Articles | Volume 18, issue 4
https://doi.org/10.5194/essd-18-2749-2026
© Author(s) 2026. This work is distributed under the Creative Commons Attribution 4.0 License.
Deriving regional and point source nitrogen oxides emissions in China from TROPOMI using the directional derivative approach with nonlinear chemical lifetime fitting
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- Final revised paper (published on 21 Apr 2026)
- Supplement to the final revised paper
- Preprint (discussion started on 03 Nov 2025)
- Supplement to the preprint
Interactive discussion
Status: closed
Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor
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RC1: 'Comment on essd-2025-480', Anonymous Referee #1, 22 Dec 2025
- AC1: 'Reply on RC1', Ling Chen, 09 Mar 2026
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RC2: 'Comment on essd-2025-480', Anonymous Referee #2, 09 Feb 2026
- AC2: 'Reply on RC2', Ling Chen, 09 Mar 2026
Peer review completion
AR – Author's response | RR – Referee report | ED – Editor decision | EF – Editorial file upload
AR by Ling Chen on behalf of the Authors (10 Mar 2026)
Author's response
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ED: Publish subject to minor revisions (review by editor) (18 Mar 2026) by Graciela Raga
AR by Ling Chen on behalf of the Authors (20 Mar 2026)
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ED: Publish subject to minor revisions (review by editor) (22 Mar 2026) by Graciela Raga
AR by Ling Chen on behalf of the Authors (22 Mar 2026)
Author's response
Author's tracked changes
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ED: Publish as is (05 Apr 2026) by Graciela Raga
AR by Ling Chen on behalf of the Authors (08 Apr 2026)
Author's response
Manuscript
The authors present NOx emissions in China derived from TROPOMI column measurements and wind data. The dataset matches the scope of ESSD.
The paper is generally well written and shoul be published after dealing with the following issues:
Manuscript:
Data:
Please specify the processor version for the used TROPOMI data.
Recent processor updates have made some modifications that results in overall higher tropospheric VCDs, which would affect the discussion of the observed low bias in emissions.
Methods:
- The authors refer to previous work, in particular Ayazpour et al. It is not clear to me how far the current dataset is derived from the method described in Ayazpour, or if modifications/extensions have been made. Please explicitly specify what is new/different in this study as compared to Ayazpour.
- The lifetime and inverse scale height are fitted based on Eq. (3) for different levels of NO2 VCDs. However, the basic assumption for this is that emissions are negligible. While this is a good approximation over remote regions (most parts of WN and WS), I wonder how far this assumption can be made over EN for high NO2 VCDs. Please extend the discussion accordingly.
Results:
- Fitted lifetimes are presented in Fig. 4 and discussed in the text. Please provide and discuss the results for scale height as well. I would expect that scale height increases with distance from source regions, i.e. the assumption of constant X needs to be discussed. I would also expect that X might change seasonally due to different lifetimes.
- Table S1: Lifetimes for the test setups are far longer that for control, and also far longer than those reported in several recent studies that estimated NOx lifetimes of the order of 5 hours from (TROP)OMI NO2 patterns downwind strong sources. What is the reason for the large lifetimes in the test setups?
At the same time, fit performance seems to be often better in the test setups than in the control setup. Please comment.
Dataset:
Data is provided on zenodo in form of annual nc files.
The data is easily accessible and readable.
The following items should be clarified/improved:
- please provide some further information how this data was generated or just add a link to the ESSD paper to the attributes.
- please specify the molecular mass the given emissions are refering to (NO2?)
- the unit "tons" is misleading, as this is used differently in e.g. Europe (metric tons) and the US ("short ton").
Please switch to SI units, e.g. 1e3 kg.
- the given emissions are just given in tons. From the context, I conclude that these values are referring to "per year" (as there are annual files) and "per pixel".
This should be clarified.
Due to the link to "pixel", the results depend on the chosen grid, and can NOT be simply interpolated for comparisons to other data.
I would thus recommend to switch to emission rate densities (mass per time per area), which then could be easily interpolated and integrated to any other grid.
Then also the unit would be self-explaining.
In any case, I recommend to add an additional field "area" (lat coordinate only) which would allow for easy conversion between densities and integrated values by the user.