Preprints
https://doi.org/10.5194/essd-2025-377
https://doi.org/10.5194/essd-2025-377
02 Jul 2025
 | 02 Jul 2025
Status: this preprint is currently under review for the journal ESSD.

The global database of deep-time marine nitrogen isotope data

Yong Du, Huyue Song, Thomas J. Algeo, Hui Zhang, Jianwei Peng, Yuyang Wu, Jiankang Lai, Xiang Shu, Hanchen Song, Lai Wei, Jincheng Zhang, Eva E. Stüeken, Stephen E. Grasby, Jacopo Dal Corso, Xiaokang Liu, Daoliang Chu, Li Tian, Qingzhong Liang, Xinchuan Li, Hong Yao, and Haijun Song

Abstract. Stable nitrogen isotope records preserved in marine sediments provide critical insights into Earth’s climate history and biospheric evolution. Although numerous studies have documented nitrogen isotope (δ15N) records across varied geological ages (Archean to Recent) and paleogeographic settings, the scientific community remains constrained by the absence of a standardized database to systematically investigate their spatiotemporal evolution. Here, we present the database of Deep-time Sediment Nitrogen Isotopes in Marine Systems (DSMS-NI), a comprehensive global compilation of δ15N data and associated geochemical parameters, spanning a vast collection of sediment samples dating from the Recent to the Archean. This database encompasses 71 040 δ15N records derived from 424 publications, systematically organized with 29 metadata fields categories (e.g., chronostratigraphic ages, coordinates, lithology, metamorphic grade, sedimentary facies, references) encompassing 1 927 829 metadata. This repository further incorporates 130 proxy data fields, including 285 715 geochemical data spanning total organic carbon (TOC), total nitrogen (TN), and organic carbon isotopes (δ13Corg), major and trace elements and iron species. These integrated parameters enable evaluation of sample fidelity and factors influencing δ15N signatures. The DSMS-NI database will facilitate research across key geological intervals such as the Permian-Triassic boundary and the Cretaceous ocean anoxic events. Researchers can leverage temporal and paleogeographic information, alongside geochemical data, to conduct spatiotemporal analyses, thereby uncovering changes in deep-time marine nitrogen cycles and paleoenvironmental conditions. The database is open-access via the Geobiology portal (https://geobiologydata.cug.edu.cn/, last access: 30 April 2025), allowing users to access data and submit new entries to ensure continuous updates and expansion. This resource represents a vital foundation for studies in paleoclimate, paleoenvironment, and geochemistry, offering essential data for understanding long-term Earth-system processes. The data files described in this paper are available at https://doi.org/10.5281/zenodo.15117375 (Du et al., 2025a).

Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims made in the text, published maps, institutional affiliations, or any other geographical representation in this preprint. The responsibility to include appropriate place names lies with the authors.
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Yong Du, Huyue Song, Thomas J. Algeo, Hui Zhang, Jianwei Peng, Yuyang Wu, Jiankang Lai, Xiang Shu, Hanchen Song, Lai Wei, Jincheng Zhang, Eva E. Stüeken, Stephen E. Grasby, Jacopo Dal Corso, Xiaokang Liu, Daoliang Chu, Li Tian, Qingzhong Liang, Xinchuan Li, Hong Yao, and Haijun Song

Status: open (until 08 Aug 2025)

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Yong Du, Huyue Song, Thomas J. Algeo, Hui Zhang, Jianwei Peng, Yuyang Wu, Jiankang Lai, Xiang Shu, Hanchen Song, Lai Wei, Jincheng Zhang, Eva E. Stüeken, Stephen E. Grasby, Jacopo Dal Corso, Xiaokang Liu, Daoliang Chu, Li Tian, Qingzhong Liang, Xinchuan Li, Hong Yao, and Haijun Song

Data sets

The global database of deep-time marine nitrogen isotope data Yong Du, Huyue Song, Thomas J. Algeo, Hui Zhang, Jianwei Peng, Yuyang Wu, Jiankang Lai, Xiang Shu, Hanchen Song, Lai Wei, Jincheng Zhang, Eva E. Stüeken, Stephen E. Grasby, Jacopo Dal Corso, Xiaokang Liu, Daoliang Chu, Li Tian, Qingzhong Liang, Xinchuan Li, Hong Yao, Haijun Song https://doi.org/10.5281/zenodo.15117375

Model code and software

Python code used to validate the dataset and make the figures Yong Du https://doi.org/10.5281/zenodo.15758073

Yong Du, Huyue Song, Thomas J. Algeo, Hui Zhang, Jianwei Peng, Yuyang Wu, Jiankang Lai, Xiang Shu, Hanchen Song, Lai Wei, Jincheng Zhang, Eva E. Stüeken, Stephen E. Grasby, Jacopo Dal Corso, Xiaokang Liu, Daoliang Chu, Li Tian, Qingzhong Liang, Xinchuan Li, Hong Yao, and Haijun Song
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Short summary
This study presents a global database of nitrogen isotope data from ancient ocean sediments, covering Earth's history from the present back to billions of years ago. The database includes over 71 000 nitrogen isotope records from 424 studies, along with essential geological context and related chemical data. This database will help reveal the mechanisms behind critical events like mass extinctions and major ocean changes, enhancing our understanding of Earth's long-term environmental processes.
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