Articles | Volume 8, issue 1
https://doi.org/10.5194/essd-8-221-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/essd-8-221-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Brief communication
| 
03 Jun 2016
Brief communication |
| 03 Jun 2016
Stable carbon isotopes of dissolved inorganic carbon for a zonal transect across the subpolar North Atlantic Ocean in summer 2014
Matthew P. Humphreys
CORRESPONDING AUTHOR
Ocean and Earth Science, University of Southampton,
Southampton, UK
Florence M. Greatrix
Ocean and Earth Science, University of Southampton,
Southampton, UK
Eithne Tynan
Ocean and Earth Science, University of Southampton,
Southampton, UK
Eric P. Achterberg
Ocean and Earth Science, University of Southampton,
Southampton, UK
GEOMAR Helmholtz Centre for Ocean Research, Kiel,
Germany
Alex M. Griffiths
Department of Earth Science and Engineering, Imperial
College London, London, UK
Claudia H. Fry
Ocean and Earth Science, University of Southampton,
Southampton, UK
Rebecca Garley
Bermuda Institute of Ocean Sciences, St George's,
Bermuda
Alison McDonald
Scottish Universities Environmental Research Centre, East
Kilbride, UK
Adrian J. Boyce
Scottish Universities Environmental Research Centre, East
Kilbride, UK
Related authors
Matthew P. Humphreys and Sharyn Ossebaar
EGUsphere, https://doi.org/10.5194/egusphere-2025-3644, https://doi.org/10.5194/egusphere-2025-3644, 2025
This preprint is open for discussion and under review for Ocean Science (OS).
Short summary
Short summary
The ocean is one of the main reservoirs of carbon dioxide (CO2) on Earth's surface, so it plays an important role in modulating the climate. In this paper, we propose an update to how dissolved CO2 in seawater is determined from laboratory data, which can sometimes improve the accuracy of these measurements.
Hinne Florian van der Zant, Olivier Sulpis, Jack J. Middelburg, Matthew P. Humphreys, Raphaël Savelli, Dustin Carroll, Dimitris Menemenlis, Kay Sušelj, and Vincent Le Fouest
EGUsphere, https://doi.org/10.5194/egusphere-2025-2244, https://doi.org/10.5194/egusphere-2025-2244, 2025
This preprint is open for discussion and under review for Geoscientific Model Development (GMD).
Short summary
Short summary
We developed a model to simulate seafloor biogeochemical processes across a wide range of marine environments, from shallow coastal zones to deep-sea sediments. From this model, we derived a set of simple equations that predict how carbon, oxygen, and alkalinity are exchanged between sediments and overlying waters. These equations provide an efficient way to improve how ocean models represent seafloor interactions, which are often missing or overly simplified.
Li-Qing Jiang, Amanda Fay, Jens Daniel Müller, Lydia Keppler, Dustin Carroll, Siv K. Lauvset, Tim DeVries, Judith Hauck, Christian Rödenbeck, Luke Gregor, Nicolas Metzl, Andrea J. Fassbender, Jean-Pierre Gattuso, Peter Landschützer, Rik Wanninkhof, Christopher Sabine, Simone R. Alin, Mario Hoppema, Are Olsen, Matthew P. Humphreys, Kumiko Azetsu-Scott, Dorothee C. E. Bakker, Leticia Barbero, Nicholas R. Bates, Nicole Besemer, Henry C. Bittig, Albert E. Boyd, Daniel Broullón, Wei-Jun Cai, Brendan R. Carter, Thi-Tuyet-Trang Chau, Chen-Tung Arthur Chen, Frédéric Cyr, John E. Dore, Ian Enochs, Richard A. Feely, Hernan E. Garcia, Marion Gehlen, Lucas Gloege, Melchor González-Dávila, Nicolas Gruber, Yosuke Iida, Masao Ishii, Esther Kennedy, Alex Kozyr, Nico Lange, Claire Lo Monaco, Derek P. Manzello, Galen A. McKinley, Natalie M. Monacci, Xose A. Padin, Ana M. Palacio-Castro, Fiz F. Pérez, Alizée Roobaert, J. Magdalena Santana-Casiano, Jonathan Sharp, Adrienne Sutton, Jim Swift, Toste Tanhua, Maciej Telszewski, Jens Terhaar, Ruben van Hooidonk, Anton Velo, Andrew J. Watson, Angelicque E. White, Zelun Wu, Hyelim Yoo, and Jiye Zeng
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2025-255, https://doi.org/10.5194/essd-2025-255, 2025
Preprint under review for ESSD
Short summary
Short summary
This review article provides an overview of 60 existing ocean carbonate chemistry data products, encompassing a broad range of types, including compilations of cruise datasets, gap-filled observational products, model simulations, and more. It is designed to help researchers identify and access the data products that best support their scientific objectives, thereby facilitating progress in understanding the ocean's changing carbonate chemistry.
Louise Delaigue, Gert-Jan Reichart, Chris Galley, Yasmina Ourradi, and Matthew Paul Humphreys
EGUsphere, https://doi.org/10.5194/egusphere-2024-2853, https://doi.org/10.5194/egusphere-2024-2853, 2024
Short summary
Short summary
Our study analyzed pH in ocean surface waters to understand how they fluctuate with changes in temperature, salinity, and biological activities. We found that temperature mainly controls daily pH variations, but biological processes also play a role, especially in affecting CO2 levels between the ocean and atmosphere. Our research shows how these factors together maintain the balance of ocean chemistry, which is crucial for predicting changes in marine environments.
Matthew P. Humphreys
Ocean Sci., 20, 1325–1350, https://doi.org/10.5194/os-20-1325-2024, https://doi.org/10.5194/os-20-1325-2024, 2024
Short summary
Short summary
The ocean takes up carbon dioxide (CO2) from the atmosphere, slowing climate change. This CO2 uptake is controlled by a property called ƒCO2. Seawater ƒCO2 changes as seawater warms or cools, although by an uncertain amount; measurements and calculations give inconsistent results. Here, we work out how ƒCO2 should, in theory, respond to temperature. This matches field data and model calculations but still has discrepancies with scarce laboratory results, which need more measurements to resolve.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Marta Álvarez, Kumiko Azetsu-Scott, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Akihiko Murata, Jens Daniel Müller, Fiz F. Pérez, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 16, 2047–2072, https://doi.org/10.5194/essd-16-2047-2024, https://doi.org/10.5194/essd-16-2047-2024, 2024
Short summary
Short summary
GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2023 is the fifth update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality controlling, including systematic evaluation of measurement biases. This version contains data from 1108 hydrographic cruises covering the world's oceans from 1972 to 2021.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Simone Alin, Marta Álvarez, Kumiko Azetsu-Scott, Leticia Barbero, Susan Becker, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Richard A. Feely, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Li-Qing Jiang, Steve D. Jones, Claire Lo Monaco, Akihiko Murata, Jens Daniel Müller, Fiz F. Pérez, Benjamin Pfeil, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Bronte Tilbrook, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 14, 5543–5572, https://doi.org/10.5194/essd-14-5543-2022, https://doi.org/10.5194/essd-14-5543-2022, 2022
Short summary
Short summary
GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2022 is the fourth update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality controlling, including systematic evaluation of measurement biases. This version contains data from 1085 hydrographic cruises covering the world's oceans from 1972 to 2021.
Olivier Sulpis, Matthew P. Humphreys, Monica M. Wilhelmus, Dustin Carroll, William M. Berelson, Dimitris Menemenlis, Jack J. Middelburg, and Jess F. Adkins
Geosci. Model Dev., 15, 2105–2131, https://doi.org/10.5194/gmd-15-2105-2022, https://doi.org/10.5194/gmd-15-2105-2022, 2022
Short summary
Short summary
A quarter of the surface of the Earth is covered by marine sediments rich in calcium carbonates, and their dissolution acts as a giant antacid tablet protecting the ocean against human-made acidification caused by massive CO2 emissions. Here, we present a new model of sediment chemistry that incorporates the latest experimental findings on calcium carbonate dissolution kinetics. This model can be used to predict how marine sediments evolve through time in response to environmental perturbations.
Matthew P. Humphreys, Erik H. Meesters, Henk de Haas, Szabina Karancz, Louise Delaigue, Karel Bakker, Gerard Duineveld, Siham de Goeyse, Andreas F. Haas, Furu Mienis, Sharyn Ossebaar, and Fleur C. van Duyl
Biogeosciences, 19, 347–358, https://doi.org/10.5194/bg-19-347-2022, https://doi.org/10.5194/bg-19-347-2022, 2022
Short summary
Short summary
A series of submarine sinkholes were recently discovered on Luymes Bank, part of Saba Bank, a carbonate platform in the Caribbean Netherlands. Here, we investigate the waters inside these sinkholes for the first time. One of the sinkholes contained a body of dense, low-oxygen and low-pH water, which we call the
acid lake. We use measurements of seawater chemistry to work out what processes were responsible for forming the acid lake and discuss the consequences for the carbonate platform.
Matthew P. Humphreys, Ernie R. Lewis, Jonathan D. Sharp, and Denis Pierrot
Geosci. Model Dev., 15, 15–43, https://doi.org/10.5194/gmd-15-15-2022, https://doi.org/10.5194/gmd-15-15-2022, 2022
Short summary
Short summary
The ocean helps to mitigate our impact on Earth's climate by absorbing about a quarter of the carbon dioxide (CO2) released by human activities each year. However, once absorbed, chemical reactions between CO2 and water reduce seawater pH (
ocean acidification), which may have adverse effects on marine ecosystems. Our Python package, PyCO2SYS, models the chemical reactions of CO2 in seawater, allowing us to quantify the corresponding changes in pH and related chemical properties.
Luca Possenti, Ingunn Skjelvan, Dariia Atamanchuk, Anders Tengberg, Matthew P. Humphreys, Socratis Loucaides, Liam Fernand, and Jan Kaiser
Ocean Sci., 17, 593–614, https://doi.org/10.5194/os-17-593-2021, https://doi.org/10.5194/os-17-593-2021, 2021
Short summary
Short summary
A Seaglider was deployed for 8 months in the Norwegian Sea mounting an oxygen and, for the first time, a CO2 optode and a chlorophyll fluorescence sensor. The oxygen and CO2 data were used to assess the spatial and temporal variability and calculate the net community production, N(O2) and N(CT). The dataset was used to calculate net community production from inventory changes, air–sea flux, diapycnal mixing and entrainment.
Hannah K. Donald, Gavin L. Foster, Nico Fröhberg, George E. A. Swann, Alex J. Poulton, C. Mark Moore, and Matthew P. Humphreys
Biogeosciences, 17, 2825–2837, https://doi.org/10.5194/bg-17-2825-2020, https://doi.org/10.5194/bg-17-2825-2020, 2020
Short summary
Short summary
The boron isotope pH proxy is increasingly being used to reconstruct ocean pH in the past. Here we detail a novel analytical methodology for measuring the boron isotopic composition (δ11B) of diatom opal and apply this to the study of the diatom Thalassiosira weissflogii grown in culture over a range of pH. To our knowledge this is the first study of its kind and provides unique insights into the way in which diatoms incorporate boron and their potential as archives of palaeoclimate records.
Robyn E. Tuerena, Raja S. Ganeshram, Matthew P. Humphreys, Thomas J. Browning, Heather Bouman, and Alexander P. Piotrowski
Biogeosciences, 16, 3621–3635, https://doi.org/10.5194/bg-16-3621-2019, https://doi.org/10.5194/bg-16-3621-2019, 2019
Short summary
Short summary
The carbon isotopes in algae can be used to predict food sources and environmental change. We explore how dissolved carbon is taken up by algae in the South Atlantic Ocean and how this affects their carbon isotope signature. We find that cell size controls isotope fractionation. We use our results to investigate how climate change may impact the carbon isotopes in algae. We suggest a shift to smaller algae in this region would decrease the carbon isotope ratio at the base of the food web.
Yingxu Wu, Mathis P. Hain, Matthew P. Humphreys, Sue Hartman, and Toby Tyrrell
Biogeosciences, 16, 2661–2681, https://doi.org/10.5194/bg-16-2661-2019, https://doi.org/10.5194/bg-16-2661-2019, 2019
Short summary
Short summary
This study takes advantage of the GLODAPv2 database to investigate the processes driving the surface ocean dissolved inorganic carbon distribution, with the focus on its latitudinal gradient between the polar oceans and the low-latitude oceans. Based on our quantitative study, we find that temperature-driven CO2 gas exchange and high-latitude upwelling of DIC- and TA-rich deep waters are the two major drivers, with the importance of the latter not having been previously realized.
Meike Becker, Nils Andersen, Helmut Erlenkeuser, Matthew P. Humphreys, Toste Tanhua, and Arne Körtzinger
Earth Syst. Sci. Data, 8, 559–570, https://doi.org/10.5194/essd-8-559-2016, https://doi.org/10.5194/essd-8-559-2016, 2016
Short summary
Short summary
The stable carbon isotope composition of dissolved inorganic carbon (δ13C-DIC) can be used to quantify fluxes within the marine carbon system such as the exchange between ocean and atmosphere or the amount of anthropogenic carbon in the water column. In this study, an internally consistent δ13C-DIC dataset for the North Atlantic is presented. The data have undergone a secondary quality control during which systematic biases between the respective cruises have been quantified and adjusted.
Dorothee C. E. Bakker, Benjamin Pfeil, Camilla S. Landa, Nicolas Metzl, Kevin M. O'Brien, Are Olsen, Karl Smith, Cathy Cosca, Sumiko Harasawa, Stephen D. Jones, Shin-ichiro Nakaoka, Yukihiro Nojiri, Ute Schuster, Tobias Steinhoff, Colm Sweeney, Taro Takahashi, Bronte Tilbrook, Chisato Wada, Rik Wanninkhof, Simone R. Alin, Carlos F. Balestrini, Leticia Barbero, Nicholas R. Bates, Alejandro A. Bianchi, Frédéric Bonou, Jacqueline Boutin, Yann Bozec, Eugene F. Burger, Wei-Jun Cai, Robert D. Castle, Liqi Chen, Melissa Chierici, Kim Currie, Wiley Evans, Charles Featherstone, Richard A. Feely, Agneta Fransson, Catherine Goyet, Naomi Greenwood, Luke Gregor, Steven Hankin, Nick J. Hardman-Mountford, Jérôme Harlay, Judith Hauck, Mario Hoppema, Matthew P. Humphreys, Christopher W. Hunt, Betty Huss, J. Severino P. Ibánhez, Truls Johannessen, Ralph Keeling, Vassilis Kitidis, Arne Körtzinger, Alex Kozyr, Evangelia Krasakopoulou, Akira Kuwata, Peter Landschützer, Siv K. Lauvset, Nathalie Lefèvre, Claire Lo Monaco, Ansley Manke, Jeremy T. Mathis, Liliane Merlivat, Frank J. Millero, Pedro M. S. Monteiro, David R. Munro, Akihiko Murata, Timothy Newberger, Abdirahman M. Omar, Tsuneo Ono, Kristina Paterson, David Pearce, Denis Pierrot, Lisa L. Robbins, Shu Saito, Joe Salisbury, Reiner Schlitzer, Bernd Schneider, Roland Schweitzer, Rainer Sieger, Ingunn Skjelvan, Kevin F. Sullivan, Stewart C. Sutherland, Adrienne J. Sutton, Kazuaki Tadokoro, Maciej Telszewski, Matthias Tuma, Steven M. A. C. van Heuven, Doug Vandemark, Brian Ward, Andrew J. Watson, and Suqing Xu
Earth Syst. Sci. Data, 8, 383–413, https://doi.org/10.5194/essd-8-383-2016, https://doi.org/10.5194/essd-8-383-2016, 2016
Short summary
Short summary
Version 3 of the Surface Ocean CO2 Atlas (www.socat.info) has 14.5 million CO2 (carbon dioxide) values for the years 1957 to 2014 covering the global oceans and coastal seas. Version 3 is an update to version 2 with a longer record and 44 % more CO2 values. The CO2 measurements have been made on ships, fixed moorings and drifting buoys. SOCAT enables quantification of the ocean carbon sink and ocean acidification, as well as model evaluation, thus informing climate negotiations.
M. P. Humphreys, E. P. Achterberg, A. M. Griffiths, A. McDonald, and A. J. Boyce
Earth Syst. Sci. Data, 7, 127–135, https://doi.org/10.5194/essd-7-127-2015, https://doi.org/10.5194/essd-7-127-2015, 2015
Short summary
Short summary
We present measurements of the stable carbon isotope composition of seawater dissolved inorganic carbon. The samples were collected during two research cruises in boreal summer 2012 in the northeastern Atlantic and Nordic Seas. The results can be used to investigate the marine carbon cycle, providing information about biological productivity and oceanic uptake of anthropogenic carbon dioxide.
Matthew P. Humphreys and Sharyn Ossebaar
EGUsphere, https://doi.org/10.5194/egusphere-2025-3644, https://doi.org/10.5194/egusphere-2025-3644, 2025
This preprint is open for discussion and under review for Ocean Science (OS).
Short summary
Short summary
The ocean is one of the main reservoirs of carbon dioxide (CO2) on Earth's surface, so it plays an important role in modulating the climate. In this paper, we propose an update to how dissolved CO2 in seawater is determined from laboratory data, which can sometimes improve the accuracy of these measurements.
Hinne Florian van der Zant, Olivier Sulpis, Jack J. Middelburg, Matthew P. Humphreys, Raphaël Savelli, Dustin Carroll, Dimitris Menemenlis, Kay Sušelj, and Vincent Le Fouest
EGUsphere, https://doi.org/10.5194/egusphere-2025-2244, https://doi.org/10.5194/egusphere-2025-2244, 2025
This preprint is open for discussion and under review for Geoscientific Model Development (GMD).
Short summary
Short summary
We developed a model to simulate seafloor biogeochemical processes across a wide range of marine environments, from shallow coastal zones to deep-sea sediments. From this model, we derived a set of simple equations that predict how carbon, oxygen, and alkalinity are exchanged between sediments and overlying waters. These equations provide an efficient way to improve how ocean models represent seafloor interactions, which are often missing or overly simplified.
Hannah Krüger, Gerhard Schmiedl, Zvi Steiner, Zhouling Zhang, Eric P. Achterberg, and Nicolaas Glock
J. Micropalaeontol., 44, 193–211, https://doi.org/10.5194/jm-44-193-2025, https://doi.org/10.5194/jm-44-193-2025, 2025
Short summary
Short summary
The biodiversity and abundance of benthic foraminifera tend to increase with distance within a transect from the Rainbow hydrothermal vent field. Miliolids dominate closer to the vents and may be better adapted to the potentially hydrothermal conditions than hyaline and agglutinated species. The reason for this remains unclear, but there are indications that elevated trace-metal concentrations in the porewater and intrusion of acidic hydrothermal fluids could have an influence on the foraminifera.
Li-Qing Jiang, Amanda Fay, Jens Daniel Müller, Lydia Keppler, Dustin Carroll, Siv K. Lauvset, Tim DeVries, Judith Hauck, Christian Rödenbeck, Luke Gregor, Nicolas Metzl, Andrea J. Fassbender, Jean-Pierre Gattuso, Peter Landschützer, Rik Wanninkhof, Christopher Sabine, Simone R. Alin, Mario Hoppema, Are Olsen, Matthew P. Humphreys, Kumiko Azetsu-Scott, Dorothee C. E. Bakker, Leticia Barbero, Nicholas R. Bates, Nicole Besemer, Henry C. Bittig, Albert E. Boyd, Daniel Broullón, Wei-Jun Cai, Brendan R. Carter, Thi-Tuyet-Trang Chau, Chen-Tung Arthur Chen, Frédéric Cyr, John E. Dore, Ian Enochs, Richard A. Feely, Hernan E. Garcia, Marion Gehlen, Lucas Gloege, Melchor González-Dávila, Nicolas Gruber, Yosuke Iida, Masao Ishii, Esther Kennedy, Alex Kozyr, Nico Lange, Claire Lo Monaco, Derek P. Manzello, Galen A. McKinley, Natalie M. Monacci, Xose A. Padin, Ana M. Palacio-Castro, Fiz F. Pérez, Alizée Roobaert, J. Magdalena Santana-Casiano, Jonathan Sharp, Adrienne Sutton, Jim Swift, Toste Tanhua, Maciej Telszewski, Jens Terhaar, Ruben van Hooidonk, Anton Velo, Andrew J. Watson, Angelicque E. White, Zelun Wu, Hyelim Yoo, and Jiye Zeng
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2025-255, https://doi.org/10.5194/essd-2025-255, 2025
Preprint under review for ESSD
Short summary
Short summary
This review article provides an overview of 60 existing ocean carbonate chemistry data products, encompassing a broad range of types, including compilations of cruise datasets, gap-filled observational products, model simulations, and more. It is designed to help researchers identify and access the data products that best support their scientific objectives, thereby facilitating progress in understanding the ocean's changing carbonate chemistry.
Frank Förster, Sebastian Flöter, Lucie Sauzéat, Stéphanie Reynaud, Eric Achterberg, Alexandra Tsay, Christine Ferrier-Pagès, and Tom E. Sheldrake
EGUsphere, https://doi.org/10.5194/egusphere-2025-1713, https://doi.org/10.5194/egusphere-2025-1713, 2025
Short summary
Short summary
Explosive volcanic eruptions produce ash that, upon ocean deposition, alters seawater chemistry by leaching or adsorbing metals. Corals like Stylophora pistillata incorporate these metals in its various compartments (tissue, symbionts and skeleton), with most metal changes appearing in the coral skeleton. We present a novel dataset of ash-seawater leaching results, trace metal analysis in the different coral compartments from cultured corals maintained under a control and ash exposed condition.
Jana Krause, Dustin Carroll, Juan Höfer, Jeremy Donaire, Eric P. Achterberg, Emilio Alarcón, Te Liu, Lorenz Meire, Kechen Zhu, and Mark J. Hopwood
The Cryosphere, 18, 5735–5752, https://doi.org/10.5194/tc-18-5735-2024, https://doi.org/10.5194/tc-18-5735-2024, 2024
Short summary
Short summary
Here we analysed calved ice samples from both the Arctic and Antarctic to assess the variability in the composition of iceberg meltwater. Our results suggest that low concentrations of nitrate and phosphate in ice are primarily from the ice matrix, whereas sediment-rich layers impart a low concentration of silica and modest concentrations of iron and manganese. At a global scale, there are very limited differences in the nutrient composition of ice.
Louise Delaigue, Gert-Jan Reichart, Chris Galley, Yasmina Ourradi, and Matthew Paul Humphreys
EGUsphere, https://doi.org/10.5194/egusphere-2024-2853, https://doi.org/10.5194/egusphere-2024-2853, 2024
Short summary
Short summary
Our study analyzed pH in ocean surface waters to understand how they fluctuate with changes in temperature, salinity, and biological activities. We found that temperature mainly controls daily pH variations, but biological processes also play a role, especially in affecting CO2 levels between the ocean and atmosphere. Our research shows how these factors together maintain the balance of ocean chemistry, which is crucial for predicting changes in marine environments.
Matthew P. Humphreys
Ocean Sci., 20, 1325–1350, https://doi.org/10.5194/os-20-1325-2024, https://doi.org/10.5194/os-20-1325-2024, 2024
Short summary
Short summary
The ocean takes up carbon dioxide (CO2) from the atmosphere, slowing climate change. This CO2 uptake is controlled by a property called ƒCO2. Seawater ƒCO2 changes as seawater warms or cools, although by an uncertain amount; measurements and calculations give inconsistent results. Here, we work out how ƒCO2 should, in theory, respond to temperature. This matches field data and model calculations but still has discrepancies with scarce laboratory results, which need more measurements to resolve.
Ingeborg Bussmann, Eric P. Achterberg, Holger Brix, Nicolas Brüggemann, Götz Flöser, Claudia Schütze, and Philipp Fischer
Biogeosciences, 21, 3819–3838, https://doi.org/10.5194/bg-21-3819-2024, https://doi.org/10.5194/bg-21-3819-2024, 2024
Short summary
Short summary
Methane (CH4) is an important greenhouse gas and contributes to climate warming. However, the input of CH4 from coastal areas to the atmosphere is not well defined. Dissolved and atmospheric CH4 was determined at high spatial resolution in or above the North Sea. The atmospheric CH4 concentration was mainly influenced by wind direction. With our detailed study on the spatial distribution of CH4 fluxes we were able to provide a detailed and more realistic estimation of coastal CH4 fluxes.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Marta Álvarez, Kumiko Azetsu-Scott, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Akihiko Murata, Jens Daniel Müller, Fiz F. Pérez, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 16, 2047–2072, https://doi.org/10.5194/essd-16-2047-2024, https://doi.org/10.5194/essd-16-2047-2024, 2024
Short summary
Short summary
GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2023 is the fifth update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality controlling, including systematic evaluation of measurement biases. This version contains data from 1108 hydrographic cruises covering the world's oceans from 1972 to 2021.
Kristian Spilling, Jonna Piiparinen, Eric P. Achterberg, Javier Arístegui, Lennart T. Bach, Maria T. Camarena-Gómez, Elisabeth von der Esch, Martin A. Fischer, Markel Gómez-Letona, Nauzet Hernández-Hernández, Judith Meyer, Ruth A. Schmitz, and Ulf Riebesell
Biogeosciences, 20, 1605–1619, https://doi.org/10.5194/bg-20-1605-2023, https://doi.org/10.5194/bg-20-1605-2023, 2023
Short summary
Short summary
We carried out an enclosure experiment using surface water off Peru with different additions of oxygen minimum zone water. In this paper, we report on enzyme activity and provide data on the decomposition of organic matter. We found very high activity with respect to an enzyme breaking down protein, suggesting that this is important for nutrient recycling both at present and in the future ocean.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Simone Alin, Marta Álvarez, Kumiko Azetsu-Scott, Leticia Barbero, Susan Becker, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Richard A. Feely, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Li-Qing Jiang, Steve D. Jones, Claire Lo Monaco, Akihiko Murata, Jens Daniel Müller, Fiz F. Pérez, Benjamin Pfeil, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Bronte Tilbrook, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 14, 5543–5572, https://doi.org/10.5194/essd-14-5543-2022, https://doi.org/10.5194/essd-14-5543-2022, 2022
Short summary
Short summary
GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2022 is the fourth update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality controlling, including systematic evaluation of measurement biases. This version contains data from 1085 hydrographic cruises covering the world's oceans from 1972 to 2021.
Olivier Sulpis, Matthew P. Humphreys, Monica M. Wilhelmus, Dustin Carroll, William M. Berelson, Dimitris Menemenlis, Jack J. Middelburg, and Jess F. Adkins
Geosci. Model Dev., 15, 2105–2131, https://doi.org/10.5194/gmd-15-2105-2022, https://doi.org/10.5194/gmd-15-2105-2022, 2022
Short summary
Short summary
A quarter of the surface of the Earth is covered by marine sediments rich in calcium carbonates, and their dissolution acts as a giant antacid tablet protecting the ocean against human-made acidification caused by massive CO2 emissions. Here, we present a new model of sediment chemistry that incorporates the latest experimental findings on calcium carbonate dissolution kinetics. This model can be used to predict how marine sediments evolve through time in response to environmental perturbations.
Matthew P. Humphreys, Erik H. Meesters, Henk de Haas, Szabina Karancz, Louise Delaigue, Karel Bakker, Gerard Duineveld, Siham de Goeyse, Andreas F. Haas, Furu Mienis, Sharyn Ossebaar, and Fleur C. van Duyl
Biogeosciences, 19, 347–358, https://doi.org/10.5194/bg-19-347-2022, https://doi.org/10.5194/bg-19-347-2022, 2022
Short summary
Short summary
A series of submarine sinkholes were recently discovered on Luymes Bank, part of Saba Bank, a carbonate platform in the Caribbean Netherlands. Here, we investigate the waters inside these sinkholes for the first time. One of the sinkholes contained a body of dense, low-oxygen and low-pH water, which we call the
acid lake. We use measurements of seawater chemistry to work out what processes were responsible for forming the acid lake and discuss the consequences for the carbonate platform.
Shao-Min Chen, Ulf Riebesell, Kai G. Schulz, Elisabeth von der Esch, Eric P. Achterberg, and Lennart T. Bach
Biogeosciences, 19, 295–312, https://doi.org/10.5194/bg-19-295-2022, https://doi.org/10.5194/bg-19-295-2022, 2022
Short summary
Short summary
Oxygen minimum zones in the ocean are characterized by enhanced carbon dioxide (CO2) levels and are being further acidified by increasing anthropogenic atmospheric CO2. Here we report CO2 system measurements in a mesocosm study offshore Peru during a rare coastal El Niño event to investigate how CO2 dynamics may respond to ongoing ocean deoxygenation. Our observations show that nitrogen limitation, productivity, and plankton community shift play an important role in driving the CO2 dynamics.
Matthew P. Humphreys, Ernie R. Lewis, Jonathan D. Sharp, and Denis Pierrot
Geosci. Model Dev., 15, 15–43, https://doi.org/10.5194/gmd-15-15-2022, https://doi.org/10.5194/gmd-15-15-2022, 2022
Short summary
Short summary
The ocean helps to mitigate our impact on Earth's climate by absorbing about a quarter of the carbon dioxide (CO2) released by human activities each year. However, once absorbed, chemical reactions between CO2 and water reduce seawater pH (
ocean acidification), which may have adverse effects on marine ecosystems. Our Python package, PyCO2SYS, models the chemical reactions of CO2 in seawater, allowing us to quantify the corresponding changes in pH and related chemical properties.
Kai G. Schulz, Eric P. Achterberg, Javier Arístegui, Lennart T. Bach, Isabel Baños, Tim Boxhammer, Dirk Erler, Maricarmen Igarza, Verena Kalter, Andrea Ludwig, Carolin Löscher, Jana Meyer, Judith Meyer, Fabrizio Minutolo, Elisabeth von der Esch, Bess B. Ward, and Ulf Riebesell
Biogeosciences, 18, 4305–4320, https://doi.org/10.5194/bg-18-4305-2021, https://doi.org/10.5194/bg-18-4305-2021, 2021
Short summary
Short summary
Upwelling of nutrient-rich deep waters to the surface make eastern boundary upwelling systems hot spots of marine productivity. This leads to subsurface oxygen depletion and the transformation of bioavailable nitrogen into inert N2. Here we quantify nitrogen loss processes following a simulated deep water upwelling. Denitrification was the dominant process, and budget calculations suggest that a significant portion of nitrogen that could be exported to depth is already lost in the surface ocean.
Neil J. Wyatt, Angela Milne, Eric P. Achterberg, Thomas J. Browning, Heather A. Bouman, E. Malcolm S. Woodward, and Maeve C. Lohan
Biogeosciences, 18, 4265–4280, https://doi.org/10.5194/bg-18-4265-2021, https://doi.org/10.5194/bg-18-4265-2021, 2021
Short summary
Short summary
Using data collected during two expeditions to the South Atlantic Ocean, we investigated how the interaction between external sources and biological activity influenced the availability of the trace metals zinc and cobalt. This is important as both metals play essential roles in the metabolism and growth of phytoplankton and thus influence primary productivity of the oceans. We found seasonal changes in both processes that helped explain upper-ocean trace metal cycling.
Luca Possenti, Ingunn Skjelvan, Dariia Atamanchuk, Anders Tengberg, Matthew P. Humphreys, Socratis Loucaides, Liam Fernand, and Jan Kaiser
Ocean Sci., 17, 593–614, https://doi.org/10.5194/os-17-593-2021, https://doi.org/10.5194/os-17-593-2021, 2021
Short summary
Short summary
A Seaglider was deployed for 8 months in the Norwegian Sea mounting an oxygen and, for the first time, a CO2 optode and a chlorophyll fluorescence sensor. The oxygen and CO2 data were used to assess the spatial and temporal variability and calculate the net community production, N(O2) and N(CT). The dataset was used to calculate net community production from inventory changes, air–sea flux, diapycnal mixing and entrainment.
Maximiliano J. Vergara-Jara, Mark J. Hopwood, Thomas J. Browning, Insa Rapp, Rodrigo Torres, Brian Reid, Eric P. Achterberg, and José Luis Iriarte
Ocean Sci., 17, 561–578, https://doi.org/10.5194/os-17-561-2021, https://doi.org/10.5194/os-17-561-2021, 2021
Short summary
Short summary
Ash from the Calbuco 2015 eruption spread across northern Patagonia, the SE Pacific and the SW Atlantic. In the Pacific, a phytoplankton bloom corresponded closely to the volcanic ash plume, suggesting that ash fertilized this region of the ocean. No such fertilization was found in the Atlantic where nutrients plausibly supplied by ash were likely already in excess of phytoplankton demand. In Patagonia, the May bloom was more intense than usual, but the mechanistic link to ash was less clear.
Yu-Te Hsieh, Walter Geibert, E. Malcolm S. Woodward, Neil J. Wyatt, Maeve C. Lohan, Eric P. Achterberg, and Gideon M. Henderson
Biogeosciences, 18, 1645–1671, https://doi.org/10.5194/bg-18-1645-2021, https://doi.org/10.5194/bg-18-1645-2021, 2021
Short summary
Short summary
The South Atlantic near 40° S is one of the high-productivity and most dynamic nutrient regions in the oceans, but the sources and fluxes of trace elements (TEs) to this region remain unclear. This study investigates seawater Ra-228 and provides important constraints on ocean mixing and dissolved TE fluxes to this region. Vertical mixing is a more important source than aeolian or shelf inputs in this region, but particulate or winter deep-mixing inputs may be required to balance the TE budgets.
Jan Lüdke, Marcus Dengler, Stefan Sommer, David Clemens, Sören Thomsen, Gerd Krahmann, Andrew W. Dale, Eric P. Achterberg, and Martin Visbeck
Ocean Sci., 16, 1347–1366, https://doi.org/10.5194/os-16-1347-2020, https://doi.org/10.5194/os-16-1347-2020, 2020
Short summary
Short summary
We analyse the intraseasonal variability of the alongshore circulation off Peru in early 2017, this circulation is very important for the supply of nutrients to the upwelling regime. The causes of this variability and its impact on the biogeochemistry are investigated. The poleward flow is strengthened during the observed time period, likely by a downwelling coastal trapped wave. The stronger current causes an increase in nitrate and reduces the deficit of fixed nitrogen relative to phosphorus.
Ruifang C. Xie, Frédéric A. C. Le Moigne, Insa Rapp, Jan Lüdke, Beat Gasser, Marcus Dengler, Volker Liebetrau, and Eric P. Achterberg
Biogeosciences, 17, 4919–4936, https://doi.org/10.5194/bg-17-4919-2020, https://doi.org/10.5194/bg-17-4919-2020, 2020
Short summary
Short summary
Thorium-234 (234Th) is widely used to study carbon fluxes from the surface ocean to depth. But few studies stress the relevance of oceanic advection and diffusion on the downward 234Th fluxes in nearshore environments. Our study in offshore Peru showed strong temporal variations in both the importance of physical processes on 234Th flux estimates and the oceanic residence time of 234Th, whereas salinity-derived seawater 238U activities accounted for up to 40 % errors in 234Th flux estimates.
Lennart Thomas Bach, Allanah Joy Paul, Tim Boxhammer, Elisabeth von der Esch, Michelle Graco, Kai Georg Schulz, Eric Achterberg, Paulina Aguayo, Javier Arístegui, Patrizia Ayón, Isabel Baños, Avy Bernales, Anne Sophie Boegeholz, Francisco Chavez, Gabriela Chavez, Shao-Min Chen, Kristin Doering, Alba Filella, Martin Fischer, Patricia Grasse, Mathias Haunost, Jan Hennke, Nauzet Hernández-Hernández, Mark Hopwood, Maricarmen Igarza, Verena Kalter, Leila Kittu, Peter Kohnert, Jesus Ledesma, Christian Lieberum, Silke Lischka, Carolin Löscher, Andrea Ludwig, Ursula Mendoza, Jana Meyer, Judith Meyer, Fabrizio Minutolo, Joaquin Ortiz Cortes, Jonna Piiparinen, Claudia Sforna, Kristian Spilling, Sonia Sanchez, Carsten Spisla, Michael Sswat, Mabel Zavala Moreira, and Ulf Riebesell
Biogeosciences, 17, 4831–4852, https://doi.org/10.5194/bg-17-4831-2020, https://doi.org/10.5194/bg-17-4831-2020, 2020
Short summary
Short summary
The eastern boundary upwelling system off Peru is among Earth's most productive ocean ecosystems, but the factors that control its functioning are poorly constrained. Here we used mesocosms, moored ~ 6 km offshore Peru, to investigate how processes in plankton communities drive key biogeochemical processes. We show that nutrient and light co-limitation keep productivity and export at a remarkably constant level while stoichiometry changes strongly with shifts in plankton community structure.
Nicolas E. Beaudoin, Aurélie Labeur, Olivier Lacombe, Daniel Koehn, Andrea Billi, Guilhem Hoareau, Adrian Boyce, Cédric M. John, Marta Marchegiano, Nick M. Roberts, Ian L. Millar, Fanny Claverie, Christophe Pecheyran, and Jean-Paul Callot
Solid Earth, 11, 1617–1641, https://doi.org/10.5194/se-11-1617-2020, https://doi.org/10.5194/se-11-1617-2020, 2020
Short summary
Short summary
This paper reports a multiproxy approach to reconstruct the depth, timing, and extent of the past fluid flow during the formation of a fold-and-thrust belt in the Northern Apennines, Italy. The unique combination of paleopiezometry and absolute dating returns the absolute timing of the sequence of deformation. Combined with burial models, this leads to predict the expected temperatures for fluid, highlighting a limited hydrothermal fluid flow we relate to the large-scale subsurface geometry.
Anna Plass, Christian Schlosser, Stefan Sommer, Andrew W. Dale, Eric P. Achterberg, and Florian Scholz
Biogeosciences, 17, 3685–3704, https://doi.org/10.5194/bg-17-3685-2020, https://doi.org/10.5194/bg-17-3685-2020, 2020
Short summary
Short summary
We compare the cycling of Fe and Cd in sulfidic sediments of the Peruvian oxygen minimum zone. Due to the contrasting solubility of their sulfide minerals, the sedimentary Fe release and Cd burial fluxes covary with spatial and temporal distributions of H2S. Depending on the solubility of their sulfide minerals, sedimentary trace metal fluxes will respond differently to ocean deoxygenation/expansion of H2S concentrations, which may change trace metal stoichiometry of upwelling water masses.
Hannah K. Donald, Gavin L. Foster, Nico Fröhberg, George E. A. Swann, Alex J. Poulton, C. Mark Moore, and Matthew P. Humphreys
Biogeosciences, 17, 2825–2837, https://doi.org/10.5194/bg-17-2825-2020, https://doi.org/10.5194/bg-17-2825-2020, 2020
Short summary
Short summary
The boron isotope pH proxy is increasingly being used to reconstruct ocean pH in the past. Here we detail a novel analytical methodology for measuring the boron isotopic composition (δ11B) of diatom opal and apply this to the study of the diatom Thalassiosira weissflogii grown in culture over a range of pH. To our knowledge this is the first study of its kind and provides unique insights into the way in which diatoms incorporate boron and their potential as archives of palaeoclimate records.
Mark J. Hopwood, Dustin Carroll, Thorben Dunse, Andy Hodson, Johnna M. Holding, José L. Iriarte, Sofia Ribeiro, Eric P. Achterberg, Carolina Cantoni, Daniel F. Carlson, Melissa Chierici, Jennifer S. Clarke, Stefano Cozzi, Agneta Fransson, Thomas Juul-Pedersen, Mie H. S. Winding, and Lorenz Meire
The Cryosphere, 14, 1347–1383, https://doi.org/10.5194/tc-14-1347-2020, https://doi.org/10.5194/tc-14-1347-2020, 2020
Short summary
Short summary
Here we compare and contrast results from five well-studied Arctic field sites in order to understand how glaciers affect marine biogeochemistry and marine primary production. The key questions are listed as follows. Where and when does glacial freshwater discharge promote or reduce marine primary production? How does spatio-temporal variability in glacial discharge affect marine primary production? And how far-reaching are the effects of glacial discharge on marine biogeochemistry?
Claudia Frey, Hermann W. Bange, Eric P. Achterberg, Amal Jayakumar, Carolin R. Löscher, Damian L. Arévalo-Martínez, Elizabeth León-Palmero, Mingshuang Sun, Xin Sun, Ruifang C. Xie, Sergey Oleynik, and Bess B. Ward
Biogeosciences, 17, 2263–2287, https://doi.org/10.5194/bg-17-2263-2020, https://doi.org/10.5194/bg-17-2263-2020, 2020
Short summary
Short summary
The production of N2O via nitrification and denitrification associated with low-O2 waters is a major source of oceanic N2O. We investigated the regulation and dynamics of these processes with respect to O2 and organic matter inputs. The transcription of the key nitrification gene amoA rapidly responded to changes in O2 and strongly correlated with N2O production rates. N2O production by denitrification was clearly stimulated by organic carbon, implying that its supply controls N2O production.
Mark J. Hopwood, Nicolas Sanchez, Despo Polyviou, Øystein Leiknes, Julián Alberto Gallego-Urrea, Eric P. Achterberg, Murat V. Ardelan, Javier Aristegui, Lennart Bach, Sengul Besiktepe, Yohann Heriot, Ioanna Kalantzi, Tuba Terbıyık Kurt, Ioulia Santi, Tatiana M. Tsagaraki, and David Turner
Biogeosciences, 17, 1309–1326, https://doi.org/10.5194/bg-17-1309-2020, https://doi.org/10.5194/bg-17-1309-2020, 2020
Short summary
Short summary
Hydrogen peroxide, H2O2, is formed naturally in sunlight-exposed water by photochemistry. At high concentrations it is undesirable to biological cells because it is a stressor. Here, across a range of incubation experiments in diverse marine environments (Gran Canaria, the Mediterranean, Patagonia and Svalbard), we determine that two factors consistently affect the H2O2 concentrations irrespective of geographical location: bacteria abundance and experiment design.
Mark J. Hopwood, Carolina Santana-González, Julian Gallego-Urrea, Nicolas Sanchez, Eric P. Achterberg, Murat V. Ardelan, Martha Gledhill, Melchor González-Dávila, Linn Hoffmann, Øystein Leiknes, Juana Magdalena Santana-Casiano, Tatiana M. Tsagaraki, and David Turner
Biogeosciences, 17, 1327–1342, https://doi.org/10.5194/bg-17-1327-2020, https://doi.org/10.5194/bg-17-1327-2020, 2020
Short summary
Short summary
Fe is an essential micronutrient. Fe(III)-organic species are thought to account for > 99 % of dissolved Fe in seawater. Here we quantified Fe(II) during experiments in Svalbard, Gran Canaria, and Patagonia. Fe(II) was always a measurable fraction of dissolved Fe up to 65 %. Furthermore, when Fe(II) was allowed to decay in the dark, it remained present longer than predicted by kinetic equations, suggesting that Fe(II) is a more important fraction of dissolved Fe in seawater than widely recognized.
Insa Rapp, Christian Schlosser, Jan-Lukas Menzel Barraqueta, Bernhard Wenzel, Jan Lüdke, Jan Scholten, Beat Gasser, Patrick Reichert, Martha Gledhill, Marcus Dengler, and Eric P. Achterberg
Biogeosciences, 16, 4157–4182, https://doi.org/10.5194/bg-16-4157-2019, https://doi.org/10.5194/bg-16-4157-2019, 2019
Short summary
Short summary
The availability of iron (Fe) affects phytoplankton growth in large parts of the ocean. Shelf sediments, particularly in oxygen minimum zones, are a major source of Fe and other essential micronutrients, such as cobalt (Co) and manganese (Mn). We observed enhanced concentrations of Fe, Co, and Mn corresponding with low oxygen concentrations along the Mauritanian shelf, indicating that the projected future decrease in oxygen concentrations may result in increases in Fe, Mn, and Co concentrations.
Robyn E. Tuerena, Raja S. Ganeshram, Matthew P. Humphreys, Thomas J. Browning, Heather Bouman, and Alexander P. Piotrowski
Biogeosciences, 16, 3621–3635, https://doi.org/10.5194/bg-16-3621-2019, https://doi.org/10.5194/bg-16-3621-2019, 2019
Short summary
Short summary
The carbon isotopes in algae can be used to predict food sources and environmental change. We explore how dissolved carbon is taken up by algae in the South Atlantic Ocean and how this affects their carbon isotope signature. We find that cell size controls isotope fractionation. We use our results to investigate how climate change may impact the carbon isotopes in algae. We suggest a shift to smaller algae in this region would decrease the carbon isotope ratio at the base of the food web.
Yingxu Wu, Mathis P. Hain, Matthew P. Humphreys, Sue Hartman, and Toby Tyrrell
Biogeosciences, 16, 2661–2681, https://doi.org/10.5194/bg-16-2661-2019, https://doi.org/10.5194/bg-16-2661-2019, 2019
Short summary
Short summary
This study takes advantage of the GLODAPv2 database to investigate the processes driving the surface ocean dissolved inorganic carbon distribution, with the focus on its latitudinal gradient between the polar oceans and the low-latitude oceans. Based on our quantitative study, we find that temperature-driven CO2 gas exchange and high-latitude upwelling of DIC- and TA-rich deep waters are the two major drivers, with the importance of the latter not having been previously realized.
Jan-Lukas Menzel Barraqueta, Jessica K. Klar, Martha Gledhill, Christian Schlosser, Rachel Shelley, Hélène F. Planquette, Bernhard Wenzel, Geraldine Sarthou, and Eric P. Achterberg
Biogeosciences, 16, 1525–1542, https://doi.org/10.5194/bg-16-1525-2019, https://doi.org/10.5194/bg-16-1525-2019, 2019
Short summary
Short summary
We used surface water dissolved aluminium concentrations collected in four different GEOTRACES cruises to determine atmospheric deposition fluxes to the ocean. We calculate atmospheric deposition fluxes for largely under-sampled regions of the Atlantic Ocean and thus provide new constraints for models of atmospheric deposition. The use of the MADCOW model is of major importance as dissolved aluminium is analysed within the GEOTRACES project at high spatial resolution.
Géraldine Sarthou, Pascale Lherminier, Eric P. Achterberg, Fernando Alonso-Pérez, Eva Bucciarelli, Julia Boutorh, Vincent Bouvier, Edward A. Boyle, Pierre Branellec, Lidia I. Carracedo, Nuria Casacuberta, Maxi Castrillejo, Marie Cheize, Leonardo Contreira Pereira, Daniel Cossa, Nathalie Daniault, Emmanuel De Saint-Léger, Frank Dehairs, Feifei Deng, Floriane Desprez de Gésincourt, Jérémy Devesa, Lorna Foliot, Debany Fonseca-Batista, Morgane Gallinari, Maribel I. García-Ibáñez, Arthur Gourain, Emilie Grossteffan, Michel Hamon, Lars Eric Heimbürger, Gideon M. Henderson, Catherine Jeandel, Catherine Kermabon, François Lacan, Philippe Le Bot, Manon Le Goff, Emilie Le Roy, Alison Lefèbvre, Stéphane Leizour, Nolwenn Lemaitre, Pere Masqué, Olivier Ménage, Jan-Lukas Menzel Barraqueta, Herlé Mercier, Fabien Perault, Fiz F. Pérez, Hélène F. Planquette, Frédéric Planchon, Arnout Roukaerts, Virginie Sanial, Raphaëlle Sauzède, Catherine Schmechtig, Rachel U. Shelley, Gillian Stewart, Jill N. Sutton, Yi Tang, Nadine Tisnérat-Laborde, Manon Tonnard, Paul Tréguer, Pieter van Beek, Cheryl M. Zurbrick, and Patricia Zunino
Biogeosciences, 15, 7097–7109, https://doi.org/10.5194/bg-15-7097-2018, https://doi.org/10.5194/bg-15-7097-2018, 2018
Short summary
Short summary
The GEOVIDE cruise (GEOTRACES Section GA01) was conducted in the North Atlantic Ocean and Labrador Sea in May–June 2014. In this special issue, results from GEOVIDE, including physical oceanography and trace element and isotope cyclings, are presented among 17 articles. Here, the scientific context, project objectives, and scientific strategy of GEOVIDE are provided, along with an overview of the main results from the articles published in the special issue.
Chris J. Daniels, Alex J. Poulton, William M. Balch, Emilio Marañón, Tim Adey, Bruce C. Bowler, Pedro Cermeño, Anastasia Charalampopoulou, David W. Crawford, Dave Drapeau, Yuanyuan Feng, Ana Fernández, Emilio Fernández, Glaucia M. Fragoso, Natalia González, Lisa M. Graziano, Rachel Heslop, Patrick M. Holligan, Jason Hopkins, María Huete-Ortega, David A. Hutchins, Phoebe J. Lam, Michael S. Lipsen, Daffne C. López-Sandoval, Socratis Loucaides, Adrian Marchetti, Kyle M. J. Mayers, Andrew P. Rees, Cristina Sobrino, Eithne Tynan, and Toby Tyrrell
Earth Syst. Sci. Data, 10, 1859–1876, https://doi.org/10.5194/essd-10-1859-2018, https://doi.org/10.5194/essd-10-1859-2018, 2018
Short summary
Short summary
Calcifying marine algae (coccolithophores) are key to oceanic biogeochemical processes, such as calcium carbonate production and export. We compile a global database of calcium carbonate production from field samples (n = 2756), alongside primary production rates and coccolithophore abundance. Basic statistical analysis highlights global distribution, average surface and integrated rates, patterns with depth and the importance of considering cell-normalised rates as a simple physiological index.
Jan-Lukas Menzel Barraqueta, Christian Schlosser, Hélène Planquette, Arthur Gourain, Marie Cheize, Julia Boutorh, Rachel Shelley, Leonardo Contreira Pereira, Martha Gledhill, Mark J. Hopwood, François Lacan, Pascale Lherminier, Geraldine Sarthou, and Eric P. Achterberg
Biogeosciences, 15, 5271–5286, https://doi.org/10.5194/bg-15-5271-2018, https://doi.org/10.5194/bg-15-5271-2018, 2018
Short summary
Short summary
In the North Atlantic and Labrador Sea, low aerosol deposition and enhanced primary productivity control the dissolved aluminium (dAl) surface distribution, while remineralization of particles seems to control the distribution at depth. DAl in the ocean allows us to indirectly quantify the amount of dust deposited to a given region for a given period. Hence, the study of its distribution, cycling, sources, and sinks is of major importance to improve aerosol deposition models and climate models.
Christian Schlosser, Katrin Schmidt, Alfred Aquilina, William B. Homoky, Maxi Castrillejo, Rachel A. Mills, Matthew D. Patey, Sophie Fielding, Angus Atkinson, and Eric P. Achterberg
Biogeosciences, 15, 4973–4993, https://doi.org/10.5194/bg-15-4973-2018, https://doi.org/10.5194/bg-15-4973-2018, 2018
Short summary
Short summary
Iron (Fe) emanating from the South Georgia shelf system fuels large phytoplankton blooms downstream of the island. However, the actual supply mechanisms of Fe are unclear. We found that shelf-sediment-derived iron and iron released from Antarctic krill control the Fe distribution in the shelf waters around South Georgia. The majority of the Fe appears to be derived from recycling of Fe-enriched particles that are transported with the water masses into the bloom region.
Helen E. K. Smith, Alex J. Poulton, Rebecca Garley, Jason Hopkins, Laura C. Lubelczyk, Dave T. Drapeau, Sara Rauschenberg, Ben S. Twining, Nicholas R. Bates, and William M. Balch
Biogeosciences, 14, 4905–4925, https://doi.org/10.5194/bg-14-4905-2017, https://doi.org/10.5194/bg-14-4905-2017, 2017
Short summary
Short summary
The Great Calcite Belt (GCB), a region of high calcite concentration from coccolithophores, covers 60 % of the Southern Ocean area. We examined the influence of temperature, macronutrients, and carbonate chemistry on the distribution of mineralizing phytoplankton in the GCB. Coccolithophores occupy a niche in the Southern Ocean after the diatom spring bloom depletes silicic acid. No single environmental variable holds a dominant influence over phytoplankton biogeography in summer GCB conditions.
Thomas Hornick, Lennart T. Bach, Katharine J. Crawfurd, Kristian Spilling, Eric P. Achterberg, Jason N. Woodhouse, Kai G. Schulz, Corina P. D. Brussaard, Ulf Riebesell, and Hans-Peter Grossart
Biogeosciences, 14, 1–15, https://doi.org/10.5194/bg-14-1-2017, https://doi.org/10.5194/bg-14-1-2017, 2017
Kristian Spilling, Kai G. Schulz, Allanah J. Paul, Tim Boxhammer, Eric P. Achterberg, Thomas Hornick, Silke Lischka, Annegret Stuhr, Rafael Bermúdez, Jan Czerny, Kate Crawfurd, Corina P. D. Brussaard, Hans-Peter Grossart, and Ulf Riebesell
Biogeosciences, 13, 6081–6093, https://doi.org/10.5194/bg-13-6081-2016, https://doi.org/10.5194/bg-13-6081-2016, 2016
Short summary
Short summary
We performed an experiment in the Baltic Sea in order to investigate the consequences of the increasing CO2 levels on biological processes in the free water mass. There was more accumulation of organic carbon at high CO2 levels. Surprisingly, this was caused by reduced loss processes (respiration and bacterial production) in a high-CO2 environment, and not by increased photosynthetic fixation of CO2. Our carbon budget can be used to better disentangle the effects of ocean acidification.
Meike Becker, Nils Andersen, Helmut Erlenkeuser, Matthew P. Humphreys, Toste Tanhua, and Arne Körtzinger
Earth Syst. Sci. Data, 8, 559–570, https://doi.org/10.5194/essd-8-559-2016, https://doi.org/10.5194/essd-8-559-2016, 2016
Short summary
Short summary
The stable carbon isotope composition of dissolved inorganic carbon (δ13C-DIC) can be used to quantify fluxes within the marine carbon system such as the exchange between ocean and atmosphere or the amount of anthropogenic carbon in the water column. In this study, an internally consistent δ13C-DIC dataset for the North Atlantic is presented. The data have undergone a secondary quality control during which systematic biases between the respective cruises have been quantified and adjusted.
Dorothee C. E. Bakker, Benjamin Pfeil, Camilla S. Landa, Nicolas Metzl, Kevin M. O'Brien, Are Olsen, Karl Smith, Cathy Cosca, Sumiko Harasawa, Stephen D. Jones, Shin-ichiro Nakaoka, Yukihiro Nojiri, Ute Schuster, Tobias Steinhoff, Colm Sweeney, Taro Takahashi, Bronte Tilbrook, Chisato Wada, Rik Wanninkhof, Simone R. Alin, Carlos F. Balestrini, Leticia Barbero, Nicholas R. Bates, Alejandro A. Bianchi, Frédéric Bonou, Jacqueline Boutin, Yann Bozec, Eugene F. Burger, Wei-Jun Cai, Robert D. Castle, Liqi Chen, Melissa Chierici, Kim Currie, Wiley Evans, Charles Featherstone, Richard A. Feely, Agneta Fransson, Catherine Goyet, Naomi Greenwood, Luke Gregor, Steven Hankin, Nick J. Hardman-Mountford, Jérôme Harlay, Judith Hauck, Mario Hoppema, Matthew P. Humphreys, Christopher W. Hunt, Betty Huss, J. Severino P. Ibánhez, Truls Johannessen, Ralph Keeling, Vassilis Kitidis, Arne Körtzinger, Alex Kozyr, Evangelia Krasakopoulou, Akira Kuwata, Peter Landschützer, Siv K. Lauvset, Nathalie Lefèvre, Claire Lo Monaco, Ansley Manke, Jeremy T. Mathis, Liliane Merlivat, Frank J. Millero, Pedro M. S. Monteiro, David R. Munro, Akihiko Murata, Timothy Newberger, Abdirahman M. Omar, Tsuneo Ono, Kristina Paterson, David Pearce, Denis Pierrot, Lisa L. Robbins, Shu Saito, Joe Salisbury, Reiner Schlitzer, Bernd Schneider, Roland Schweitzer, Rainer Sieger, Ingunn Skjelvan, Kevin F. Sullivan, Stewart C. Sutherland, Adrienne J. Sutton, Kazuaki Tadokoro, Maciej Telszewski, Matthias Tuma, Steven M. A. C. van Heuven, Doug Vandemark, Brian Ward, Andrew J. Watson, and Suqing Xu
Earth Syst. Sci. Data, 8, 383–413, https://doi.org/10.5194/essd-8-383-2016, https://doi.org/10.5194/essd-8-383-2016, 2016
Short summary
Short summary
Version 3 of the Surface Ocean CO2 Atlas (www.socat.info) has 14.5 million CO2 (carbon dioxide) values for the years 1957 to 2014 covering the global oceans and coastal seas. Version 3 is an update to version 2 with a longer record and 44 % more CO2 values. The CO2 measurements have been made on ships, fixed moorings and drifting buoys. SOCAT enables quantification of the ocean carbon sink and ocean acidification, as well as model evaluation, thus informing climate negotiations.
Allanah J. Paul, Eric P. Achterberg, Lennart T. Bach, Tim Boxhammer, Jan Czerny, Mathias Haunost, Kai-Georg Schulz, Annegret Stuhr, and Ulf Riebesell
Biogeosciences, 13, 3901–3913, https://doi.org/10.5194/bg-13-3901-2016, https://doi.org/10.5194/bg-13-3901-2016, 2016
Monika Nausch, Lennart Thomas Bach, Jan Czerny, Josephine Goldstein, Hans-Peter Grossart, Dana Hellemann, Thomas Hornick, Eric Pieter Achterberg, Kai-Georg Schulz, and Ulf Riebesell
Biogeosciences, 13, 3035–3050, https://doi.org/10.5194/bg-13-3035-2016, https://doi.org/10.5194/bg-13-3035-2016, 2016
Short summary
Short summary
Studies investigating the effect of increasing CO2 levels on the phosphorus cycle in natural waters are lacking although phosphorus often controls phytoplankton development in aquatic systems. The aim of our study was to analyse effects of elevated CO2 levels on phosphorus pool sizes and uptake. Therefore, we conducted a CO2-manipulation mesocosm experiment in the Storfjärden (western Gulf of Finland, Baltic Sea) in summer 2012. We compared the phosphorus dynamics in different mesocosm treatment
A. J. Paul, L. T. Bach, K.-G. Schulz, T. Boxhammer, J. Czerny, E. P. Achterberg, D. Hellemann, Y. Trense, M. Nausch, M. Sswat, and U. Riebesell
Biogeosciences, 12, 6181–6203, https://doi.org/10.5194/bg-12-6181-2015, https://doi.org/10.5194/bg-12-6181-2015, 2015
Y. Zhang, N. Mahowald, R. A. Scanza, E. Journet, K. Desboeufs, S. Albani, J. F. Kok, G. Zhuang, Y. Chen, D. D. Cohen, A. Paytan, M. D. Patey, E. P. Achterberg, J. P. Engelbrecht, and K. W. Fomba
Biogeosciences, 12, 5771–5792, https://doi.org/10.5194/bg-12-5771-2015, https://doi.org/10.5194/bg-12-5771-2015, 2015
Short summary
Short summary
A new technique to determine a size-fractionated global soil elemental emission inventory based on a global soil and mineralogical data set is introduced. Spatial variability of mineral dust elemental fractions (8 elements, e.g., Ca, Fe, Al) is identified on a global scale, particularly for Ca. The Ca/Al ratio ranged between 0.1 and 5.0 and is confirmed as an indicator of dust source regions by a global dust model. Total and soluble dust element fluxes into different ocean basins are estimated.
M. P. Humphreys, E. P. Achterberg, A. M. Griffiths, A. McDonald, and A. J. Boyce
Earth Syst. Sci. Data, 7, 127–135, https://doi.org/10.5194/essd-7-127-2015, https://doi.org/10.5194/essd-7-127-2015, 2015
Short summary
Short summary
We present measurements of the stable carbon isotope composition of seawater dissolved inorganic carbon. The samples were collected during two research cruises in boreal summer 2012 in the northeastern Atlantic and Nordic Seas. The results can be used to investigate the marine carbon cycle, providing information about biological productivity and oceanic uptake of anthropogenic carbon dioxide.
N. R. Bates, R. Garley, K. E. Frey, K. L. Shake, and J. T. Mathis
Biogeosciences, 11, 6769–6789, https://doi.org/10.5194/bg-11-6769-2014, https://doi.org/10.5194/bg-11-6769-2014, 2014
Short summary
Short summary
In a era or rapid warming and sea-ice loss in the Arctic Ocean, the paper describes the variability of seawater carbon dioxide (CO2) in summertime sea-ice melt pond water in the Pacific Arctic region, and the impact of melt pond chemistry upon the underlying upper ocean.
N. R. Bates, M. I. Orchowska, R. Garley, and J. T. Mathis
Biogeosciences, 10, 5281–5309, https://doi.org/10.5194/bg-10-5281-2013, https://doi.org/10.5194/bg-10-5281-2013, 2013
Related subject area
Chemical oceanography
Exploring the CO2 fugacity along the east coast of South America aboard the schooner Tara
Mapping the global distribution of lead and its isotopes in seawater with explainable machine learning
Global database of actual nitrogen loss rates in coastal and marine sediments
Tracer-based Rapid Anthropogenic Carbon Estimation (TRACE)
A continual-learning-based multilayer perceptron for improved reconstruction of three-dimensional nitrate concentrations
An updated synthesis of ocean total alkalinity and dissolved inorganic carbon measurements from 1993 to 2023: the SNAPO-CO2-v2 dataset
A global monthly 3D field of seawater pH over 3 decades: a machine learning approach
The high-resolution global shipping emission inventory by the Shipping Emission Inventory Model (SEIM)
A machine-learning reconstruction of sea surface pCO2 in the North American Atlantic Coastal Ocean Margin from 1993 to 2021
A consistent ocean oxygen profile dataset with new quality control and bias assessment
CO2 and hydrography acquired by autonomous surface vehicles from the Atlantic Ocean to the Mediterranean Sea: data correction and validation
A consistent regional dataset of dissolved oxygen in the Western Mediterranean Sea (2004–2023): O2WMED
A 20-year (1998–2017) global sea surface dimethyl sulfide gridded dataset with daily resolution
Distributions of in situ parameters, dissolved (in)organic carbon, and nutrients in the water column and pore waters of Arctic fjords (western Spitsbergen) during a melting season
Climatological distribution of ocean acidification variables along the North American ocean margins
Updated climatological mean ΔfCO2 and net sea–air CO2 flux over the global open ocean regions
The annual update GLODAPv2.2023: the global interior ocean biogeochemical data product
Synthesis Product for Ocean Time Series (SPOTS) – a ship-based biogeochemical pilot
French coastal network for carbonate system monitoring: the CocoriCO2 dataset
A global database of dissolved organic matter (DOM) concentration measurements in coastal waters (CoastDOM v1)
A decade-long cruise time series (2008–2018) of physical and biogeochemical conditions in the southern Salish Sea, North America
A regional pCO2 climatology of the Baltic Sea from in situ pCO2 observations and a model-based extrapolation approach
A 12-year-long (2010–2021) hydrological and biogeochemical dataset in the Sicily Channel (Mediterranean Sea)
A decade of marine inorganic carbon chemistry observations in the northern Gulf of Alaska – insights into an environment in transition
A novel sea surface pCO2-product for the global coastal ocean resolving trends over 1982–2020
A high-resolution synthesis dataset for multistressor analyses along the US West Coast
CMEMS-LSCE: a global, 0.25°, monthly reconstruction of the surface ocean carbonate system
A synthesis of ocean total alkalinity and dissolved inorganic carbon measurements from 1993 to 2022: the SNAPO-CO2-v1 dataset
A year of transient tracers (chlorofluorocarbon 12 and sulfur hexafluoride), noble gases (helium and neon), and tritium in the Arctic Ocean from the MOSAiC expedition (2019–2020)
Database of nitrification and nitrifiers in the global ocean
GOBAI-O2: temporally and spatially resolved fields of ocean interior dissolved oxygen over nearly 2 decades
Spatiotemporal variability in pH and carbonate parameters on the Canadian Atlantic continental shelf between 2014 and 2022
Barium in seawater: dissolved distribution, relationship to silicon, and barite saturation state determined using machine learning
Global oceanic diazotroph database version 2 and elevated estimate of global oceanic N2 fixation
High-frequency, year-round time series of the carbonate chemistry in a high-Arctic fjord (Svalbard)
OceanSODA-UNEXE: a multi-year gridded Amazon and Congo River outflow surface ocean carbonate system dataset
Evaluating the transport of surface seawater from 1956 to 2021 using 137Cs deposited in the global ocean as a chemical tracer
Spatial reconstruction of long-term (2003–2020) sea surface pCO2 in the South China Sea using a machine-learning-based regression method aided by empirical orthogonal function analysis
OceanSODA-MDB: a standardised surface ocean carbonate system dataset for model–data intercomparisons
Hyperspectral reflectance dataset of pristine, weathered, and biofouled plastics
A database of marine macronutrient, temperature and salinity measurements made around the highly productive island of South Georgia, the Scotia Sea and the Antarctic Peninsula between 1980 and 2009
GLODAPv2.2022: the latest version of the global interior ocean biogeochemical data product
Oil slicks in the Gulf of Guinea – 10 years of Envisat Advanced Synthetic Aperture Radar observations
Third revision of the global surface seawater dimethyl sulfide climatology (DMS-Rev3)
The CISE-LOCEAN seawater isotopic database (1998–2021)
Revisiting five decades of 234Th data: a comprehensive global oceanic compilation
A monthly surface pCO2 product for the California Current Large Marine Ecosystem
Climatological distribution of dissolved inorganic nutrients in the western Mediterranean Sea (1981–2017)
An updated version of the global interior ocean biogeochemical data product, GLODAPv2.2021
Coastal Ocean Data Analysis Product in North America (CODAP-NA) – an internally consistent data product for discrete inorganic carbon, oxygen, and nutrients on the North American ocean margins
Léa Olivier, Jacqueline Boutin, Gilles Reverdin, Christopher Hunt, Thomas Linkowski, Alison Chase, Nils Haentjens, Pedro C. Junger, Stéphane Pesant, and Douglas Vandemark
Earth Syst. Sci. Data, 17, 3583–3598, https://doi.org/10.5194/essd-17-3583-2025, https://doi.org/10.5194/essd-17-3583-2025, 2025
Short summary
Short summary
The air–sea CO2 flux in coastal waters plays a key role in the global carbon budget but remains poorly understood. In 2021, the Tara schooner collected 14 000 km of CO2 fugacity (fCO2) data along the South American coast. This dataset improves our understanding of fCO2 in the under-sampled Brazilian coastal region and provides a unique insight into the complex biogeochemistry of the Amazon River–ocean continuum.
Arianna Olivelli, Rossella Arcucci, Mark Rehkämper, and Tina van de Flierdt
Earth Syst. Sci. Data, 17, 3679–3699, https://doi.org/10.5194/essd-17-3679-2025, https://doi.org/10.5194/essd-17-3679-2025, 2025
Short summary
Short summary
In this study, we use machine learning models to produce the first global maps of Pb concentrations and isotope compositions in the ocean. In line with observations, we find that (i) the surface Indian Ocean has the highest levels of pollution, (ii) pollution from previous decades is sinking in the North Atlantic and Pacific oceans, and (iii) waters carrying Pb pollution are spreading from the Southern Ocean throughout the Southern Hemisphere at intermediate depths.
Yongkai Chang, Ehui Tan, Dengzhou Gao, Cheng Liu, Zongxiao Zhang, Zhixiong Huang, Jianan Liu, Yu Han, Zifu Xu, Bin Chen, and Shuh-Ji Kao
Earth Syst. Sci. Data, 17, 3521–3540, https://doi.org/10.5194/essd-17-3521-2025, https://doi.org/10.5194/essd-17-3521-2025, 2025
Short summary
Short summary
Denitrification and anaerobic ammonium oxidation (anammox) are two important nitrogen removal pathways that convert reactive nitrogen into dinitrogen gas. Here, we construct a global database on actual nitrogen loss rates, covering over 30 years of observations, measured in coastal and marine sediments. This work provides a global overview of the biogeography and potential controlling factors of denitrification and anammox and highlights the potential applications of this database.
Brendan R. Carter, Jörg Schwinger, Rolf Sonnerup, Andrea J. Fassbender, Jonathan D. Sharp, Larissa M. Dias, and Daniel E. Sandborn
Earth Syst. Sci. Data, 17, 3073–3088, https://doi.org/10.5194/essd-17-3073-2025, https://doi.org/10.5194/essd-17-3073-2025, 2025
Short summary
Short summary
We infer ocean gas exchange and circulation from ocean tracer measurements and use this to create code to estimate the amount of carbon dioxide dissolved in the ocean that is there due to human emissions of CO2 into the atmosphere. The code works across the ocean depths for the past, present, or future from information about the location, temperature, and salinity of the seawater. We produce a data product with estimates throughout the ocean throughout the last ~300 and the next ~500 years.
Xiang Yu, Huadong Guo, Jiahua Zhang, Yi Ma, Xiaopeng Wang, Guangsheng Liu, Mingming Xing, Nuo Xu, and Ayalkibet M. Seka
Earth Syst. Sci. Data, 17, 2735–2759, https://doi.org/10.5194/essd-17-2735-2025, https://doi.org/10.5194/essd-17-2735-2025, 2025
Short summary
Short summary
Mapping the 3D distribution of oceanic nitrate is challenging. We developed a continual-learning-based multilayer perceptron, integrating prior knowledge from numerical models and BGC-Argo validation to reconstruct a pan-European 3D nitrate field from 2010 to 2023 (0–2000 m depth, monthly, 0.25° horizontal resolution) using sea surface environmental features. This dataset helps bridge observational gaps and enhances understanding of the ocean's interior environment.
Nicolas Metzl, Jonathan Fin, Claire Lo Monaco, Claude Mignon, Samir Alliouane, Bruno Bombled, Jacqueline Boutin, Yann Bozec, Steeve Comeau, Pascal Conan, Laurent Coppola, Pascale Cuet, Eva Ferreira, Jean-Pierre Gattuso, Frédéric Gazeau, Catherine Goyet, Emilie Grossteffan, Bruno Lansard, Dominique Lefèvre, Nathalie Lefèvre, Coraline Leseurre, Sébastien Petton, Mireille Pujo-Pay, Christophe Rabouille, Gilles Reverdin, Céline Ridame, Peggy Rimmelin-Maury, Jean-François Ternon, Franck Touratier, Aline Tribollet, Thibaut Wagener, and Cathy Wimart-Rousseau
Earth Syst. Sci. Data, 17, 1075–1100, https://doi.org/10.5194/essd-17-1075-2025, https://doi.org/10.5194/essd-17-1075-2025, 2025
Short summary
Short summary
This work presents a new synthesis of 67 000 total alkalinity and total dissolved inorganic carbon observations obtained between 1993 and 2023 in the global ocean, coastal zones, and the Mediterranean Sea. We describe the data assemblage and associated quality control and discuss some potential uses of this dataset. The dataset is provided in a single format and includes the quality flag for each sample.
Guorong Zhong, Xuegang Li, Jinming Song, Baoxiao Qu, Fan Wang, Yanjun Wang, Bin Zhang, Lijing Cheng, Jun Ma, Huamao Yuan, Liqin Duan, Ning Li, Qidong Wang, Jianwei Xing, and Jiajia Dai
Earth Syst. Sci. Data, 17, 719–740, https://doi.org/10.5194/essd-17-719-2025, https://doi.org/10.5194/essd-17-719-2025, 2025
Short summary
Short summary
The continuous uptake of atmospheric CO2 by the ocean leads to decreasing seawater pH, which is an ongoing threat to the marine ecosystem. This pH change has been globally documented in the surface ocean, but information is limited below the surface. Here, we present a monthly 1° gridded product of global seawater pH based on a machine learning method and real pH observations. The pH product covers the years from 1992 to 2020 and depths from 0 to 2000 m.
Wen Yi, Xiaotong Wang, Tingkun He, Huan Liu, Zhenyu Luo, Zhaofeng Lv, and Kebin He
Earth Syst. Sci. Data, 17, 277–292, https://doi.org/10.5194/essd-17-277-2025, https://doi.org/10.5194/essd-17-277-2025, 2025
Short summary
Short summary
This study presents a detailed global dataset on ship emissions, covering the years 2013 and 2016–2021, using advanced modeling techniques. The dataset includes emissions data for four types of greenhouse gases and five types of air pollutants. The data, available for research, offer valuable insights into ship emission spatiotemporal patterns by vessel type and age, providing a solid data foundation for fine-scale scientific research and shipping emission mitigation.
Zelun Wu, Wenfang Lu, Alizée Roobaert, Luping Song, Xiao-Hai Yan, and Wei-Jun Cai
Earth Syst. Sci. Data, 17, 43–63, https://doi.org/10.5194/essd-17-43-2025, https://doi.org/10.5194/essd-17-43-2025, 2025
Short summary
Short summary
This study addresses the lack of comprehensive sea surface partial pressure of CO2 (pCO2) data in the North American Atlantic Coastal Ocean Margin (NAACOM) by developing the Reconstructed Coastal Acidification Database (ReCAD-NAACOM-pCO2). The product reconstructed sea surface pCO2 from 1993 to 2021 using machine-learning and environmental data, capturing seasonal cycles, regional variations, and long-term trends of pCO2 for coastal carbon research.
Viktor Gouretski, Lijing Cheng, Juan Du, Xiaogang Xing, Fei Chai, and Zhetao Tan
Earth Syst. Sci. Data, 16, 5503–5530, https://doi.org/10.5194/essd-16-5503-2024, https://doi.org/10.5194/essd-16-5503-2024, 2024
Short summary
Short summary
High-quality observations are crucial to understanding ocean oxygen changes and their impact on marine biota. We developed a quality control procedure to ensure the high quality of the heterogeneous ocean oxygen data archive and to prove data consistency. Oxygen data obtained by means of oxygen sensors on autonomous Argo floats were compared with reference data based on the chemical analysis, and estimates of the residual offsets were obtained.
Riccardo Martellucci, Michele Giani, Elena Mauri, Laurent Coppola, Melf Paulsen, Marine Fourrier, Sara Pensieri, Vanessa Cardin, Carlotta Dentico, Roberto Bozzano, Carolina Cantoni, Anna Lucchetta, Alfredo Izquierdo, Miguel Bruno, and Ingunn Skjelvan
Earth Syst. Sci. Data, 16, 5333–5356, https://doi.org/10.5194/essd-16-5333-2024, https://doi.org/10.5194/essd-16-5333-2024, 2024
Short summary
Short summary
As part of the ATL2MED demonstration experiment, two autonomous surface vehicles undertook a 9-month mission from the northeastern Atlantic to the Adriatic Sea. Biofouling affected the measurement of variables such as conductivity and dissolved oxygen. COVID-19 limited the availability of discrete samples for validation. We present correction methods for salinity and dissolved oxygen. We use model products to correct salinity and apply the Argo floats in-air correction method for oxygen
Malek Belgacem, Katrin Schroeder, Siv K. Lauvset, Marta Álvarez, Jacopo Chiggiato, Mireno Borghini, Carolina Cantoni, Tiziana Ciuffardi, and Stefania Sparnocchia
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-365, https://doi.org/10.5194/essd-2024-365, 2024
Revised manuscript accepted for ESSD
Short summary
Short summary
Having consistent dissolved Oxygen (O2) data is crucial for understanding the health of our oceans. By monitoring O2 levels, we can spot changes in water quality. Reliable data helps scientist and policymakers make informed decisions to protect marine environments, ensuring practices that benefit both wildlife and people. The Mediterranean Sea is particularly sensitive to climate change. O2WMED dataset- a compilation of data that provides a clear picture of O2 changes over the past 20 years.
Shengqian Zhou, Ying Chen, Shan Huang, Xianda Gong, Guipeng Yang, Honghai Zhang, Hartmut Herrmann, Alfred Wiedensohler, Laurent Poulain, Yan Zhang, Fanghui Wang, Zongjun Xu, and Ke Yan
Earth Syst. Sci. Data, 16, 4267–4290, https://doi.org/10.5194/essd-16-4267-2024, https://doi.org/10.5194/essd-16-4267-2024, 2024
Short summary
Short summary
Dimethyl sulfide (DMS) is a crucial natural reactive gas in the global climate system due to its great contribution to aerosols and subsequent impact on clouds over remote oceans. Leveraging machine learning techniques, we constructed a long-term global sea surface DMS gridded dataset with daily resolution. Compared to previous datasets, our new dataset holds promise for improving atmospheric chemistry modeling and advancing our comprehension of the climate effects associated with oceanic DMS.
Seyed Reza Saghravani, Michael Ernst Böttcher, Wei-Li Hong, Karol Kuliński, Aivo Lepland, Arunima Sen, and Beata Szymczycha
Earth Syst. Sci. Data, 16, 3419–3431, https://doi.org/10.5194/essd-16-3419-2024, https://doi.org/10.5194/essd-16-3419-2024, 2024
Short summary
Short summary
A comprehensive study conducted in 2021 examined the distributions of dissolved nutrients and carbon in the western Spitsbergen fjords during the high-melting season. Significant spatial variability was observed in the water column and pore water concentrations of constituents, highlighting the unique biogeochemical characteristics of each fjord and their potential impact on ecosystem functioning and oceanographic processes.
Li-Qing Jiang, Tim P. Boyer, Christopher R. Paver, Hyelim Yoo, James R. Reagan, Simone R. Alin, Leticia Barbero, Brendan R. Carter, Richard A. Feely, and Rik Wanninkhof
Earth Syst. Sci. Data, 16, 3383–3390, https://doi.org/10.5194/essd-16-3383-2024, https://doi.org/10.5194/essd-16-3383-2024, 2024
Short summary
Short summary
In this paper, we unveil a data product featuring ten coastal ocean acidification variables. These indicators are provided on 1°×1° spatial grids at 14 standardized depth levels, ranging from the surface to a depth of 500 m, along the North American ocean margins.
Amanda R. Fay, David R. Munro, Galen A. McKinley, Denis Pierrot, Stewart C. Sutherland, Colm Sweeney, and Rik Wanninkhof
Earth Syst. Sci. Data, 16, 2123–2139, https://doi.org/10.5194/essd-16-2123-2024, https://doi.org/10.5194/essd-16-2123-2024, 2024
Short summary
Short summary
Presented here is a near-global monthly climatological estimate of the difference between atmosphere and ocean carbon dioxide concentrations. The ocean's ability to take up carbon, both now and in the future, is defined by this difference in concentrations. With over 30 million measurements of surface ocean carbon over the last 40 years and utilization of an extrapolation technique, a mean estimate of surface ocean ΔfCO2 is presented.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Marta Álvarez, Kumiko Azetsu-Scott, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Akihiko Murata, Jens Daniel Müller, Fiz F. Pérez, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 16, 2047–2072, https://doi.org/10.5194/essd-16-2047-2024, https://doi.org/10.5194/essd-16-2047-2024, 2024
Short summary
Short summary
GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2023 is the fifth update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality controlling, including systematic evaluation of measurement biases. This version contains data from 1108 hydrographic cruises covering the world's oceans from 1972 to 2021.
Nico Lange, Björn Fiedler, Marta Álvarez, Alice Benoit-Cattin, Heather Benway, Pier Luigi Buttigieg, Laurent Coppola, Kim Currie, Susana Flecha, Dana S. Gerlach, Makio Honda, I. Emma Huertas, Siv K. Lauvset, Frank Muller-Karger, Arne Körtzinger, Kevin M. O'Brien, Sólveig R. Ólafsdóttir, Fernando C. Pacheco, Digna Rueda-Roa, Ingunn Skjelvan, Masahide Wakita, Angelicque White, and Toste Tanhua
Earth Syst. Sci. Data, 16, 1901–1931, https://doi.org/10.5194/essd-16-1901-2024, https://doi.org/10.5194/essd-16-1901-2024, 2024
Short summary
Short summary
The Synthesis Product for Ocean Time Series (SPOTS) is a novel achievement expanding and complementing the biogeochemical data landscape by providing consistent and high-quality biogeochemical time-series data from 12 ship-based fixed time-series programs. SPOTS covers multiple unique marine environments and time-series ranges, including data from 1983 to 2021. All in all, it facilitates a variety of applications that benefit from the collective value of biogeochemical time-series observations.
Sébastien Petton, Fabrice Pernet, Valérian Le Roy, Matthias Huber, Sophie Martin, Éric Macé, Yann Bozec, Stéphane Loisel, Peggy Rimmelin-Maury, Émilie Grossteffan, Michel Repecaud, Loïc Quemener, Michael Retho, Soazig Manac'h, Mathias Papin, Philippe Pineau, Thomas Lacoue-Labarthe, Jonathan Deborde, Louis Costes, Pierre Polsenaere, Loïc Rigouin, Jérémy Benhamou, Laure Gouriou, Joséphine Lequeux, Nathalie Labourdette, Nicolas Savoye, Grégory Messiaen, Elodie Foucault, Vincent Ouisse, Marion Richard, Franck Lagarde, Florian Voron, Valentin Kempf, Sébastien Mas, Léa Giannecchini, Francesca Vidussi, Behzad Mostajir, Yann Leredde, Samir Alliouane, Jean-Pierre Gattuso, and Frédéric Gazeau
Earth Syst. Sci. Data, 16, 1667–1688, https://doi.org/10.5194/essd-16-1667-2024, https://doi.org/10.5194/essd-16-1667-2024, 2024
Short summary
Short summary
Our research highlights the concerning impact of rising carbon dioxide levels on coastal areas. To better understand these changes, we've established an observation network in France. By deploying pH sensors and other monitoring equipment at key coastal sites, we're gaining valuable insights into how various factors, such as freshwater inputs, tides, temperature, and biological processes, influence ocean pH.
Christian Lønborg, Cátia Carreira, Gwenaël Abril, Susana Agustí, Valentina Amaral, Agneta Andersson, Javier Arístegui, Punyasloke Bhadury, Mariana B. Bif, Alberto V. Borges, Steven Bouillon, Maria Ll. Calleja, Luiz C. Cotovicz Jr., Stefano Cozzi, Maryló Doval, Carlos M. Duarte, Bradley Eyre, Cédric G. Fichot, E. Elena García-Martín, Alexandra Garzon-Garcia, Michele Giani, Rafael Gonçalves-Araujo, Renee Gruber, Dennis A. Hansell, Fuminori Hashihama, Ding He, Johnna M. Holding, William R. Hunter, J. Severino P. Ibánhez, Valeria Ibello, Shan Jiang, Guebuem Kim, Katja Klun, Piotr Kowalczuk, Atsushi Kubo, Choon-Weng Lee, Cláudia B. Lopes, Federica Maggioni, Paolo Magni, Celia Marrase, Patrick Martin, S. Leigh McCallister, Roisin McCallum, Patricia M. Medeiros, Xosé Anxelu G. Morán, Frank E. Muller-Karger, Allison Myers-Pigg, Marit Norli, Joanne M. Oakes, Helena Osterholz, Hyekyung Park, Maria Lund Paulsen, Judith A. Rosentreter, Jeff D. Ross, Digna Rueda-Roa, Chiara Santinelli, Yuan Shen, Eva Teira, Tinkara Tinta, Guenther Uher, Masahide Wakita, Nicholas Ward, Kenta Watanabe, Yu Xin, Youhei Yamashita, Liyang Yang, Jacob Yeo, Huamao Yuan, Qiang Zheng, and Xosé Antón Álvarez-Salgado
Earth Syst. Sci. Data, 16, 1107–1119, https://doi.org/10.5194/essd-16-1107-2024, https://doi.org/10.5194/essd-16-1107-2024, 2024
Short summary
Short summary
In this paper, we present the first edition of a global database compiling previously published and unpublished measurements of dissolved organic matter (DOM) collected in coastal waters (CoastDOM v1). Overall, the CoastDOM v1 dataset will be useful to identify global spatial and temporal patterns and to facilitate reuse in studies aimed at better characterizing local biogeochemical processes and identifying a baseline for modelling future changes in coastal waters.
Simone R. Alin, Jan A. Newton, Richard A. Feely, Dana Greeley, Beth Curry, Julian Herndon, and Mark Warner
Earth Syst. Sci. Data, 16, 837–865, https://doi.org/10.5194/essd-16-837-2024, https://doi.org/10.5194/essd-16-837-2024, 2024
Short summary
Short summary
The Salish cruise data product provides 2008–2018 oceanographic data from the southern Salish Sea and nearby coastal sampling stations. Temperature, salinity, oxygen, nutrient, and dissolved inorganic carbon measurements from 715 oceanographic profiles will facilitate further study of ocean acidification, hypoxia, and marine heatwave impacts in this region. Three subsets of the compiled datasets from 35 cruises are available with consistent formatting and multiple commonly used units.
Henry C. Bittig, Erik Jacobs, Thomas Neumann, and Gregor Rehder
Earth Syst. Sci. Data, 16, 753–773, https://doi.org/10.5194/essd-16-753-2024, https://doi.org/10.5194/essd-16-753-2024, 2024
Short summary
Short summary
We present a pCO2 climatology of the Baltic Sea using a new approach to extrapolate from individual observations to the entire Baltic Sea. The extrapolation approach uses (a) a model to inform on how data at one location are connected to data at other locations, together with (b) very accurate pCO2 observations from 2003 to 2021 as the base data. The climatology can be used e.g. to assess uptake and release of CO2 or to identify extreme events.
Francesco Placenti, Marco Torri, Katrin Schroeder, Mireno Borghini, Gabriella Cerrati, Angela Cuttitta, Vincenzo Tancredi, Carmelo Buscaino, and Bernardo Patti
Earth Syst. Sci. Data, 16, 743–752, https://doi.org/10.5194/essd-16-743-2024, https://doi.org/10.5194/essd-16-743-2024, 2024
Short summary
Short summary
Oceanographic surveys were conducted in the Strait of Sicily between 2010 and 2021. This paper provides a description of the time series of nutrients and hydrological data collected in this zone. The dataset fills an important gap in field observations of a crucial area where exchanges with the Mediterranean sub-basin take place, providing support for studies aimed at describing ongoing processes and at realizing reliable projections of the effects of these processes in the near future.
Natalie M. Monacci, Jessica N. Cross, Wiley Evans, Jeremy T. Mathis, and Hongjie Wang
Earth Syst. Sci. Data, 16, 647–665, https://doi.org/10.5194/essd-16-647-2024, https://doi.org/10.5194/essd-16-647-2024, 2024
Short summary
Short summary
As carbon dioxide is released into the air through human-generated activity, about one third dissolves into the surface water of oceans, lowering pH and increasing acidity. This is known as ocean acidification. We merged 10 years of ocean carbon data and made them publicly available for adaptation planning during a time of change. The data confirmed that Alaska is already experiencing the effects of ocean acidification due to naturally cold water, high productivity, and circulation patterns.
Alizée Roobaert, Pierre Regnier, Peter Landschützer, and Goulven G. Laruelle
Earth Syst. Sci. Data, 16, 421–441, https://doi.org/10.5194/essd-16-421-2024, https://doi.org/10.5194/essd-16-421-2024, 2024
Short summary
Short summary
The quantification of the coastal air–sea CO2 exchange (FCO2) has improved in recent years, but its multiannual variability remains unclear. This study, based on interpolated observations, reconstructs the longest global time series of coastal FCO2 (1982–2020). Results show the coastal ocean acts as a CO2 sink, with increasing intensity over time. This new coastal FCO2-product allows establishing regional carbon budgets and provides new constraints for closing the global carbon cycle.
Esther G. Kennedy, Meghan Zulian, Sara L. Hamilton, Tessa M. Hill, Manuel Delgado, Carina R. Fish, Brian Gaylord, Kristy J. Kroeker, Hannah M. Palmer, Aurora M. Ricart, Eric Sanford, Ana K. Spalding, Melissa Ward, Guadalupe Carrasco, Meredith Elliott, Genece V. Grisby, Evan Harris, Jaime Jahncke, Catherine N. Rocheleau, Sebastian Westerink, and Maddie I. Wilmot
Earth Syst. Sci. Data, 16, 219–243, https://doi.org/10.5194/essd-16-219-2024, https://doi.org/10.5194/essd-16-219-2024, 2024
Short summary
Short summary
We present a new synthesis of oceanographic observations along the US West Coast that has been optimized for multiparameter investigations of coastal warming, deoxygenation, and acidification risk. This synthesis includes both previously published and new observations, all of which have been consistently formatted and quality-controlled to facilitate high-resolution investigations of climate risks and consequences across a wide range of spatial and temporal scales.
Thi-Tuyet-Trang Chau, Marion Gehlen, Nicolas Metzl, and Frédéric Chevallier
Earth Syst. Sci. Data, 16, 121–160, https://doi.org/10.5194/essd-16-121-2024, https://doi.org/10.5194/essd-16-121-2024, 2024
Short summary
Short summary
CMEMS-LSCE leads as the first global observation-based reconstructions of six carbonate system variables for the years 1985–2021 at monthly and 0.25° resolutions. The high-resolution reconstructions outperform their 1° counterpart in reproducing horizontal and temporal gradients of observations over various oceanic regions to nearshore time series stations. New datasets can be exploited in numerous studies, including monitoring changes in ocean carbon uptake and ocean acidification.
Nicolas Metzl, Jonathan Fin, Claire Lo Monaco, Claude Mignon, Samir Alliouane, David Antoine, Guillaume Bourdin, Jacqueline Boutin, Yann Bozec, Pascal Conan, Laurent Coppola, Frédéric Diaz, Eric Douville, Xavier Durrieu de Madron, Jean-Pierre Gattuso, Frédéric Gazeau, Melek Golbol, Bruno Lansard, Dominique Lefèvre, Nathalie Lefèvre, Fabien Lombard, Férial Louanchi, Liliane Merlivat, Léa Olivier, Anne Petrenko, Sébastien Petton, Mireille Pujo-Pay, Christophe Rabouille, Gilles Reverdin, Céline Ridame, Aline Tribollet, Vincenzo Vellucci, Thibaut Wagener, and Cathy Wimart-Rousseau
Earth Syst. Sci. Data, 16, 89–120, https://doi.org/10.5194/essd-16-89-2024, https://doi.org/10.5194/essd-16-89-2024, 2024
Short summary
Short summary
This work presents a synthesis of 44 000 total alkalinity and dissolved inorganic carbon observations obtained between 1993 and 2022 in the Global Ocean and the Mediterranean Sea at the surface and in the water column. Seawater samples were measured using the same method and calibrated with international Certified Reference Material. We describe the data assemblage, quality control and some potential uses of this dataset.
Céline Heuzé, Oliver Huhn, Maren Walter, Natalia Sukhikh, Salar Karam, Wiebke Körtke, Myriel Vredenborg, Klaus Bulsiewicz, Jürgen Sültenfuß, Ying-Chih Fang, Christian Mertens, Benjamin Rabe, Sandra Tippenhauer, Jacob Allerholt, Hailun He, David Kuhlmey, Ivan Kuznetsov, and Maria Mallet
Earth Syst. Sci. Data, 15, 5517–5534, https://doi.org/10.5194/essd-15-5517-2023, https://doi.org/10.5194/essd-15-5517-2023, 2023
Short summary
Short summary
Gases dissolved in the ocean water not used by the ecosystem (or "passive tracers") are invaluable to track water over long distances and investigate the processes that modify its properties. Unfortunately, especially so in the ice-covered Arctic Ocean, such gas measurements are sparse. We here present a data set of several passive tracers (anthropogenic gases, noble gases and their isotopes) collected over the full ocean depth, weekly, during the 1-year drift in the Arctic during MOSAiC.
Weiyi Tang, Bess B. Ward, Michael Beman, Laura Bristow, Darren Clark, Sarah Fawcett, Claudia Frey, François Fripiat, Gerhard J. Herndl, Mhlangabezi Mdutyana, Fabien Paulot, Xuefeng Peng, Alyson E. Santoro, Takuhei Shiozaki, Eva Sintes, Charles Stock, Xin Sun, Xianhui S. Wan, Min N. Xu, and Yao Zhang
Earth Syst. Sci. Data, 15, 5039–5077, https://doi.org/10.5194/essd-15-5039-2023, https://doi.org/10.5194/essd-15-5039-2023, 2023
Short summary
Short summary
Nitrification and nitrifiers play an important role in marine nitrogen and carbon cycles by converting ammonium to nitrite and nitrate. Nitrification could affect microbial community structure, marine productivity, and the production of nitrous oxide – a powerful greenhouse gas. We introduce the newly constructed database of nitrification and nitrifiers in the marine water column and guide future research efforts in field observations and model development of nitrification.
Jonathan D. Sharp, Andrea J. Fassbender, Brendan R. Carter, Gregory C. Johnson, Cristina Schultz, and John P. Dunne
Earth Syst. Sci. Data, 15, 4481–4518, https://doi.org/10.5194/essd-15-4481-2023, https://doi.org/10.5194/essd-15-4481-2023, 2023
Short summary
Short summary
Dissolved oxygen content is a critical metric of ocean health. Recently, expanding fleets of autonomous platforms that measure oxygen in the ocean have produced a wealth of new data. We leverage machine learning to take advantage of this growing global dataset, producing a gridded data product of ocean interior dissolved oxygen at monthly resolution over nearly 2 decades. This work provides novel information for investigations of spatial, seasonal, and interannual variability in ocean oxygen.
Olivia Gibb, Frédéric Cyr, Kumiko Azetsu-Scott, Joël Chassé, Darlene Childs, Carrie-Ellen Gabriel, Peter S. Galbraith, Gary Maillet, Pierre Pepin, Stephen Punshon, and Michel Starr
Earth Syst. Sci. Data, 15, 4127–4162, https://doi.org/10.5194/essd-15-4127-2023, https://doi.org/10.5194/essd-15-4127-2023, 2023
Short summary
Short summary
The ocean absorbs large quantities of carbon dioxide (CO2) released into the atmosphere as a result of the burning of fossil fuels. This, in turn, causes ocean acidification, which poses a major threat to global ocean ecosystems. In this study, we compiled 9 years (2014–2022) of ocean carbonate data (i.e., ocean acidification parameters) collected in Atlantic Canada as part of the Atlantic Zone Monitoring Program.
Öykü Z. Mete, Adam V. Subhas, Heather H. Kim, Ann G. Dunlea, Laura M. Whitmore, Alan M. Shiller, Melissa Gilbert, William D. Leavitt, and Tristan J. Horner
Earth Syst. Sci. Data, 15, 4023–4045, https://doi.org/10.5194/essd-15-4023-2023, https://doi.org/10.5194/essd-15-4023-2023, 2023
Short summary
Short summary
We present results from a machine learning model that accurately predicts dissolved barium concentrations for the global ocean. Our results reveal that the whole-ocean barium inventory is significantly lower than previously thought and that the deep ocean below 1000 m is at equilibrium with respect to barite. The model output can be used for a number of applications, including intercomparison, interpolation, and identification of regions warranting additional investigation.
Zhibo Shao, Yangchun Xu, Hua Wang, Weicheng Luo, Lice Wang, Yuhong Huang, Nona Sheila R. Agawin, Ayaz Ahmed, Mar Benavides, Mikkel Bentzon-Tilia, Ilana Berman-Frank, Hugo Berthelot, Isabelle C. Biegala, Mariana B. Bif, Antonio Bode, Sophie Bonnet, Deborah A. Bronk, Mark V. Brown, Lisa Campbell, Douglas G. Capone, Edward J. Carpenter, Nicolas Cassar, Bonnie X. Chang, Dreux Chappell, Yuh-ling Lee Chen, Matthew J. Church, Francisco M. Cornejo-Castillo, Amália Maria Sacilotto Detoni, Scott C. Doney, Cecile Dupouy, Marta Estrada, Camila Fernandez, Bieito Fernández-Castro, Debany Fonseca-Batista, Rachel A. Foster, Ken Furuya, Nicole Garcia, Kanji Goto, Jesús Gago, Mary R. Gradoville, M. Robert Hamersley, Britt A. Henke, Cora Hörstmann, Amal Jayakumar, Zhibing Jiang, Shuh-Ji Kao, David M. Karl, Leila R. Kittu, Angela N. Knapp, Sanjeev Kumar, Julie LaRoche, Hongbin Liu, Jiaxing Liu, Caroline Lory, Carolin R. Löscher, Emilio Marañón, Lauren F. Messer, Matthew M. Mills, Wiebke Mohr, Pia H. Moisander, Claire Mahaffey, Robert Moore, Beatriz Mouriño-Carballido, Margaret R. Mulholland, Shin-ichiro Nakaoka, Joseph A. Needoba, Eric J. Raes, Eyal Rahav, Teodoro Ramírez-Cárdenas, Christian Furbo Reeder, Lasse Riemann, Virginie Riou, Julie C. Robidart, Vedula V. S. S. Sarma, Takuya Sato, Himanshu Saxena, Corday Selden, Justin R. Seymour, Dalin Shi, Takuhei Shiozaki, Arvind Singh, Rachel E. Sipler, Jun Sun, Koji Suzuki, Kazutaka Takahashi, Yehui Tan, Weiyi Tang, Jean-Éric Tremblay, Kendra Turk-Kubo, Zuozhu Wen, Angelicque E. White, Samuel T. Wilson, Takashi Yoshida, Jonathan P. Zehr, Run Zhang, Yao Zhang, and Ya-Wei Luo
Earth Syst. Sci. Data, 15, 3673–3709, https://doi.org/10.5194/essd-15-3673-2023, https://doi.org/10.5194/essd-15-3673-2023, 2023
Short summary
Short summary
N2 fixation by marine diazotrophs is an important bioavailable N source to the global ocean. This updated global oceanic diazotroph database increases the number of in situ measurements of N2 fixation rates, diazotrophic cell abundances, and nifH gene copy abundances by 184 %, 86 %, and 809 %, respectively. Using the updated database, the global marine N2 fixation rate is estimated at 223 ± 30 Tg N yr−1, which triplicates that using the original database.
Jean-Pierre Gattuso, Samir Alliouane, and Philipp Fischer
Earth Syst. Sci. Data, 15, 2809–2825, https://doi.org/10.5194/essd-15-2809-2023, https://doi.org/10.5194/essd-15-2809-2023, 2023
Short summary
Short summary
The Arctic Ocean is subject to high rates of ocean warming and acidification, with critical implications for marine organisms, ecosystems and the services they provide. We report here on the first high-frequency (1 h), multi-year (5 years) dataset of the carbonate system at a coastal site in a high-Arctic fjord (Kongsfjorden, Svalbard). This site is a significant sink for CO2 every month of the year (9 to 17 mol m-2 yr-1). The saturation state of aragonite can be as low as 1.3.
Richard P. Sims, Thomas M. Holding, Peter E. Land, Jean-Francois Piolle, Hannah L. Green, and Jamie D. Shutler
Earth Syst. Sci. Data, 15, 2499–2516, https://doi.org/10.5194/essd-15-2499-2023, https://doi.org/10.5194/essd-15-2499-2023, 2023
Short summary
Short summary
The flow of carbon between the land and ocean is poorly quantified with existing measurements. It is not clear how seasonality and long-term variability impact this flow of carbon. Here, we demonstrate how satellite observations can be used to create decadal time series of the inorganic carbonate system in the Amazon and Congo River outflows.
Yayoi Inomata and Michio Aoyama
Earth Syst. Sci. Data, 15, 1969–2007, https://doi.org/10.5194/essd-15-1969-2023, https://doi.org/10.5194/essd-15-1969-2023, 2023
Short summary
Short summary
The behavior of 137Cs in surface seawater in the global ocean was analyzed by using the HAMGlobal2021 database. Approximately 32 % of 137Cs existed in the surface seawater in 1970. The 137Cs released into the North Pacific Ocean by large-scale nuclear weapons tests was transported to the Indian Ocean and then the Atlantic Ocean on a 4–5 decadal timescale, whereas 137Cs released from nuclear reprocessing plants was transported northward to the Arctic Ocean on a decadal scale.
Zhixuan Wang, Guizhi Wang, Xianghui Guo, Yan Bai, Yi Xu, and Minhan Dai
Earth Syst. Sci. Data, 15, 1711–1731, https://doi.org/10.5194/essd-15-1711-2023, https://doi.org/10.5194/essd-15-1711-2023, 2023
Short summary
Short summary
We reconstructed monthly sea surface pCO2 data with a high spatial resolution in the South China Sea (SCS) from 2003 to 2020. We validate our reconstruction with three independent testing datasets and present a new method to assess the uncertainty of the data. The results strongly suggest that our reconstruction effectively captures the main features of the spatiotemporal patterns of pCO2 in the SCS. Using this dataset, we found that the SCS is overall a weak source of atmospheric CO2.
Peter Edward Land, Helen S. Findlay, Jamie D. Shutler, Jean-Francois Piolle, Richard Sims, Hannah Green, Vassilis Kitidis, Alexander Polukhin, and Irina I. Pipko
Earth Syst. Sci. Data, 15, 921–947, https://doi.org/10.5194/essd-15-921-2023, https://doi.org/10.5194/essd-15-921-2023, 2023
Short summary
Short summary
Measurements of the ocean’s carbonate system (e.g. CO2 and pH) have increased greatly in recent years, resulting in a need to combine these data with satellite measurements and model results, so they can be used to test predictions of how the ocean reacts to changes such as absorption of the CO2 emitted by humans. We show a method of combining data into regions of interest (100 km circles over a 10 d period) and apply it globally to produce a harmonised and easy-to-use data archive.
Giulia Leone, Ana I. Catarino, Liesbeth De Keukelaere, Mattias Bossaer, Els Knaeps, and Gert Everaert
Earth Syst. Sci. Data, 15, 745–752, https://doi.org/10.5194/essd-15-745-2023, https://doi.org/10.5194/essd-15-745-2023, 2023
Short summary
Short summary
This paper illustrates a dataset of hyperspectral reflectance measurements of macroplastics. Plastic samples consisted of pristine, artificially weathered, and biofouled plastic items and field plastic debris. Samples were measured in dry conditions and a subset of plastics in wet and submerged conditions. This dataset can be used to better understand plastic optical features when exposed to natural agents and to support the development of algorithms for monitoring environmental plastics.
Michael J. Whitehouse, Katharine R. Hendry, Geraint A. Tarling, Sally E. Thorpe, and Petra ten Hoopen
Earth Syst. Sci. Data, 15, 211–224, https://doi.org/10.5194/essd-15-211-2023, https://doi.org/10.5194/essd-15-211-2023, 2023
Short summary
Short summary
We present a database of Southern Ocean macronutrient, temperature and salinity measurements collected on 20 oceanographic cruises between 1980 and 2009. Vertical profiles and underway surface measurements were collected year-round as part of an integrated ecosystem study. Our data provide a novel view of biogeochemical cycling in biologically productive regions across a critical period in recent climate history and will contribute to a better understanding of the drivers of primary production.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Simone Alin, Marta Álvarez, Kumiko Azetsu-Scott, Leticia Barbero, Susan Becker, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Richard A. Feely, Mario Hoppema, Matthew P. Humphreys, Masao Ishii, Emil Jeansson, Li-Qing Jiang, Steve D. Jones, Claire Lo Monaco, Akihiko Murata, Jens Daniel Müller, Fiz F. Pérez, Benjamin Pfeil, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Bronte Tilbrook, Adam Ulfsbo, Anton Velo, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 14, 5543–5572, https://doi.org/10.5194/essd-14-5543-2022, https://doi.org/10.5194/essd-14-5543-2022, 2022
Short summary
Short summary
GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2022 is the fourth update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality controlling, including systematic evaluation of measurement biases. This version contains data from 1085 hydrographic cruises covering the world's oceans from 1972 to 2021.
Zhour Najoui, Nellya Amoussou, Serge Riazanoff, Guillaume Aurel, and Frédéric Frappart
Earth Syst. Sci. Data, 14, 4569–4588, https://doi.org/10.5194/essd-14-4569-2022, https://doi.org/10.5194/essd-14-4569-2022, 2022
Short summary
Short summary
Oil spills could have serious repercussions for both the marine environment and ecosystem. The Gulf of Guinea is a very active area with respect to maritime traffic as well as oil and gas exploitation (platforms). As a result, the region is subject to a large number of oil pollution events. This study aims to detect oil slicks in the Gulf of Guinea and analyse their spatial and temporal distribution using satellite data.
Shrivardhan Hulswar, Rafel Simó, Martí Galí, Thomas G. Bell, Arancha Lana, Swaleha Inamdar, Paul R. Halloran, George Manville, and Anoop Sharad Mahajan
Earth Syst. Sci. Data, 14, 2963–2987, https://doi.org/10.5194/essd-14-2963-2022, https://doi.org/10.5194/essd-14-2963-2022, 2022
Short summary
Short summary
The third climatological estimation of sea surface dimethyl sulfide (DMS) concentrations based on in situ measurements was created (DMS-Rev3). The update includes a much larger input dataset and includes improvements in the data unification, filtering, and smoothing algorithm. The DMS-Rev3 climatology provides more realistic monthly estimates of DMS, and shows significant regional differences compared to past climatologies.
Gilles Reverdin, Claire Waelbroeck, Catherine Pierre, Camille Akhoudas, Giovanni Aloisi, Marion Benetti, Bernard Bourlès, Magnus Danielsen, Jérôme Demange, Denis Diverrès, Jean-Claude Gascard, Marie-Noëlle Houssais, Hervé Le Goff, Pascale Lherminier, Claire Lo Monaco, Herlé Mercier, Nicolas Metzl, Simon Morisset, Aïcha Naamar, Thierry Reynaud, Jean-Baptiste Sallée, Virginie Thierry, Susan E. Hartman, Edward W. Mawji, Solveig Olafsdottir, Torsten Kanzow, Anton Velo, Antje Voelker, Igor Yashayaev, F. Alexander Haumann, Melanie J. Leng, Carol Arrowsmith, and Michael Meredith
Earth Syst. Sci. Data, 14, 2721–2735, https://doi.org/10.5194/essd-14-2721-2022, https://doi.org/10.5194/essd-14-2721-2022, 2022
Short summary
Short summary
The CISE-LOCEAN seawater stable isotope dataset has close to 8000 data entries. The δ18O and δD isotopic data measured at LOCEAN have uncertainties of at most 0.05 ‰ and 0.25 ‰, respectively. Some data were adjusted to correct for evaporation. The internal consistency indicates that the data can be used to investigate time and space variability to within 0.03 ‰ and 0.15 ‰ in δ18O–δD17; comparisons with data analyzed in other institutions suggest larger differences with other datasets.
Elena Ceballos-Romero, Ken O. Buesseler, and María Villa-Alfageme
Earth Syst. Sci. Data, 14, 2639–2679, https://doi.org/10.5194/essd-14-2639-2022, https://doi.org/10.5194/essd-14-2639-2022, 2022
Short summary
Short summary
Thorium-234 is widely used for studying the removal rate of material on sinking particles from the upper ocean and for determining the downward flux of carbon. In this study, we present a compilation of the 50 years of 234Th measurements in the ocean and provide a broad overview of the character of the datasets. This provides a valuable resource useful to better understand and quantify how the contemporary oceanic carbon uptake functions and how it will change in future.
Jonathan D. Sharp, Andrea J. Fassbender, Brendan R. Carter, Paige D. Lavin, and Adrienne J. Sutton
Earth Syst. Sci. Data, 14, 2081–2108, https://doi.org/10.5194/essd-14-2081-2022, https://doi.org/10.5194/essd-14-2081-2022, 2022
Short summary
Short summary
Oceanographers calculate the exchange of carbon between the ocean and atmosphere by comparing partial pressures of carbon dioxide (pCO2). Because seawater pCO2 is not measured everywhere at all times, interpolation schemes are required to fill observational gaps. We describe a monthly gap-filled dataset of pCO2 in the northeast Pacific Ocean off the west coast of North America created by machine-learning interpolation. This dataset is unique in its robust representation of coastal seasonality.
Malek Belgacem, Katrin Schroeder, Alexander Barth, Charles Troupin, Bruno Pavoni, Patrick Raimbault, Nicole Garcia, Mireno Borghini, and Jacopo Chiggiato
Earth Syst. Sci. Data, 13, 5915–5949, https://doi.org/10.5194/essd-13-5915-2021, https://doi.org/10.5194/essd-13-5915-2021, 2021
Short summary
Short summary
The Mediterranean Sea exhibits an anti-estuarine circulation, responsible for its low productivity. Understanding this peculiar character is still a challenge since there is no exact quantification of nutrient sinks and sources. Because nutrient in situ observations are generally infrequent and scattered in space and time, climatological mapping is often applied to sparse data in order to understand the biogeochemical state of the ocean. The dataset presented here partly addresses these issues.
Siv K. Lauvset, Nico Lange, Toste Tanhua, Henry C. Bittig, Are Olsen, Alex Kozyr, Marta Álvarez, Susan Becker, Peter J. Brown, Brendan R. Carter, Leticia Cotrim da Cunha, Richard A. Feely, Steven van Heuven, Mario Hoppema, Masao Ishii, Emil Jeansson, Sara Jutterström, Steve D. Jones, Maren K. Karlsen, Claire Lo Monaco, Patrick Michaelis, Akihiko Murata, Fiz F. Pérez, Benjamin Pfeil, Carsten Schirnick, Reiner Steinfeldt, Toru Suzuki, Bronte Tilbrook, Anton Velo, Rik Wanninkhof, Ryan J. Woosley, and Robert M. Key
Earth Syst. Sci. Data, 13, 5565–5589, https://doi.org/10.5194/essd-13-5565-2021, https://doi.org/10.5194/essd-13-5565-2021, 2021
Short summary
Short summary
GLODAP is a data product for ocean inorganic carbon and related biogeochemical variables measured by the chemical analysis of water bottle samples from scientific cruises. GLODAPv2.2021 is the third update of GLODAPv2 from 2016. The data that are included have been subjected to extensive quality control, including systematic evaluation of measurement biases. This version contains data from 989 hydrographic cruises covering the world's oceans from 1972 to 2020.
Li-Qing Jiang, Richard A. Feely, Rik Wanninkhof, Dana Greeley, Leticia Barbero, Simone Alin, Brendan R. Carter, Denis Pierrot, Charles Featherstone, James Hooper, Chris Melrose, Natalie Monacci, Jonathan D. Sharp, Shawn Shellito, Yuan-Yuan Xu, Alex Kozyr, Robert H. Byrne, Wei-Jun Cai, Jessica Cross, Gregory C. Johnson, Burke Hales, Chris Langdon, Jeremy Mathis, Joe Salisbury, and David W. Townsend
Earth Syst. Sci. Data, 13, 2777–2799, https://doi.org/10.5194/essd-13-2777-2021, https://doi.org/10.5194/essd-13-2777-2021, 2021
Short summary
Short summary
Coastal ecosystems account for most of the economic activities related to commercial and recreational fisheries and aquaculture industries, supporting about 90 % of the global fisheries yield and 80 % of known species of marine fish. Despite the large potential risks from ocean acidification (OA), internally consistent water column OA data products in the coastal ocean still do not exist. This paper is the first time we report a high quality OA data product in North America's coastal waters.
Cited articles
Achterberg, E. P.: Grand challenges in marine biogeochemistry, Front. Mar. Sci., 1, 7, https://doi.org/10.3389/fmars.2014.00007, 2014.
Becker, M., Andersen, N., Erlenkeuser, H., Humphreys, Matthew. P., Tanhua, T., and Körtzinger, A.: An Internally Consistent Dataset of δ13C-DIC in the North Atlantic Ocean – NAC13v1, Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2016-7, in review, 2016.
Brewer, P. G.: Direct observation of the oceanic CO2 increase, Geophys. Res. Lett., 5, 997–1000, https://doi.org/10.1029/GL005i012p00997, 1978.
Caldeira, K. and Wickett, M. E.: Anthropogenic carbon and ocean pH, Nature, 425, 365–365, https://doi.org/10.1038/425365a, 2003.
Chen, G.-T. and Millero, F. J.: Gradual increase of oceanic CO2, Nature, 277, 205–206, https://doi.org/10.1038/277205a0, 1979.
Coplen, T. B.: Reporting of stable hydrogen, carbon, and oxygen isotopic abundances, Geothermics, 24, 707–712, https://doi.org/10.1016/0375-6505(95)00024-0, 1995.
Dickson, A. G., Afghan, J. D., and Anderson, G. C.: Reference materials for oceanic CO2 analysis: a method for the certification of total alkalinity, Mar. Chem., 80, 185–197, https://doi.org/10.1016/S0304-4203(02)00133-0, 2003.
Dickson, A. G., Sabine, C. L., and Christian, J. R.: Guide to best practices for ocean CO2 measurements, PICES Special Publication 3, 191 pp., 2007.
Doney, S. C., Fabry, V. J., Feely, R. A., and Kleypas, J. A.: Ocean Acidification: The Other CO2 Problem, Annual Review of Marine Science, 1, 169–192, https://doi.org/10.1146/annurev.marine.010908.163834, 2009.
Friis, K., Körtzinger, A., Pätsch, J., and Wallace, D. W. R.: On the temporal increase of anthropogenic CO2 in the subpolar North Atlantic, Deep-Sea Res. Pt. I, 52, 681–698, https://doi.org/10.1016/j.dsr.2004.11.017, 2005.
Gaylord, B., Kroeker, K. J., Sunday, J. M., Anderson, K. M., Barry, J. P., Brown, N. E., Connell, S. D., Dupont, S., Fabricius, K. E., Hall-Spencer, J. M., Klinger, T., Milazzo, M., Munday, P. L., Russell, B. D., Sanford, E., Schreiber, S. J., Thiyagarajan, V., Vaughan, M. L. H., Widdicombe, S., and Harley, C. D. G.: Ocean acidification through the lens of ecological theory, Ecology, 96, 3–15, https://doi.org/10.1890/14-0802.1, 2015.
Griffith, D. R., McNichol, A. P., Xu, L., McLaughlin, F. A., Macdonald, R. W., Brown, K. A., and Eglinton, T. I.: Carbon dynamics in the western Arctic Ocean: insights from full-depth carbon isotope profiles of DIC, DOC, and POC, Biogeosciences, 9, 1217–1224, https://doi.org/10.5194/bg-9-1217-2012, 2012.
Gruber, N., Sarmiento, J. L., and Stocker, T. F.: An improved method for detecting anthropogenic CO2 in the oceans, Global Biogeochem. Cy., 10, 809–837, https://doi.org/10.1029/96GB01608, 1996.
Hall, T. M., Haine, T. W. N., and Waugh, D. W.: Inferring the concentration of anthropogenic carbon in the ocean from tracers, Global Biogeochem. Cy., 16, 1131, https://doi.org/10.1029/2001GB001835, 2002.
Holliday, N. P. and Cunningham, S.: The Extended Ellett Line: Discoveries from 65 years of marine observations west of the UK, Oceanography, 26, 156–163, https://doi.org/10.5670/oceanog.2013.17, 2013.
Humphreys, M. P.: Cross-over analysis of hydrographic variables: XOVER v1.0, Ocean and Earth Science, University of Southampton, UK, 8 pp., https://doi.org/10.13140/RG.2.1.1629.0405, 2015.
Humphreys, M. P., Achterberg, E. P., Griffiths, A. M., McDonald, A., and Boyce, A. J.: Ellett Line measurements of stable isotope composition of dissolved inorganic carbon in the Northeastern Atlantic and Nordic Seas during summer 2012, British Oceanographic Data Centre, Natural Environment Research Council, UK, https://doi.org/10/xph, 2014a.
Humphreys, M. P., Achterberg, E. P., Griffiths, A. M., McDonald, A., and Boyce, A. J.: UKOA measurements of the stable isotope composition of dissolved inorganic carbon in the Northeastern Atlantic and Nordic Seas during summer 2012, British Oceanographic Data Centre, Natural Environment Research Council, UK, https://doi.org/10/xpj, 2014b.
Humphreys, M. P., Achterberg, E. P., Griffiths, A. M., McDonald, A., and Boyce, A. J.: Measurements of the stable carbon isotope composition of dissolved inorganic carbon in the northeastern Atlantic and Nordic Seas during summer 2012, Earth Syst. Sci. Data, 7, 127–135, https://doi.org/10.5194/essd-7-127-2015, 2015a.
Humphreys, M. P., Greatrix, F. M., Tynan, E., Griffiths, A. M., Fry, C. H., Garley, R., Achterberg, E. P., McDonald, A., and Boyce, A. J.: Stable carbon isotopes of dissolved inorganic carbon for RRS James Clark Ross cruise JR302 in the subpolar North Atlantic Ocean from June to July 2014, British Oceanographic Data Centre, Natural Environment Research Council, UK, https://doi.org/10.5285/22235f1a-b7f3-687f-e053-6c86abc0c8a6, 2015b.
Humphreys, M. P., Griffiths, A. M., Achterberg, E. P., Holliday, N. P., Rérolle, V. M. C., Menzel Barraqueta, J.-L., Couldrey, M. P., Oliver, K. I. C., Hartman, S. E., Esposito, M., and Boyce, A. J.: Multidecadal accumulation of anthropogenic and remineralized dissolved inorganic carbon along the Extended Ellett Line in the northeast Atlantic Ocean, Global Biogeochem. Cy., 30, 2015GB005246, https://doi.org/10.1002/2015GB005246, 2016.
Keeling, C. D.: The Suess effect: 13Carbon-14Carbon interrelations, Environ. Int., 2, 229–300, https://doi.org/10.1016/0160-4120(79)90005-9, 1979.
Khatiwala, S., Primeau, F., and Hall, T.: Reconstruction of the history of anthropogenic CO2 concentrations in the ocean, Nature, 462, 346–349, https://doi.org/10.1038/nature08526, 2009.
Khatiwala, S., Tanhua, T., Mikaloff Fletcher, S., Gerber, M., Doney, S. C., Graven, H. D., Gruber, N., McKinley, G. A., Murata, A., Ríos, A. F., and Sabine, C. L.: Global ocean storage of anthropogenic carbon, Biogeosciences, 10, 2169–2191, https://doi.org/10.5194/bg-10-2169-2013, 2013.
King, B. A. and Holliday, N. P.: JR302 Cruise Report, The 2014 RAGNARoCC, OSNAP and Extended Ellett Line cruise, National Oceanography Centre, Southampton, UK, 76 pp., 2015.
Körtzinger, A., Quay, P. D., and Sonnerup, R. E.: Relationship between anthropogenic CO2 and the 13C Suess effect in the North Atlantic Ocean, Global Biogeochem. Cy., 17, 5-1–5-20, https://doi.org/10.1029/2001GB001427, 2003.
Lauvset, S. K. and Tanhua, T.: A toolbox for secondary quality control on ocean chemistry and hydrographic data, Limnol. Oceanogr.-Meth., https://doi.org/10.1002/lom3.10050, 2015.
Le Quéré, C., Raupach, M. R., Canadell, J. G., Marland, G., Bopp, L., Ciais, P., Conway, T. J., Doney, S. C., Feely, R. A., Foster, P., Friedlingstein, P., Gurney, K., Houghton, R. A., House, J. I., Huntingford, C., Levy, P. E., Lomas, M. R., Majkut, J., Metzl, N., Ometto, J. P., Peters, G. P., Prentice, I. C., Randerson, J. T., Running, S. W., Sarmiento, J. L., Schuster, U., Sitch, S., Takahashi, T., Viovy, N., van der Werf, G. R., and Woodward, F. I.: Trends in the sources and sinks of carbon dioxide, Nat. Geosci., 2, 831–836, https://doi.org/10.1038/ngeo689, 2009.
Levene, H.: Robust tests for equality of variances, in Contributions to Probability and Statistics: Essays in Honor of Harold Hotelling, 278–292, Stanford University Press, USA, 1960.
McNichol, A., Quay, P. D., Gagnon, A. R., and Burton, J. R.: Collection and measurement of carbon isotopes in seawater DIC, in The GO-SHIP Repeat Hydrography Manual: A Collection of Expert Reports and Guidelines, IOCCP Report No. 14, ICPO Publication Series No. 134, Version 1, 2010.
Olsen, A. and Ninnemann, U.: Large δ13C Gradients in the Preindustrial North Atlantic Revealed, Science, 330, 658–659, https://doi.org/10.1126/science.1193769, 2010.
Olsen, A., Omar, A. M., Bellerby, R. G. J., Johannessen, T., Ninnemann, U., Brown, K. R., Olsson, K. A., Olafsson, J., Nondal, G., Kivimäe, C., Kringstad, S., Neill, C., and Olafsdottir, S.: Magnitude and origin of the anthropogenic CO2 increase and 13C Suess effect in the Nordic seas since 1981, Global Biogeochem. Cy., 20, GB3027, https://doi.org/10.1029/2005GB002669, 2006.
Quay, P., Sonnerup, R., Westby, T., Stutsman, J., and McNichol, A.: Changes in the 13C/12C of dissolved inorganic carbon in the ocean as a tracer of anthropogenic CO2 uptake, Global Biogeochem. Cy., 17, GB1004, https://doi.org/10.1029/2001GB001817, 2003.
Quay, P. D., Tilbrook, B., and Wong, C. S.: Oceanic Uptake of Fossil Fuel CO2: Carbon-13 Evidence, Science, 256, 74–79, https://doi.org/10.1126/science.256.5053.74, 1992.
Quay, P. D., Sonnerup, R., Stutsman, J., Maurer, J., Körtzinger, A., Padin, X. A., and Robinson, C.: Anthropogenic CO2 accumulation rates in the North Atlantic Ocean from changes in the 13C/12C of dissolved inorganic carbon, Global Biogeochem. Cy., 21, GB1009, https://doi.org/10.1029/2006GB002761, 2007.
Rubino, M., Etheridge, D. M., Trudinger, C. M., Allison, C. E., Battle, M. O., Langenfelds, R. L., Steele, L. P., Curran, M., Bender, M., White, J. W. C., Jenk, T. M., Blunier, T., and Francey, R. J.: A revised 1000? year atmospheric δ13C-CO2 record from Law Dome and South Pole, Antarctica, J. Geophys. Res. Atmos., 118, 8482–8499, https://doi.org/10.1002/jgrd.50668, 2013.
Sabine, C. L. and Tanhua, T.: Estimation of Anthropogenic CO2 Inventories in the Ocean, Annual Review of Marine Science, 2, 175–198, https://doi.org/10.1146/annurev-marine-120308-080947, 2010.
Sabine, C. L., Feely, R. A., Gruber, N., Key, R. M., Lee, K., Bullister, J. L., Wanninkhof, R., Wong, C. S., Wallace, D. W. R., Tilbrook, B., Millero, F. J., Peng, T.-H., Kozyr, A., Ono, T., and Rios, A. F.: The Oceanic Sink for Anthropogenic CO2, Science, 305, 367–371, https://doi.org/10.1126/science.1097403, 2004.
Schmittner, A., Gruber, N., Mix, A. C., Key, R. M., Tagliabue, A., and Westberry, T. K.: Biology and air–sea gas exchange controls on the distribution of carbon isotope ratios (δ13C) in the ocean, Biogeosciences, 10, 5793–5816, https://doi.org/10.5194/bg-10-5793-2013, 2013.
Sonnerup, R. E. and Quay, P. D.: 13C constraints on ocean carbon cycle models, Global Biogeochem. Cy., 26, GB2014, https://doi.org/10.1029/2010GB003980, 2012.
Sonnerup, R. E., Quay, P. D., McNichol, A. P., Bullister, J. L., Westby, T. A., and Anderson, H. L.: Reconstructing the oceanic 13C Suess Effect, Global Biogeochem. Cy., 13, 857–872, https://doi.org/10.1029/1999GB900027, 1999.
Sonnerup, R. E., McNichol, A. P., Quay, P. D., Gammon, R. H., Bullister, J. L., Sabine, C. L., and Slater, R. D.: Anthropogenic δ13C changes in the North Pacific Ocean reconstructed using a multiparameter mixing approach (MIX), Tellus B, 59, 303–317, https://doi.org/10.1111/j.1600-0889.2007.00250.x, 2007.
Tanhua, T., Körtzinger, A., Friis, K., Waugh, D. W., and Wallace, D. W. R.: An estimate of anthropogenic CO2 inventory from decadal changes in oceanic carbon content, Proc. Natl. Acad. Sci. USA, 104, 3037–3042, https://doi.org/10.1073/pnas.0606574104, 2007.
Thompson, M. and Howarth, R. J.: The rapid estimation and control of precision by duplicate determinations, Analyst, 98, 153–160, https://doi.org/10.1039/AN9739800153, 1973.
Waugh, D. W., Hall, T. M., McNeil, B. I., Key, R., and Matear, R. J.: Anthropogenic CO2 in the oceans estimated using transit time distributions, Tellus B, 58, 376–389, https://doi.org/10.1111/j.1600-0889.2006.00222.x, 2006.
Welch, B. L.: The Generalization of Student's Problem When Several Different Population Variances Are Involved, Biometrika, 34, 28–35, https://doi.org/10.1093/biomet/34.1-2.28, 1947.
Short summary
This paper reports the stable isotope composition of dissolved inorganic carbon in seawater for a transect from west to east across the North Atlantic Ocean. The results can be used to study oceanic uptake of anthropogenic carbon dioxide, and also to investigate the natural biological carbon pump. We also provide stable DIC isotope results for two batches of Dickson seawater CRMs to enable intercomparisons with other studies.
This paper reports the stable isotope composition of dissolved inorganic carbon in seawater for...
Altmetrics
Final-revised paper
Preprint