General Comments: Liu et al. processed 16 years of MISR Level-3 aerosol products to derive global black carbon (BC) information, including its column concentration and microphysical properties, based on a theoretical Mie model. The authors developed the new dataset to support investigations of the spatial and temporal variations of BC concentrations and emissions at both global and regional scales. Comparisons with AERONET observations and MERRA-2 model products are valuable additions that help demonstrate the dataset’s performance.

Specific comments:

However, several major issues need to be addressed before the manuscript can be considered for publication, even prior to providing more specific comments. Overall, the current manuscript compiles a large amount of information without clear organization or illustration, which significantly reduces its readability and scientific value. Therefore, the paper requires substantial restructuring to clearly separate each section.

At present, much of the introductory and methodological content is misplaced within the Results section, while the Discussion section mixes results with interpretation.

Recommend reorganizing the manuscript so that  all methodological descriptions are moved to the Methods section, and all results are presented in the Results section, and relevant interpretations and implications are discussed in the Discussion section. The authors can also follow the structure and presentation style of other published ESSD data papers to effectively demonstrate their dataset and provide illustrative examples.

The Methodology section, needs significant improvement. In addition to relocating relevant content from the Results section, the authors should provide detailed explanations of the equations used, explicitly listing and defining all key variables. Without these details, the equations appear as disconnected expressions without clear purpose or interpretability. Furthermore, the procedures for spatial and temporal aggregation of the MISR product should be clearly described, and the QA/QC processes for the MISR L3 aerosol data must be clarified, including an assessment of associated uncertainties. The uncertainties associated with AERONET and MERRA-2 estimates should also be carefully discussed.

Finally, the description of the new dataset should be more comprehensive. The authors need to clearly specify the data structure, file format, and accessibility. For example, if the dataset is mainly provided in “.mat” format, they should offer example MATLAB scripts or guidance for reading and visualizing the data.

Overall, I recommend that the authors substantially revise and better structure the manuscript before it can be further considered for publication.

Review comments on “A Global Black Carbon Dataset of Column Concentration and Microphysical Information Derived from MISR Multi-band Observations and Mie Scattering Simulation” by Liu et al. submitted to the journal Earth System Science Data.

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General comments:

This study by Liu et al. described an integrated method to estimate global BC mixing state, column concentration by using MISR VIS-NIR spectral SSA products with MIE calculation. The comparison with AERONET and MERRA-2 data show reliability of the developed method. The manuscript mainly focuses on the discussion about the >15 years global BC column concentration results. Overall, the topic is interesting. However, in my view, the manuscript still needs substantial improvements before it can be considered for publication.

The main concerns are as follows:

1. The introduction and data description sections lack appropriate context and references. For example, Section 2.1 presents the MISR data on which the study heavily relies, yet it does not include a single reference. In addition, the description of MIE scattering in Section 2.2 is presented at a very general level and without any proper references. I don't see any connection with the method used in this study 
2. The most critical issue lies in the methodology section: the manuscript lacks a detailed description and evaluation of the methods used. As a result, the subsequent discussion of global BC column concentrations is not grounded on a sufficiently robust basis. For example, the refractive index of BC can significantly affect the derived column concentrations; however, the manuscript does not specify the key parameters used, such as the refractive index or particle density.
3. In accordance with ESSD guidelines, the authors should include the generated dataset and its registered DOI in the abstract. Furthermore, the main text must provide a general overview of the data structure.

Specific comments:

L12: Multi-angle Imaging SpectroRadiometer (MISR)

L25-27: this statement is debatable according to the latest IPCC AR6

L32: secondary aerosol vapors? precursors?

L58-59: this is not the case for studies such as Li et al., 2019.

L64: -> have been proven

L75: what do you mean daily preprocessing?

L80: validate with MERRA-2 reanalysis seems to be the other way around.

Section 2.1: the first paragraph misses important references about MISR. The same for entire Section 2.1, it’s difficult for me to imagine that you used MISR data without citing any references.

L135-150: I find this section meaningless, as it is merely a repetition of the classical Mie theory. Reiterating this part does not seem to contribute to the study, and moreover, it does not include any references.

L153: retrievals are not observations

L160: I find out that there’s no discussions about MISR AAOD accuracy, the authors can easily validate MISR AAOD or SSA with AERONET.

L192: ±0.03 doesn’t mean the uncertainty of MISR SSA products used in your calculation, you’d better to evaluate or refer to specific MISR studies.

L198: I don’t find detailed description of about your method, and another key is how you assume BC refractive index?

Section 3.3: before in-depth discussion about the global BC results, I would see more about the method.