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ESSD | Articles | Volume 12, issue 2
Earth Syst. Sci. Data, 12, 1203–1216, 2020
https://doi.org/10.5194/essd-12-1203-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
Earth Syst. Sci. Data, 12, 1203–1216, 2020
https://doi.org/10.5194/essd-12-1203-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.

Data description paper 03 Jun 2020

Data description paper | 03 Jun 2020

Database for the kinetics of the gas-phase atmospheric reactions of organic compounds

Max R. McGillen et al.

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Cited articles

ACD/ChemSketch: ACD/ChemSketch, Advanced Chemistry Development, Toronto, ON, Canada, 2018. 
Ammann, M., Cox, R. A., Crowley, J. N., Jenkin, M. E., Mellouki, A., Rossi, M. J., Troe, J., and Wallington, T. J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VI – heterogeneous reactions with liquid substrates, Atmos. Chem. Phys., 13, 8045–8228, https://doi.org/10.5194/acp-13-8045-2013, 2013. 
Arif, M., Dellinger, B., and Taylor, P. H.: Rate Coefficients of Hydroxyl Radical Reaction with Dimethyl Ether and Methyl tert-Butyl Ether over an Extended Temperature Range, J. Phys. Chem. A, 101, 2436–2441, https://doi.org/10.1021/jp963119w, 1997. 
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., and Troe, J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I – gas phase reactions of Ox, HOx, NOx and SOx species, Atmos. Chem. Phys., 4, 1461–1738, https://doi.org/10.5194/acp-4-1461-2004, 2004. 
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., Troe, J., and IUPAC Subcommittee: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – gas phase reactions of organic species, Atmos. Chem. Phys., 6, 3625-4055, https://doi.org/10.5194/acp-6-3625-2006, 2006. 
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The gas-phase reactions of organic compounds in the atmosphere are a crucial step in the degradation of anthropogenic and biogenic emissions and the formation of secondary pollutants. This work is an attempt to produce a dataset that is as comprehensive as possible regarding the multitude of chemicals that react in the atmosphere. We find that we are able to make substantial improvements upon previous compendia and that this progress will help improve our understanding of atmospheric chemistry.
The gas-phase reactions of organic compounds in the atmosphere are a crucial step in the...
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