the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Artificial Intelligence for Stable Isotope Tracers (AISIT): A Database of δ18O and ancillary data in the Pan-Arctic
Abstract. The Arctic is undergoing rapid change. Near-surface air temperatures are rising at around four times the global average, ocean temperatures are increasing, sea ice is thinning, retreating rapidly, and growing younger on average, while pan-arctic river run-off and glacial melt are both increasing. The increased fluxes of nutrient-loaded freshwater into the Arctic significantly impact marine systems both locally and globally. Arctic nutrient supplies underpin marine productivity not only within the Arctic Ocean, but also in temperate and tropical regions via oceanic exports. This makes the tracing of freshwater sources from land, the cryosphere and the atmosphere into and throughout the ocean a critical priority for understanding the global consequences of Arctic climate change. When combined with salinity measurements, stable oxygen isotope ratios (δ18O) in seawater are a powerful tracer for distinguishing freshwater contributions from meteoric sources (precipitation, rivers, glaciers) and sea-ice. While major previous efforts have compiled extensive δ18O observations in other regions, no up-to-date, centralised, accessible, and curated pan-Arctic compilation exists, despite the rapid growth in observational coverage over the recent decades. Here, we present a unified pan-Arctic seawater δ18O database comprising observations collected north of 60 °N, compiled from public repositories, peer-reviewed literature, and datasets contributed directly by colleagues across the scientific community. To unify these records, we harmonised metadata, applied standardised quality-control procedures, and integrated records into a single Artificial Intelligence (AI) compatible dataset adhering to FAIR (Findable, Accessible, Interoperable, and Reusable) data principles. We further added available barium (Ba) concentration data as another freshwater tracer, capable in some conditions of further de-convolving Arctic river run-off into separate sources. The resulting database comprises 45,714 unique δ18O measurements, paired with salinity measurements for non-freshwater samples, and 5531 unique Ba measurements spanning 1967–2025 (Thorpe-Morgan et al., 2026). This dataset provides a useful resource for quantifying sources of freshwater in the Arctic Ocean, in a format which facilitates data-driven and machine-learning approaches to spatio-temporally-sparse environmental datasets.
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Status: open (until 10 Dec 2026)
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RC1: 'Comment on essd-2026-624', Anonymous Referee #1, 02 Nov 2026
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AC1: 'Reply on RC1', Charles Thorpe-Morgan, 04 Nov 2026
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Dear Reviewer,
Thank you for the review of our manuscript, we're grateful for your insight. We're glad that the goals of AISIT, to produce a FAIR and comprehensive database of pan-arctic data, have come across in this work and we're looking forward to opening this up to the community further. Thank you for bringing to our attention these datasets that were not included within the database yet. While we made every effort to make the database as comprehensive as possible, unfortunately with such a plethora of data available in so many formats, there was always the possibility of missing some data sets. Since minting the DOI on version 1.0.0, we've also internally received a number of datasets that could be included to expand the database. Given the scope of this, our intention was to include these in a version 2.0.0 of the database in the future, something to which we'll ensure to add the datasets you mentioned. We had intended for this to occur after the publication of the paper, thus allowing for any further contributions from the community who have heard about the dataset through the paper, to be received. This would allow us to maximise the additions to the dataset in one minting and avoid several stages of minting as more data came in. This would therefore allow use to maximise the impact of a future release while minimising the internal workload.
Kind regards,
Charles (on behalf of the AISIT team)
Citation: https://doi.org/10.5194/essd-2026-624-AC1
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AC1: 'Reply on RC1', Charles Thorpe-Morgan, 04 Nov 2026
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Data sets
AISIT Database of Pan-Arctic stable oxygen isotope (delta18O) and barium measurements from seawater, freshwater, rivers, fjords, and precipitation north of 60 degrees North, 1967-2025 Thorpe-Morgan et al. https://doi.org/10.5285/0dfb14d6-73a9-4273-99ed-b231ca581b1d
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Review of Charles Thorpe-Morgan et al. “Artificial Intelligence for Stable Isotope Tracers (AISIT): A Database of δ18O and ancillary data in the Pan-Arctic”
Although substantial efforts have compiled extensive seawater δ¹⁸O observations across several regions, an up-to-date, centralised, accessible, and curated pan-Arctic compilation are lacking. Thorpe-Morgan et al. (submitted) present a unified pan-Arctic seawater δ¹⁸O database comprising observations collected north of 60°N, assembled from public repositories, peer-reviewed literature, and datasets contributed directly by the scientific community. To ensure consistency and interoperability, they harmonised metadata, applied standardised quality-control procedures, and integrated the records into a single AI-compatible dataset adhering to FAIR data principles. They further incorporated available barium (Ba) concentration measurements as a complementary freshwater tracer, which under certain conditions enables further discrimination of individual freshwater sources, particularly Arctic river runoff. The resulting database contains 45,714 unique δ¹⁸O measurements, paired with salinity measurements for non-freshwater samples, and 5,531 unique Ba measurements, spanning the period 1967–2025.
Relevance: A pan-Arctic database of water isotopes (δ¹⁸O and δ²H) and barium (Ba) is essential for quantifying and distinguishing the increasing freshwater inputs from rivers, precipitation, glacial melt and sea-ice melt. Together, these tracers provide a powerful framework for understanding changes in Arctic freshwater distribution, ocean circulation, mixing and biogeochemical cycling. A centralised, quality-controlled database will enable regional comparisons, improve freshwater budgets, identify long-term changes and provide a critical observational baseline for assessing how the rapidly changing Arctic hydrological cycle affects marine ecosystems and the global ocean.
The manuscript is well written and structured. A key strength of their database (AISIT) is its systematic and transparent data selection procedure, combining an extensive search of international data repositories, peer-reviewed literature, and direct contributions from data originators. All candidate datasets were assessed against clearly defined metadata requirements developed by subject experts, with essential criteria ensuring the traceability and interpretability of individual measurements. Missing metadata were actively recovered from original sources and authors, while records failing essential requirements were excluded. Further quality assurance included standardised data formatting, duplicate identification and removal, and harmonisation of quality flags according to WOCE conventions. Importantly, the distinction between essential and desirable metadata allowed the database to maintain rigorous quality standards while maximising the retention of valuable historical observations.
Although effort has been made to find data in public databases and in the searchable litterature there may still be data out there that are not indcluded. Below you will find a few extra datasets that are not included in your study although these datasets have all be reported to public data bases according to the FAIR principle and published in peer-review littereture.
Burgers, T. M., Miller, L. A., Rysgaard, S., Mortensen, J., Else, B., Tremblay, J.-.., & Papakyriakou, T. (2023). Distinguishing physical and biological controls on the carbon dynamics in a high-Arctic outlet strait. Journal of Geophysical Research: Oceans, 128, e2022JC019393. https://doi.org/10.1029/2022JC019393
Rysgaard, S., Mortensen, J., Haxen, M., Gillard, L. C., & Risgaard‐Petersen, N. (2024). Summer hydrography conditions at proglacial fjord entrances along East Greenland. Journal of Geophysical Research: Oceans, 129, e2023JC020665.https://doi.org/10.1029/2023JC020665
Willcox, E. W., Bendtsen, J., Mortensen, J., Mohn, C., Lemes, M., Pedersen, T.-J., et al. (2023). An updated view of thewater masses on the Northeast Greenland shelf and their link to the Laptev Sea and Lena River. Journal of GeophysicalResearch: Oceans, 128, e2022JC019052. https://doi.org/10.1029/2022JC019052
Geilfus, N-X, et al. 2023. Gas dynamics within landfast sea ice of an Arctic fjord (NE Greenland) during the spring–summer transition. Elem Sci Anth, 11: 1. DOI: https://doi.org/10.1525/elementa.2022.00056