Articles | Volume 15, issue 12
https://doi.org/10.5194/essd-15-5403-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/essd-15-5403-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Data description paper
| 
04 Dec 2023
Data description paper |
| 04 Dec 2023
| 04 Dec 2023
Enhanced dataset of global marine isoprene emissions from biogenic and photochemical processes for the period 2001–2020
Lehui Cui
Institute of Surface-Earth System Science, School of Earth System Science, Tianjin University, Tianjin, 300072, China
Yunting Xiao
Institute of Surface-Earth System Science, School of Earth System Science, Tianjin University, Tianjin, 300072, China
Institute of Surface-Earth System Science, School of Earth System Science, Tianjin University, Tianjin, 300072, China
Lei Song
Center for Monsoon System Research, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
Yujue Wang
Frontiers Science Center for Deep Ocean Multispheres and Earth System, and Key Laboratory of Marine Environment and Ecology, Ministry of Education, Ocean University of China, Qingdao 266100, China
Chao Zhang
Frontiers Science Center for Deep Ocean Multispheres and Earth System, and Key Laboratory of Marine Environment and Ecology, Ministry of Education, Ocean University of China, Qingdao 266100, China
Pingqing Fu
Institute of Surface-Earth System Science, School of Earth System Science, Tianjin University, Tianjin, 300072, China
Institute of Surface-Earth System Science, School of Earth System Science, Tianjin University, Tianjin, 300072, China
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Yanhong Zhu, Weijun Li, Yue Wang, Jian Zhang, Lei Liu, Liang Xu, Jingsha Xu, Jinhui Shi, Longyi Shao, Pingqing Fu, Daizhou Zhang, and Zongbo Shi
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Yaqing Zhou, Nan Ma, Qiaoqiao Wang, Zhibin Wang, Chunrong Chen, Jiangchuan Tao, Juan Hong, Long Peng, Yao He, Linhong Xie, Shaowen Zhu, Yuxuan Zhang, Guo Li, Wanyun Xu, Peng Cheng, Uwe Kuhn, Guangsheng Zhou, Pingqing Fu, Qiang Zhang, Hang Su, and Yafang Cheng
Atmos. Chem. Phys., 22, 2029–2047, https://doi.org/10.5194/acp-22-2029-2022, https://doi.org/10.5194/acp-22-2029-2022, 2022
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Jiaxing Sun, Zhe Wang, Wei Zhou, Conghui Xie, Cheng Wu, Chun Chen, Tingting Han, Qingqing Wang, Zhijie Li, Jie Li, Pingqing Fu, Zifa Wang, and Yele Sun
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We analyzed 9-year measurements of BC and aerosol optical properties from 2012 to 2020 in Beijing, China. Our results showed large reductions in BC and light extinction coefficient due to the Clean Air Action Plan. As a response, both SSA and mass extinction efficiency (MEE) showed considerable increases, demonstrating a future challenge in visibility improvement. The primary and secondary BrC was also separated and quantified, and the changes in radiative forcing of BC and BrC were estimated.
Yuting Zhang, Hang Liu, Shandong Lei, Wanyun Xu, Yu Tian, Weijie Yao, Xiaoyong Liu, Qi Liao, Jie Li, Chun Chen, Yele Sun, Pingqing Fu, Jinyuan Xin, Junji Cao, Xiaole Pan, and Zifa Wang
Atmos. Chem. Phys., 21, 17631–17648, https://doi.org/10.5194/acp-21-17631-2021, https://doi.org/10.5194/acp-21-17631-2021, 2021
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In this study, the authors used a single-particle soot photometer (SP2) to characterize the particle size, mixing state, and optical properties of black carbon aerosols in rural areas of the North China Plain in winter. Relatively warm and high-RH environments (RH > 50 %, −4° < T < 4 °) were more favorable to rBC aging than dry and cold environments (RH < 60 %, T < −8°). The paper emphasizes the importance of meteorological parameters in the mixing state of black carbon.
Deepchandra Srivastava, Jingsha Xu, Tuan V. Vu, Di Liu, Linjie Li, Pingqing Fu, Siqi Hou, Natalia Moreno Palmerola, Zongbo Shi, and Roy M. Harrison
Atmos. Chem. Phys., 21, 14703–14724, https://doi.org/10.5194/acp-21-14703-2021, https://doi.org/10.5194/acp-21-14703-2021, 2021
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This study presents the source apportionment of PM2.5 performed by positive matrix factorization (PMF) at urban and rural sites in Beijing. These factors are interpreted as traffic emissions, biomass burning, road and soil dust, coal and oil combustion, and secondary inorganics. PMF failed to resolve some sources identified by CMB and AMS and appears to overestimate the dust sources. Comparison with earlier PMF studies from the Beijing area highlights inconsistent findings using this method.
Michael Biggart, Jenny Stocker, Ruth M. Doherty, Oliver Wild, David Carruthers, Sue Grimmond, Yiqun Han, Pingqing Fu, and Simone Kotthaus
Atmos. Chem. Phys., 21, 13687–13711, https://doi.org/10.5194/acp-21-13687-2021, https://doi.org/10.5194/acp-21-13687-2021, 2021
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Heat-related illnesses are of increasing concern in China given its rapid urbanisation and our ever-warming climate. We examine the relative impacts that land surface properties and anthropogenic heat have on the urban heat island (UHI) in Beijing using ADMS-Urban. Air temperature measurements and satellite-derived land surface temperatures provide valuable means of evaluating modelled spatiotemporal variations. This work provides critical information for urban planners and UHI mitigation.
Hong Ren, Wei Hu, Lianfang Wei, Siyao Yue, Jian Zhao, Linjie Li, Libin Wu, Wanyu Zhao, Lujie Ren, Mingjie Kang, Qiaorong Xie, Sihui Su, Xiaole Pan, Zifa Wang, Yele Sun, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 21, 12949–12963, https://doi.org/10.5194/acp-21-12949-2021, https://doi.org/10.5194/acp-21-12949-2021, 2021
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This study presents vertical profiles of biogenic and anthropogenic secondary organic aerosols (SOAs) in the urban boundary layer based on a 325 m tower in Beijing in late summer. The increases in the isoprene and toluene SOAs with height were found to be more related to regional transport, whereas the decrease in those from monoterpenes and sesquiterpene were more subject to local emissions. Such complicated vertical distributions of SOA should be considered in future modeling work.
Qiaorong Xie, Sihui Su, Jing Chen, Yuqing Dai, Siyao Yue, Hang Su, Haijie Tong, Wanyu Zhao, Lujie Ren, Yisheng Xu, Dong Cao, Ying Li, Yele Sun, Zifa Wang, Cong-Qiang Liu, Kimitaka Kawamura, Guibin Jiang, Yafang Cheng, and Pingqing Fu
Atmos. Chem. Phys., 21, 11453–11465, https://doi.org/10.5194/acp-21-11453-2021, https://doi.org/10.5194/acp-21-11453-2021, 2021
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This study investigated the role of nighttime chemistry during Chinese New Year's Eve that enhances the formation of nitrooxy organosulfates in the aerosol phase. Results show that anthropogenic precursors, together with biogenic ones, considerably contribute to the formation of low-volatility nitrooxy OSs. Our study provides detailed molecular composition of firework-related aerosols, which gives new insights into the physicochemical properties and potential health effects of urban aerosols.
Haijie Tong, Fobang Liu, Alexander Filippi, Jake Wilson, Andrea M. Arangio, Yun Zhang, Siyao Yue, Steven Lelieveld, Fangxia Shen, Helmi-Marja K. Keskinen, Jing Li, Haoxuan Chen, Ting Zhang, Thorsten Hoffmann, Pingqing Fu, William H. Brune, Tuukka Petäjä, Markku Kulmala, Maosheng Yao, Thomas Berkemeier, Manabu Shiraiwa, and Ulrich Pöschl
Atmos. Chem. Phys., 21, 10439–10455, https://doi.org/10.5194/acp-21-10439-2021, https://doi.org/10.5194/acp-21-10439-2021, 2021
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We measured radical yields of aqueous PM2.5 extracts and found lower yields at higher concentrations of PM2.5. Abundances of water-soluble transition metals and aromatics in PM2.5 were positively correlated with the relative fraction of •OH but negatively correlated with the relative fraction of C-centered radicals among detected radicals. Composition-dependent reactive species yields may explain differences in the reactivity and health effects of PM2.5 in clean versus polluted air.
Siqi Hou, Di Liu, Jingsha Xu, Tuan V. Vu, Xuefang Wu, Deepchandra Srivastava, Pingqing Fu, Linjie Li, Yele Sun, Athanasia Vlachou, Vaios Moschos, Gary Salazar, Sönke Szidat, André S. H. Prévôt, Roy M. Harrison, and Zongbo Shi
Atmos. Chem. Phys., 21, 8273–8292, https://doi.org/10.5194/acp-21-8273-2021, https://doi.org/10.5194/acp-21-8273-2021, 2021
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This study provides a newly developed method which combines radiocarbon (14C) with organic tracers to enable source apportionment of primary and secondary fossil vs. non-fossil sources of carbonaceous aerosols at an urban and a rural site of Beijing. The source apportionment results were compared with those by chemical mass balance and AMS/ACSM-PMF methods. Correlations of WINSOC and WSOC with different sources of OC were also performed to elucidate the formation mechanisms of SOC.
Jingsha Xu, Di Liu, Xuefang Wu, Tuan V. Vu, Yanli Zhang, Pingqing Fu, Yele Sun, Weiqi Xu, Bo Zheng, Roy M. Harrison, and Zongbo Shi
Atmos. Chem. Phys., 21, 7321–7341, https://doi.org/10.5194/acp-21-7321-2021, https://doi.org/10.5194/acp-21-7321-2021, 2021
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Source apportionment of fine aerosols in an urban site of Beijing used a chemical mass balance (CMB) model. Seven primary sources (industrial/residential coal burning, biomass burning, gasoline/diesel vehicles, cooking and vegetative detritus) explained an average of 75.7 % and 56.1 % of fine OC in winter and summer, respectively. CMB was found to resolve more primary OA sources than AMS-PMF, but the latter apportioned more secondary OA sources.
Philippe Massicotte, Rainer M. W. Amon, David Antoine, Philippe Archambault, Sergio Balzano, Simon Bélanger, Ronald Benner, Dominique Boeuf, Annick Bricaud, Flavienne Bruyant, Gwenaëlle Chaillou, Malik Chami, Bruno Charrière, Jing Chen, Hervé Claustre, Pierre Coupel, Nicole Delsaut, David Doxaran, Jens Ehn, Cédric Fichot, Marie-Hélène Forget, Pingqing Fu, Jonathan Gagnon, Nicole Garcia, Beat Gasser, Jean-François Ghiglione, Gaby Gorsky, Michel Gosselin, Priscillia Gourvil, Yves Gratton, Pascal Guillot, Hermann J. Heipieper, Serge Heussner, Stanford B. Hooker, Yannick Huot, Christian Jeanthon, Wade Jeffrey, Fabien Joux, Kimitaka Kawamura, Bruno Lansard, Edouard Leymarie, Heike Link, Connie Lovejoy, Claudie Marec, Dominique Marie, Johannie Martin, Jacobo Martín, Guillaume Massé, Atsushi Matsuoka, Vanessa McKague, Alexandre Mignot, William L. Miller, Juan-Carlos Miquel, Alfonso Mucci, Kaori Ono, Eva Ortega-Retuerta, Christos Panagiotopoulos, Tim Papakyriakou, Marc Picheral, Louis Prieur, Patrick Raimbault, Joséphine Ras, Rick A. Reynolds, André Rochon, Jean-François Rontani, Catherine Schmechtig, Sabine Schmidt, Richard Sempéré, Yuan Shen, Guisheng Song, Dariusz Stramski, Eri Tachibana, Alexandre Thirouard, Imma Tolosa, Jean-Éric Tremblay, Mickael Vaïtilingom, Daniel Vaulot, Frédéric Vaultier, John K. Volkman, Huixiang Xie, Guangming Zheng, and Marcel Babin
Earth Syst. Sci. Data, 13, 1561–1592, https://doi.org/10.5194/essd-13-1561-2021, https://doi.org/10.5194/essd-13-1561-2021, 2021
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The MALINA oceanographic expedition was conducted in the Mackenzie River and the Beaufort Sea systems. The sampling was performed across seven shelf–basin transects to capture the meridional gradient between the estuary and the open ocean. The main goal of this research program was to better understand how processes such as primary production are influencing the fate of organic matter originating from the surrounding terrestrial landscape during its transition toward the Arctic Ocean.
Steven J. Campbell, Kate Wolfer, Battist Utinger, Joe Westwood, Zhi-Hui Zhang, Nicolas Bukowiecki, Sarah S. Steimer, Tuan V. Vu, Jingsha Xu, Nicholas Straw, Steven Thomson, Atallah Elzein, Yele Sun, Di Liu, Linjie Li, Pingqing Fu, Alastair C. Lewis, Roy M. Harrison, William J. Bloss, Miranda Loh, Mark R. Miller, Zongbo Shi, and Markus Kalberer
Atmos. Chem. Phys., 21, 5549–5573, https://doi.org/10.5194/acp-21-5549-2021, https://doi.org/10.5194/acp-21-5549-2021, 2021
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In this study, we quantify PM2.5 oxidative potential (OP), a metric widely suggested as a potential measure of particle toxicity, in Beijing in summer and winter using four acellular assays. We correlate PM2.5 OP with a comprehensive range of atmospheric and particle composition measurements, demonstrating inter-assay differences and seasonal variation of PM2.5 OP. Using multivariate statistical analysis, we highlight specific particle chemical components and sources that influence OP.
Weiqi Xu, Chun Chen, Yanmei Qiu, Ying Li, Zhiqiang Zhang, Eleni Karnezi, Spyros N. Pandis, Conghui Xie, Zhijie Li, Jiaxing Sun, Nan Ma, Wanyun Xu, Pingqing Fu, Zifa Wang, Jiang Zhu, Douglas R. Worsnop, Nga Lee Ng, and Yele Sun
Atmos. Chem. Phys., 21, 5463–5476, https://doi.org/10.5194/acp-21-5463-2021, https://doi.org/10.5194/acp-21-5463-2021, 2021
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Here aerosol volatility and viscosity at a rural site (Gucheng) and an urban site (Beijing) in the North China Plain (NCP) were investigated in summer and winter. Our results showed that organic aerosol (OA) in winter in the NCP is more volatile than that in summer due to enhanced primary emissions from coal combustion and biomass burning. We also found that OA existed mainly as a solid in winter in Beijing but as semisolids in Beijing in summer and Gucheng in winter.
Santosh Kumar Verma, Kimitaka Kawamura, Fei Yang, Pingqing Fu, Yugo Kanaya, and Zifa Wang
Atmos. Chem. Phys., 21, 4959–4978, https://doi.org/10.5194/acp-21-4959-2021, https://doi.org/10.5194/acp-21-4959-2021, 2021
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We studied aerosol samples collected in autumn 2007 with day and night intervals in a rural site of Mangshan, north of Beijing, for sugar compounds (SCs) that are abundant organic aerosol components and can influence the air quality and climate. We found higher concentrations of biomass burning (BB) products at nighttime than daytime, whereas pollen tracers and other SCs showed an opposite diurnal trend, because this site is meteorologically characterized by a mountain/valley breeze.
Lei Liu, Jian Zhang, Yinxiao Zhang, Yuanyuan Wang, Liang Xu, Qi Yuan, Dantong Liu, Yele Sun, Pingqing Fu, Zongbo Shi, and Weijun Li
Atmos. Chem. Phys., 21, 2251–2265, https://doi.org/10.5194/acp-21-2251-2021, https://doi.org/10.5194/acp-21-2251-2021, 2021
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We found that large numbers of light-absorbing primary organic particles with high viscosity, especially tarballs, from domestic coal and biomass burning occurred in rural and even urban hazes in the winter of North China. For the first time, we characterized the atmospheric aging process of these burning-related primary organic particles by microscopic analysis and further evaluated their light absorption enhancement resulting from the “lensing effect” of secondary inorganic coatings.
Lisa K. Whalley, Eloise J. Slater, Robert Woodward-Massey, Chunxiang Ye, James D. Lee, Freya Squires, James R. Hopkins, Rachel E. Dunmore, Marvin Shaw, Jacqueline F. Hamilton, Alastair C. Lewis, Archit Mehra, Stephen D. Worrall, Asan Bacak, Thomas J. Bannan, Hugh Coe, Carl J. Percival, Bin Ouyang, Roderic L. Jones, Leigh R. Crilley, Louisa J. Kramer, William J. Bloss, Tuan Vu, Simone Kotthaus, Sue Grimmond, Yele Sun, Weiqi Xu, Siyao Yue, Lujie Ren, W. Joe F. Acton, C. Nicholas Hewitt, Xinming Wang, Pingqing Fu, and Dwayne E. Heard
Atmos. Chem. Phys., 21, 2125–2147, https://doi.org/10.5194/acp-21-2125-2021, https://doi.org/10.5194/acp-21-2125-2021, 2021
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To understand how emission controls will impact ozone, an understanding of the sources and sinks of OH and the chemical cycling between peroxy radicals is needed. This paper presents measurements of OH, HO2 and total RO2 taken in central Beijing. The radical observations are compared to a detailed chemistry model, which shows that under low NO conditions, there is a missing OH source. Under high NOx conditions, the model under-predicts RO2 and impacts our ability to model ozone.
Rutambhara Joshi, Dantong Liu, Eiko Nemitz, Ben Langford, Neil Mullinger, Freya Squires, James Lee, Yunfei Wu, Xiaole Pan, Pingqing Fu, Simone Kotthaus, Sue Grimmond, Qiang Zhang, Ruili Wu, Oliver Wild, Michael Flynn, Hugh Coe, and James Allan
Atmos. Chem. Phys., 21, 147–162, https://doi.org/10.5194/acp-21-147-2021, https://doi.org/10.5194/acp-21-147-2021, 2021
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Black carbon (BC) is a component of particulate matter which has significant effects on climate and human health. Sources of BC include biomass burning, transport, industry and domestic cooking and heating. In this study, we measured BC emissions in Beijing, finding a dominance of traffic emissions over all other sources. The quantitative method presented here has benefits for revising widely used emissions inventories and for understanding BC sources with impacts on air quality and climate.
W. Joe F. Acton, Zhonghui Huang, Brian Davison, Will S. Drysdale, Pingqing Fu, Michael Hollaway, Ben Langford, James Lee, Yanhui Liu, Stefan Metzger, Neil Mullinger, Eiko Nemitz, Claire E. Reeves, Freya A. Squires, Adam R. Vaughan, Xinming Wang, Zhaoyi Wang, Oliver Wild, Qiang Zhang, Yanli Zhang, and C. Nicholas Hewitt
Atmos. Chem. Phys., 20, 15101–15125, https://doi.org/10.5194/acp-20-15101-2020, https://doi.org/10.5194/acp-20-15101-2020, 2020
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Air quality in Beijing is of concern to both policy makers and the general public. In order to address concerns about air quality it is vital that the sources of atmospheric pollutants are understood. This work presents the first top-down measurement of volatile organic compound (VOC) emissions in Beijing. These measurements are used to evaluate the emissions inventory and assess the impact of VOC emission from the city centre on atmospheric chemistry.
Eloise J. Slater, Lisa K. Whalley, Robert Woodward-Massey, Chunxiang Ye, James D. Lee, Freya Squires, James R. Hopkins, Rachel E. Dunmore, Marvin Shaw, Jacqueline F. Hamilton, Alastair C. Lewis, Leigh R. Crilley, Louisa Kramer, William Bloss, Tuan Vu, Yele Sun, Weiqi Xu, Siyao Yue, Lujie Ren, W. Joe F. Acton, C. Nicholas Hewitt, Xinming Wang, Pingqing Fu, and Dwayne E. Heard
Atmos. Chem. Phys., 20, 14847–14871, https://doi.org/10.5194/acp-20-14847-2020, https://doi.org/10.5194/acp-20-14847-2020, 2020
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The paper details atmospheric chemistry in a megacity (Beijing), focussing on radicals which mediate the formation of secondary pollutants such as ozone and particles. Highly polluted conditions were experienced, including the highest ever levels of nitric oxide (NO), with simultaneous radical measurements. Radical concentrations were large during "haze" events, demonstrating active photochemistry. Modelling showed that our understanding of the chemistry at high NOx levels is incomplete.
Junjun Deng, Hao Guo, Hongliang Zhang, Jialei Zhu, Xin Wang, and Pingqing Fu
Atmos. Chem. Phys., 20, 14419–14435, https://doi.org/10.5194/acp-20-14419-2020, https://doi.org/10.5194/acp-20-14419-2020, 2020
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One-year source apportionment of BC aerosols in a coastal city in China was conducted with the light-absorption observation-based method and source-oriented model. Source contributions identified by the two source apportionment methods were compared. Temporal variability, potential sources and transport pathways of BC from fossil fuel and biomass burning were characterized. Significant influence of biomass burning in North and East–Central China on BC in the region was highlighted.
Jingsha Xu, Shaojie Song, Roy M. Harrison, Congbo Song, Lianfang Wei, Qiang Zhang, Yele Sun, Lu Lei, Chao Zhang, Xiaohong Yao, Dihui Chen, Weijun Li, Miaomiao Wu, Hezhong Tian, Lining Luo, Shengrui Tong, Weiran Li, Junling Wang, Guoliang Shi, Yanqi Huangfu, Yingze Tian, Baozhu Ge, Shaoli Su, Chao Peng, Yang Chen, Fumo Yang, Aleksandra Mihajlidi-Zelić, Dragana Đorđević, Stefan J. Swift, Imogen Andrews, Jacqueline F. Hamilton, Ye Sun, Agung Kramawijaya, Jinxiu Han, Supattarachai Saksakulkrai, Clarissa Baldo, Siqi Hou, Feixue Zheng, Kaspar R. Daellenbach, Chao Yan, Yongchun Liu, Markku Kulmala, Pingqing Fu, and Zongbo Shi
Atmos. Meas. Tech., 13, 6325–6341, https://doi.org/10.5194/amt-13-6325-2020, https://doi.org/10.5194/amt-13-6325-2020, 2020
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An interlaboratory comparison was conducted for the first time to examine differences in water-soluble inorganic ions (WSIIs) measured by 10 labs using ion chromatography (IC) and by two online aerosol chemical speciation monitor (ACSM) methods. Major ions including SO42−, NO3− and NH4+ agreed well in 10 IC labs and correlated well with ACSM data. WSII interlab variability strongly affected aerosol acidity results based on ion balance, but aerosol pH computed by ISORROPIA II was very similar.
Junfeng Wang, Jianhuai Ye, Dantong Liu, Yangzhou Wu, Jian Zhao, Weiqi Xu, Conghui Xie, Fuzhen Shen, Jie Zhang, Paul E. Ohno, Yiming Qin, Xiuyong Zhao, Scot T. Martin, Alex K. Y. Lee, Pingqing Fu, Daniel J. Jacob, Qi Zhang, Yele Sun, Mindong Chen, and Xinlei Ge
Atmos. Chem. Phys., 20, 14091–14102, https://doi.org/10.5194/acp-20-14091-2020, https://doi.org/10.5194/acp-20-14091-2020, 2020
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We compared the organics in total submicron matter and those coated on BC cores during summertime in Beijing and found large differences between them. Traffic-related OA was associated significantly with BC, while cooking-related OA did not coat BC. In addition, a factor likely originated from primary biomass burning OA was only identified in BC-containing particles. Such a unique BBOA requires further field and laboratory studies to verify its presence and elucidate its properties and impacts.
Yujue Wang, Min Hu, Nan Xu, Yanhong Qin, Zhijun Wu, Liwu Zeng, Xiaofeng Huang, and Lingyan He
Atmos. Chem. Phys., 20, 13721–13734, https://doi.org/10.5194/acp-20-13721-2020, https://doi.org/10.5194/acp-20-13721-2020, 2020
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Field straw residue burning is a widespread type of biomass burning in Asia, while its emissions are poorly understood. In this study, we designed lab-controlled experiments to comprehensively investigate the emission factors, chemical compositions and light absorption properties of both water-soluble and water-insoluble carbonaceous aerosols emitted from straw burning. The results clearly highlight the significant influences of burning conditions and combustion efficiency on the emissions.
Jiawei Li, Zhiwei Han, Pingqing Fu, and Xiaohong Yao
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-1016, https://doi.org/10.5194/acp-2020-1016, 2020
Revised manuscript not accepted
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Organic aerosols of marine origin are so far poorly understood. An on-line coupled regional chemistry-climate model is developed to firstly explore and characterize the seasonality and annual feature of emission, distribution and radiative effects of marine organic aerosols specifically for the western Pacific over East Asia. This study reveals an important role of marine organic aerosols in radiation and cloud and would be valuable for climate research at both regional and global scales.
Wei Hu, Kotaro Murata, Chunlan Fan, Shu Huang, Hiromi Matsusaki, Pingqing Fu, and Daizhou Zhang
Biogeosciences, 17, 4477–4487, https://doi.org/10.5194/bg-17-4477-2020, https://doi.org/10.5194/bg-17-4477-2020, 2020
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This paper reports the first estimate of the status of bacteria in long-distance-transported Asian dust, demonstrating that airborne dust, which can carry viable and nonviable bacteria on particle surfaces, is an efficient medium for constantly spreading bacteria at regional and even global scales. Such data are essential to better model and understand the roles and activities of bioaerosols in environmental evolution and climate change and the potential risks of bioaerosols to human health.
Wanyu Zhao, Hong Ren, Kimitaka Kawamura, Huiyun Du, Xueshun Chen, Siyao Yue, Qiaorong Xie, Lianfang Wei, Ping Li, Xin Zeng, Shaofei Kong, Yele Sun, Zifa Wang, and Pingqing Fu
Atmos. Chem. Phys., 20, 10331–10350, https://doi.org/10.5194/acp-20-10331-2020, https://doi.org/10.5194/acp-20-10331-2020, 2020
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Our observations provide detailed information on the abundance and vertical distribution of dicarboxylic acids, oxoacids and α-dicarbonyls in PM2.5 collected at three heights based on a 325 m meteorological tower in Beijing in summer. Our results demonstrate that organic acids at the ground surface are largely associated with local traffic emissions, while long-range atmospheric transport followed by photochemical ageing contributes more in the urban boundary layer than the ground surface.
Cited articles
Abbatt, J. P. D., Leaitch, W. R., Aliabadi, A. A., Bertram, A. K., Blanchet, J.-P., Boivin-Rioux, A., Bozem, H., Burkart, J., Chang, R. Y. W., Charette, J., Chaubey, J. P., Christensen, R. J., Cirisan, A., Collins, D. B., Croft, B., Dionne, J., Evans, G. J., Fletcher, C. G., Galí, M., Ghahreman, R., Girard, E., Gong, W., Gosselin, M., Gourdal, M., Hanna, S. J., Hayashida, H., Herber, A. B., Hesaraki, S., Hoor, P., Huang, L., Hussherr, R., Irish, V. E., Keita, S. A., Kodros, J. K., Köllner, F., Kolonjari, F., Kunkel, D., Ladino, L. A., Law, K., Levasseur, M., Libois, Q., Liggio, J., Lizotte, M., Macdonald, K. M., Mahmood, R., Martin, R. V., Mason, R. H., Miller, L. A., Moravek, A., Mortenson, E., Mungall, E. L., Murphy, J. G., Namazi, M., Norman, A.-L., O'Neill, N. T., Pierce, J. R., Russell, L. M., Schneider, J., Schulz, H., Sharma, S., Si, M., Staebler, R. M., Steiner, N. S., Thomas, J. L., von Salzen, K., Wentzell, J. J. B., Willis, M. D., Wentworth, G. R., Xu, J.-W., and Yakobi-Hancock, J. D.: Overview paper: New insights into aerosol and climate in the Arctic, Atmos. Chem. Phys., 19, 2527–2560, https://doi.org/10.5194/acp-19-2527-2019, 2019.
Alvain, S., Moulin, C., Dandonneau, Y., and Breon, F. M.: Remote sensing of phytoplankton groups in case 1 waters from global SeaWiFS imagery, Deep-Sea Res. Pt I, 52, 1989–2004, https://doi.org/10.1016/j.dsr.2005.06.015, 2005.
Alvain, S., Moulin, C., Dandonneau, Y., and Loisel, H.: Seasonal distribution and succession of dominant phytoplankton groups in the global ocean: A satellite view, Global Biogeochem. Cy., 22, Gb3001, https://doi.org/10.1029/2007gb003154, 2008.
Ardyna, M., Babin, M., Gosselin, M., Devred, E., Rainville, L., & Tremblay, J. E.: Recent Arctic Ocean sea ice loss triggers novel fall phytoplankton blooms, Geophys. Res. Lett., 41, 6207–6212, https://doi.org/10.1002/2014gl061047, 2014.
Arnold, S. R., Spracklen, D. V., Williams, J., Yassaa, N., Sciare, J., Bonsang, B., Gros, V., Peeken, I., Lewis, A. C., Alvain, S., and Moulin, C.: Evaluation of the global oceanic isoprene source and its impacts on marine organic carbon aerosol, Atmos. Chem. Phys., 9, 1253–1262, https://doi.org/10.5194/acp-9-1253-2009, 2009.
Bonsang, B., Polle, C., and Lambert, G.: Evidence for marine production of isoprene, Geophys. Res. Lett., 19, 1129–1132, https://doi.org/10.1029/92GL00083, 1992.
Booge, D., Marandino, C. A., Schlundt, C., Palmer, P. I., Schlundt, M., Atlas, E. L., Bracher, A., Saltzman, E. S., and Wallace, D. W. R.: Can simple models predict large-scale surface ocean isoprene concentrations?, Atmos. Chem. Phys., 16, 11807–11821, https://doi.org/10.5194/acp-16-11807-2016, 2016.
Booge, D., Schlundt, C., Bracher, A., Endres, S., Zäncker, B., and Marandino, C. A.: Marine isoprene production and consumption in the mixed layer of the surface ocean – a field study over two oceanic regions, Biogeosciences, 15, 649–667, https://doi.org/10.5194/bg-15-649-2018, 2018.
Brüggemann, M., Hayeck, N., Bonnineau, C., Pesce, S., Alpert, P. A., Perrier, S., Zuth, C., Hoffmann, T., Chen, J. M., and George, C.: Interfacial photochemistry of biogenic surfactants: a major source of abiotic volatile organic compounds, Faraday Discuss., 200, 59–74, https://doi.org/10.1039/c7fd00022g, 2017.
Brüggemann, M., Hayeck, N., and George, C.: Interfacial photochemistry at the ocean surface is a global source of organic vapors and aerosols, Nat. Commun., 9, 2101, https://doi.org/10.1038/s41467-018-04528-7, 2018.
Carslaw, K. S., Boucher, O., Spracklen, D. V., Mann, G. W., Rae, J. G. L., Woodward, S., and Kulmala, M.: A review of natural aerosol interactions and feedbacks within the Earth system, Atmos. Chem. Phys., 10, 1701–1737, https://doi.org/10.5194/acp-10-1701-2010, 2010.
Ciuraru, R., Fine, L., van Pinxteren, M., D'Anna, B., Herrmann, H., and George, C.: Unravelling New Processes at Interfaces: Photochemical Isoprene Production at the Sea Surface, Environ. Sci. Technol., 49, 13199–13205, https://doi.org/10.1021/acs.est.5b02388, 2015a.
Ciuraru, R., Fine, L., van Pinxteren, M., D'Anna, B., Herrmann, H., and George, C.: Photosensitized production of functionalized and unsaturated organic compounds at the air-sea interface, Sci. Rep.-Uk, 5, 12741, https://doi.org/10.1038/srep12741, 2015b.
Claeys, M., Wang, W., Ion, A. C., Kourtchev, I., Gelencser, A., and Maenhaut, W.: Formation of secondary organic aerosols from isoprene and its gas-phase oxidation products through reaction with hydrogen peroxide, Atmos. Environ., 38, 4093–4098, https://doi.org/10.1016/j.atmosenv.2004.06.001, 2004.
Conte, L., Szopa, S., Aumont, O., Gros, V., and Bopp, L.: Sources and Sinks of Isoprene in the Global Open Ocean: Simulated Patterns and Emissions to the Atmosphere, J. Geophys. Res.-Oceans, 125, e2019JC015946, https://doi.org/10.1029/2019JC015946, 2020.
Cui, L. and Zhu, J.: Global marine isoprene emission data set (2001–2020), National Tibetan Plateau/Third Pole Environment Data Center [data set], https://doi.org/10.11888/Atmos.tpdc.300521, 2023.
Dai, Y., Yang, S., Zhao, D., Hu, C., Xu, W., Anderson, D. M., Li, Y., Song, X.-P., Boyce, D. G., Gibson, L., Zheng, C., and Feng, L.: Coastal phytoplankton blooms expand and intensify in the 21st century, Nature, 615, 280–284, https://doi.org/10.1038/s41586-023-05760-y, 2023.
Dani, K. G. S. and Loreto, F.: Trade-Off Between Dimethyl Sulfide and Isoprene Emissions from Marine Phytoplankton, Trends Plant Sci., 22, 361–372, https://doi.org/10.1016/j.tplants.2017.01.006, 2017.
Gantt, B., Meskhidze, N., and Kamykowski, D.: A new physically-based quantification of marine isoprene and primary organic aerosol emissions, Atmos. Chem. Phys., 9, 4915–4927, https://doi.org/10.5194/acp-9-4915-2009, 2009.
Gantt, B., Xu, J., Meskhidze, N., Zhang, Y., Nenes, A., Ghan, S. J., Liu, X., Easter, R., and Zaveri, R.: Global distribution and climate forcing of marine organic aerosol – Part 2: Effects on cloud properties and radiative forcing, Atmos. Chem. Phys., 12, 6555–6563, https://doi.org/10.5194/acp-12-6555-2012, 2012.
Guenther, A. B., Jiang, X., Heald, C. L., Sakulyanontvittaya, T., Duhl, T., Emmons, L. K., and Wang, X.: The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions, Geosci. Model Dev., 5, 1471–1492, https://doi.org/10.5194/gmd-5-1471-2012, 2012.
Guo, S. J., Feng, Y. Y., Wang, L., Dai, M. H., Liu, Z. L., Bai, Y., and Sun, J.: Seasonal variation in the phytoplankton community of a continental-shelf sea: the East China Sea, Mar. Ecol. Prog. Ser., 516, 103–126, https://doi.org/10.3354/meps10952, 2014.
Hackenberg, S. C., Andrews, S. J., Airs, R., Arnold, S. R., Bouman, H. A., Brewin, R. J. W., Chance, R. J., Cummings, D., Dall'Olmo, G., Lewis, A. C., Minaeian, J. K., Reifel, K. M., Small, A., Tarran, G. A., Tilstone, G. H., and Carpenter, L. J.: Potential controls of isoprene in the surface ocean, Global Biogeochem. Cy., 31, 644–662, https://doi.org/10.1002/2016gb005531, 2017.
Hersbach, H., Bell, B., Berrisford, P., Biavati, G., Horányi, A., Muñoz Sabater, J., Nicolas, J., Peubey, C., Radu, R., Rozum, I., Schepers, D., Simmons, A., Soci, C., Dee, D., Thépaut, J.-N.: ERA5 hourly data on single levels from 1940 to present, Copernicus Climate Change Service (C3S) Climate Data Store (CDS), https://doi.org/10.24381/cds.adbb2d47, 2023.
Kameyama, S., Yoshida, S., Tanimoto, H., Inomata, S., Suzuki, K., and Yoshikawa-Inoue, H.: High-resolution observations of dissolved isoprene in surface seawater in the Southern Ocean during austral summer 2010-2011, J, Oceanogr,, 70, 225–239, https://doi.org/10.1007/s10872-014-0226-8, 2014.
Kim, M. J., Novak, G. A., Zoerb, M. C., Yang, M. X., Blomquist, B. W., Huebert, B. J., Cappa, C. D., and Bertram, T. H.: Air-Sea exchange of biogenic volatile organic compounds and the impact on aerosol particle size distributions, Geophys. Res. Lett., 44, 3887–3896, https://doi.org/10.1002/2017gl072975, 2017.
Li, J. L., Zhang, H. H., and Yang, G. P.: Distribution and sea-to-air flux of isoprene in the East China Sea and the South Yellow Sea during summer, Chemosphere, 178, 291–300, https://doi.org/10.1016/j.chemosphere.2017.03.037, 2017.
Li, J. L., Zhai, X., Zhang, H. H., and Yang, G. P.: Temporal variations in the distribution and sea-to-air flux of marine isoprene in the East China Sea, Atmos. Environ., 187, 131–143, https://doi.org/10.1016/j.atmosenv.2018.05.054, 2018.
Li, J. L., Zhai, X., Ma, Z., Zhang, H. H., and Yang, G. P.: Spatial distributions and sea-to-air fluxes of non-methane hydrocarbons in the atmosphere and seawater of the Western Pacific Ocean, Sci. Total Environ., 672, 491–501, https://doi.org/10.1016/j.scitotenv.2019.04.019, 2019.
Li, J. L., Kameyama, S., and Yang, G. P.: In-situ measurement of trace isoprene and dimethyl sulfide in seawater and oceanic atmosphere based on room temperature adsorption-thermal desorption, Mar. Chem., 222, 103787, https://doi.org/10.1016/j.marchem.2020.103787, 2020.
Liu, H., Probert, I., Uitz, J., Claustre, H., Aris-Brosou, S., Frada, M., Not, F., and de Vargas, C.: Extreme diversity in noncalcifying haptophytes explains a major pigment paradox in open oceans, P. Natl. Acad. Sci. USA, 106, 12803–12808, https://doi.org/10.1073/pnas.0905841106, 2009.
Liu, X., Xiao, W. P., Landry, M. R., Chiang, K. P., Wang, L., and Huang, B. Q.: Responses of Phytoplankton Communities to Environmental Variability in the East China Sea, Ecosystems, 19, 832–849, https://doi.org/10.1007/s10021-016-9970-5, 2016.
Luo, G. and Yu, F.: A numerical evaluation of global oceanic emissions of α-pinene and isoprene, Atmos. Chem. Phys., 10, 2007–2015, https://doi.org/10.5194/acp-10-2007-2010, 2010.
McGillis, W. R., Edson, J. B., Zappa, C. J., Ware, J. D., McKenna, S. P., Terray, E. A., Hare, J. E., Fairall, C. W., Drennan, W., Donelan, M., DeGrandpre, M. D., Wanninkhof, R., and Feely, R. A.: Air-sea CO2 exchange in the equatorial Pacific, J. Geophys. Res.-Oceans, 109, C08s02, https://doi.org/10.1029/2003jc002256, 2004.
Mochalski, P., King, J., Kupferthaler, A., Unterkofler, K., Hinterhuber, H., and Amann, A.: Measurement of isoprene solubility in water, human blood and plasma by multiple headspace extraction gas chromatography coupled with solid phase microextraction, J. Breath Res., 5, 046010, https://doi.org/10.1088/1752-7155/5/4/046010, 2011.
Myriokefalitakis, S., Vignati, E., Tsigaridis, K., Papadimas, C., Sciare, J., Mihalopoulos, N., Facchini, M. C., Rinaldi, M., Dentener, F. J., Ceburnis, D., Hatzianastasiou, N., O'Dowd, C. D., van Weele, M., and Kanakidou, M.: Global Modeling of the Oceanic Source of Organic Aerosols, Adv. Meteorol., 2010, 939171, https://doi.org/10.1155/2010/939171, 2010.
NASA Ocean Biology Processing Group: Terra MODIS Level 3 Mapped Chlorophyll Data, Version R2022.0, NASA Ocean Biology Distributed Active Archive Center [data set], https://doi.org/10.5067/TERRA/MODIS/L3M/CHL/2022, 2022a.
NASA Ocean Biology Processing Group: Terra MODIS Level 3 Mapped Downwelling Diffuse Attenuation Coefficient Data, Version R2022.0, NASA Ocean Biology Distributed Active Archive Center [data set], https://doi.org/10.5067/TERRA/MODIS/L3M/KD/2022, 2022b.
Novak, G. A. and Bertram, T. H.: Reactive VOC Production from Photochemical and Heterogeneous Reactions Occurring at the Air-Ocean Interface, Accounts Chem. Res., 53, 1014–1023, https://doi.org/10.1021/acs.accounts.0c00095, 2020.
Ooki, A., Nomura, D., Nishino, S., Kikuchi, T., and Yokouchi, Y.: A global-scale map of isoprene and volatile organic iodine in surface seawater of the Arctic, Northwest Pacific, Indian, and Southern Oceans, J. Geophys. Res.-Oceans, 120, 4108–4128, https://doi.org/10.1002/2014jc010519, 2015.
Palmer, P. I. and Shaw, S. L.: Quantifying global marine isoprene fluxes using MODIS chlorophyll observations, Geophys. Res. Lett., 32, L09805, https://doi.org/10.1029/2005gl022592, 2005.
Phillips, D. P., Hopkins, F. E., Bell, T. G., Liss, P. S., Nightingale, P. D., Reeves, C. E., Wohl, C., and Yang, M.: Air–sea exchange of acetone, acetaldehyde, DMS and isoprene at a UK coastal site, Atmos. Chem. Phys., 21, 10111–10132, https://doi.org/10.5194/acp-21-10111-2021, 2021.
Rosenfeld, D., Andreae, M. O., Asmi, A., Chin, M., de Leeuw, G., Donovan, D. P., Kahn, R., Kinne, S., Kivekas, N., Kulmala, M., Lau, W., Schmidt, K. S., Suni, T., Wagner, T., Wild, M., and Quaas, J.: Global observations of aerosol-cloud-precipitation-climate interactions, Rev. Geophys., 52, 750–808, https://doi.org/10.1002/2013RG000441, 2014.
Sabbaghzadeh, B., Upstill-Goddard, R. C., Beale, R., Pereira, R., and Nightingale, P. D.: The Atlantic Ocean surface microlayer from 50 degrees N to 50 degrees S is ubiquitously enriched in surfactants at wind speeds up to 13ms(-1), Geophys. Res. Lett., 44, 2852–2858, https://doi.org/10.1002/2017gl072988, 2017.
Shaw, S. L., Chisholm, S. W., and Prinn, R. G.: Isoprene production by Prochlorococcus, a marine cyanobacterium, and other phytoplankton, Mar. Chem., 80, 227–245, https://doi.org/10.1016/S0304-4203(02)00101-9, 2003.
Shaw, S. L., Gantt, B., and Meskhidze, N.: Production and Emissions of Marine Isoprene and Monoterpenes: A Review, Adv. Meteorol., 2010, 408696, https://doi.org/10.1155/2010/408696, 2010.
Simo, R., Cortes-Greus, P., Rodriguez-Ros, P., and Masdeu-Navarro, M.: Substantial loss of isoprene in the surface ocean due to chemical and biological consumption, Commun. Earth Environ., 3, 20, https://doi.org/10.1038/s43247-022-00352-6, 2022.
Sinha, V., Williams, J., Meyerhöfer, M., Riebesell, U., Paulino, A. I., and Larsen, A.: Air-sea fluxes of methanol, acetone, acetaldehyde, isoprene and DMS from a Norwegian fjord following a phytoplankton bloom in a mesocosm experiment, Atmos. Chem. Phys., 7, 739–755, https://doi.org/10.5194/acp-7-739-2007, 2007.
Tripathi, N., Sahu, L. K., Singh, A., Yadav, R., and Karati, K. K.: High Levels of Isoprene in the Marine Boundary Layer of the Arabian Sea during Spring Inter-Monsoon: Role of Phytoplankton Blooms, Acs Earth Space Chem., 4, 583–590, https://doi.org/10.1021/acsearthspacechem.9b00325, 2020.
Uning, R., Latif, M. T., Abd Hamid, H. H., Nadzir, M. S. M., Khan, M. F., and Suratman, S.: Sea-to-Air Fluxes of Isoprene and Monoterpenes in the Coastal Upwelling Region of Peninsular Malaysia, Acs Earth Space Chem., 5, 3429–3436, https://doi.org/10.1021/acsearthspacechem.1c00270, 2021.
Wanninkhof, R.: Relationship between wind speed and gas exchange over the ocean revisited, Limnol. Oceanogr.-Meth., 12, 351–362, https://doi.org/10.4319/lom.2014.12.351, 2014.
Warneke, C., de Gouw, J. A., Goldan, P. D., Kuster, W. C., Williams, E. J., Lerner, B. M., Jakoubek, R., Brown, S. S., Stark, H., Aldener, M., Ravishankara, A. R., Roberts, J. M., Marchewka, M., Bertman, S., Sueper, D. T., McKeen, S. A., Meagher, J. F., and Fehsenfeld, F. C.: Comparison of daytime and nighttime oxidation of biogenic and anthropogenic VOCs along the New England coast in summer during New England Air Quality Study 2002, J. Geophys. Res.-Atmos., 109, D10309, 10.1029/2003jd004424, 2004.
Wohl, C., Jones, A. E., Sturges, W. T., Nightingale, P. D., Else, B., Butterworth, B. J., and Yang, M.: Sea ice concentration impacts dissolved organic gases in the Canadian Arctic, Biogeosciences, 19, 1021–1045, https://doi.org/10.5194/bg-19-1021-2022, 2022.
Wohl, C., Li, Q. Y., Cuevas, C. A., Fernandez, R. P., Yang, M. X., Saiz-Lopez, A., and Simo, R.: Marine biogenic emissions of benzene and toluene and their contribution to secondary organic aerosols over the polar oceans, Sci. Adv., 9, eadd9031, https://doi.org/10.1126/sciadv.add9031, 2023.
Wurl, O., Wurl, E., Miller, L., Johnson, K., and Vagle, S.: Formation and global distribution of sea-surface microlayers, Biogeosciences, 8, 121–135, https://doi.org/10.5194/bg-8-121-2011, 2011.
Xu, L., Cameron-Smith, P., Russell, L. M., Ghan, S. J., Liu, Y., Elliott, S., Yang, Y., Lou, S., Lamjiri, M. A., and Manizza, M.: DMS role in ENSO cycle in the tropics, J. Geophys. Res.-Atmos., 121, 13537–13558, https://doi.org/10.1002/2016jd025333, 2016.
Yokouchi, Y., Li, H.-J., Machida, T., Aoki, S., and Akimoto, H.: Isoprene in the marine boundary layer (southeast Asian Sea, eastern Indian Ocean, and Southern Ocean): Comparison with dimethyl sulfide and bromoform, J. Geophys. Res., 104, 8067–8076, https://doi.org/10.1029/1998JD100013, 1999.
Yu, Z. J. and Li, Y.: Marine volatile organic compounds and their impacts on marine aerosol-A review, Sci. Total Environ., 768, 145054, https://doi.org/10.1016/j.scitotenv.2021.145054, 2021.
Zhang, W. T. and Gu, D. S.: Geostationary satellite reveals increasing marine isoprene emissions in the center of the equatorial Pacific Ocean, Npj Clim. Atmos. Sci., 5, 83, https://doi.org/10.1038/s41612-022-00311-0, 2022.
Zhou, L., Booge, D., Zhang, M., and Marandino, C. A.: Winter season Southern Ocean distributions of climate-relevant trace gases, Biogeosciences, 19, 5021–5040, https://doi.org/10.5194/bg-19-5021-2022, 2022.
Short summary
Isoprene is a crucial non-methane biogenic volatile organic compound with the largest global emissions, which has high chemical reactivity and serves as the primary source of natural secondary organic aerosols. This study built a module to present a 20-year global hourly dataset of marine phytoplankton-generated biological and photochemistry-generated isoprene emissions in the sea microlayers based on the latest advancements in biological, physical, and chemical processes.
Isoprene is a crucial non-methane biogenic volatile organic compound with the largest global...
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