. This relation has never been tested in the Mediterranean Sea.
Phillip Williamson, Hans-Otto Pörtner, Steve Widdicombe, and Jean-Pierre Gattuso
Biogeosciences, 18, 1787–1792, https://doi.org/10.5194/bg-18-1787-2021, https://doi.org/10.5194/bg-18-1787-2021, 2021
Short summary
Short summary
The reliability of ocean acidification research was challenged in early 2020 when a high-profile paper failed to corroborate previously observed impacts of high CO2 on the behaviour of coral reef fish. We now know the reason why: the
replicatedstudies differed in many ways. Open-minded and collaborative assessment of all research results, both negative and positive, remains the best way to develop process-based understanding of the impacts of ocean acidification on marine organisms.
Claudia Christine Stephan, Sabrina Schnitt, Hauke Schulz, Hugo Bellenger, Simon P. de Szoeke, Claudia Acquistapace, Katharina Baier, Thibaut Dauhut, Rémi Laxenaire, Yanmichel Morfa-Avalos, Renaud Person, Estefanía Quiñones Meléndez, Gholamhossein Bagheri, Tobias Böck, Alton Daley, Johannes Güttler, Kevin C. Helfer, Sebastian A. Los, Almuth Neuberger, Johannes Röttenbacher, Andreas Raeke, Maximilian Ringel, Markus Ritschel, Pauline Sadoulet, Imke Schirmacher, M. Katharina Stolla, Ethan Wright, Benjamin Charpentier, Alexis Doerenbecher, Richard Wilson, Friedhelm Jansen, Stefan Kinne, Gilles Reverdin, Sabrina Speich, Sandrine Bony, and Bjorn Stevens
Earth Syst. Sci. Data, 13, 491–514, https://doi.org/10.5194/essd-13-491-2021, https://doi.org/10.5194/essd-13-491-2021, 2021
Short summary
Short summary
The EUREC4A field campaign took place in the western tropical Atlantic during January and February 2020. A total of 811 radiosondes, launched regularly (usually 4-hourly) from Barbados, and 4 ships measured wind, temperature, and relative humidity. They sampled atmospheric variability associated with different ocean surface conditions, synoptic variability, and mesoscale convective organization. The methods of data collection and post-processing for the radiosonde data are described here.
Caroline Ulses, Claude Estournel, Marine Fourrier, Laurent Coppola, Fayçal Kessouri, Dominique Lefèvre, and Patrick Marsaleix
Biogeosciences, 18, 937–960, https://doi.org/10.5194/bg-18-937-2021, https://doi.org/10.5194/bg-18-937-2021, 2021
Short summary
Short summary
We analyse the seasonal cycle of O2 and estimate an annual O2 budget in the north-western Mediterranean deep-convection region, using a numerical model. We show that this region acts as a large sink of atmospheric O2 and as a major source of O2 for the western Mediterranean Sea. The decrease in the deep convection intensity predicted in recent projections may have important consequences on the overall uptake of O2 in the Mediterranean Sea and on the O2 exchanges with the Atlantic Ocean.
Anastasiia Tarasenko, Alexandre Supply, Nikita Kusse-Tiuz, Vladimir Ivanov, Mikhail Makhotin, Jean Tournadre, Bertrand Chapron, Jacqueline Boutin, Nicolas Kolodziejczyk, and Gilles Reverdin
Ocean Sci., 17, 221–247, https://doi.org/10.5194/os-17-221-2021, https://doi.org/10.5194/os-17-221-2021, 2021
Short summary
Short summary
Data from the ARKTIKA-2018 expedition and new satellite data help us to follow rapid changes in the upper layer of the Laptev and East Siberian seas (LS, ESS) in summer 2018. With satellite-derived surface temperature, an improved SMOS salinity, and wind, we study how the fresh river water is mixed with cold sea water and ice-melted water at small time and spatial scales. The wind pushes fresh water northward and northeastward, close to and under the ice, forcing it into the deep Arctic Ocean.
Katixa Lajaunie-Salla, Frédéric Diaz, Cathy Wimart-Rousseau, Thibaut Wagener, Dominique Lefèvre, Christophe Yohia, Irène Xueref-Remy, Brian Nathan, Alexandre Armengaud, and Christel Pinazo
Geosci. Model Dev., 14, 295–321, https://doi.org/10.5194/gmd-14-295-2021, https://doi.org/10.5194/gmd-14-295-2021, 2021
Short summary
Short summary
A biogeochemical model of planktonic food webs including a carbonate balance module is applied in the Bay of Marseille (France) to represent the carbon marine cycle expected to change in the future owing to significant increases in anthropogenic emissions of CO2. The model correctly simulates the ranges and seasonal dynamics of most variables of the carbonate system (pH). This study shows that external physical forcings have an important impact on the carbonate equilibrium in this coastal area.
Kahina Djaoudi, France Van Wambeke, Aude Barani, Nagib Bhairy, Servanne Chevaillier, Karine Desboeufs, Sandra Nunige, Mohamed Labiadh, Thierry Henry des Tureaux, Dominique Lefèvre, Amel Nouara, Christos Panagiotopoulos, Marc Tedetti, and Elvira Pulido-Villena
Biogeosciences, 17, 6271–6285, https://doi.org/10.5194/bg-17-6271-2020, https://doi.org/10.5194/bg-17-6271-2020, 2020
Cécile Guieu, Fabrizio D'Ortenzio, François Dulac, Vincent Taillandier, Andrea Doglioli, Anne Petrenko, Stéphanie Barrillon, Marc Mallet, Pierre Nabat, and Karine Desboeufs
Biogeosciences, 17, 5563–5585, https://doi.org/10.5194/bg-17-5563-2020, https://doi.org/10.5194/bg-17-5563-2020, 2020
Short summary
Short summary
We describe here the objectives and strategy of the PEACETIME project and cruise, dedicated to dust deposition and its impacts in the Mediterranean Sea. Our strategy to go a step further forward than in previous approaches in understanding these impacts by catching a real deposition event at sea is detailed. We summarize the work performed at sea, the type of data acquired and their valorization in the papers published in the special issue.
Cited articles
Álvarez, M., Catalá, T. S., Civitarese, G., Coppola, L., Hassoun, A. E. R., Ibello, V., Lazzari, P., Lefèvre, D., Macías, D., Santinelli, C., and Ulses, C.: Chapter 11 – Mediterranean Sea general biogeochemistry, Editor(s): Katrin Schroeder, Jacopo Chiggiato, Oceanography of the Mediterranean Sea, Elsevier, 387–451, https://doi.org/10.1016/B978-0-12-823692-5.00004-2, 2023.
Argo: Argo float data and metadata from Global Data Assembly Centre (Argo GDAC), SEANOE [data set], https://doi.org/10.17882/42182, 2023.
Bakker, D. C. E., Pfeil, B., Smith, K., Hankin, S., Olsen, A., Alin, S. R., Cosca, C., Harasawa, S., Kozyr, A., Nojiri, Y., O'Brien, K. M., Schuster, U., Telszewski, M., Tilbrook, B., Wada, C., Akl, J., Barbero, L., Bates, N. R., Boutin, J., Bozec, Y., Cai, W.-J., Castle, R. D., Chavez, F. P., Chen, L., Chierici, M., Currie, K., de Baar, H. J. W., Evans, W., Feely, R. A., Fransson, A., Gao, Z., Hales, B., Hardman-Mountford, N. J., Hoppema, M., Huang, W.-J., Hunt, C. W., Huss, B., Ichikawa, T., Johannessen, T., Jones, E. M., Jones, S. D., Jutterström, S., Kitidis, V., Körtzinger, A., Landschützer, P., Lauvset, S. K., Lefèvre, N., Manke, A. B., Mathis, J. T., Merlivat, L., Metzl, N., Murata, A., Newberger, T., Omar, A. M., Ono, T., Park, G.-H., Paterson, K., Pierrot, D., Ríos, A. F., Sabine, C. L., Saito, S., Salisbury, J., Sarma, V. V. S. S., Schlitzer, R., Sieger, R., Skjelvan, I., Steinhoff, T., Sullivan, K. F., Sun, H., Sutton, A. J., Suzuki, T., Sweeney, C., Takahashi, T., Tjiputra, J., Tsurushima, N., van Heuven, S. M. A. C., Vandemark, D., Vlahos, P., Wallace, D. W. R., Wanninkhof, R., and Watson, A. J.: An update to the Surface Ocean CO2 Atlas (SOCAT version 2), Earth Syst. Sci. Data, 6, 69–90, https://doi.org/10.5194/essd-6-69-2014, 2014.
Bakker, D. C. E., Pfeil, B., Landa, C. S., Metzl, N., O'Brien, K. M., Olsen, A., Smith, K., Cosca, C., Harasawa, S., Jones, S. D., Nakaoka, S., Nojiri, Y., Schuster, U., Steinhoff, T., Sweeney, C., Takahashi, T., Tilbrook, B., Wada, C., Wanninkhof, R., Alin, S. R., Balestrini, C. F., Barbero, L., Bates, N. R., Bianchi, A. A., Bonou, F., Boutin, J., Bozec, Y., Burger, E. F., Cai, W.-J., Castle, R. D., Chen, L., Chierici, M., Currie, K., Evans, W., Featherstone, C., Feely, R. A., Fransson, A., Goyet, C., Greenwood, N., Gregor, L., Hankin, S., Hardman-Mountford, N. J., Harlay, J., Hauck, J., Hoppema, M., Humphreys, M. P., Hunt, C. W., Huss, B., Ibánhez, J. S. P., Johannessen, T., Keeling, R., Kitidis, V., Körtzinger, A., Kozyr, A., Krasakopoulou, E., Kuwata, A., Landschützer, P., Lauvset, S. K., Lefèvre, N., Lo Monaco, C., Manke, A., Mathis, J. T., Merlivat, L., Millero, F. J., Monteiro, P. M. S., Munro, D. R., Murata, A., Newberger, T., Omar, A. M., Ono, T., Paterson, K., Pearce, D., Pierrot, D., Robbins, L. L., Saito, S., Salisbury, J., Schlitzer, R., Schneider, B., Schweitzer, R., Sieger, R., Skjelvan, I., Sullivan, K. F., Sutherland, S. C., Sutton, A. J., Tadokoro, K., Telszewski, M., Tuma, M., van Heuven, S. M. A. C., Vandemark, D., Ward, B., Watson, A. J., and Xu, S.: A multi-decade record of high-quality fCO2 data in version 3 of the Surface Ocean CO2 Atlas (SOCAT), Earth Syst. Sci. Data, 8, 383–413, https://doi.org/10.5194/essd-8-383-2016, 2016.
Bakker, D. C. E., Alin, S. R., Bates, N. R., Becker, M., Feely, R. A., Gritzalis, T., Jones, S. D., Kozyr, A., Lauvset, S. K., Metzl, N., Munro, D. R., Nakaoka, S.-I., Nojiri, Y., O'Brien, K., Olsen, A., Pierrot, D., Rehder, G., Steinhoff, T., Sutton, A., Sweeney, C., Tilbrook, B., Wada, C., Wanninkhof, R., and SOCAT contributors: An alarming decline in the ocean CO2 observing capacity, https://www.socat.info (last access: 22 December 2023), 2023.
Balch, W. M., Bates, N. R., Lam, P. J., Twining, B. S., Rosengard, S. Z., Bowler, B. C., Drapeau, D. T., Garley, R., Lubelczyk, L. C., Mitchell, C., and Rauschenberg S.: Factors regulating the Great Calcite Belt in the Southern Ocean and its biogeochemical significance, Global Biogeochem. Cy., 30, 1124–1144, https://doi.org/10.1002/2016GB005414, 2016.
Bates, N., Astor, Y., Church, M., Currie, K., Dore, J., González-Dávila, M., Lorenzoni, L., Muller-Karger, F., Olafsson, J., and Santa-Casiano, M.: A Time-Series View of Changing Ocean Chemistry Due to Ocean Uptake of Anthropogenic CO2 and Ocean Acidification, Oceanography, 27, 126–141, https://doi.org/10.5670/oceanog.2014.16, 2014.
Beaufort, L., Probert, I., de Garidel-Thoron, T., Bendif, E. M., Ruiz-Pino, D., Metzl, N., Goyet, C., Buchet, N., Coupel, P., Grelaud, M., Rost, B., Rickaby, R. E. M., and de Vargas C.: Sensitivity of coccolithophores to carbonate chemistry and ocean acidification, Nature, 476, 80–83, https://doi.org/10.1038/nature10295, 2011.
Bittig, H. C., Steinhoff, T., Claustre, H., Fiedler, B., Williams, N. L., Sauzède, R., Körtzinger, A., and Gattuso, J.-P.: An Alternative to Static Climatologies: Robust Estimation of Open Ocean CO2 Variables and Nutrient Concentrations From T, S, and O2 Data Using Bayesian Neural Networks, Front. Mar. Sci., 5, 328, https://doi.org/10.3389/fmars.2018.00328, 2018.
Bockmon, E. E. and Dickson, A. G.: An inter-laboratory comparison assessing the quality of seawater carbon dioxide measurements, Mar. Chem., 171, 36–43, https://doi.org/10.1016/j.marchem.2015.02.002, 2015.
Bosse, A., Testor, P., Mayot, N., Prieur, L., D'Ortenzio, F., Mortier, L., Le Goff, H., Gourcuff, C., Coppola, L., Lavigne, H., and Raimbault, P.: A submesoscale coherent vortex in the Ligurian Sea: From dynamical barriers to biological implications, J. Geophys. Res.-Oceans, 122, 6196–6217, https://doi.org/10.1002/2016JC012634, 2017.
Bozec, Y., Merlivat, L., Baudoux, A.-C., Beaumont, L., Blain, S., Bucciarelli, E., Danguy, T., Grossteffan, E., Guillot, A., Guillou, J., Répécaud, M., and Tréguer, P.: Diurnal to inter-annual dynamics of pCO2 recorded by a CARIOCA sensor in a temperate coastal ecosystem (2003–2009), Mar. Chem., 126, 13–26, https://doi.org/10.1016/j.marchem.2011.03.003, 2011.
Broullón, D., Pérez, F. F., Velo, A., Hoppema, M., Olsen, A., Takahashi, T., Key, R. M., Tanhua, T., González-Dávila, M., Jeansson, E., Kozyr, A., and van Heuven, S. M. A. C.: A global monthly climatology of total alkalinity: a neural network approach, Earth Syst. Sci. Data, 11, 1109–1127, https://doi.org/10.5194/essd-11-1109-2019, 2019.
Broullón, D., Pérez, F. F., Velo, A., Hoppema, M., Olsen, A., Takahashi, T., Key, R. M., Tanhua, T., Santana-Casiano, J. M., and Kozyr, A.: A global monthly climatology of oceanic total dissolved inorganic carbon: a neural network approach, Earth Syst. Sci. Data, 12, 1725–1743, https://doi.org/10.5194/essd-12-1725-2020, 2020.
Bushinsky, S. M., Landschützer, P., Rödenbeck, C., Gray, A. R., Baker, D., Mazloff, M. R., Resplandy L., Johnson K. S., and Sarmiento, J. L.: Reassessing Southern Ocean air-sea CO2 flux estimates with the addition of biogeochemical float observations, Global Biogeochem. Cy., 33, 1370–1388, https://doi.org/10.1029/2019GB006176, 2019.
Canesi, M., Douville, E., Montagna, P., Taviani, M., Stolarski, J., Bordier, L., Dapoigny, A., Coulibaly, G. E. H., Simon, A.-C., Agelou, M., Fin, J., Metzl, N., Iwankow, G., Allemand, D., Planes, S., Moulin, C., Lombard, F., Bourdin, G., Troublé, R., Agostini, S., Banaigs, B., Boissin, E., Boss, E., Bowler, C., de Vargas, C., Flores, M., Forcioli, D., Furla, P., Gilson, E., Galand, P. E., Pesant, S., Sunagawa, S., Thomas, O., Thurber, R. V., Voolstra, C. R., Wincker, P., Zoccola, D., and Reynaud, S.: Differences in carbonate chemistry up-regulation of long-lived reef-building corals, Sci. Rep. 13, 11589, https://doi.org/10.1038/s41598-023-37598-9, 2023.
Caniaux, G., Giordani, H., Redelsperger, J.-L., Guichard, F., Key, E., and Wade, M.: Coupling between the Atlantic cold tongue and the West African monsoon in boreal spring and summer, J. Geophys. Res., 119, C04003, https://doi.org/10.1029/2010JC006570, 2011.
Carter, B. R., Williams, N. L., Gray, A. R., and Feely, R. A.: Locally interpolated alkalinity regression for global alkalinity estimation, Limnol. Oceanogr.-Meth., 14, 268–277, https://doi.org/10.1002/lom3.10087, 2016.
Chen, H., Haumann, F. A., Talley, L. D., Johnson, K. S., and Sarmiento, J. L.: The deep ocean's carbon exhaust, Global Biogeochem. Cy., 36, e2021GB007156, https://doi.org/10.1002/essoar.10507757.1, 2022.
Cheng, L. J., Abraham, J., Zhu, J., Trenberth, K. E., Fasullo, J., Boyer, T., Locarnini, R., Zhang, B., Yu, F. J., Wan, L. Y., Chen, X. R., Song, X. Z., Liu, Y. L., and Mann, M. E.: Record-setting ocean warmth continued in 2019, Adv. Atmos. Sci, 37, 137–142, https://doi.org/10.1007/s00376-020-9283-7, 2020.
Claustre, H., Johnson, K. S., and Takeshita, Y.: Observing the Global Ocean with Biogeochemical-Argo, Annu. Rev. Mar. Sci., 12, 23–48, https://doi.org/10.1146/annurev-marine-010419-010956, 2020.
Copin-Montégut, C.: Alkalinity and carbon budgets in the Mediterranean Sea, Global Biogeochem. Cy., 7, 915–925, 1993.
Copin-Montégut, C. and Bégovic, M.: Distributions of carbonate properties and oxygen along the water column (0–2000 m) in the central part of the NW Mediterranean Sea (Dyfamed site): influence of the winter vertical mixing on air–sea CO2 and O2 exchanges, Deep-Sea Res. Pt. II, 49, 2049–2066, https://doi.org/10.1016/S0967-0645(02)00027-9,2002.
Coppola, L., Raimbault, P., Mortier, L., and Testor, P.: Monitoring the environment in the northwestern Mediterranean Sea, Eos, 100, https://doi.org/10.1029/2019EO125951, 2019.
Coppola, L., Boutin, J., Gattuso, J.-P., Lefèvre, D., and Metzl, N.: The Carbonate System in the Ligurian Sea, in: The Mediterranean Sea in the Era of Global Change: Evidence from 30 years of multidisciplinary study of the Ligurian Sea, edited by: Migon, C., Nival, P., and Sciandra, A., vol. 1, chap. 4, ISTE Science Publishing LTD, London, UK, 79–104, ISBN 9781786304285, https://doi.org/10.1002/9781119706960.ch4, 2020.
Coppola, L., Fourrier, M., Pasqueron de Fommervault, O., Poteau, A., Riquier, E. D., and Béguery, L.: Highresolution study of the air-sea CO2 flux and net community oxygen production in the Ligurian Sea by a fleet of gliders, Front. Mar. Sci., 10, 1233845, https://doi.org/10.3389/fmars.2023.1233845, 2023.
Corbière, A., Metzl, N., Reverdin, G., Brunet, C., and Takahashi, T.: Interannual and decadal variability of the oceanic carbon sink in the North Atlantic subpolar gyre, Tellus B, 59, 168–179, https://doi.org/10.1111/j.1600-0889.2006.00232.x, 2007.
De Carlo, E. H., Mousseau, L., Passafiume, O., Drupp, P., and Gattuso J.-P.: Carbonate chemistry and air-sea CO2 flux in a NW Mediterranean bay over a four-year period: 2007–2011, Aquat. Geochem., 19, 399–442, https://doi.org/10.1007/s10498-013-9217-4, 2013.
Dickson, A. G., Sabine, C. L., and Christian, J. R.: Guide to best practices for ocean CO2 measurements, North Pacific Marine Science Organization, Sidney, British Columbia, 191, https://doi.org/10.25607/OBP-1342, 2007.
Doney, S. C., Fabry, V. J., Feely, R. A., and Kleypas, J. A.: Ocean acidification: The other CO2 problem, Annu. Rev. Mar. Sci., 1, 169–192, https://doi.org/10.1146/annurev.marine.010908.163834, 2009.
Doney, S. C., Busch, D. S., Cooley, S. R., and Kroeker, K. J.: The Impacts of Ocean Acidification on Marine Ecosystems and Reliant Human Communities, Annu. Rev. Env. Resour., 45, 83–112, https://doi.org/10.1146/annurev-environ-012320-083019, 2020.
Douville, E., Bourdin, G., Lombard, F., Gorsky, G., Fin, J., Metzl, N., Pesant, S., and Tara Pacific Consortium: Seawater carbonate chemistry dataset collected during the Tara Pacific Expedition 2016–2018, PANGAEA [data set], https://doi.org/10.1594/PANGAEA.944420, 2022.
Edmond, J. M.: High precision determination of titration alkalinity and total carbon dioxide content of sea water by potentiometric titration, Deep-Sea Res., 17, 737–750, https://doi.org/10.1016/0011-7471(70)90038-0, 1970.
Eyring, V., Righi, M., Lauer, A., Evaldsson, M., Wenzel, S., Jones, C., Anav, A., Andrews, O., Cionni, I., Davin, E. L., Deser, C., Ehbrecht, C., Friedlingstein, P., Gleckler, P., Gottschaldt, K.-D., Hagemann, S., Juckes, M., Kindermann, S., Krasting, J., Kunert, D., Levine, R., Loew, A., Mäkelä, J., Martin, G., Mason, E., Phillips, A. S., Read, S., Rio, C., Roehrig, R., Senftleben, D., Sterl, A., van Ulft, L. H., Walton, J., Wang, S., and Williams, K. D.: ESMValTool (v1.0) – a community diagnostic and performance metrics tool for routine evaluation of Earth system models in CMIP, Geosci. Model Dev., 9, 1747–1802, https://doi.org/10.5194/gmd-9-1747-2016, 2016.
Fabry, V. J., Seibel, B. A., Feely, R. A., and Orr, J. C.: Impacts of ocean acidification on marine fauna and ecosystem processes, ICES J. Mar. Sci., 65, 414–432, https://doi.org/10.1093/icesjms/fsn048, 2008.
Fassbender, A. J., Sabine, C. L., and Palevsky, H. I.: Nonuniform ocean acidification and attenuation of the ocean carbon sink, Geophys. Res. Lett., 44, 8404–8413, https://doi.org/10.1002/2017GL074389, 2017.
Fassbender, A. J., Alin, S. R., Feely, R. A., Sutton, A. J., Newton, J. A., Krembs, C., Bos, J., Keyzers, M., Devol, A., Ruef, W., and Pelletier, G.: Seasonal carbonate chemistry variability in marine surface waters of the US Pacific Northwest, Earth Syst. Sci. Data, 10, 1367–1401, https://doi.org/10.5194/essd-10-1367-2018, 2018.
Feely, R. A., Sabine, C. L., Byrne, R. H., Millero, F. J., Dickson, A. G., Wanninkhof, R., Murata, A., Miller, L. A., and Greeley, D.: Decadal changes in the aragonite and calcite saturation state of the Pacific Ocean, Global Biogeochem. Cy., 26, GB3001, https://doi.org/10.1029/2011GB004157, 2012.
Feely, R. A., Jiang, L.-Q., Wanninkhof, R., Carter, B. R., Alin, S. R., Bednaršek, N., and Cosca, C. E.: Acidification of the global surface ocean: What we have learned from observations, Oceanography, 36, 120–129, https://doi.org/10.5670/oceanog.2023.222, 2023.
Fleury, E., Petton, S., Benabdelmouna, A., and Pouvreau, S., (coord.): Observatoire national du cycle de vie de l'huître creuse en France, Rapport annuel ECOSCOPA 2022, R.INT.BREST RBE/PFOM/PI 2023-1, https://archimer.ifremer.fr/doc/00840/95240/102991.pdf, last access: 22 December 2023.
Fourrier, M., Coppola, L., Claustre, H., D'Ortenzio, F., Sauzède, R., and Gattuso, J.-P.: A regional neural network approach to estimate water-column nutrient concentrations and carbonate system variables in the Mediterranean Sea: CANYON-MED, Front. Mar. Sci., 7, 620, https://doi.org/10.3389/fmars.2020.00620, 2020.
Fourrier, M., Coppola, L., D'Ortenzio, F., Migon, C., and Gattuso, J.-P.: Impact of intermittent convection in the northwestern Mediterranean Sea on oxygen content, nutrients, and the carbonate system, J. Geophys. Res.-Oceans, 127, e2022JC018615, https://doi.org/10.1029/2022JC018615, 2022.
Fröb, F., Olsen, A., Becker, M., Chafik, L., Johannessen, T., Reverdin, G., and Omar, A.: Wintertime fCO2 variability in the subpolar North Atlantic since 2004, Geophys. Res. Lett., 46, 1580–1590, https://doi.org/10.1029/2018GL080554, 2019.
Gac, J.-P., Marrec, P., Cariou, T., Guillerm, C., Macé, E., Vernet, M., and Bozec, Y.: Cardinal buoys: An opportunity for the study of air-sea CO2 fluxes in coastal ecosystems, Front. Mar. Sci., 7, 712, https://doi.org/10.3389/fmars.2020.00712, 2020.
Gac, J.-P., Marrec, P., Cariou, T., Grosstefan, E., Macé, E., Rimmelin-Maury, P., Vernet, M., and Bozec, Y.: Decadal Dynamics of the CO2 System and Associated Ocean Acidification in Coastal Ecosystems of the North East Atlantic Ocean, Front. Mar. Sci., 8, 688008, https://doi.org/10.3389/fmars.2021.688008, 2021.
Ganachaud, A., Cravatte, S., Sprintall, J., Germineaud, C., Alberty, M., Jeandel, C., Eldin, G., Metzl, N., Bonnet, S., Benavides, M., Heimburger, L.-E, Lefèvre, J., Michael, S., Resing, J., Quéroué, F., Sarthou, G., Rodier, M., Berthelot, H., Baurand, F., Grelet, J., Hasegawa, T., Kessler, W., Kilepak, M., Lacan, F., Privat, E., Send, U., Van Beek, P., Souhaut, M., and Sonke, J. E.:. The Solomon Sea: its circulation, chemistry, geochemistry and biology explored during two oceanographic cruises, Elem. Sci. Anth., 5, 33, https://doi.org/10.1525/elementa.221, 2017.
Gattuso, J.-P., Magnan, A., Billé, R., Cheung, W. W. L., Howes, E. L., Joos, F., Allemand, D., Bopp, L., Cooley, S., Eakin, M., Hoegh-Guldberg, O., Kelly, R. P., Pörtner, H.-O., Rogers, A. D., Baxter, J. M., Laffoley, D., Osborn, D., Rankovic, A., Rochette, J., Sumaila, U. R., Treyer, S., and Turley, C.: Contrasting futures for ocean and society from different anthropogenic CO2 emissions scenarios, Science, 349, aac4722, https://doi.org/10.1126/science.aac4722, 2015.
Gattuso, J.-P., Alliouane, S., and Fischer, P.: High-frequency, year-round time series of the carbonate chemistry in a high-Arctic fjord (Svalbard), Earth Syst. Sci. Data, 15, 2809–2825, https://doi.org/10.5194/essd-15-2809-2023, 2023.
Gemayel, E., Hassoun, A. E. R., Benallal, M. A., Goyet, C., Rivaro, P., Abboud-Abi Saab, M., Krasakopoulou, E., Touratier, F., and Ziveri, P.: Climatological variations of total alkalinity and total dissolved inorganic carbon in the Mediterranean Sea surface waters, Earth Syst. Dynam., 6, 789–800, https://doi.org/10.5194/esd-6-789-2015, 2015.
Golbol M., Boutin J., Merlivat L., Vellucci, V., and Antoine, D.: Dissolved Inorganic Carbon and Total Alkalinity sampled at Boussole site in the Medditerranean Sea, SEANOE [data set], https://doi.org/10.17882/71911, 2020.
Goris, N., Tjiputra, J. F., Olsen, A., Schwinger, J., Lauvset, S. K., and Jeansson, E.: Constraining projection-based estimates of the future North Atlantic carbon uptake, J. Climate, 31, 3959–3978, https://doi.org/10.1175/JCLI-D-17-0564.1, 2018.
Goyet, C., Beauverger, C., Brunet, C., and Poisson, A.: Distribution of carbon dioxide partial pressure in surface waters of the Southwest Indian Ocean, Tellus B, 43, 1–11, https://doi.org/10.3402/tellusb.v43i1.15242, 1991.
Gregor, L. and Gruber, N.: OceanSODA-ETHZ: a global gridded data set of the surface ocean carbonate system for seasonal to decadal studies of ocean acidification, Earth Syst. Sci. Data, 13, 777–808, https://doi.org/10.5194/essd-13-777-2021, 2021.
Gruber, N., Clement, D., Carter, B. R., Feely, R. A., van Heuven, S., Hoppema, M., Ishii, M., Key, R. M., Kozyr, A., Lauvset, S. K., Lo Monaco, C. , Mathis, J. T., Murata, A., Olsen, A., Perez, F. F., Sabine, C. L., Tanhua, T., and Wanninkhof, R.: The oceanic sink for anthropogenic CO2 from 1994 to 2007, Science, 363, 1193–1199, https://doi.org/10.1126/science.aau5153, 2019.
Hagens, M. and Middelburg, J. J.: Attributing seasonal pH variability in surface ocean waters to governing factors, Geophys. Res. Lett., 43, 12528–12537, https://doi.org/10.1002/2016GL071719, 2016.
Henson, S. A., Painter, S. C., Holliday, N. P., Stinchcombe, M. C., and Giering, S. L. C.: Unusual subpolar North Atlantic phytoplankton bloom in 2010: Volcanic fertilization or North Atlantic Oscillation?, J. Geophys. Res.-Oceans, 118, 4771–4780, https://doi.org/10.1002/jgrc.20363, 2013.
Hoegh-Guldberg, O., Mumby, P. J., Hooten, A. J., Steneck, R. S., Greenfield, P., Gomez, E., Harvell, C. D., Sale, P. F., Edwards, A. J., Caldeira, K., Knowlton, N., Eakin, C. M., Iglesias-Prieto, R., Muthiga, N., Bradbury, R. H., Dubi, A., and Hatziolos, M. E.: Coral reefs under rapid climate change and ocean acidification, Science, 14, 1737–1742, https://doi.org/10.1126/science.1152509, 2007.
Hood, E. M. and Merlivat, L.: Annual to interannual variations of fCO2 in the northwestern Mediterranean Sea: Results from hourly measurements made by CARIOCA buoys, 1995–1997, J. Mar. Res., 59, 113–131, https://elischolar.library.yale.edu/journal_of_marine_research/2386 (last access: 22 December 2023), 2001.
Howes, E., Stemmann, L., Assailly, C., Irisson, J.-O., Dima, M., Bijma, J., and Gattuso, J.-P.: Pteropod time series from the North Western Mediterranean (1967–2003): impacts of pH and climate variability, Mar. Ecol. Prog. Ser., 531, 193–206, https://doi.org/10.3354/meps11322, 2015.
Howes, E. L., Eagle, R., Gattuso, J.-P., and Bijma, J.: Comparison of Mediterranean pteropod shell biometrics and ultrastructure from historical (1910 and 1921) and present day (2012) samples provides baseline for monitoring effects of global change, PLoS ONE, 12, e0167891, https://doi.org/10.1371/journal.pone.0167891, 2017.
IPCC: Changing Ocean, Marine Ecosystems, and Dependent Communities, in: The Ocean and Cryosphere in a Changing Climate, Cambridge University Press, 447–588, https://doi.org/10.1017/9781009157964.007, 2022.
Jiang, L.-Q., Feely, R. A., Carter, B. R., Greeley, D. J., Gledhill, D. K., and Arzayus K. M.: Climatological distribution of aragonite saturation state in the global oceans, Global Biogeochem. Cy., 29, 1656–1673, https://doi.org/10.1002/2015GB005198, 2015.
Jiang, L.-Q., Carter, B. R., Feely, R. A., Lauvset, S. K., and Olsen, A.: Surface ocean pH and buffer capacity: past, present and future, Sci. Rep., 9, 18624, https://doi.org/10.1038/s41598-019-55039-4, 2019.
Jiang, L.-Q., Feely, R. A., Wanninkhof, R., Greeley, D., Barbero, L., Alin, S., Carter, B. R., Pierrot, D., Featherstone, C., Hooper, J., Melrose, C., Monacci, N., Sharp, J. D., Shellito, S., Xu, Y.-Y., Kozyr, A., Byrne, R. H., Cai, W.-J., Cross, J., Johnson, G. C., Hales, B., Langdon, C., Mathis, J., Salisbury, J., and Townsend, D. W.: Coastal Ocean Data Analysis Product in North America (CODAP-NA) – an internally consistent data product for discrete inorganic carbon, oxygen, and nutrients on the North American ocean margins, Earth Syst. Sci. Data, 13, 2777–2799, https://doi.org/10.5194/essd-13-2777-2021, 2021.
Jiang, L.-Q., Dunne, J., Carter, B. R., Tjiputra, J. F., Terhaar, J., Sharp, J. D., Olsen, A., Alin, S., Bakker, D. C. E., Feely, R. A., Gattuso, J.-P., Hogan, P., Ilyina, T., Lange, N., Lauvset, S. K., Lewis, E. R., Lovato, T., Palmieri, J., Santana-Falcón, Y., Schwinger, J., Séférian, R., Strand, G., Swart, N., Tanhua, T., Tsujino, H., Wanninkhof, R., Watanabe, M., Yamamoto, A., and Ziehn, T.: Global surface ocean acidification indicators from 1750 to 2100, J. Adv. Model. Earth Sy., 15, e2022MS003563, https://doi.org/10.1029/2022MS003563, 2023a.
Jiang, L. Q., Kozyr, A., Relph, J. M., Ronje, E. I., Kamb, L., Burger, E., Myer, J., Nguyen, L., and Arzayus, K. M.: The Ocean Carbon and Acidification Data System, Sci. Data, 10, 136, https://doi.org/10.1038/s41597-023-02042-0, 2023b.
Jiang, Z.-P., Tyrrell, T., Hydes, D. J., Dai, M., and Hartman, S. E.: Variability of alkalinity and the alkalinity-salinity relationship in the tropical and subtropical surface ocean, Global Biogeochem. Cy., 28, 729–742, https://doi.org/10.1002/2013GB004678, 2014.
Johnson, K. S., Mazloff, M. R., Bif, M. B., Takeshita, Y., Jannasch, H. W., Maurer, T. L., Plant, J. N., Verdy, A., Walz, P. M., Riser, S. C., and Talley, L. D.: Carbon to nitrogen uptake ratios observed across the Southern Ocean by the SOCCOM profiling float array, J. Geophys. Res.-Oceans, 127, e2022JC018859, https://doi.org/10.1029/2022JC018859, 2022.
Joos, F., Hameau, A., Frölicher, T. L., and Stephenson, D. B.: Anthropogenic attribution of the increasing seasonal amplitude in surface ocean pCO2, Geophys. Res. Lett., 50, e2023GL102857, https://doi.org/10.1029/2023GL102857, 2023.
Joyce, T. and Corry, C. (Eds.): Requirements for WOCE Hydrographic Programme Data Reporting, WHPO Publication 90-1 Revision 2, WOCE Report 67/91, Woods Hole, Mass., USA, https://cchdo.github.io/hdo-assets/documentation/manuals/pdf/90_1/title.pdf (last access: 22 December 2023), 1994.
Kapsenberg, L., Alliouane, S., Gazeau, F., Mousseau, L., and Gattuso, J.-P.: Coastal ocean acidification and increasing total alkalinity in the northwestern Mediterranean Sea, Ocean Sci., 13, 411–426, https://doi.org/10.5194/os-13-411-2017, 2017.
Keppler, L., Landschützer, P., Gruber, N., Lauvset, S. K., and Stemmler, I.: Seasonal carbon dynamics in the near-global ocean, Global Biogeochem. Cy., 34, e2020GB006571, https://doi.org/10.1029/2020GB006571, 2020.
Keppler, L., Landschützer, P., Lauvset, S. K., and Gruber, N.: Recent trends and variability in the oceanic storage of dissolved inorganic carbon, Global Biogeochem. Cy., 37, e2022GB007677, https://doi.org/10.1029/2022GB007677, 2023.
Keraghel, M. A., Louanchi, F., Zerrouki, M., Kaci, M. A., Aït-Ameur, N., Labaste, M., Legoff, H., Taillandier, V., Harid, R., and Mortier, L.: Carbonate system properties and anthropogenic carbon inventory in the Algerian Basin during SOMBA cruise (2014): Acidification estimate, Mar. Chem., 221, 103783, https://doi.org/10.1016/j.marchem.2020.103783, 2020.
Key, R. M., Kozyr, A., Sabine, C. L., Lee, K., Wanninkhof, R., Bullister, J. L., Feely, R. A., Millero, F. J., Mordy, C., and Peng, T. H.: A global ocean carbon climatology: Results from Global Data Analysis Project (GLODAP), Global Biogeochem. Cy., 18, GB4031, https://doi.org/10.1029/2004GB002247, 2004.
Key, R. M., Tanhua, T., Olsen, A., Hoppema, M., Jutterström, S., Schirnick, C., van Heuven, S., Kozyr, A., Lin, X., Velo, A., Wallace, D. W. R., and Mintrop, L.: The CARINA data synthesis project: introduction and overview, Earth Syst. Sci. Data, 2, 105–121, https://doi.org/10.5194/essd-2-105-2010, 2010.
Khatiwala, S., Tanhua, T., Mikaloff Fletcher, S., Gerber, M., Doney, S. C., Graven, H. D., Gruber, N., McKinley, G. A., Murata, A., Ríos, A. F., and Sabine, C. L.: Global ocean storage of anthropogenic carbon, Biogeosciences, 10, 2169–2191, https://doi.org/10.5194/bg-10-2169-2013, 2013.
Kitidis, V., Shutler, J. D., Ashton, I., Warren, M., Brown, I., Findlay, H., Hartman, S. E., Sanders, R., Humphreys, M., Kivimäe, C., Greenwood, N., Hull, T., Pearce, D., McGrath, T., Stewart, B. M., Walsham, P., McGovern, E., Bozec, Y., Gac, J.-P., van Heuven, S., Hoppema, M., Schuster, U., Johannessen, T., Omar, A., Lauvset, S. K., Skjelvan, I., Olsen, A., Steinhoff, T., Körtzinger, A., Becker, M., Lefèvre, N., Diverrès, D., Gkritzalis, T., Cattrijsse, A., Petersen, W., Voynova, Y., Chapron, B., Grouazel, A., Land, P. E., Sharples, J., and Nightingale, P. D.: Winter weather controls net influx of atmospheric CO2 on the north-west European shelf, Sci. Rep., 9, 20153, https://doi.org/10.1038/s41598-019-56363-5, 2019.
Koffi, U., Lefèvre, N., Kouadio, G., and Boutin, J.: Surface CO2 parameters and air-sea CO2 fluxes distribution in the eastern equatorial Altantic Ocean, J. Marine Syst., 82, 135–144, https://doi.org/10.1016/j.jmarsys.2010.04.010, 2010.
Koseki, S., Tjiputra, J., Fransner, F., Crespo, Lander R., and Keenlyside, N. S.: Disentangling the impact of Atlantic Niño on sea-air CO2 flux, Nat. Commun., 14, 3649, https://doi.org/10.1038/s41467-023-38718-9, 2023.
Kwiatkowski, L., Torres, O., Bopp, L., Aumont, O., Chamberlain, M., Christian, J. R., Dunne, J. P., Gehlen, M., Ilyina, T., John, J. G., Lenton, A., Li, H., Lovenduski, N. S., Orr, J. C., Palmieri, J., Santana-Falcón, Y., Schwinger, J., Séférian, R., Stock, C. A., Tagliabue, A., Takano, Y., Tjiputra, J., Toyama, K., Tsujino, H., Watanabe, M., Yamamoto, A., Yool, A., and Ziehn, T.: Twenty-first century ocean warming, acidification, deoxygenation, and upper-ocean nutrient and primary production decline from CMIP6 model projections, Biogeosciences, 17, 3439–3470, https://doi.org/10.5194/bg-17-3439-2020, 2020.
Land, P. E., Findlay, H. S., Shutler, J. D., Ashton, I. G., Holding, T., Grouazel, A., Girard-Ardhuin, F., Reul, N., Piolle, J. F., Chapron, B., and Quilfen, Y.: Optimum satellite remote sensing of the marine carbonate system using empirical algorithms in the global ocean, the Greater Caribbean, the Amazon Plume and the Bay of Bengal, Remote Sens. Environ., 235, 111469, https://doi.org/10.1016/j.rse.2019.111469, 2019.
Lauvset, S. K., Gruber, N., Landschützer, P., Olsen, A., and Tjiputra, J.: Trends and drivers in global surface ocean pH over the past 3 decades, Biogeosciences, 12, 1285–1298, https://doi.org/10.5194/bg-12-1285-2015, 2015.
Lauvset, S. K., Carter, B. R., Perez, F. F., Jiang, L.-Q., Feely, R. A., Velo, A., and Olsen, A.: Processes Driving Global Interior Ocean pH Distribution, Global Biogeochem. Cy., 34, e2019GB006229, https://doi.org/10.1029/2019GB006229, 2020.
Lauvset, S. K., Lange, N., Tanhua, T., Bittig, H. C., Olsen, A., Kozyr, A., Álvarez, M., Becker, S., Brown, P. J., Carter, B. R., Cotrim da Cunha, L., Feely, R. A., van Heuven, S., Hoppema, M., Ishii, M., Jeansson, E., Jutterström, S., Jones, S. D., Karlsen, M. K., Lo Monaco, C., Michaelis, P., Murata, A., Pérez, F. F., Pfeil, B., Schirnick, C., Steinfeldt, R., Suzuki, T., Tilbrook, B., Velo, A., Wanninkhof, R., Woosley, R. J., and Key, R. M.: An updated version of the global interior ocean biogeochemical data product, GLODAPv2.2021, Earth Syst. Sci. Data, 13, 5565–5589, https://doi.org/10.5194/essd-13-5565-2021, 2021.
Lauvset, S. K., Lange, N., Tanhua, T., Bittig, H. C., Olsen, A., Kozyr, A., Alin, S., Álvarez, M., Azetsu-Scott, K., Barbero, L., Becker, S., Brown, P. J., Carter, B. R., da Cunha, L. C., Feely, R. A., Hoppema, M., Humphreys, M. P., Ishii, M., Jeansson, E., Jiang, L.-Q., Jones, S. D., Lo Monaco, C., Murata, A., Müller, J. D., Pérez, F. F., Pfeil, B., Schirnick, C., Steinfeldt, R., Suzuki, T., Tilbrook, B., Ulfsbo, A., Velo, A., Woosley, R. J., and Key, R. M.: GLODAPv2.2022: the latest version of the global interior ocean biogeochemical data product, Earth Syst. Sci. Data, 14, 5543–5572, https://doi.org/10.5194/essd-14-5543-2022, 2022.
Lebehot, A. D., Halloran, P. R., Watson, A. J., McNeall, D., Ford, D. A., Landschützer, P., Lauvset, S. K., and Schuster, U.: Reconciling Observation and Model Trends in North Atlantic Surface CO2, Global Biogeochem. Cy., 33, 1204–1222, https://doi.org/10.1029/2019GB006186, 2019.
Lee, K., Wanninkhof, R., Feely, R. A., Millero, F. J., and Peng, T.-H.: Global relationships of total inorganic carbon with temperature and nitrate in surface seawater, Global Biogeochem. Cy., 14, 979–994, https://doi.org/10.1029/1998GB001087, 2000.
Lee, K., Tong, L. T., Millero, F. J., Sabine, C. L., Dickson, A. G., Goyet, C., Park, G. H., Wanninkhof, R., Feely, R. A., and Key, R. M.: Global relationships of total alkalinity with salinity and temperature in surface waters of the world's oceans, Geophys. Res. Lett., 33, L19605, doi10.1029/2006GL027207, 2006.
Lefèvre, N. and Merlivat, L.: Carbon and oxygen net community production in the eastern tropical Atlantic estimated from a moored buoy, Global Biogeochem. Cy., 26, GB1009, https://doi.org/10.1029/2010GB004018, 2012.
Lefèvre, N., Guillot, A., Beaumont, L., and Danguy, T.: Variability of fCO2 in the Eastern Tropical Atlantic from a moored buoy, J. Geophys. Res.-Oceans, 113, C01015, https://doi.org/10.1029/2007JC004146, 2008.
Lefèvre, N., Diverres, D., and Gallois, F.: Origin of CO2 undersaturation in the western tropical Atlantic, Tellus B, 62, 595–607, https://doi.org/10.1111/j.1600-0889.2010.00475.x, 2010.
Lefèvre, N., Veleda, D., Araujo, M., and Caniaux, G.: Variability and trends of carbon parameters at a time series in the eastern tropical Atlantic, Tellus B, 68, 30305, https://doi.org/10.3402/tellusb.v68.30305, 2016.
Lefèvre, N., Mejia, C., Khvorostyanov, D., Beaumont, L., and Koffi, U.: Ocean Circulation Drives the Variability of the Carbon System in the Eastern Tropical Atlantic, Oceans, 2021, 126–148, https://doi.org/10.3390/oceans2010008, 2021.
Lerner, P., Romanou, A., Kelley, M., Romanski, J., Ruedy, R., and Russell, G.: Drivers of Air-Sea CO2 Flux Seasonality and its Long-Term Changes in the NASA-GISS model CMIP6 submission, J. Adv. Model. Earth Sy., 13, e2019MS002028, https://doi.org/10.1029/2019MS002028, 2021.
Leseurre, C., Lo Monaco, C., Reverdin, G., Metzl, N., Fin, J., Olafsdottir, S., and Racapé, V.: Ocean carbonate system variability in the North Atlantic Subpolar surface water (1993–2017), Biogeosciences, 17, 2553–2577, https://doi.org/10.5194/bg-17-2553-2020, 2020.
Leseurre, C., Lo Monaco, C., Reverdin, G., Metzl, N., Fin, J., Mignon, C., and Benito, L.: Summer trends and drivers of sea surface fCO2 and pH changes observed in the southern Indian Ocean over the last two decades (1998–2019), Biogeosciences, 19, 2599–2625, https://doi.org/10.5194/bg-19-2599-2022, 2022.
Lherminier, P., Mercier, H., Gourcuff, C., Alvarez, M., Bacon, S., and Kermabon, C.: Transports across the 2002 Greenland-Portugal OVIDE section and comparison with 1997, J. Geophys. Res., 112, C07003, https://doi.org/10.1029/2006JC003716, 2007.
Li, B. F., Watanabe, Y. W., Hosoda, S., Sato, K., and Nakano, Y.: Quasireal-time and high-resolution spatiotemporal distribution of ocean anthropogenic CO2, Geophys. Res. Lett., 46, 4836–4843, https://doi.org/10.1029/2018GL081639, 2019.
Lombard, F., Bourdin, G., Pesant, S., Agostini, S., Baudena, A., Boissin, E., Cassar, N., Clampitt, M., Conan, P., Da Silva, O., Dimier, C., Douville, E., Elineau, A., Fin, J., Flores, J.-M., Ghiglione, J.-F., Hume, B. C. C., Jalabert, L., John, S. G., Kelly, R. L., Koren, I., Lin, Y., Marie, D., McMinds, R., Mériguet, Z., Metzl, N., Paz-García, D. A., Luiza Pedrotti, M., Poulain, J., Pujo-Pay, M., Ras, J., Reverdin, G., Romac, S., Röttinger, E., Vardi, A., Voolstra, C. R., Moulin, C., Iwankow, G., Banaigs, B., Bowler, C., de Vargas, C., Forcioli, D., Furla, P., Galand, P. E., Gilson, E., Reynaud, S., Sunagawa, S., Thomas, O., Troublé, R., Vega Thurber, R., Wincker, P., Zoccola, D., Allemand, D., Planes, S., Boss, E., and Gorsky, G.: Open science resources from the Tara Pacific expedition across the surface ocean and coral reef ecosystems, Sci. Data, 10, 324, https://doi.org/10.1038/s41597-022-01757-w, 2023.
Lo Monaco, C., Álvarez, M., Key, R. M., Lin, X., Tanhua, T., Tilbrook, B., Bakker, D. C. E., van Heuven, S., Hoppema, M., Metzl, N., Ríos, A. F., Sabine, C. L., and Velo, A.: Assessing the internal consistency of the CARINA database in the Indian sector of the Southern Ocean, Earth Syst. Sci. Data, 2, 51–70, https://doi.org/10.5194/essd-2-51-2010, 2010.
Lo Monaco, C., Metzl, N., Fin, J., and Tribollet, A.: Sea surface measurements of dissolved inorganic carbon (DIC) and total alkalinity (TALK), temperature and salinity during the R/V Marion-Dufresne cruise CLIM-EPARSES (EXPOCODE 35MV20190405) in the Indian Ocean and Mozambique Channel from 2019-04-04 to 2019-04-30, NCEI Accession 0212218, NOAA National Centers for Environmental Information [data set] https://doi.org/10.25921/26rw-w185, 2020.
Lo Monaco, C., Metzl, N., Fin, J., Mignon, C., Cuet, P., Douville, E., Gehlen, M., Trang Chau, T. T., and Tribollet, A.: Distribution and long-term change of the sea surface carbonate system in the Mozambique Channel (1963–2019), Deep-Sea Res. Pt. II, 186–188, 104936, https://doi.org/10.1016/j.dsr2.2021.104936, 2021.
Lueker, T. J., Dickson, A. G., and Keeling, C. D.: Ocean pCO2 calculated from dissolved inorganic carbon, alkalinity, and equations for K1 and K2: validation based on laboratory measurements of CO2 in gas and seawater at equilibrium, Mar. Chem., 70, 105–119, https://doi.org/10.1016/S0304-4203(00)00022-0, 2000.
Ma, D., Gregor, L., and Gruber, N: Four decades of trends and drivers of global surface ocean acidification, Global Biogeochem. Cy., 37, e2023GB007765, https://doi.org/10.1029/2023GB007765, 2023.
Maier, C., Watremez, P., Taviani, M., Weinbauer, M. G., and Gattuso, J.-P.: Calcification rates and the effect of ocean acidification on Mediterranean cold-water corals, P. Roy. Soc. B-Biol. Sci., 279, 1716–1723, https://doi.org/10.1098/rspb.2011.1763, 2012.
Margirier, F., Testor, P., Heslop, E. Mallil, K., Bosse, A., Houpert, L., Mortier, L., Bouin, M.-N., Coppola, L., D’Ortenzio, F., Durrieu de Madron, X., Mourre, B., Prieur, L., Raimbault, P., and Taillandier, V.: Abrupt warming and salinification of intermediate waters interplays with decline of deep convection in the Northwestern Mediterranean Sea, Sci. Rep., 10, 20923, https://doi.org/10.1038/s41598-020-77859-5, 2020.
Marrec, P., Cariou, T., Collin, E., Durand, A., Latimier, M., Macé, E., Morin, P., Raimund, S., Vernet, M., and Bozec, Y.: Seasonal and latitudinal variability of the CO2 system in the western English Channel based on Voluntary Observing Ship (VOS) measurements, Mar. Chem., 155, 29–41, 2013.
Marrec, P., Cariou, T., Latimier, M., Macé, E., Morin, P., Vernet, M., and Bozec, Y.: Spatio-temporal dynamics of biogeochemical processes and air–sea CO2 fluxes in the Western English Channel based on two years of FerryBox deployment, J. Marine Syst., 140, 26–38, https://doi.org/10.1016/j.jmarsys.2014.05.010, 2014.
Marrec, P., Cariou, T., Macé, E., Morin, P., Salt, L. A., Vernet, M., Taylor, B., Paxman, K., and Bozec, Y.: Dynamics of air–sea CO2 fluxes in the northwestern European shelf based on voluntary observing ship and satellite observations, Biogeosciences, 12, 5371–5391, https://doi.org/10.5194/bg-12-5371-2015, 2015.
Marrec, P. and Bozec, Y.: Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, alkalinity and salinity collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer and other instruments from ARMORIQUE in the English Channel from 2012-04-25 to 2013-01-03 (NCEI Accession 0157472), Version 1.1, NOAA National Centers for Environmental Information [data set], https://doi.org/10.3334/CDIAC/OTG.COAST_FERRYBOX_ROSCOFF_PLYMOUTH_2012, 2016a.
Marrec, P. and Bozec, Y.: Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, alkalinity and salinity collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer and other instruments from ARMORIQUE in the English Channel from 2013-03-15 to 2013-12-22 (NCEI Accession 0157444), Version 1.1, NOAA National Centers for Environmental Information [data set], https://doi.org/10.3334/CDIAC/OTG.COAST_FERRYBOX_ROSCOFF_PLYMOUTH_2013, 2016b.
Marrec, P. and Bozec, Y.: Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, alkalinity and salinity collected from surface underway observations using Carbon dioxide (CO2) gas analyzer and other instruments from ARMORIQUE in the English Channel from 2014-03-18 to 2014-10-09 (NCEI Accession 0163193), Version 1.1, NOAA National Centers for Environmental Information [data set], https://doi.org/10.3334/CDIAC/OTG.COAST_FERRYBOX_ROSCOFF_PLYMOUTH_2014, 2017.
Mazloff, M. R., Verdy, A., Gille, S. T., Johnson, K. S., Cornuelle, B. D., and Sarmiento, J.: Southern Ocean acidification revealed by biogeochemical-Argo floats, J. Geophys. Res.-Oceans, 128, e2022JC019530, https://doi.org/10.1029/2022JC019530, 2023.
McCulloch, M., Trotter, J., Montagna, P., Falter, J., Dunbar, R., Freiwald, A., Försterra, G., López Correa, M., Maier, C., Rüggeberg, A., and Taviani, M.: Resilience of cold-water scleractinian corals to ocean acidification: Boron isotopic systematics of pH and saturation state up-regulation, Geochim. Cosmochim. Ac., 87, 21–34, https://doi.org/10.1016/j.gca.2012.03.027, 2012.
McKinley, G. A., Fay, A. R., Takahashi, T., and Metzl, N.: Convergence of atmospheric and North Atlantic carbon dioxide trends on multidecadal timescales, Nat. Geosci., 4, 606–610, https://doi.org/10.1038/NGEO1193, 2011.
McKinley, G. A., Ritzer, A. L., and Lovenduski, N. S.: Mechanisms of northern North Atlantic biomass variability, Biogeosciences, 15, 6049–6066, https://doi.org/10.5194/bg-15-6049-2018, 2018.
Meier, K. J. S., Beaufort, L., Heussner, S., and Ziveri, P.: The role of ocean acidification in Emiliania huxleyi coccolith thinning in the Mediterranean Sea, Biogeosciences, 11, 2857–2869, https://doi.org/10.5194/bg-11-2857-2014, 2014.
Mercier, H., Lherminier, P., Sarafanov, A., Gaillard, F., Daniault, N., Desbruyères, D., Falina, A., Ferron, B., Huck, T., and Thierry, V.: Variability of the meridional overturning circulation at the Greenland-Portugal Ovide section from 1993 to 2010, Prog. Oceanogr., 132, 250–261, https://doi.org/10.1016/j.pocean.2013.11.001, 2015.
Merlivat, L., Boutin, J., Antoine, D., Beaumont, L., Golbol, M., and Vellucci, V.: Increase of dissolved inorganic carbon and decrease in pH in near-surface waters in the Mediterranean Sea during the past two decades, Biogeosciences, 15, 5653–5662, https://doi.org/10.5194/bg-15-5653-2018, 2018.
Metzl, N., Brunet, C., Jabaud-Jan, A., Poisson, A., and Schauer, B.: Summer and winter air-sea CO2 fluxes in the Southern Ocean, Deep-Sea Res. Pt. I, 53, 1548–1563, https://doi.org/10.1016/j.dsr.2006.07.006, 2006.
Metzl, N., Tilbrook, B., Bakker, D., Le Quéré, C., Doney, S., Feely, R., Hood M., and Dargaville, R.: Global Changes in Ocean Carbon: Variability and Vulnerability, Eos, 88, 286–287, https://doi.org/10.1029/2007EO280005, 2007.
Metzl, N., Corbière, A., Reverdin, G., Lenton, A., Takahashi, T., Olsen, A., Johannessen, T., Pierrot, D., Wanninkhof, R., Ólafsdóttir, S. R., Olafsson, J., and Ramonet, M.: Recent acceleration of the sea surface fCO2 growth rate in the North Atlantic subpolar gyre (1993–2008) revealed by winter observations, Global Biogeochem. Cy., 24, GB4004, https://doi.org/10.1029/2009GB003658, 2010.
Metzl, N., Ferron, B., Lherminier, P., Sarthou, G., and Thierry, V.: Discrete profile measurements of dissolved inorganic carbon (DIC), total alkalinity (TALK), temperature and salinity during the multiple ships Observatoire de la variabilité interannuelle et décennale en Atlantique Nord (OVIDE) project, OVIDE-2006, OVIDE-2008, OVIDE-2010, OVIDE-2012, OVIDE-2014 cruises in the North Atlantic Ocean from 2006-05-23 to 2014-06-30 (NCEI Accession 0177219), Version 1.1, NOAA National Centers for Environmental Information [data set], https://doi.org/10.25921/v0qt-ms48, 2018.
Metzl, N., Fin, J., Lo Monaco, C., et al.: A synthesis of total alkalinity and dissolved inorganic carbon measurements in the global ocean (1993–2022) SNAPO-CO2-V1 dataset, SEANOE [data set], https://doi.org/10.17882/95414, 2023.
Mignot, A., Claustre, H., Cossarini, G., D'Ortenzio, F., Gutknecht, E., Lamouroux, J., Lazzari, P., Perruche, C., Salon, S., Sauzède, R., Taillandier, V., and Teruzzi, A.: Using machine learning and Biogeochemical-Argo (BGC-Argo) floats to assess biogeochemical models and optimize observing system design, Biogeosciences, 20, 1405–1422, https://doi.org/10.5194/bg-20-1405-2023, 2023.
Millero, F. J., Lee, K., and Roche, M.: Distribution of alkalinity in the surface waters of the major oceans, Mar. Chem., 60, 111–130, https://doi.org/10.1016/S0304-4203(97)00084-4, 1998.
Mongwe, N. P., Vichi, M., and Monteiro, P. M. S.: The seasonal cycle of pCO2 and CO2 fluxes in the Southern Ocean: diagnosing anomalies in CMIP5 Earth system models, Biogeosciences, 15, 2851–2872, https://doi.org/10.5194/bg-15-2851-2018, 2018.
Moutin, T., Wagener, T., Caffin, M., Fumenia, A., Gimenez, A., Baklouti, M., Bouruet-Aubertot, P., Pujo-Pay, M., Leblanc, K., Lefevre, D., Helias Nunige, S., Leblond, N., Grosso, O., and de Verneil, A.: Nutrient availability and the ultimate control of the biological carbon pump in the western tropical South Pacific Ocean, Biogeosciences, 15, 2961–2989, https://doi.org/10.5194/bg-15-2961-2018, 2018.
Newton, J. A., Feely, R. A., Jewett, E. B., Williamson, P., and Mathis, J.: Global Ocean Acidification Observing Network: Requirements and Governance Plan. Second Edition, GOA-ON, https://www.iaea.org/sites/default/files/18/06/goa-on-second-edition-2015.pdf (last access: 22 December 2023), 2015.
Nykjaer, L.: Mediterranean Sea surface warming 1985–2006, Clim. Res., 39, 11–17, https://doi.org/10.3354/cr00794, 2009.
OCADS: Coastal Carbon Data, https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/coastal_carbon_data.html, last access: 22 December 2023.
Olafsson, J., Olafsdottir, S. R., Benoit-Cattin, A., Danielsen, M., Arnarson, T. S., and Takahashi, T.: Rate of Iceland Sea acidification from time series measurements, Biogeosciences, 6, 2661–2668, https://doi.org/10.5194/bg-6-2661-2009, 2009.
Olivier, L., Boutin, J., Reverdin, G., Lefèvre, N., Landschützer, P., Speich, S., Karstensen, J., Labaste, M., Noisel, C., Ritschel, M., Steinhoff, T., and Wanninkhof, R.: Wintertime process study of the North Brazil Current rings reveals the region as a larger sink for CO2 than expected, Biogeosciences, 19, 2969–2988, https://doi.org/10.5194/bg-19-2969-2022, 2022.
Olsen, A., Key, R. M., van Heuven, S., Lauvset, S. K., Velo, A., Lin, X., Schirnick, C., Kozyr, A., Tanhua, T., Hoppema, M., Jutterström, S., Steinfeldt, R., Jeansson, E., Ishii, M., Pérez, F. F., and Suzuki, T.: The Global Ocean Data Analysis Project version 2 (GLODAPv2) – an internally consistent data product for the world ocean, Earth Syst. Sci. Data, 8, 297–323, https://doi.org/10.5194/essd-8-297-2016, 2016.
Olsen, A., Lange, N., Key, R. M., Tanhua, T., Álvarez, M., Becker, S., Bittig, H. C., Carter, B. R., Cotrim da Cunha, L., Feely, R. A., van Heuven, S., Hoppema, M., Ishii, M., Jeansson, E., Jones, S. D., Jutterström, S., Karlsen, M. K., Kozyr, A., Lauvset, S. K., Lo Monaco, C., Murata, A., Pérez, F. F., Pfeil, B., Schirnick, C., Steinfeldt, R., Suzuki, T., Telszewski, M., Tilbrook, B., Velo, A., and Wanninkhof, R.: GLODAPv2.2019 – an update of GLODAPv2, Earth Syst. Sci. Data, 11, 1437–1461, https://doi.org/10.5194/essd-11-1437-2019, 2019.
Olsen, A., Lange, N., Key, R. M., Tanhua, T., Bittig, H. C., Kozyr, A., Álvarez, M., Azetsu-Scott, K., Becker, S., Brown, P. J., Carter, B. R., Cotrim da Cunha, L., Feely, R. A., van Heuven, S., Hoppema, M., Ishii, M., Jeansson, E., Jutterström, S., Landa, C. S., Lauvset, S. K., Michaelis, P., Murata, A., Pérez, F. F., Pfeil, B., Schirnick, C., Steinfeldt, R., Suzuki, T., Tilbrook, B., Velo, A., Wanninkhof, R., and Woosley, R. J.: An updated version of the global interior ocean biogeochemical data product, GLODAPv2.2020, Earth Syst. Sci. Data, 12, 3653–3678, https://doi.org/10.5194/essd-12-3653-2020, 2020.
Orr, J. C., Epitalon, J.-M., and Gattuso, J.-P.: Comparison of ten packages that compute ocean carbonate chemistry, Biogeosciences, 12, 1483–1510, https://doi.org/10.5194/bg-12-1483-2015, 2015.
Orr, J. C., Epitalon, J.-M., Dickson, A. G., and Gattuso, J.-P.: Routine uncertainty propagation for the marine carbon dioxide system, Mar. Chem., 207, 84–107, https://doi.org/10.1016/j.marchem.2018.10.006, 2018.
Parard, G., Lefèvre, N., and Boutin, J.: Sea water fugacity of CO2 at the PIRATA mooring at 6∘ S, 10∘ W, Tellus B, 62, 636–648, https://doi.org/10.1111/j.1600-0889.2010.00503.x, 2010.
Pérez, F. F., Vázquez-Rodríguez, M., Mercier, H., Velo, A., Lherminier, P., and Ríos, A. F.: Trends of anthropogenic CO2 storage in North Atlantic water masses, Biogeosciences, 7, 1789–1807, https://doi.org/10.5194/bg-7-1789-2010, 2010.
Pérez, F. F., Mercier, H., Vazquez-Rodriguez, M., Lherminier, P., Velo, A., Pardo, P., Roson, G., and Rios, A.: Reconciling air-sea CO2 fluxes and anthropogenic CO2 budgets in a changing North Atlantic, Nat. Geosci., 6, 146–152, https://doi.org/10.1038/ngeo1680, 2013.
Pérez, F., Fontela, M., García-Ibáñez, M., Mercier, H., Velo, A., Lherminier, P., Zunino, P., de la Paz, M., Alonso-Pérez, F., Guallart, E. F., and Padin, X. A.: Meridional overturning circulation conveys fast acidification to the deep Atlantic Ocean, Nature, 554, 515–518, https://doi.org/10.1038/nature25493, 2018.
Petrenko, A. A., Doglioli, A. M., Nencioli, F., Kersalé, M., Hu, Z., and d'Ovidio, F.: A review of the LATEX project: mesoscale to submesoscale processes in a coastal environment, Ocean Dynam., 67, 513–533, https://doi.org/10.1007/s10236-017-1040-9, 2017.
Petton, S., Pouvreau, S., and Fleury, E.: ECOSCOPA network: high frequency environmental databasem SEANOE [data set], https://doi.org/10.17882/86131, 2023.
Pfeil, B., Olsen, A., Bakker, D. C. E., Hankin, S., Koyuk, H., Kozyr, A., Malczyk, J., Manke, A., Metzl, N., Sabine, C. L., Akl, J., Alin, S. R., Bates, N., Bellerby, R. G. J., Borges, A., Boutin, J., Brown, P. J., Cai, W.-J., Chavez, F. P., Chen, A., Cosca, C., Fassbender, A. J., Feely, R. A., González-Dávila, M., Goyet, C., Hales, B., Hardman-Mountford, N., Heinze, C., Hood, M., Hoppema, M., Hunt, C. W., Hydes, D., Ishii, M., Johannessen, T., Jones, S. D., Key, R. M., Körtzinger, A., Landschützer, P., Lauvset, S. K., Lefèvre, N., Lenton, A., Lourantou, A., Merlivat, L., Midorikawa, T., Mintrop, L., Miyazaki, C., Murata, A., Nakadate, A., Nakano, Y., Nakaoka, S., Nojiri, Y., Omar, A. M., Padin, X. A., Park, G.-H., Paterson, K., Perez, F. F., Pierrot, D., Poisson, A., Ríos, A. F., Santana-Casiano, J. M., Salisbury, J., Sarma, V. V. S. S., Schlitzer, R., Schneider, B., Schuster, U., Sieger, R., Skjelvan, I., Steinhoff, T., Suzuki, T., Takahashi, T., Tedesco, K., Telszewski, M., Thomas, H., Tilbrook, B., Tjiputra, J., Vandemark, D., Veness, T., Wanninkhof, R., Watson, A. J., Weiss, R., Wong, C. S., and Yoshikawa-Inoue, H.: A uniform, quality controlled Surface Ocean CO2 Atlas (SOCAT), Earth Syst. Sci. Data, 5, 125–143, https://doi.org/10.5194/essd-5-125-2013, 2013.
Pilcher, D. J., Brody, S. R., Johnson, L., and Bronselaer, B.: Assessing the abilities of CMIP5 models to represent the seasonal cycle of surface ocean pCO2, J. Geophys. Res.-Oceans, 120, 4625–4637, https://doi.org/10.1002/2015JC010759, 2015.
Poisson, A., Culkin, F., and Ridout, P.: Intercomparison of CO2 measurements, Deep-Sea Res. Pt. I, 37, 1647–1650, https://doi.org/10.1016/0198-0149(90)90067-6, 1990.
Racapé, V., Metzl, N., Pierre, C., Reverdin, G., Quay, P. D., and Olafsdottir, S. R.: The seasonal cycle of δ3CDIC in the North Atlantic subpolar gyre, Biogeosciences, 11, 1683–1692, https://doi.org/10.5194/bg-11-1683-2014, 2014.
Revelle, R. and Suess, H. E.: Carbon dioxide exchange between atmosphere and ocean and the question of an increase of atmospheric CO2 during the past decades, Tellus, 9, 18–27, https://doi.org/10.1111/j.2153-3490.1957.tb01849.x, 1957.
Reverdin, G., Metzl, N., Olafsdottir, S., Racapé, V., Takahashi, T., Benetti, M., Valdimarsson, H., Benoit-Cattin, A., Danielsen, M., Fin, J., Naamar, A., Pierrot, D., Sullivan, K., Bringas, F., and Goni, G.: SURATLANT: a 1993–2017 surface sampling in the central part of the North Atlantic subpolar gyre, Earth Syst. Sci. Data, 10, 1901–1924, https://doi.org/10.5194/essd-10-1901-2018, 2018.
Ridame, C., Dekaezemacker, J., Guieu, C., Bonnet, S., L'Helguen, S., and Malien, F.: Contrasted Saharan dust events in LNLC environments: impact on nutrient dynamics and primary production, Biogeosciences, 11, 4783–4800, https://doi.org/10.5194/bg-11-4783-2014, 2014.
Robertson, J. E., Robinson, C., Turner, D. R., Holligan, P., Watson, A. J., Boyd, P., Fernandez, E., and Finch, M.: The impact of a coccolithophore bloom on oceanic carbon uptake in the northeast Atlantic during summer 1991, Deep-Sea Res. Pt. I, 41, 297–314, 1994.
Rödenbeck, C., Keeling, R. F., Bakker, D. C. E., Metzl, N., Olsen, A., Sabine, C., and Heimann, M.: Global surface-ocean pCO2 and sea–air CO2 flux variability from an observation-driven ocean mixed-layer scheme, Ocean Sci., 9, 193–216, https://doi.org/10.5194/os-9-193-2013, 2013.
Rödenbeck, C., Bakker, D. C. E., Gruber, N., Iida, Y., Jacobson, A. R., Jones, S., Landschützer, P., Metzl, N., Nakaoka, S., Olsen, A., Park, G.-H., Peylin, P., Rodgers, K. B., Sasse, T. P., Schuster, U., Shutler, J. D., Valsala, V., Wanninkhof, R., and Zeng, J.: Data-based estimates of the ocean carbon sink variability – first results of the Surface Ocean pCO2 Mapping intercomparison (SOCOM), Biogeosciences, 12, 7251–7278, https://doi.org/10.5194/bg-12-7251-2015, 2015.
Sabine, C. L., Feely, R. A., Gruber, N., Key, R. M., Lee, K., Bullister, J. L., Wanninkhof, R., Wong, C. S., Wallace, D. W. R., Tilbrook, B., Millero, F. J., Peng, T.-H., Kozyr, A., Ono, T., and Rios, A. F.: The Oceanic Sink for Anthropogenic CO2, Science, 305, 367–371, https://doi.org/10.1126/science.1097403, 2004.
Sabine, C. L., Hankin, S., Koyuk, H., Bakker, D. C. E., Pfeil, B., Olsen, A., Metzl, N., Kozyr, A., Fassbender, A., Manke, A., Malczyk, J., Akl, J., Alin, S. R., Bellerby, R. G. J., Borges, A., Boutin, J., Brown, P. J., Cai, W.-J., Chavez, F. P., Chen, A., Cosca, C., Feely, R. A., González-Dávila, M., Goyet, C., Hardman-Mountford, N., Heinze, C., Hoppema, M., Hunt, C. W., Hydes, D., Ishii, M., Johannessen, T., Key, R. M., Körtzinger, A., Landschützer, P., Lauvset, S. K., Lefèvre, N., Lenton, A., Lourantou, A., Merlivat, L., Midorikawa, T., Mintrop, L., Miyazaki, C., Murata, A., Nakadate, A., Nakano, Y., Nakaoka, S., Nojiri, Y., Omar, A. M., Padin, X. A., Park, G.-H., Paterson, K., Perez, F. F., Pierrot, D., Poisson, A., Ríos, A. F., Salisbury, J., Santana-Casiano, J. M., Sarma, V. V. S. S., Schlitzer, R., Schneider, B., Schuster, U., Sieger, R., Skjelvan, I., Steinhoff, T., Suzuki, T., Takahashi, T., Tedesco, K., Telszewski, M., Thomas, H., Tilbrook, B., Vandemark, D., Veness, T., Watson, A. J., Weiss, R., Wong, C. S., and Yoshikawa-Inoue, H.: Surface Ocean CO2 Atlas (SOCAT) gridded data products, Earth Syst. Sci. Data, 5, 145–153, https://doi.org/10.5194/essd-5-145-2013, 2013.
Salt, L. A., Beaumont, L., Blain, S., Bucciarelli, E., Grossteffan, E., Guillot, A., L'Helguen, S., Merlivat, L., Répécaud, M., Quéméner, L., Rimmelin-Maury, P., Tréguer, P., and Bozec, Y.: The annual and seasonal variability of the carbonate system in the Bay of Brest (Northwest Atlantic Shelf, 2008–2014), Mar. Chem., 187, 1–15, https://doi.org/10.1016/j.marchem.2016.09.003, 2016.
Sasse, T. P., McNeil, B. I., and Abramowitz, G.: A novel method for diagnosing seasonal to inter-annual surface ocean carbon dynamics from bottle data using neural networks, Biogeosciences, 10, 4319–4340, https://doi.org/10.5194/bg-10-4319-2013, 2013.
Sauzède, R., Claustre, H., Pasqueron de Fommervault, O., Bittig, H., Gattuso, J.-P., Legendre, L., and Johnson, K. S.: Estimates of water-column nutrients and carbonate system parameters in the global ocean: A novel approach based on neural networks, Front. Mar. Sci., 4, 128, https://doi.org/10.3389/fmars.2017.00128, 2017.
Schlitzer, R.: Ocean Data View, http://odv.awi.de (last access: 13 March 2019), 2018.
Schneider, A., Wallace, D. W. R., and Körtzinger, A.: Alkalinity of the Mediterranean Sea, Geophys. Res. Lett., 34, L15608, https://doi.org/10.1029/2006GL028842, 2007.
Schuster, U., Watson, A. J., Bates, N., Corbière, A., Gonzalez-Davila, M., Metzl, N., Pierrot, D., and Santana-Casiano, M.: Trends in North Atlantic sea surface pCO2 from 1990 to 2006, Deep-Sea Res. Pt. II, 56, 620–629, https://doi.org/10.1016/j.dsr2.2008.12.011, 2009.
Schuster, U., McKinley, G. A., Bates, N., Chevallier, F., Doney, S. C., Fay, A. R., González-Dávila, M., Gruber, N., Jones, S., Krijnen, J., Landschützer, P., Lefèvre, N., Manizza, M., Mathis, J., Metzl, N., Olsen, A., Rios, A. F., Rödenbeck, C., Santana-Casiano, J. M., Takahashi, T., Wanninkhof, R., and Watson, A. J.: An assessment of the Atlantic and Arctic sea–air CO2 fluxes, 1990–2009, Biogeosciences, 10, 607–627, https://doi.org/10.5194/bg-10-607-2013, 2013.
Seelmann, K., Steinhoff, T., Aßmann, S., and Körtzinger, A.:. Enhance Ocean Carbon Observations: Successful Implementation of a Novel Autonomous Total Alkalinity Analyzer on a Ship of Opportunity, Front. Mar. Sci., 7, 571301, https://doi.org/10.3389/fmars.2020.571301, 2020.
Sims, R. P., Holding, T. M., Land, P. E., Piolle, J.-F., Green, H. L., and Shutler, J. D.: OceanSODA-UNEXE: a multi-year gridded Amazon and Congo River outflow surface ocean carbonate system dataset, Earth Syst. Sci. Data, 15, 2499–2516, https://doi.org/10.5194/essd-15-2499-2023, 2023.
Skjelvan, I., Lauvset, S. K., Johannessen, T., Gundersen, K., and Skagseth, Ø.: Decadal trends in Ocean Acidification from the Ocean Weather Station M in the Norwegian Sea, J. Marine Syst., 234, 103775, https://doi.org/10.1016/j.jmarsys.2022.103775, 2022.
Takahashi, T., Sutherland, S. C., Sweeney, C., Poisson, A., Metzl, N., Tilbrook, B., Bates, N., Wanninkhof, R., Feely, R. A., Sabine, C., Olafsson, J., and Nojiri, Y.: Global Sea-Air CO2 Flux Based on Climatological Surface Ocean pCO2, and Seasonal Biological and Temperature Effect, Deep-Sea Res. Pt. II, 49, 1601–1622, https://doi.org/10.1016/S0967-0645(02)00003-6, 2002.
Takahashi, T., Sutherland, S. C., Wanninkhof, R., Sweeney, C., Feely, R. A., Chipman, D. W., Hales, B., Friederich, G., Chavez, F., Sabine, C., Watson, A. J., Bakker, D. C., Schuster, U., Metzl, N., Yoshikawa-Inoue, H., Ishii, M., Midorikawa, T., Nojiri, Y., Körtzinger, A., Steinhoff, T., Hoppema, M., Olafsson, J., Arnarson, T. S., Tilbrook, B., Johannessen, T., Olsen, A., Bellerby, R., Wong, C., Delille, B., Bates, N., and de Baar, H. J.: Climatological mean and decadal change in surface ocean pCO2, and net sea air CO2 flux over the global oceans, Deep-Sea Res. Pt. II, 56, 554–577, https://doi.org/10.1016/j.dsr2.2008.12.009, 2009.
Takahashi, T., Sutherland, S. C., Chipman, D. W., Goddard, J. G., Ho, C., Newberger, T., Sweeney, C., and Munro, D. R.: Climatological distributions of pH, pCO2, total CO2, alkalinity, and CaCO3 saturation in the global surface ocean, and temporal changes at selected locations, Mar. Chem., 164, 95–125, https://doi.org/10.1016/j.marchem.2014.06.004, 2014.
Tanhua, T., Pouliquen, S., Hausman, J., O'Brien, K., Bricher, P., de Bruin, T., Buck, J. J. H., Burger, E. F., Carval, T., Casey, K. S., Diggs, S., Giorgetti, A., Glaves, H., Harscoat, V., Kinkade, D., Muelbert, J. H., Novellino, A., Pfeil, B., Pulsifer, P. L., Van de Putte, A., Robinson, E., Schaap, D., Smirnov, A., Smith, N., Snowden, D., Spears, T., Stall, S., Tacoma, M., Thijsse, P., Tronstad, S., Vandenberghe, T., Wengren, M., Wyborn, L., and Zhao, Z.: Ocean FAIR Data Services, Front. Mar. Sci., 6, 440, https://doi.org/10.3389/fmars.2019.00440, 2019.
Tanhua, T., Lauvset, S. K., Lange, N. et al.: A vision for FAIR ocean data products, Commun. Earth Environ., 2, 136, https://doi.org/10.1038/s43247-021-00209-4, 2021.
Testor, P., Bosse, A., and Coppola, L.: MOOSE-GE, https://doi.org/10.18142/235, 2010.
Tilbrook, B., Jewett, E. B., DeGrandpre, M. D., Hernandez-Ayon, J. M., Feely, R. A., Gledhill, D. K., Hansson, L., Isensee, K., Kurz, M. L., Newton, J. A., Siedlecki, S. A., Chai, F., Dupont, S., Graco, M., Calvo, E., Greeley, D., Kapsenberg, L., Lebrec, M., Pelejero, C., Schoo, K. L., and Telszewski, M.: An Enhanced Ocean Acidification Observing Network: From People to Technology to Data Synthesis and Information Exchange, Front. Mar. Sci., 6, 337, https://doi.org/10.3389/fmars.2019.00337, 2019.
Touratier, F., and Goyet, C.: Decadal evolution of anthropogenic CO2 in the north western Mediterranean Sea from the mid-1990's to the mid-2000's, Deep-Sea Res. Pt I, 56, 1708–1716, https://doi.org/10.1016/j.dsr.2009.05.015, 2009.
Touratier, F., Azouzi, L., and Goyet, C.: CFC-11, Δ14C and 3H tracers as a means to assess anthropogenic CO2 concentrations in the ocean, Tellus B, 59, 318–325, https://doi.org/10.1111/j.1600-0889.2006.00247.x, 2007.
Touratier, F., Goyet, C., Houpert, L., Durrieu de Madron, X., Lefèvre, D., Stabholz, M., and Guglielmi, V.: Role of deep convection on anthropogenic CO2 sequestration in the Gulf of Lions (northwestern Mediterranean Sea), Deep-Sea Res. Pt. I, 113, 33–48, https://doi.org/10.1016/j.dsr.2016.04.003, 2016.
Turk, D., Dowd, M., Lauvset, S. K., Koelling, J., Alonso-Pérez, F., and Pérez, F. F.: Can Empirical Algorithms Successfully Estimate Aragonite Saturation State in the Subpolar North Atlantic?, Front. Mar. Sci., 4, 385, https://doi.org/10.3389/fmars.2017.00385, 2017.
UNESCO: Intercomparison of total alkalinity and total inorganic carbon determinations in seawater, UNESCO Tech. Pap. Mar. Sci., 59, https://www.jodc.go.jp/jodcweb/info/ioc_doc/UNESCO_tech/090199eb.pdf (last access: 22 December 2023), 1990.
UNESCO: Reference materials for oceanic carbon dioxide measurements, UNESCO Tech. Pap. Mar. Sci., 60, https://www.jodc.go.jp/jodcweb/info/ioc_doc/UNESCO_tech/090200eb.pdf (last access: 22 December 2023), 1991.
United Nations: The Sustainable Development Goals 2020, 68 pp. https://unstats.un.org/sdgs/report/2020/ (last access: 22 December 2023), 2020.
Vangriesheim A., Pierre, C., Aminot, A., Metzl, N., Baurand, F., and Caprais, J.-C.: The influence of Congo river discharges in the surface and deep layers of the Gulf of Guinea, Deep-Sea Res. Pt. II, https://doi.org/10.1016/j.dsr2.2009.04.002, 2009.
Vázquez-Rodríguez, M., Pérez, F. F., Velo, A., Ríos, A. F., and Mercier, H.: Observed acidification trends in North Atlantic water masses, Biogeosciences, 9, 5217–5230, https://doi.org/10.5194/bg-9-5217-2012, 2012.
Velo, A., Perez, F. F., Brown, P., Tanhua, T., Schuster, U., and Key, R. M.: CARINA alkalinity data in the Atlantic Ocean, Earth Syst. Sci. Data, 1, 45–61, https://doi.org/10.5194/essd-1-45-2009, 2009.
von Schuckmann, K., Cheng, L., Palmer, M. D., Hansen, J., Tassone, C., Aich, V., Adusumilli, S., Beltrami, H., Boyer, T., Cuesta-Valero, F. J., Desbruyères, D., Domingues, C., García-García, A., Gentine, P., Gilson, J., Gorfer, M., Haimberger, L., Ishii, M., Johnson, G. C., Killick, R., King, B. A., Kirchengast, G., Kolodziejczyk, N., Lyman, J., Marzeion, B., Mayer, M., Monier, M., Monselesan, D. P., Purkey, S., Roemmich, D., Schweiger, A., Seneviratne, S. I., Shepherd, A., Slater, D. A., Steiner, A. K., Straneo, F., Timmermans, M.-L., and Wijffels, S. E.: Heat stored in the Earth system: where does the energy go?, Earth Syst. Sci. Data, 12, 2013–2041, https://doi.org/10.5194/essd-12-2013-2020, 2020.
von Schuckmann, K., Minière, A., Gues, F., Cuesta-Valero, F. J., Kirchengast, G., Adusumilli, S., Straneo, F., Ablain, M., Allan, R. P., Barker, P. M., Beltrami, H., Blazquez, A., Boyer, T., Cheng, L., Church, J., Desbruyeres, D., Dolman, H., Domingues, C. M., García-García, A., Giglio, D., Gilson, J. E., Gorfer, M., Haimberger, L., Hakuba, M. Z., Hendricks, S., Hosoda, S., Johnson, G. C., Killick, R., King, B., Kolodziejczyk, N., Korosov, A., Krinner, G., Kuusela, M., Landerer, F. W., Langer, M., Lavergne, T., Lawrence, I., Li, Y., Lyman, J., Marti, F., Marzeion, B., Mayer, M., MacDougall, A. H., McDougall, T., Monselesan, D. P., Nitzbon, J., Otosaka, I., Peng, J., Purkey, S., Roemmich, D., Sato, K., Sato, K., Savita, A., Schweiger, A., Shepherd, A., Seneviratne, S. I., Simons, L., Slater, D. A., Slater, T., Steiner, A. K., Suga, T., Szekely, T., Thiery, W., Timmermans, M.-L., Vanderkelen, I., Wjiffels, S. E., Wu, T., and Zemp, M.: Heat stored in the Earth system 1960–2020: where does the energy go?, Earth Syst. Sci. Data, 15, 1675–1709, https://doi.org/10.5194/essd-15-1675-2023, 2023.
Wagener, T., Metzl, N., Caffin, M., Fin, J., Helias Nunige, S., Lefevre, D., Lo Monaco, C., Rougier, G., and Moutin, T.: Carbonate system distribution, anthropogenic carbon and acidification in the western tropical South Pacific (OUTPACE 2015 transect), Biogeosciences, 15, 5221–5236, https://doi.org/10.5194/bg-15-5221-2018, 2018a.
Wagener, T., Metzl, N., Caffin, M., Fin, J., Helias Nunige, S., Lefèvre, D., Lo Monaco, C., Rougier, G., and Moutin, T.: Discrete profile measurements of dissolved inorganic carbon (DIC), total alkalinity (TALK), temperature, salinity and other parameters during the R/V L'Atalante “Oligotrophy from Ultra-oligoTrophy PACific Experiment” (OUTPACE) cruise (EXPOCODE 35A320150218) in the South Pacific Ocean from 2015-02-18 to 2015-04-03 (NCEI Accession 0177706), Version 1.1, NOAA National Centers for Environmental Information [data set], https://doi.org/10.25921/wbkb-0q19, 2018b.
Walton, D. W. H. and Thomas, J.: Cruise Report – Antarctic Circumnavigation Expedition (ACE) 20th December 2016–19th March 2017 (1.0), Zenodo [data set], https://doi.org/10.5281/zenodo.1443511, 2018.
Wanninkhof, R., Park, G.-H., Takahashi, T., Sweeney, C., Feely, R., Nojiri, Y., Gruber, N., Doney, S. C., McKinley, G. A., Lenton, A., Le Quéré, C., Heinze, C., Schwinger, J., Graven, H., and Khatiwala, S.: Global ocean carbon uptake: magnitude, variability and trends, Biogeosciences, 10, 1983–2000, https://doi.org/10.5194/bg-10-1983-2013, 2013.
Watson, A. J., Schuster, U., Bakker, D. C. E., Bates, N., Corbiere, A., Gonzalez-Davila, M., Freidrich, T., Hauck, J., Heinze, C., Johannessen, T., Koertzinger, A., Metzl, N., Olafsson, J., Olsen, A., Oschlies, A., Padin, X., Pfeil, B., Rios, A., Santana-Casiano, M, Steinhoff, T., Telszewski, M., Wallace, D. W. R., and Wanninkhof, R.: Tracking the variable North Atlantic sink for atmospheric CO2, Science, 326, 1391, https://doi.org/10.1126/science.1177394, 2009.
Watson, A. J., Schuster, U., Shutler, J. D., Holding, T., Ashton, I. G. C., Landschützer, P., Woolf, D. K., and Goddijn-Murphy, L.: Revised estimates of ocean-atmosphere CO2 flux are consistent with ocean carbon inventory, Nat. Commun., 11, 4422, https://doi.org/10.1038/s41467-020-18203-3, 2020.
Williams, N. L., Juranek, L. W., Johnson, K. S., Feely, R. A., Riser, S. C., Talley, L. D., Russell, J. L., Sarmiento, J. L., and Wanninkhof, R.: Empirical algorithms to estimate water column pH in the Southern Ocean, Geophys. Res. Lett., 43, 3415–3422, https://doi.org/10.1002/2016GL068539, 2016.
Williams, N. L., Juranek, L. W., Feely, R. A., Johnson, K. S., Sarmiento, J. L., Talley, L. D., Dickson, A. G., Gray, A. R., Wanninkhof, R., Russell, J. L., Riser, S. C., and Takeshita, Y.: Calculating surface ocean pCO2 from biogeochemical Argo floats equipped with pH: An uncertainty analysis, Global Biogeochem. Cy., 31, 591–604, https://doi.org/10.1002/2016GB005541, 2017.
Williams, N. L., Juranek, L. W., Feely, R. A., Russell, J. L., Johnson, K. S., and Hales, B.: Assessment of the carbonate chemistry seasonal cycles in the Southern Ocean from persistent observational platforms, J. Geophys. Res.-Oceans, 123, 4833–4852, https://doi.org/10.1029/2017JC012917, 2018.
Wimart-Rousseau, C., Lajaunie-Salla, K., Marrec, P., Wagener, T., Raimbault, P., Lagadec, V., Lafont, M., Garcia, N., Diaz, F., Pinazo, C., Yohia, C., Garcia, F., Xueref-Remy, I., Blanc, P.-E., Armengaud, A., and Lefèvre, D.: Temporal variability of the carbonate system and air-sea CO2 exchanges in a Mediterranean human-impacted coastal site, Estuar. Coast. Shelf S., 236, 106641, https://doi.org/10.1016/j.ecss.2020.106641, 2020.
Wimart-Rousseau, C., Wagener, T., Álvarez, M., Moutin, T., Fourrier, M., Coppola, L., Niclas-Chirurgien, L., Raimbault, P., D'Ortenzio, F., Durrieu de Madron, X., Taillandier, V., Dumas, F., Conan, P., Pujo-Pay, M., and Lefèvre, D.: Seasonal and Interannual Variability of the CO2 System in the Eastern Mediterranean Sea: A Case Study in the North Western Levantine Basin, Front. Mar. Sci., 8, 649246, https://doi.org/10.3389/fmars.2021.649246, 2021.
WMO/GCOS: Global Climate Indicators, https://gcos.wmo.int/en/global-climate-indicators (last access: 22 December 2023), 2018.
Wu, Y., Hain, M. P., Humphreys, M. P., Hartman, S., and Tyrrell, T.: What drives the latitudinal gradient in open-ocean surface dissolved inorganic carbon concentration?, Biogeosciences, 16, 2661–2681, https://doi.org/10.5194/bg-16-2661-2019, 2019.
Short summary
This work presents a synthesis of 44 000 total alkalinity and dissolved inorganic carbon observations obtained between 1993 and 2022 in the Global Ocean and the Mediterranean Sea at the surface and in the water column. Seawater samples were measured using the same method and calibrated with international Certified Reference Material. We describe the data assemblage, quality control and some potential uses of this dataset.
This work presents a synthesis of 44 000 total alkalinity and dissolved inorganic carbon...
Altmetrics
Final-revised paper
Preprint