Articles | Volume 13, issue 9
https://doi.org/10.5194/essd-13-4465-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/essd-13-4465-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Data description paper
| 
14 Sep 2021
Data description paper |
| 14 Sep 2021
| 14 Sep 2021
A spectral library for laser-induced fluorescence analysis as a tool for rare earth element identification
Helmholtz-Zentrum Dresden-Rossendorf, Helmholtz Institute Freiberg for Resource Technology, Chemnitzer Str. 40, 09599 Freiberg, Germany
Jan Beyer
Institute of Applied Physics, TU Bergakademie Freiberg, Leipziger Strasse 23, 09599 Freiberg, Germany
Sandra Lorenz
Helmholtz-Zentrum Dresden-Rossendorf, Helmholtz Institute Freiberg for Resource Technology, Chemnitzer Str. 40, 09599 Freiberg, Germany
Suchinder Sharma
Helmholtz-Zentrum Dresden-Rossendorf, Helmholtz Institute Freiberg for Resource Technology, Chemnitzer Str. 40, 09599 Freiberg, Germany
Institute of Applied Physics, TU Bergakademie Freiberg, Leipziger Strasse 23, 09599 Freiberg, Germany
Axel D. Renno
Helmholtz-Zentrum Dresden-Rossendorf, Helmholtz Institute Freiberg for Resource Technology, Chemnitzer Str. 40, 09599 Freiberg, Germany
Johannes Heitmann
Institute of Applied Physics, TU Bergakademie Freiberg, Leipziger Strasse 23, 09599 Freiberg, Germany
Richard Gloaguen
Helmholtz-Zentrum Dresden-Rossendorf, Helmholtz Institute Freiberg for Resource Technology, Chemnitzer Str. 40, 09599 Freiberg, Germany
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Marine terraces of the last interglacial period along the Pacific coast of South America (1° N–40° S)
A standardized database of Marine Isotope Stage 5e sea-level proxies in southern Africa (Angola, Namibia and South Africa)
Database of global glendonite and ikaite records throughout the Phanerozoic
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Lake and mire isolation data set for the estimation of post-glacial land uplift in Fennoscandia
William Colgan, Agnes Wansing, Kenneth Mankoff, Mareen Lösing, John Hopper, Keith Louden, Jörg Ebbing, Flemming G. Christiansen, Thomas Ingeman-Nielsen, Lillemor Claesson Liljedahl, Joseph A. MacGregor, Árni Hjartarson, Stefan Bernstein, Nanna B. Karlsson, Sven Fuchs, Juha Hartikainen, Johan Liakka, Robert S. Fausto, Dorthe Dahl-Jensen, Anders Bjørk, Jens-Ove Naslund, Finn Mørk, Yasmina Martos, Niels Balling, Thomas Funck, Kristian K. Kjeldsen, Dorthe Petersen, Ulrik Gregersen, Gregers Dam, Tove Nielsen, Shfaqat A. Khan, and Anja Løkkegaard
Earth Syst. Sci. Data, 14, 2209–2238, https://doi.org/10.5194/essd-14-2209-2022, https://doi.org/10.5194/essd-14-2209-2022, 2022
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We assemble all available geothermal heat flow measurements collected in and around Greenland into a new database. We use this database of point measurements, in combination with other geophysical datasets, to model geothermal heat flow in and around Greenland. Our geothermal heat flow model is generally cooler than previous models of Greenland, especially in southern Greenland. It does not suggest any high geothermal heat flows resulting from Icelandic plume activity over 50 million years ago.
Daniel R. Muhs
Earth Syst. Sci. Data, 14, 1271–1330, https://doi.org/10.5194/essd-14-1271-2022, https://doi.org/10.5194/essd-14-1271-2022, 2022
Short summary
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The last interglacial period, known as marine isotope substage (MIS) 5e, was the last time in recent geologic history when sea level was substantially higher than present. It is an important time period to understand because climate models forecast a higher global sea level in the not-too-distant future. Geologic records of this high-sea stand (marine terraces, reefs) along the Pacific coast of North America are reviewed here with the identification of knowledge gaps where more work is needed.
Alessandro Tibaldi, Federico Pasquaré Mariotto, Paolo Oppizzi, Fabio Luca Bonali, Nino Tsereteli, Levan Mebonia, and Johni Chania
Earth Syst. Sci. Data, 13, 3321–3335, https://doi.org/10.5194/essd-13-3321-2021, https://doi.org/10.5194/essd-13-3321-2021, 2021
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Under a NATO project, we installed a monitoring system at the Khoko landslide facing the Enguri artificial reservoir (Greater Caucasus). During 2016–2019, we compare slope deformation with meteorological factors and variations in the water level of the reservoir. Our results indicate that the landslide displacements appear to be controlled by variations in hydraulic load and partially by rainfall.
Roland Freisleben, Julius Jara-Muñoz, Daniel Melnick, José Miguel Martínez, and Manfred R. Strecker
Earth Syst. Sci. Data, 13, 2487–2513, https://doi.org/10.5194/essd-13-2487-2021, https://doi.org/10.5194/essd-13-2487-2021, 2021
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Tectonically active coasts are dynamic environments that host densely populated areas and associated infrastructure. We measured and described last interglacial marine terraces along 5000 km of the western South American coast. The pattern of terrace elevations displays short- to long-wavelength structures that may be controlled by crustal faults and the subduction of major bathymetric anomalies. Latitudinal climate characteristics may further influence their generation and preservation.
J. Andrew G. Cooper and Andrew N. Green
Earth Syst. Sci. Data, 13, 953–968, https://doi.org/10.5194/essd-13-953-2021, https://doi.org/10.5194/essd-13-953-2021, 2021
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A standardized database compiled to a common format is presented for indicators of sea level during the last interglacial from the southern African coast (Angola, Namibia and South Africa). These enable further analysis of the nature of the sea-level highstand and its regional variability.
Mikhail Rogov, Victoria Ershova, Oleg Vereshchagin, Kseniia Vasileva, Kseniia Mikhailova, and Aleksei Krylov
Earth Syst. Sci. Data, 13, 343–356, https://doi.org/10.5194/essd-13-343-2021, https://doi.org/10.5194/essd-13-343-2021, 2021
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A database of a modern metastable cold-water mineral (ikaite) and its replacement mineral (glendonite) spanning 540 million years has been created to understand their distribution in space and time. A significant body of evidence suggests that glendonite occurrences are restricted mainly to cold-water settings; however they do not occur during every glaciation or cooling event reported from the Phanerozoic. This compilation improves our understanding of climatic conditions of the past.
Hong-He Xu, Zhi-Bin Niu, and Yan-Sen Chen
Earth Syst. Sci. Data, 12, 3443–3452, https://doi.org/10.5194/essd-12-3443-2020, https://doi.org/10.5194/essd-12-3443-2020, 2020
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We introduce here a comprehensive database of stratigraphy and palaeontology biodiversity, the Geobiodiversity Database (GBDB). The GBDB collects and provides a big volume of fossil and stratum record data and aims to be more widely used by geoscientists and contribute to better quantitative research on palaeontology and stratigraphy, and furthermore, to a deeper understanding of the evolution of life and of Earth's history.
Jari Pohjola, Jari Turunen, and Tarmo Lipping
Earth Syst. Sci. Data, 12, 869–873, https://doi.org/10.5194/essd-12-869-2020, https://doi.org/10.5194/essd-12-869-2020, 2020
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When modelling land uplift processes, there is a need for historical data in which dating, elevation and consequently spatial data are connected to the shore level at that time. In addition, human settlements were located above the seawater level in Fennoscandia. This information can be used to validate and update the post-glacial land uplift model. In this paper, a collection of data consisting of geological and archaeological data sets is presented.
Cited articles
Ahmed, Z. and Iftikhar, K.: Red, orange-red and near-infrared light emitting
ternary lanthanide tris β-diketonate complexes with distorted C4v
geometrical structures, Dalton Trans., 48, 4973–4986,
https://doi.org/10.1039/C9DT00198K, 2019. a
Barakos, G., Gutzmer, J., and Mischo, H.: An outlook on the rare earth elements
mining industry, AusIMM Bulletin, 2, 62–66, 2016. a
Barmarin, G.: Luminescent Mineral Database, available at:
http://www.fluomin.org/uk/accueil.php, last access: 25 April 2020. a
Beleites, C. and Sergo, V.: hyperSpec: a package to handle hyperspectral data
sets in R, r package
version 0.99-20180627, available at: http://hyperspec.r-forge.r-project.org (last access: 27 November 2020), 2018. a
Binnemans, K.: Interpretation of europium(III) spectra, Coordin. Chem. Rev., 295, 1–45, https://doi.org/10.1016/j.ccr.2015.02.015, 2015. a
Boesche, N. K., Rogass, C., Lubitz, C., Brell, M., Herrmann, S., Mielke, C.,
Tonn, S., Appelt, O., Altenberger, U., and Kaufmann, H.: Hyperspectral REE
(Rare Earth Element) Mapping of Outcrops – Applications for Neodymium
Detection, Remote Sensing, 7, 5160, https://doi.org/10.3390/rs70505160, 2015. a, b
Booysen, R., Zimmermann, R., Lorenz, S., Gloaguen, R., Nex, P. A. M., Andreani,
L., and Möckel, R.: Towards Multiscale and Multisource Remote Sensing
Mineral Exploration Using RPAS: A Case Study in the Lofdal Carbonatite-Hosted
REE Deposit, Namibia, Remote Sensing, 11, 2500, https://doi.org/10.3390/rs11212500, 2019. a
Broicher, H.: Bulk sorting by LIF: quality control of ores for bulk sorting
and blending – by laser-induced fluorescence analysis, Min. Eng.,
52, 24–28, 2000. a
Broicher, H.: Dilution control – online and real-time recognition of ore and
waste by LIF, SME Annual Meeting, 28 February–2 March 2005, Salt Lake City, UT 1–5, 2005. a
Chakraborty, A., Debnath, G. H., Saha, N. R., Chattopadhyay, D., Waldeck,
D. H., and Mukherjee, P.: Identifying the Correct Host–Guest Combination To
Sensitize Trivalent Lanthanide (Guest) Luminescence: Titanium Dioxide
Nanoparticles as a Model Host System, J. Phys. Chem. C,
120, 23870–23882, 2016. a
Chen, H., Ni, Y., and Ma, X.: Phase-controllable synthesis, shape evolution
and optical performances of CePO4 nanocrystals via a simple oil-bath
route, RSC Adv., 4, 36553–36559, https://doi.org/10.1039/C4RA07052F, 2014. a
CSIRO: CSIRO Luminescence database, available at:
https://luminescence.csiro.au/luminescence/default.aspx, last access:
1 August 2019. a
Czaja, M., Bodyl-Gajowska, S., Gluchowski, P., Mazurak, Z., and Strek, W.:
Luminescence properties of rare earth ions in fluorite, apatite and
scheelite mineral, J. Alloy. Compd., 451, 290–292,
https://doi.org/10.1016/j.jallcom.2007.04.058, 2008. a
Czaja, M., Bodyl-Gajowska, S., and Mazurak, Z. G.: Steady-state luminescence
measurement for qualitative identification of rare earth ions in minerals,
J. Miner. Petrol. Sci., 108, 47–54,
https://doi.org/10.2465/jmps.111229, 2013. a
Donovan, J., Hanchar, J., Piccoli, P., Schrier, M., Boatner, L., and
Jarosewich, E.: A reexamination of the rare-earth element orthophosphate
reference samples for electron microprobe analysis, Can. Mineral.,
41, 221–232, https://doi.org/10.2113/gscanmin.41.1.221, 2003. a, b, c
Emsbo, P., McLaughlin, P. I., Breit, G. N., du Bray, E. A., and Koenig, A. E.:
Rare earth elements in sedimentary phosphate deposits: Solution to the
global REE crisis?, Gondwana Res., 27, 776–785,
https://doi.org/10.1016/j.gr.2014.10.008, 2015. a
European Commission: Report on critical raw materials for the EU, Report of
the Ad-hoc Working Group on defining critical raw materials, European
Commission, availablea at: https://ec.europa.eu/docsroom/documents/10010/attachments/1/translations/en/renditions/pdf (last access: 20 July 2021), 2014. a
European Commission: Report on critical raw materials and the Circular
Economy, European Commission, Brussels, available at: https://op.europa.eu/de/publication-detail/-/publication/d1be1b43-e18f-11e8-b690-01aa75ed71a1/language-en/format-PDF/source-80004733 (last access: 20 July 2021), 2018. a
Fang, H., Wei, X., Zhou, S., Li, X., Chen, Y., Duan, C.-K., and Yin, M.:
Terbium and holmium codoped yttrium phosphate as non-contact optical
temperature sensors, RSC Adv., 7, 10200–10205,
https://doi.org/10.1039/C6RA27971F, 2017. a
Fasnacht, L., Vogt, M.-L., Renard, P., and Brunner, P.: A 2D hyperspectral
library of mineral reflectance, from 900 to 2500 nm, Sci. Data, 6,
268, https://doi.org/10.1038/s41597-019-0261-9, 2019. a
Fuchs, M. C., Beyer, J., Lorenz, S., Sharma, S., Renno, A. D., Heitmann, J.,
and Gloaguen, R.: Spectral library of laser-induced fluorescence (LiF)
properties from Smithsonian rare-earth element (REE) orthophosphate
standards, Zenodo [data set],
https://doi.org/10.5281/zenodo.4054606, 2020. a, b, c, d, e
Gaft, M. and Panczer, G.: Laser-induced time-resolved luminescence
spectroscopy of minerals – a powerful tool for studying the nature of
emission centres, Miner. Petrol., 107, 363–373,
https://doi.org/10.1007/s00710-013-0293-3, 2013. a
Gaft, M., Reisfeld, R., Panczer, G., Blank, P., and Boulon, G.: Laser-induced
time-resolved luminescence of minerals, Spectrochim. Acta A, 54, 2163–2175,
https://doi.org/10.1016/S1386-1425(98)00134-6, 1998. a, b
Gandhi, M., Agrawal, N., and Bhatia, H.: Quantum Cutting down Conversion by
Cooperative Energy Transfer from Tb3+ to Yb3+ in CeF3
Nanophosphors, in: Energy Development, vol. 860 of Advanced Materials
Research, Trans Tech Publications Ltd, 124–127,
https://doi.org/10.4028/www.scientific.net/AMR.860-863.124, 2014. a
Gavrilović, T. V., Jovanović, D. J., Trandafilović, L. V., and Dramićanin,
M. D.: Effects of Ho3+ and Yb3+ doping concentrations and Li+
co-doping on the luminescence of GdVO4 powders, Opt. Mater., 45,
76–81, https://doi.org/10.1016/j.optmat.2015.03.013, 2015. a
Goodenough, K., Schilling, J., Jonsson, E., Kalvig, P., Charles, N., Tuduri,
J., Deady, E., Sadeghi, M., Schiellerup, H., Müller, A., Bertrand, G.,
Arvanitidis, N., Eliopoulos, D., Shaw, R., Thrane, K., and Keulen, N.:
Europe's rare earth element resource potential: An overview of REE
metallogenetic provinces and their geodynamic setting, Ore Geol. Rev.,
72, 838–856, https://doi.org/10.1016/j.oregeorev.2015.09.019, 2016. a
Guan, H., Sheng, Y., Song, Y., Zheng, K., Xu, C., Xie, X., Dai, Y., and Zou,
H.: White light-emitting, tunable color luminescence, energy transfer and
paramagnetic properties of terbium and samarium doped BaGdF5
multifunctional nanomaterials, RSC Adv., 6, 73160–73169,
https://doi.org/10.1039/C6RA14296F, 2016. a, b
Ha, H. M., Hoa, T. T. Q., Vu, L. V., and Long, N. N.: Photoluminescence and
Energy Transfer Between Sm3+ Ions in LaF3 Nanocrystals Prepared by
Hydrothermal Method, International Journal of Materials Science and
Applications, 5, 284–289, https://doi.org/10.11648/j.ijmsa.20160506.18, 2016. a
He, S., Xia, H., Zhang, J., Zhu, Y., and Chen, B.: Highly efficient
up-conversion luminescence in Er3+/Yb3+ co-doped
Na5Lu9F32 single crystals by vertical Bridgman method,
Sci. Rep., 7, 8751, https://doi.org/10.1038/s41598-017-09222-0, 2017. a
Kalashnikov, A., Konopleva, N., Ivanyuk, G., and Pakhomovsky, Y.: Rare Earth
Deposits of the Murmansk Region, Russia – A Review, Econ. Geol., 111,
1529–1559, https://doi.org/10.2113/econgeo.111.7.1529, 2016. a
Kang, X., Lü, W., Wang, H., and Ling, D.: Multicolor-tunable up-conversion
emissions of Yb3+, Er3+/Ho3+ co-doped
Ba3Lu2Zn5O11: crystal structure, luminescence and
energy transfer properties, Dalton Trans., 48, 2917–2925,
https://doi.org/10.1039/C8DT04577A, 2019. a, b
Kauppinen, T., Khajehzadeh, N., and Haavisto, O.: Laser-induced fluorescence
images and Raman spectroscopy studies on rapid scanning of rock drillcore
samples, Int. J. Miner. Process., 132, 26–33,
https://doi.org/10.1016/j.minpro.2014.09.003, 2014. a
Lafuente, B., Downs, R. T., Yang, H., and Stone, N.: he power of databases:
the RRUFF project, in: Highlights in Mineralogical Crystallography, edited by: Armbruster, T.
and Danisi, R. M., W. De Gruyter, Berlin, Germany, 1–30,
2015. a
Lenz, C., Talla, D., Ruschel, K., Škoda, R., Götze, J., and Nasdala,
L.: Factors affecting the Nd3+ (REE3+) luminescence of minerals,
Miner. Petrol., 107, 415–428, https://doi.org/10.1007/s00710-013-0286-2,
2013. a
Liang, Y.-J., Liu, F., Chen, Y.-F., Wang, X.-J., Sun, K.-N., and Pan, Z.: New
function of the Yb3+ ion as an efficient emitter of persistent
luminescence in the short-wave infrared, Light Science Applications, 5,
e16124, https://doi.org/10.1038/lsa.2016.124, 2016. a, b
Liang, Y.-J., Liu, F., Chen, Y., Wang, X., Sun, K., and Pan, Z.:
Red/near-infrared/short-wave infrared multi-band persistent luminescence in
Pr3+-doped persistent phosphors, Dalton Trans., 46, 11149,
https://doi.org/10.1039/c7dt02271a, 2017. a
Lima, I. B. D. and Filho, W. L. (Eds.): Rare Earths Industry – Technological,
Economic, and Environmental Implications, Elsevier, Boston,
https://doi.org/10.1016/C2014-0-01863-1, 2015. a, b
Lorenz, S., Beyer, J., Fuchs, M., Seidel, P., Turner, D., Heitmann, J., and
Gloaguen, R.: The Potential of Reflectance and Laser Induced Luminescence
Spectroscopy for Near-Field Rare Earth Element Detection in Mineral
Exploration, Remote Sensing, 11, 21, https://doi.org/10.3390/rs11010021, 2019. a, b, c, d
National Research Council: Minerals, Critical Minerals, and the U.S.
Economy, The National Academies Press, Washington, DC, https://doi.org/10.17226/12034,
2008. a
Nazarov, M., Tsukerblat, B., Byeon, C., Arellano, I., Popovici, E.-J., and Noh,
D.: Polarization selection rules and optical transitions in terbium
activated yttrium tantalate phosphor under x-ray, vacuum-ultraviolet, and
ultraviolet excitations, Appl. Optics, 48, 17–21,
https://doi.org/10.1364/AO.48.000017, 2009. a
Neave, D. A., Black, M., Riley, T. R., Gibson, S. A., Ferrier, G., Wall, F.,
and Broom-Fendley, S.: On the Feasibility of Imaging Carbonatite-Hosted Rare
Earth Element Deposits Using Remote Sensing, Econ. Geol., 111,
641–665, https://doi.org/10.2113/econgeo.111.3.641, 2016. a
Nienhaus, K. and Bayer, A.: Innovative Systems for Horizon Control of Mining
Machines by Means of Laser Induced Fluorescence (LIF), Mine Planning and
Equipment Selection, Kalgoorlie, WA, 1–7, 2003. a
Pandey, A. and Swart, H. C.: Luminescence investigation of visible light
emitting Ho3+ doped tellurite glass, J. Lumin., 169,
93–98, https://doi.org/10.1016/j.jlumin.2015.08.060, 2016. a, b, c
Prasad, V. R., Damodaraiah, S., Devara, S., and Ratnakaram, Y.:
Photoluminescence studies on holmium (III) and praseodymium (III) doped
calcium borophosphate (CBP) phosphors, J. Mol. Struct., 1160,
383–392, https://doi.org/10.1016/j.molstruc.2018.02.034, 2018. a, b, c, d
Qin, F., Zheng, Y., Yu, Y., Cheng, Z., Tayebi, P. S., Cao, W., and Zhang, Z.:
Ultraviolet and violet upconversion luminescence in Ho3+-doped
Y2O3 ceramic induced by 532-nm CW laser, J. Alloy. Compd., 509, 1115–1118, https://doi.org/10.1016/j.jallcom.2010.09.188, 2011. a, b, c
R Core Team: R: A Language and Environment for Statistical Computing, R
Foundation for Statistical Computing, Vienna, Austria,
available at: http://www.R-project.org (last access: 20 July 2021), 2014. a
Ropp, R.: Phosphors Based on Rare Earth Phosphates: II. Reflection Spectra of
Rare Earth Phosphates, J. Electrochem. Soc., 116,
623–629, https://doi.org/10.1149/1.2411989, 1969. a, b
Runowski, M., Woźny, P., Martín, I. R., Lavín, V., and Lis, S.:
Praseodymium doped YF3:Pr3+ nanoparticles as optical thermometer based on
luminescence intensity ratio (LIR) – Studies in visible and NIR range,
J. Lumin., 214, 116571, https://doi.org/10.1016/j.jlumin.2019.116571,
2019. a, b, c, d
Samanta, T., Sarkar, S., Adusumalli, V. N. K. B., Praveen, A. E., and
Mahalingam, V.: Enhanced visible and near infrared emissions via Ce3+
to Ln3+ energy transfer in Ln3+-doped CeF3 nanocrystals (Ln =
Nd and Sm), Dalton Trans., 45, 78–84, https://doi.org/10.1039/c5dt02974k, 2016. a
Seidel, P., Lorenz, S., Heinig, T., Zimmermann, R., Booysen, R., Beyer, J.,
Heitmann, J., and Gloaguen, R.: Fast 2D Laser-Induced Fluorescence
Spectroscopy Mapping of Rare Earth Elements in Rock Samples, Sensors, 19, 2219,
https://doi.org/10.3390/s19102219, 2019. a
Sharma, S. K., Köhler, T., Beyer, J., Fuchs, M., Gloaguen, R., and Heitmann,
J.: Extending the temperature sensing range using Eu3+ luminescence up to
865 K in a single crystal of EuPO4, Phys. Chem. Chem. Phys., 21,
16329–16336, https://doi.org/10.1039/C9CP03501J, 2019. a
Tang, L., Ye, H., and Xiao, D.: Photo-induced luminescence degradation in
Ce, Yb co-doped yttrium aluminum garnet phosphors, Appl. Optics, 57,
7627–7633, https://doi.org/10.1364/AO.57.007627, 2018. a
Turner, D. J., Rivard, B., and Groat, L. A.: Visible and short-wave infrared
reflectance spectroscopy of REE fluorocarbonates, Am/ Mineral/, 99,
1335–1346, https://doi.org/10.2138/am.2014.4674, 2014. a, b
Wang, S., Xu, J., Wang, J., Wang, K.-Y., Dang, S., Song, S., Liu, D., and Wang,
C.: Luminescence of samarium(iii) bis-dithiocarbamate frameworks: codoped
lanthanide emitters that cover visible and near-infrared domains, J. Mater.
Chem. C, 5, 6620–6628, https://doi.org/10.1039/C7TC01844D, 2017. a
Wang, X., Li, X., Zhong, H., Xu, S., Cheng, L., Sun, J., Zhang, J., Li, L., and
Chen, B.: Up-conversion luminescence, temperature sensing properties and
laser-induced heating effect of Er3+/Yb3+ co-doped YNbO4
phosphors under 1550 nm excitation, Sci. Rep., 8, 5736,
https://doi.org/10.1038/s41598-018-23981-4, 2018. a
Wantana, N., Kaewjaeng, S., Kothan, S., Kim, H. J., and Kaewkhao, J.: Energy
transfer from Gd3+ to Sm3+ and luminescence characteristics of
CaO–Gd2O3–SiO2–B2O3 scintillating glasses,
J. Lumin., 181, 382–386, https://doi.org/10.1016/j.jlumin.2016.09.050,
2017. a
Wei, X., Li, Y., Cheng, X., Chen, Y., and Yin, M.: Strong dependence of
upconversion luminescence on doping concentration in holmium and ytterbium
co-doped Y2O3 phosphor, J. Rare Earths, 29, 536–539,
https://doi.org/10.1016/S1002-0721(10)60493-0, 2011. a
White, W. B.: Diffuse-reflectance spectra of rare-earth oxides, Appl.
Spectrosc., 21, 167–171, 1967. a
Yashodha, S. R., Dhananjaya, N., and Manjunath, C.: Synthesis and
photoluminescence properties of Sm3+ doped LaOCl phosphor with reddish
orange emission and it's Judd-Ofelt analysis, Mater. Res Express, 7,
015003, https://doi.org/10.1088/2053-1591/ab57a6, 2019. a
Yu, D. C., Ye, S., Huang, X. Y., and Zhang, Q. Y.: Enhanced three-photon
near-infrared quantum splitting in β-NaYF4:Ho3+ by codoping
Yb3+, AIP Adv., 2, 022124, https://doi.org/10.1063/1.4718412, 2012. a, b
Zhou, B., Tao, L., Tsang, Y. H., Jin, W., and Pun, E. Y.-B.: Superbroadband
near-IR photoluminescence from Pr3+-doped fluorotellurite glasses, Opt.
Express, 20, 3803–3813, https://doi.org/10.1364/OE.20.003803, 2012. a, b, c
Zimmermann, R., Brandmeier, M., Andreani, L., Mhopjeni, K., and Gloaguen, R.:
Remote Sensing Exploration of Nb-Ta-LREE-Enriched Carbonatite
(Epembe/Namibia), Remote Sensing, 8, 620, https://doi.org/10.3390/rs8080620, 2016.
a
Zirner, A. L., Marks, M. A., Wenzel, T., Jacob, D. E., and Markl, G.: Rare
earth elements in apatite as a monitor of magmatic and metasomatic processes:
The Ilímaussaq complex, South Greenland, Lithos, 228–229, 12–22,
https://doi.org/10.1016/j.lithos.2015.04.013, 2015. a
Short summary
We present a library of high-resolution laser-induced fluorescence (LiF) reference spectra using the Smithsonian rare earth phosphate standards for electron microprobe analysis. With the recurring interest in rare earth elements (REEs), LiF may provide a powerful tool for their rapid and accurate identification. Applications of the spectral LiF library to natural materials such as rocks could complement the spectroscopy-based toolkit for innovative, non-invasive exploration technologies.
We present a library of high-resolution laser-induced fluorescence (LiF) reference spectra using...
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