<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing with OASIS Tables v3.0 20080202//EN" "https://jats.nlm.nih.gov/nlm-dtd/publishing/3.0/journalpub-oasis3.dtd">
<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" xml:lang="en" dtd-version="3.0" article-type="data-paper">
  <front>
    <journal-meta><journal-id journal-id-type="publisher">ESSD</journal-id><journal-title-group>
    <journal-title>Earth System Science Data</journal-title>
    <abbrev-journal-title abbrev-type="publisher">ESSD</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Earth Syst. Sci. Data</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1866-3516</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/essd-18-5643-2026</article-id><title-group><article-title>Long-term solar-induced fluorescence data record from GOME-2A and GOME-2B (2007–2023) using the SIFTER v3 algorithm</article-title><alt-title>Long-term GOME-2 solar-induced fluorescence data record</alt-title>
      </title-group>
      <contrib-group>
        <contrib contrib-type="author" corresp="no" rid="aff1 aff2">
          <name><surname>Anema</surname><given-names>Juliëtte C. S.</given-names></name>
          
        <ext-link>https://orcid.org/0009-0009-1129-6138</ext-link></contrib>
        <contrib contrib-type="author" corresp="yes" rid="aff1 aff2">
          <name><surname>Boersma</surname><given-names>K. Folkert</given-names></name>
          <email>folkert.boersma@knmi.nl</email>
        <ext-link>https://orcid.org/0000-0002-4591-7635</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Tilstra</surname><given-names>Lieuwe G.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>van 't Loo</surname><given-names>Ruben</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Tuinder</surname><given-names>Olaf N. E.</given-names></name>
          
        </contrib>
        <aff id="aff1"><label>1</label><institution>Satellite Observations Department, Royal Netherlands Meteorological Institute, De Bilt, 3730 AE, the Netherlands</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Meteorology and Air Quality group, Wageningen University, Wageningen, 6700 AA, the Netherlands</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">K. Folkert Boersma (folkert.boersma@knmi.nl)</corresp></author-notes><pub-date><day>31</day><month>July</month><year>2026</year></pub-date>
      
      <volume>18</volume>
      <issue>7</issue>
      <fpage>5643</fpage><lpage>5661</lpage>
      <history>
        <date date-type="received"><day>15</day><month>September</month><year>2025</year></date>
           <date date-type="rev-request"><day>28</day><month>November</month><year>2025</year></date>
           <date date-type="rev-recd"><day>12</day><month>May</month><year>2026</year></date>
           <date date-type="accepted"><day>24</day><month>June</month><year>2026</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2026 Juliëtte C. S. Anema et al.</copyright-statement>
        <copyright-year>2026</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026.html">This article is available from https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026.html</self-uri><self-uri xlink:href="https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026.pdf">The full text article is available as a PDF file from https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026.pdf</self-uri>
      <abstract><title>Abstract</title>

      <p id="d2e127">Design differences in sensors and retrieval algorithms complicate the harmonisation of space-based solar-induced fluorescence (SIF) observations. The GOME-2 series, with its identical sensor design, offers potential for constructing a long-term coherent record. However, instrumental artefacts, such as degradation, affect the sensors differently and diverge the intersensor SIF observations. Achieving internal consistency within each record is therefore a critical first step in harmonisation. We present a combined GOME-2 SIF dataset for 2007–2023 that consists of GOME-2A (January 2007–December 2017) and GOME-2B SIF (July 2013–December 2023) data. Both individual records are retrieved using the previously developed SIFTER v3 algorithm, which applies time-, wavelength-, and scan-angle-dependent degradation corrections. Spatial agreement between GOME-2A and GOME-2B SIF during the overlapping period was strong (<inline-formula><mml:math id="M1" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>≥</mml:mo></mml:mrow></mml:math></inline-formula> 0.96), although viewing geometry differences caused substantial systematic biases, specifically over high activity regions; these were reduced to within 2 % by constraining to common viewing zenith angle ranges. In terms of temporal alignment, most analysed regions showed no significant step change at the July 2013 sensor transition, from full-swath GOME-2A to GOME-2B SIF. Small offsets in Eastern China and the Amazon were corrected for using a simple additive correction, which improved the coherence and agreement with independent GPP estimations from FluxSat. Finally, the GOME-2 records align closely with FluxSat GPP and TROPOMI SIF across various biomes, and support monitoring of vegetation activity over 17 years. Our work presents a framework for detecting and, when necessary, correcting intersensor offset biases, enabling the use of GOME-2A and GOME-2B SIF as a single record. Moreover, it offers guidance for harmonising multi-sensor datasets and for other causes of potential structural breaks in long-term observation records. The GOME-2A and GOME-2B SIF (obtained in this study) datasets are available at <ext-link xlink:href="https://doi.org/10.21944/gome2a-sifter-v3-solar-induced-fluorescence" ext-link-type="DOI">10.21944/gome2a-sifter-v3-solar-induced-fluorescence</ext-link> <xref ref-type="bibr" rid="bib1.bibx2" id="paren.1"/> and <ext-link xlink:href="https://doi.org/10.21944/gome2b-sifter-v3-solar-induced-fluorescence" ext-link-type="DOI">10.21944/gome2b-sifter-v3-solar-induced-fluorescence</ext-link> <xref ref-type="bibr" rid="bib1.bibx3" id="paren.2"/>, respectively.</p>
  </abstract>
    
<funding-group>
<award-group id="gs1">
<funding-source>European Organization for the Exploitation of Meteorological Satellites</funding-source>
<award-id>ACSAF CDOP-4</award-id>
</award-group>
<award-group id="gs2">
<funding-source>European Commission</funding-source>
<award-id>LANDMARC - LAND-use based MitigAtion for Resilient Climate pathways (869367)</award-id>
</award-group>
</funding-group>
</article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d2e161">Terrestrial vegetation plays a crucial role in the carbon cycle, yet it also represents one of the largest uncertainties in future climate scenarios. Understanding changes in vegetation dynamics is essential for quantifying global carbon fluxes and sustaining food production. This highlights the need for long-term, global-scale vegetation monitoring. Satellite-based retrievals of solar-induced fluorescence (SIF) constitute a powerful tool to track vegetation dynamics at local to global scales. SIF observations are directly related to photosynthetic activity and, thus, carbon uptake <xref ref-type="bibr" rid="bib1.bibx27" id="paren.3"/>. Previous studies have shown SIF to be sensitive to disturbances such as droughts, wildfire impact, and land-use change and to outperform traditional greenness indices like NDVI <xref ref-type="bibr" rid="bib1.bibx5 bib1.bibx26 bib1.bibx1 bib1.bibx49 bib1.bibx10" id="paren.4"><named-content content-type="pre">e.g.</named-content></xref>.</p>
      <p id="d2e172">In recent years, advancements in SIF retrieval from spectrometer instruments have facilitated the growing number of SIF datasets obtained from various satellite missions, such as GOME, SCIAMACHY <xref ref-type="bibr" rid="bib1.bibx19 bib1.bibx21" id="paren.5"/>, GOSAT, the GOME-2 series <xref ref-type="bibr" rid="bib1.bibx15 bib1.bibx38 bib1.bibx2" id="paren.6"/>, TROPOMI <xref ref-type="bibr" rid="bib1.bibx22 bib1.bibx12" id="paren.7"/>, OCO-2 <xref ref-type="bibr" rid="bib1.bibx33" id="paren.8"/>, OCO-3 <xref ref-type="bibr" rid="bib1.bibx7" id="paren.9"/>, and upcoming missions like FLEX <xref ref-type="bibr" rid="bib1.bibx40" id="paren.10"/> and the CO2M series <xref ref-type="bibr" rid="bib1.bibx29" id="paren.11"/>. These datasets have proven to be highly valuable for monitoring vegetation phenology and ecosystem productivity across various spatial and temporal scales <xref ref-type="bibr" rid="bib1.bibx36 bib1.bibx41 bib1.bibx47 bib1.bibx25" id="paren.12"><named-content content-type="pre">e.g.,</named-content></xref>. However, the harmonisation of these datasets is challenging as merging is complicated by discrepancies in satellite characteristics and retrieval settings, such as local overpass time, observation geometry, spectral, spatial and temporal sampling, and the retrieval window spectral range <xref ref-type="bibr" rid="bib1.bibx30 bib1.bibx33" id="paren.13"/>.</p>
      <p id="d2e205">Retrieving SIF from the GOME-2 instruments offers a unique opportunity to circumvent many of the intersensor discrepancies that limit harmonisation. Three instruments, launched in sequence as part of the Metop series, GOME-2A in 2006, GOME-2B in 2012, and GOME-2C in 2019, follow the same design and have consistent equatorial overpass times, all crossing at 09:30 a.m. The instrumental similarities minimise biases between sensors, offering potential to obtain a consistent long-term SIF record. Currently, GOME-2A provides the longest individual SIF record with continuous global coverage to date and has been widely used to investigate vegetation dynamics <xref ref-type="bibr" rid="bib1.bibx10 bib1.bibx5 bib1.bibx9" id="paren.14"/>. A robust merged GOME-2 record enhances our ability to study long-term vegetation dynamics, but would also serve as a valuable benchmark for harmonising SIF datasets, owing to its long duration and limited intersensor biases.</p>
      <p id="d2e211">To our knowledge, no study has combined GOME-2 SIF into a long-term SIF record and assessed its coherence. A major challenge in obtaining a robust GOME-2 SIF record is its sensitivity to instrumental artefacts, particularly reflectance degradation, which can lead to false temporal trends in SIF <xref ref-type="bibr" rid="bib1.bibx38 bib1.bibx48 bib1.bibx23" id="paren.15"/>. If not adequately corrected for, these trends make the data unsuitable for long-term vegetation analysis <xref ref-type="bibr" rid="bib1.bibx30" id="paren.16"/>, and hinder harmonisation across sensors <xref ref-type="bibr" rid="bib1.bibx45 bib1.bibx43" id="paren.17"/>. Our SIFTER v3 retrieval algorithm addresses this issue with an advanced degradation correction that is time, wavelength, and scan-angle dependent, following the reflectance degradation characteristics closely <xref ref-type="bibr" rid="bib1.bibx2" id="paren.18"/>. Other GOME-2 SIF products, such as TCSIF and LT<inline-formula><mml:math id="M2" display="inline"><mml:mi mathvariant="italic">_</mml:mi></mml:math></inline-formula>SIFc<sup>*</sup> <xref ref-type="bibr" rid="bib1.bibx43 bib1.bibx50" id="paren.19"/>, also apply time-dependent corrections, but ignore wavelength and scan-angle dependencies of degradation. Notably, the scan-angle dependency was found to be of similar magnitude to the temporal component, making its omission a substantial source of bias <xref ref-type="bibr" rid="bib1.bibx2" id="paren.20"/>. <xref ref-type="bibr" rid="bib1.bibx2" id="text.21"/> demonstrated the algorithm's effectiveness by obtaining a 2007–2017 GOME-2A SIF record with temporal stability, internal consistency, and strong correlation with independent data. Building on this work, we apply the same approach to retrieve GOME-2B SIF over mid-2013 to 2023 and evaluate its potential to use both datasets as a single coherent combined SIF record spanning from 2007 to 2023.</p>
      <p id="d2e253">Our objectives are threefold. First, we retrieve GOME-2B SIF using the SIFTER v3 algorithm and level-1b Release-3 (R3) data to ensure consistency with the existing GOME-2A SIF record by <xref ref-type="bibr" rid="bib1.bibx2" id="text.22"/>. The degradation correction parameters are tailored to the specific reflectance degradation characteristics of GOME-2B. Second, we assess the spatial intersensor consistency during their overlapping tandem phase (from July 2013), using co-sampling methods to isolate sensor-specific biases. Third, we evaluate temporal coherence and demonstrate a framework to identify and, where necessary, correct intersensor offsets, enabling a coherent long-term combined GOME-2 SIF record. Six representative vegetated regions across diverse biomes are used as case studies to examine the intersensor agreement and GOME-2 SIF performance in capturing vegetation dynamics accurately. We present the GOME-2B SIF dataset, with measurement uncertainties, which can be combined with our previous GOME-2A SIF dataset into one GOME-2 SIF data record spanning from 2007 to 2023.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>GOME-2 instruments</title>
      <p id="d2e267">The GOME-2 instruments are part of the payload on the Metop satellite series, which consists of three identical satellites, Metop-A, Metop-B, and Metop-C, launched sequentially to enable long-term consistent monitoring of meteorology and air quality <xref ref-type="bibr" rid="bib1.bibx20 bib1.bibx28" id="paren.23"/>. The GOME-2 instruments follow an identical design, and in the following, we refer to this design as “the GOME-2 instrument”. In this study, we focus on observations from the first two launched instruments: GOME-2A and GOME-2B.</p>
      <p id="d2e273">GOME-2 is an optical spectrometer instrument that measures the radiance and solar irradiance from four main spectral channels, providing continuous spectral coverage between 240 and 790 nm. The instrument builds on the heritage of the Global Ozone Monitoring Experiment (GOME) instrument, continuing the monitoring of ozone and other trace gases, including NO<sub>2</sub>, BrO, OCIO, HCHO, SO<sub>2</sub>, and H<sub>2</sub>O. Additionally, the covering of the near-infrared (NIR, channel 4) enables the retrieval of SIF from GOME-2 <xref ref-type="bibr" rid="bib1.bibx15 bib1.bibx21 bib1.bibx38" id="paren.24"><named-content content-type="pre">e.g.</named-content></xref>. Channel 4 has a spectral resolution and spectral sampling of <inline-formula><mml:math id="M7" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.5 and <inline-formula><mml:math id="M8" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula>0.2 nm, respectively.</p>
      <p id="d2e323">The GOME-2 instrument uses a scan mirror scheme that enables across-track scanning of the nominal swath with a default width of 1920 km. There are 24 forward pixels (80 <inline-formula><mml:math id="M9" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 40 km<sup>2</sup> resolution in default swath) and eight backward scan pixels. For the SIF retrieval, only the forward scan pixels are used. For each GOME-2 ground pixel, the effective cloud fraction is retrieved using the Fast Retrieval Scheme for Clouds from the Oxygen A band (FRESCO<inline-formula><mml:math id="M11" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>) <xref ref-type="bibr" rid="bib1.bibx42" id="paren.25"/>.</p>
      <p id="d2e352">Following the launch of Metop-B in 2012, the GOME-2A and GOME-2B instruments operated in tandem. After its commissioning phase, Metop-B became the prime operational satellite from 16 July  2013, onwards. At that point, the swath of GOME-2A was reduced to 960 km, increasing its spatial resolution to 40 <inline-formula><mml:math id="M12" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 40 km<sup>2</sup>, while the swath of GOME-2B operated under the nominal swath of 1920 km. The satellites are 174° out of phase within the same orbital plane, leading to a local time difference of 48.9 min between two overlapping observations <xref ref-type="bibr" rid="bib1.bibx28 bib1.bibx11" id="paren.26"/>.</p>
      <p id="d2e375">Table <xref ref-type="table" rid="T1"/> summarises the key instrumental properties of both instruments, distinguishing the periods of GOME-2A under nominal and reduced swath configuration. The resulting coverage and overlap of both sensors are illustrated in Fig. <xref ref-type="fig" rid="F1"/>. The tandem operation ended in 2021, when Metop-A was de-orbited. However, in this study, we limit our analysis of GOME-2A to the 2007–2017 period to avoid possible effects of the orbital drift, which began in early 2018. Similarly, we restrict the analysis of GOME-2B until the end of 2023, as orbital drift started thereafter.</p>

<table-wrap id="T1" specific-use="star"><label>Table 1</label><caption><p id="d2e385">Summary of instrumental properties of the GOME-2A and GOME-2B sensors.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="4">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:colspec colnum="4" colname="col4" align="left"/>
     <oasis:thead>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry rowsep="1" namest="col2" nameend="col3" align="center">GOME-2A </oasis:entry>

         <oasis:entry rowsep="1" colname="col4" morerows="1">GOME-2B</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2">Before 15/07/2013</oasis:entry>

         <oasis:entry colname="col3">After 15/07/2013</oasis:entry>

       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>

         <oasis:entry colname="col1">Launch</oasis:entry>

         <oasis:entry namest="col2" nameend="col3" align="center">October 2006 </oasis:entry>

         <oasis:entry colname="col4">September 2012</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">Equator crossing time</oasis:entry>

         <oasis:entry namest="col2" nameend="col3" align="center">09:30 a.m. LT </oasis:entry>

         <oasis:entry colname="col4">09:30 a.m. LT</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">Global coverage</oasis:entry>

         <oasis:entry colname="col2">1.5 d</oasis:entry>

         <oasis:entry colname="col3">3 d</oasis:entry>

         <oasis:entry colname="col4">1.5 d</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">Swath width</oasis:entry>

         <oasis:entry colname="col2">1920 km</oasis:entry>

         <oasis:entry colname="col3">960 km</oasis:entry>

         <oasis:entry colname="col4">1920 km</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">Viewing range</oasis:entry>

         <oasis:entry colname="col2"><inline-formula><mml:math id="M14" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>52, <inline-formula><mml:math id="M15" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>52°</oasis:entry>

         <oasis:entry colname="col3"><inline-formula><mml:math id="M16" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>35, <inline-formula><mml:math id="M17" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>35°</oasis:entry>

         <oasis:entry colname="col4"><inline-formula><mml:math id="M18" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>52, <inline-formula><mml:math id="M19" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>52°</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">Spatial resolution</oasis:entry>

         <oasis:entry colname="col2">80 <inline-formula><mml:math id="M20" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 40 km<sup>2</sup></oasis:entry>

         <oasis:entry colname="col3">40 <inline-formula><mml:math id="M22" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 40 km<sup>2</sup></oasis:entry>

         <oasis:entry colname="col4">80 <inline-formula><mml:math id="M24" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 40 km<sup>2</sup></oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">Spectral coverage, NIR</oasis:entry>

         <oasis:entry namest="col2" nameend="col3" align="center">593–790 nm </oasis:entry>

         <oasis:entry colname="col4">593–791 nm</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">Spectral sampling</oasis:entry>

         <oasis:entry namest="col2" nameend="col3" align="center">0.21 nm </oasis:entry>

         <oasis:entry colname="col4">0.20 nm</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">Spectral resolution</oasis:entry>

         <oasis:entry namest="col2" nameend="col3" align="center">0.48 nm </oasis:entry>

         <oasis:entry colname="col4">0.50 nm</oasis:entry>

       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <fig id="F1"><label>Figure 1</label><caption><p id="d2e637">Coverage and overlap of GOME-2A (in blue) and GOME-2B (in green) when both are <bold>(a)</bold> in nominal swath mode and <bold>(b)</bold> in tandem mode with GOME-2A in reduced swath mode. The tandem operation started from 15 July 2013 when GOME-2B was fully operational (after the commissioning phase), and lasted until the de-orbiting of GOME-2A in 2021. </p></caption>
        <graphic xlink:href="https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026-f01.png"/>

      </fig>

      <p id="d2e652">While orbital drift constrains the time window of reliable data analysis, instrumental artefacts impacted the GOME-2 observations more persistently. Specifically, the effects of instrument degradation on the observed reflectance represent a significant challenge for all three instruments. These effects exhibit varying patterns over time, occur early in operational life, and have sensor-specific characteristics  <xref ref-type="bibr" rid="bib1.bibx8" id="paren.27"/>. This degradation is thought to arise from build-up contamination on the scan mirror and is shown to be wavelength and scan-angle-dependent <xref ref-type="bibr" rid="bib1.bibx35 bib1.bibx8 bib1.bibx2" id="paren.28"/>. Although the shorter wavelengths are more heavily affected, the effects in the NIR can't be neglected and are known to impact the temporal consistency of SIF retrievals <xref ref-type="bibr" rid="bib1.bibx48 bib1.bibx10 bib1.bibx43 bib1.bibx2" id="paren.29"/>.</p>
      <p id="d2e664">The consistency and comparability of the individual instruments' observations are also affected by their thermal stability. Temperature variations of the optical bench along the orbit lead to changes in the spectral alignment, with noted seasonal and long-term effects <xref ref-type="bibr" rid="bib1.bibx28" id="paren.30"/>. Additionally, these temperature variations also affect the slit function width. This variation in slit function width is believed to influence retrieved SIF values, potentially causing underestimation (false negatives) or overestimation of their magnitude <xref ref-type="bibr" rid="bib1.bibx21 bib1.bibx19 bib1.bibx38" id="paren.31"/>.</p>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Application of SIFTER v3 to GOME-2B</title>
      <p id="d2e681">In this study, we retrieve SIF from the GOME-2B sensor using the SIFTER v3 retrieval algorithm. The retrieval methodology and its underlying principles are kept identical to those applied to GOME-2A <xref ref-type="bibr" rid="bib1.bibx2" id="paren.32"/> to secure consistency between the two datasets. For clarity, we briefly summarise the methodology before outlining the algorithm's parameter settings tailored to GOME-2B. The SIFTER v3 retrieval consists of three main steps: degradation correction of the reflectance, the SIF retrieval, and post-hoc correction for latitude bias effects. Details about the applied corrections and their impact on the alignment of GOME-2A and GOME-2B observations are provided in Sect. S1 in the Supplement.</p>
<sec id="Ch1.S3.SS1">
  <label>3.1</label><title>Reflectance correction</title>
      <p id="d2e694">The time, wavelength, and scan-angle dependent degradation correction is derived from analysing daily global reflectance trends over time. First, GOME-2B reflectance data for the spectral range of 712–785 nm are collected between 60° S and 60° N, and with solar zenith angles below 85°. Scenes are not filtered on cloud conditions or sun glint, but data corresponding to static or narrow swath observations are excluded. Daily averages are then obtained for scan-index <inline-formula><mml:math id="M26" display="inline"><mml:mi>s</mml:mi></mml:math></inline-formula> (<inline-formula><mml:math id="M27" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">24</mml:mn></mml:mrow></mml:math></inline-formula>) and detector pixel at wavelength <inline-formula><mml:math id="M28" display="inline"><mml:mi mathvariant="italic">λ</mml:mi></mml:math></inline-formula>.</p>
      <p id="d2e723">As an illustration, Fig. <xref ref-type="fig" rid="F2"/> shows the daily global reflectances at <inline-formula><mml:math id="M29" display="inline"><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 747.2 nm and <inline-formula><mml:math id="M30" display="inline"><mml:mrow><mml:mi>s</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M31" display="inline"><mml:mrow><mml:mi>s</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">24</mml:mn></mml:mrow></mml:math></inline-formula> in green. Different long-term temporal reflectance patterns are observed over the easternmost (<inline-formula><mml:math id="M32" display="inline"><mml:mrow><mml:mi>s</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula>) and westernmost (<inline-formula><mml:math id="M33" display="inline"><mml:mrow><mml:mi>s</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">24</mml:mn></mml:mrow></mml:math></inline-formula>) pixel. The reflectance over the easternmost pixel shows a clear decreasing pattern over time, whereas it remains more stable over the westernmost pixel. The stronger eastward degradation is consistent with patterns observed in GOME-2A and predecessors GOME and SCIAMACHY <xref ref-type="bibr" rid="bib1.bibx2 bib1.bibx8" id="paren.33"/>. The degree of degradation, or signal attenuation, depends on the properties of the contamination layer that develops on the scan mirrors over time and its interaction with polarised light <xref ref-type="bibr" rid="bib1.bibx8" id="paren.34"/>. Eastward light is likely more affected due to the higher degree of polarisation.</p>
      <p id="d2e793">Next, we model the temporal variation in global mean reflectance (<inline-formula><mml:math id="M34" display="inline"><mml:mrow><mml:msubsup><mml:mi>R</mml:mi><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi>s</mml:mi></mml:mrow><mml:mo>*</mml:mo></mml:msubsup></mml:mrow></mml:math></inline-formula>(t)). Global mean reflectances are expected to vary seasonally due to changing geometry and scene observation. Although no major long-term trends are expected, substantial long-term trends are noted (Fig. <xref ref-type="fig" rid="F2"/>). Therefore, <inline-formula><mml:math id="M35" display="inline"><mml:mrow><mml:msubsup><mml:mi>R</mml:mi><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi>s</mml:mi></mml:mrow><mml:mo>*</mml:mo></mml:msubsup></mml:mrow></mml:math></inline-formula>(t) is represented by a combination of a polynomial <inline-formula><mml:math id="M36" display="inline"><mml:mrow><mml:msubsup><mml:mi>P</mml:mi><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi>s</mml:mi></mml:mrow><mml:mi>p</mml:mi></mml:msubsup></mml:mrow></mml:math></inline-formula>(t) and a finite Fourier series <inline-formula><mml:math id="M37" display="inline"><mml:mrow><mml:msubsup><mml:mi>F</mml:mi><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi>s</mml:mi></mml:mrow><mml:mi>q</mml:mi></mml:msubsup></mml:mrow></mml:math></inline-formula>(t):

            <disp-formula id="Ch1.E1" content-type="numbered"><label>1</label><mml:math id="M38" display="block"><mml:mrow><mml:msubsup><mml:mi>R</mml:mi><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi>s</mml:mi></mml:mrow><mml:mo>*</mml:mo></mml:msubsup><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msubsup><mml:mi>P</mml:mi><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi>s</mml:mi></mml:mrow><mml:mi>p</mml:mi></mml:msubsup><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mo>[</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>+</mml:mo><mml:msubsup><mml:mi>F</mml:mi><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi>s</mml:mi></mml:mrow><mml:mi>q</mml:mi></mml:msubsup><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mo>]</mml:mo></mml:mrow></mml:math></disp-formula>

          <inline-formula><mml:math id="M39" display="inline"><mml:mrow><mml:msubsup><mml:mi>F</mml:mi><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi>s</mml:mi></mml:mrow><mml:mi>q</mml:mi></mml:msubsup><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M40" display="inline"><mml:mrow><mml:msubsup><mml:mi>P</mml:mi><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi>s</mml:mi></mml:mrow><mml:mi>p</mml:mi></mml:msubsup></mml:mrow></mml:math></inline-formula>(t) capture the seasonal variation and long-term trends, respectively. For GOME-2B, the Fourier order <inline-formula><mml:math id="M41" display="inline"><mml:mi>q</mml:mi></mml:math></inline-formula> is set to 6, and the polynomial degree <inline-formula><mml:math id="M42" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> to 5. A high polynomial degree was necessary for the fit of GOME-2B reflectances to accurately capture the abrupt drop in signal from around 2020, particularly on the eastern side, as visible in Fig. <xref ref-type="fig" rid="F2"/>. While geophysical changes, such as variations in cloud fraction, aerosols, and global greening, can affect long-term trends in global mean reflectance, their impact is expected to be minor compared to the observed trends and attributed impact of throughput loss following instrument degradation <xref ref-type="bibr" rid="bib1.bibx24 bib1.bibx8" id="paren.35"/>. Moreover, the pronounced scan-angle dependence strongly indicates an instrumental origin.</p>

      <fig id="F2" specific-use="star"><label>Figure 2</label><caption><p id="d2e1007">The observed (green dots) and fitted (solid black) global mean reflectance from GOME-2B at <inline-formula><mml:math id="M43" display="inline"><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 747.2 nm and scan-index <bold>(a)</bold> <inline-formula><mml:math id="M44" display="inline"><mml:mrow><mml:mi>s</mml:mi><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 1 (easternmost) and <bold>(b)</bold> <inline-formula><mml:math id="M45" display="inline"><mml:mrow><mml:mi>s</mml:mi><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 24 (westernmost). The dashed line shows the fitted polynomial, which captures the long-term change in the reflectance over time that is thought to be caused by the impact of instrument degradation. The reference day <inline-formula><mml:math id="M46" display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, set at 1 November 2012, is indicated by the pink star. </p></caption>
          <graphic xlink:href="https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026-f02.png"/>

        </fig>

      <p id="d2e1064">To obtain the correction factors (<inline-formula><mml:math id="M47" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi>s</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>), Eq. (<xref ref-type="disp-formula" rid="Ch1.E1"/>) is fitted to the observed reflectances using least-squares regression. The obtained coefficients of the polynomial <inline-formula><mml:math id="M48" display="inline"><mml:mrow><mml:msubsup><mml:mi>P</mml:mi><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi>s</mml:mi></mml:mrow><mml:mi>p</mml:mi></mml:msubsup></mml:mrow></mml:math></inline-formula> are then used to correct the long-term trends. We scale the reflectance value at day <inline-formula><mml:math id="M49" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> to the value at a reference day <inline-formula><mml:math id="M50" display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, as

            <disp-formula id="Ch1.E2" content-type="numbered"><label>2</label><mml:math id="M51" display="block"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi>s</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msubsup><mml:mi>P</mml:mi><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi>s</mml:mi></mml:mrow><mml:mi>p</mml:mi></mml:msubsup><mml:mo>(</mml:mo><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>)</mml:mo><mml:mo>/</mml:mo><mml:msubsup><mml:mi>P</mml:mi><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi>s</mml:mi></mml:mrow><mml:mi>p</mml:mi></mml:msubsup><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></disp-formula>

          With <inline-formula><mml:math id="M52" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi>s</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>(t) as correction factor at day <inline-formula><mml:math id="M53" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula>, wavelength <inline-formula><mml:math id="M54" display="inline"><mml:mi mathvariant="italic">λ</mml:mi></mml:math></inline-formula> and scan-index <inline-formula><mml:math id="M55" display="inline"><mml:mi>s</mml:mi></mml:math></inline-formula>. The reference day <inline-formula><mml:math id="M56" display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> represents a day early on in the mission, assuming no spectral degradation at that time. For GOME-2B,  <inline-formula><mml:math id="M57" display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is selected as 1 November 2012. The resulting correction factors are applied to each observed reflectance value before the SIF retrieval to counteract the identified degradation patterns.</p>
      <p id="d2e1254">Figure <xref ref-type="fig" rid="F3"/> shows the relative change in reflectance at <inline-formula><mml:math id="M58" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 740.1 nm across the swath for multiple years, for both GOME-2A and GOME-2B. The reflectance degradation pattern represents an inconsistency in the relative loss of throughput between the observed radiance and solar irradiance. As reflectance is defined as the ratio of radiance to solar irradiance signal, a decrease in reflectance, for instance,  indicates a stronger degradation of the radiance signal. In both sensors, reflectance degradation is more pronounced on the eastern side of the swath, and an increasing East-West bias develops over time. For GOME-2A, reflectances at all scanning positions increase over the first six years, then decline and eventually drop below the reference value. For GOME-2B, an overall decreasing trend in reflectances is noted.</p>

      <fig id="F3" specific-use="star"><label>Figure 3</label><caption><p id="d2e1268">Reflectance degradation of <bold>(a)</bold> GOME-2A and <bold>(b)</bold> GOME-2B as a function of scanner angle for different moments and at <inline-formula><mml:math id="M59" display="inline"><mml:mrow><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 740.1 nm. The dashed line indicates the selected reference day for each instrument, where it is expected that there is no impact of reflectance degradation (yet). The pink arrows indicate the 10th years past the reference day.</p></caption>
          <graphic xlink:href="https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026-f03.png"/>

        </fig>

      <p id="d2e1293">These results confirm that the reflectance degradation of GOME-2B, similar to GOME-2A <xref ref-type="bibr" rid="bib1.bibx2" id="paren.36"/>, is strongly scan-angle dependent and of the same order of magnitude as the temporal dependency. Importantly, the degradation trends substantially differ between sensors. Furthermore, when GOME-2B launched in 2013, GOME-2A had already drifted significantly from its original reflectance values, amplifying intersensor divergence.</p>
</sec>
<sec id="Ch1.S3.SS2">
  <label>3.2</label><title>SIF retrieval</title>
      <p id="d2e1307">The SIFTER retrieval algorithm obtains far-red SIF by making use of the relative infilling by fluorescence of solar Fraunhofer absorption lines near the 740 nm peak. A narrow retrieval window of 734 to 758 nm is used. This window represents the trade-off of minimising interference from water vapour and O<sub>2</sub> absorption features, while still capturing sufficient Fraunhofer lines and spectral points to ensure reliable SIF retrieval <xref ref-type="bibr" rid="bib1.bibx38 bib1.bibx30" id="paren.37"/>. However, some residual sensitivity due to inclusion of water vapour absorption features may remain under humid conditions. In this work, this sensitivity is reduced by using the SIFTER v3 algorithm, which includes an improved representation of atmospheric variability in the principal component construction <xref ref-type="bibr" rid="bib1.bibx4" id="paren.38"/>. We use the latest reprocessed level-1b dataset, Release-3 (R3), as input. The R3 dataset ensures consistent processing and auxiliary data for GOME-2A and GOME-2B up to July 2020 <xref ref-type="bibr" rid="bib1.bibx8" id="paren.39"/>. From July 2020 onwards, a different processor version is used, but this is not expected to introduce significant inconsistencies in the level-1b data.</p>
      <p id="d2e1328">The retrieval isolates the additional vegetation fluorescence signal from atmospheric features by matching a modeled reflectance spectrum to the observed spectrum. We model the reflectance (<inline-formula><mml:math id="M61" display="inline"><mml:mi>R</mml:mi></mml:math></inline-formula>) using a Lambertian surface reflectance model, as described by:

            <disp-formula id="Ch1.E3" content-type="numbered"><label>3</label><mml:math id="M62" display="block"><mml:mtable rowspacing="0.2ex" class="split" displaystyle="true" columnalign="right left"><mml:mtr><mml:mtd><mml:mrow><mml:mi>R</mml:mi><mml:mo>(</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">μ</mml:mi><mml:mo>,</mml:mo><mml:msub><mml:mi mathvariant="italic">μ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mo>≈</mml:mo><mml:msub><mml:mi>a</mml:mi><mml:mi>s</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo><mml:msup><mml:mi>T</mml:mi><mml:mo>↓</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:msub><mml:mi mathvariant="italic">μ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>)</mml:mo><mml:msup><mml:mi>T</mml:mi><mml:mo>↑</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">μ</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mo>+</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi mathvariant="italic">π</mml:mi><mml:msub><mml:mi>I</mml:mi><mml:mi mathvariant="normal">SIF</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>(</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>)</mml:mo><mml:msub><mml:mi mathvariant="italic">μ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:msup><mml:mi>T</mml:mi><mml:mo>↑</mml:mo></mml:msup><mml:mo>(</mml:mo><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="italic">μ</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:math></disp-formula>

          where <inline-formula><mml:math id="M63" display="inline"><mml:mi mathvariant="italic">μ</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M64" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">μ</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> are the cosines of the viewing and solar zenith angles, respectively. The surface albedo is denoted by <inline-formula><mml:math id="M65" display="inline"><mml:mrow><mml:msub><mml:mi>a</mml:mi><mml:mi>s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>(<inline-formula><mml:math id="M66" display="inline"><mml:mi mathvariant="italic">λ</mml:mi></mml:math></inline-formula>), the SIF emissions from the vegetated surface by <inline-formula><mml:math id="M67" display="inline"><mml:mrow><mml:msub><mml:mi>I</mml:mi><mml:mi mathvariant="normal">SIF</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, and the atmospheric transmission –both downwards and upwards – by <inline-formula><mml:math id="M68" display="inline"><mml:mrow><mml:msup><mml:mi>T</mml:mi><mml:mo>↓</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M69" display="inline"><mml:mrow><mml:msup><mml:mi>T</mml:mi><mml:mo>↑</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>. The modeled reflectance contains 16 unknowns, one of which is the SIF signal to be extracted. These unknowns are solved by minimising the difference between the modeled and observed <inline-formula><mml:math id="M70" display="inline"><mml:mi>R</mml:mi></mml:math></inline-formula> using a Levenberg-Marquardt least-squares regression <xref ref-type="bibr" rid="bib1.bibx38 bib1.bibx2" id="paren.40"/>. Among the other 15 unknowns, five coefficients come from the surface albedo, which is estimated using a fourth-order polynomial, and ten are related to the atmospheric transmittance, which is characterised by 10 principal component (PC) functions.</p>
      <p id="d2e1549">The atmospheric transmittance varies with each scene and atmospheric conditions. To capture its variability, we apply principal component analysis (PCA) to a large selection of spectra across the Sahara region (16–30° N, 8° W–29° E). These observations are filtered for barren areas using land classification data to ensure the absence of vegetation and, therefore, SIF emission. We select GOME-2B spectra from five complete years (2013–2018), matching the period length used for the PC calculations of GOME-2A (2007–2012). Note that degradation corrected spectra are used (Sect. <xref ref-type="sec" rid="Ch1.S3.SS1"/>) to avoid biases. Furthermore, as introduced in SIFTER v3 <xref ref-type="bibr" rid="bib1.bibx2" id="paren.41"/>, the spectra are mean-centered and scaled by standard deviation before the PCA.</p>
      <p id="d2e1557">Figure <xref ref-type="fig" rid="F4"/> presents the first principal component (PC) for both GOME-2A and GOME-2B, and the cumulative explained variance for each PC (10 in total) for both datasets. For both sensors, PC <inline-formula><mml:math id="M71" display="inline"><mml:mi mathvariant="italic">#</mml:mi></mml:math></inline-formula>1 shows a similar overall structure, but the GOME-2A pattern is more sharply defined, with more pronounced features, such as deeper troughs and higher peaks. The less defined pattern in GOME-2B may reflect its generally higher reflectance uncertainty in the NIR and/or its slightly courser spectral resolution (0.5 nm vs 0.48 nm, Table <xref ref-type="table" rid="T1"/>) compared to GOME-2A. Nevertheless, the PCs capture 99.95 % of the total variance, indicating that the main spectral structures are consistently represented in both sensors.</p>

      <fig id="F4" specific-use="star"><label>Figure 4</label><caption><p id="d2e1574">Panel <bold>(a)</bold> shows the leading principal component, PC <inline-formula><mml:math id="M72" display="inline"><mml:mi mathvariant="italic">#</mml:mi></mml:math></inline-formula>1, obtained for GOME-2A under nominal swath and GOME-2B. Panel <bold>(b)</bold> shows the cumulative explained variance of PCs 1 to 10 for both instruments. In both panels GOME-2A is shown in blue and GOME-2B is shown in green.</p></caption>
          <graphic xlink:href="https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026-f04.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS3">
  <label>3.3</label><title>Latitude bias correction</title>
      <p id="d2e1604">The SIFTER retrieval algorithm detects the SIF signal as variations in the relative depth of Fraunhofer lines; however, instrumental artifacts can also cause false “in-filling” or “deepening” of these lines and can therefore mimic fluorescence signals <xref ref-type="bibr" rid="bib1.bibx19 bib1.bibx14 bib1.bibx38" id="paren.42"><named-content content-type="pre">e.g.</named-content></xref>. These biases are latitude-dependent and may stem from temperature-driven changes in slit function width throughout the orbit, affecting the observed depth of Fraunhofer lines. Moreover, recent work by <xref ref-type="bibr" rid="bib1.bibx32" id="text.43"/> demonstrated that rotational Raman scattering can induce seemingly large SIF values. Such effects are particularly evident over oceans and deserts, where fluorescence should be near zero, as a zero-level offset.</p>
      <p id="d2e1615">Figure <xref ref-type="fig" rid="F5"/> shows the zero-level offset observed in GOME-2A and GOME-2B SIF over the Pacific Ocean (130–150° W), plotted by latitude. In GOME-2A SIF, a clear annual pattern of negative SIF values is noticeable, which shifts from north to south across latitudes. Additionally, the negative offsets intensify over time, with larger negative values observed in the later years. In GOME-2B, a different pattern is noticeable with strong positive offsets appearing early in the years ranging between 20° N–20° S. Additionally, GOME-2B shows strong variation between positive and negative offsets across latitude. Due to the differing patterns observed in both instruments, SIF values from GOME-2A and GOME-2B are not directly comparable. Consequently, it is necessary to apply a correction to account for these discrepancies, reduce intersensor biases, and ensure spatial consistency within and across the datasets.</p>

      <fig id="F5" specific-use="star"><label>Figure 5</label><caption><p id="d2e1622">Observed zero-level offset of SIF retrieved from <bold>(a)</bold> GOME-2A and <bold>(b)</bold> GOME-2B across the Pacific ocean – where SIF is expected to be 0 – per latitude and over time. The SIF values shown are not adjusted for the latitude bias. The shown data are monthly averaged, gridded at 0.5° <inline-formula><mml:math id="M73" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 0.5° resolution, and subsequently averaged over 130–150° W.</p></caption>
          <graphic xlink:href="https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026-f05.png"/>

        </fig>

      <p id="d2e1645">To address the latitude bias effects and create higher consistency between GOME-2A and GOME-2B, we apply the post-hoc correction method from SIFTER v3 <xref ref-type="bibr" rid="bib1.bibx2" id="paren.44"/>. This additive correction adjusts the retrieved SIF retrieval based on daily- and latitude-specific biases observed across reference areas over the Pacific and Atlantic Ocean. The correction is characterised as a function of reflectance (at 744 nm) per latitude band and on a daily basis, thereby accounting for brightness-dependent effects. The latitude bias correction brings SIF values over the Pacific Ocean region, within the expected near-zero range for both GOME-2A and GOME-2B (shown in Fig. S3). This confirms that latitude-dependent offsets were effectively corrected for, reducing the correlated intersensor divergence.</p>
</sec>
</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Comparison of GOME-2A and GOME-2B SIF</title>
<sec id="Ch1.S4.SS1">
  <label>4.1</label><title>Spatial consistency</title>
      <p id="d2e1667">Here, we compare the spatial distribution of SIF as retrieved from GOME-2A and GOME-2B over the period when both sensors operated in tandem. For both datasets, valid SIF data were selected and seasonally averaged over the 2013–2017 period at a 0.5° <inline-formula><mml:math id="M74" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 0.5° spatial resolution. To avoid potential biases, we excluded the GOME-2B commissioning phase and only used complete seasons.</p>
      <p id="d2e1677">Figure <xref ref-type="fig" rid="F6"/> shows the mean SIF retrieved from GOME-2A and GOME-2B for the December–February (DJF) and June–August (JJA) seasons. Both datasets exhibit similar spatial distributions in SIF and align strongly with each other. However, slight differences are noted. GOME-2B SIF tends to be more negative over barren areas, such as Western China. Moreover, on average, GOME-2B SIF values exceed those of GOME-2A SIF by approximately 5 %–6 %. This positive bias appears to be most pronounced in regions with high vegetation activity, such as the Corn Belt region in JJA and the Amazon in DJF.</p>

      <fig id="F6" specific-use="star"><label>Figure 6</label><caption><p id="d2e1684">Seasonal averaged GOME-2A and GOME-2B SIF over December–February (DJF), and June–August (JJA) 2014–2017. DJF includes December of the preceding year, e.g., DJF 2014 includes December 2013. Panels <bold>(e)</bold> and <bold>(f)</bold> show the correlation between GOME-2A and GOME-2B SIF for these periods; panels <bold>(g)</bold> and <bold>(h)</bold> show the correlation between their respective uncertainty. Major axis regressions are used for the correlations (pink line). Only land pixels are shown and presented to focus on biosphere-relevant differences. SIF values are filtered for cloud fractions <inline-formula><mml:math id="M75" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 0.3 (FRESCO<inline-formula><mml:math id="M76" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> v2) and gridded at 0.5° <inline-formula><mml:math id="M77" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 0.5°. The blue rectangles mark selected study regions. </p></caption>
          <graphic xlink:href="https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026-f06.png"/>

        </fig>

      <p id="d2e1728">Aside from the differences in SIF values, GOME-2B also shows consistently higher uncertainty in SIF than GOME-2A, on the order of 17 %–18 %. This likely reflects a combination of larger uncertainties in the input reflectance, lower spectral resolution (Table <xref ref-type="table" rid="T1"/>), and the less sharply defined principal components (Fig. <xref ref-type="fig" rid="F4"/>), all of which can propagate through the retrieval and increase the final uncertainty.</p>
      <p id="d2e1735">Overall, GOME-2A and GOME-2B SIF values agree well with consistent spatial patterns and strong correlations (<inline-formula><mml:math id="M78" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.96</mml:mn></mml:mrow></mml:math></inline-formula> for JJA, and <inline-formula><mml:math id="M79" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.97</mml:mn></mml:mrow></mml:math></inline-formula> for DJF). These results indicate coherence between both datasets. Nonetheless, GOME-2B SIF values are slightly but systematically biased against GOME-2A SIF values. In the following subsections, we examine to what extent this divergence reflects true biases or results from sampling differences.</p>
</sec>
<sec id="Ch1.S4.SS2">
  <label>4.2</label><title>Impact of viewing geometry differences</title>
      <p id="d2e1770">During the operational tandem phase, GOME-2A and GOME-2B operated under different swath configurations. The swath reduction of GOME-2A limited the viewing zenith angle (VZA) range of the observations from <inline-formula><mml:math id="M80" display="inline"><mml:mo>∈</mml:mo></mml:math></inline-formula> [<inline-formula><mml:math id="M81" display="inline"><mml:mo lspace="0mm">-</mml:mo></mml:math></inline-formula>52, <inline-formula><mml:math id="M82" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>52°] to [<inline-formula><mml:math id="M83" display="inline"><mml:mo lspace="0mm">-</mml:mo></mml:math></inline-formula>35, <inline-formula><mml:math id="M84" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>35°] (Table <xref ref-type="table" rid="T1"/>). As a result, the GOME-2B SIF averages shown in Fig. <xref ref-type="fig" rid="F6"/> include observations made under larger VZA angles (<inline-formula><mml:math id="M85" display="inline"><mml:mo lspace="0mm">|</mml:mo></mml:math></inline-formula>VZA<inline-formula><mml:math id="M86" display="inline"><mml:mo>|</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M87" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 35°) than GOME-2A. To understand how these discrepancies in viewing geometry might induce biases between GOME-2A and GOME-2B SIF, we first discuss the principle behind the angular dependence of SIF observations.</p>
      <p id="d2e1834">The SIF signal detected by the satellite sensor reflects the fraction of total emitted chlorophyll fluorescence that escaped the canopy and reached the sensor. This fraction depends on the photon scattering, leaf properties, and canopy architecture, influencing the propagation of SIF photons through the canopy <xref ref-type="bibr" rid="bib1.bibx39 bib1.bibx31 bib1.bibx18 bib1.bibx34" id="paren.45"><named-content content-type="pre">e.g.,</named-content></xref>. As a result, the SIF signal is anisotropic and therefore depends on the viewing geometry between the Sun, vegetation, and the satellite sensor <xref ref-type="bibr" rid="bib1.bibx46 bib1.bibx39 bib1.bibx6" id="paren.46"><named-content content-type="pre">e.g.</named-content></xref>.</p>
      <p id="d2e1847">Figure <xref ref-type="fig" rid="F7"/> illustrates the scan and illumination dependencies of the observed SIF by GOME-2. In the following, we describe each individual mechanism contributing to these dependencies on SIF. The relative importance of these mechanisms depend on the conditions, such as canopy structure and illumination geometry. At nadir, the sensor mainly detects photons emitted from the top of the canopy. Toward the swath edges, at larger viewing zenith angles (VZA), the sensor observes the canopy from a slanted angle, thereby enhancing the probability of detecting photons originating deeper within the canopy. Moreover, the viewing perspective determines whether the sunlit or shaded side of the canopy is viewed, leading to higher or lower observed values, respectively. For GOME-2A observations, the western ground pixels are typically sunlit, whereas eastern ground pixels tend to be shaded.</p>

      <fig id="F7" specific-use="star"><label>Figure 7</label><caption><p id="d2e1855">Schematic of the scan-angle dependencies of GOME-2 SIF observations. The instrument scans from east (pixel 1) to west (pixel 24), with a total scanning time of around 50 min.</p></caption>
          <graphic xlink:href="https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026-f07.png"/>

        </fig>

      <p id="d2e1864">Wide-swath instruments, such as GOME-2 and TROPOMI, also introduce across-track variations in incoming solar irradiance <xref ref-type="bibr" rid="bib1.bibx18" id="paren.47"/>. The wide swaths cover an extensive longitudinal range that spans different local solar times and thus solar zenith angles (SZA). As a result, GOME-2 observes eastern pixels later in the morning when solar illumination is typically higher (lower SZA), leading to potentially higher SIF values. Together, these viewing geometry factors can lead to systematic asymmetry in the observed SIF values across-track <xref ref-type="bibr" rid="bib1.bibx18" id="paren.48"/>. The geometry effects on observed SIF are well known, and SIF is generally averaged over a sufficient number of observations to mitigate these effects <xref ref-type="bibr" rid="bib1.bibx36" id="paren.49"><named-content content-type="pre">e.g.</named-content></xref>.</p>
      <p id="d2e1878">To assess the effect of discrepancy in viewing geometry between GOME-2A and GOME-2B, we average both datasets across scan positions. Figure <xref ref-type="fig" rid="F8"/> shows seasonal SIF as a function of VZA for both sensors across various geographical regions. A consistent across-track asymmetry is observed in all regions during the peak seasons, specifically JJA in the Northern Hemisphere and DJF in the Southern Hemisphere. During these high activity seasons, large SIF values near the eastern and, more prominently, the western edges of GOME-2B's 1920 km swath contribute to a higher overall average (<inline-formula><mml:math id="M88" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>x</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mi mathvariant="normal">B</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>), compared to GOME-2A SIF (<inline-formula><mml:math id="M89" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>x</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mi mathvariant="normal">A</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>). For instance, GOME-2B SIF has a bias of 13.9 % compared to GOME-2A SIF over Zambia. SIF values from both sensors align well when restricted to the shared VZA range of [<inline-formula><mml:math id="M90" display="inline"><mml:mo lspace="0mm">-</mml:mo></mml:math></inline-formula>35, <inline-formula><mml:math id="M91" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>35°]. The largest divergence across-track emerges when the <inline-formula><mml:math id="M92" display="inline"><mml:mo>|</mml:mo></mml:math></inline-formula>VZA<inline-formula><mml:math id="M93" display="inline"><mml:mo>|</mml:mo></mml:math></inline-formula> exceeds <inline-formula><mml:math id="M94" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 30°. Within GOME-2B's wide swath, westward pixels can exhibit up to 35 % higher SIF values than eastward pixels during peak seasons (see Sect. S2.2 for more detail).</p>

      <fig id="F8" specific-use="star"><label>Figure 8</label><caption><p id="d2e1949">Seasonally averaged SIF from GOME-2A (blue) and GOME-2B (green) across the viewing zenith angle (in °). Showing seasonal SIF for June–August (JJA) 2014–2017 (top plots) and December–February (DJF) 2014–2017 (bottom plots), over Eastern Europe, the United States Corn Belt, Eastern China, the Amazon, and Zambia.</p></caption>
          <graphic xlink:href="https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026-f08.png"/>

        </fig>

      <p id="d2e1958">Figure <xref ref-type="fig" rid="F9"/> shows zonal averages of SIF from GOME-2A (in solid blue), GOME-2B using observations from the full VZA range (in solid green), and VZA ranges matched with GOME-2A (in dashed green). Overall, GOME-2A and GOME-2B SIF values converge when their VZA ranges match. For instance, the difference in DJF SIF between GOME-2A and GOME-2B over 0 to 40° S decreased from 13.8 % to 4.9 %. These results indicate that a significant portion of the inter-sensor differences in SIF can be attributed to variations in VZA sampling. Nonetheless, some divergence between GOME-2A and GOME-2B SIF remains. The remaining biases may result from differences in spatial and temporal sampling, as well as from differences in sensor and orbit characteristics.</p>

      <fig id="F9"><label>Figure 9</label><caption><p id="d2e1966">Zonal averaged SIF from GOME-2A (solid blue line), GOME-2B considering all observations (solid green line), and only those with <inline-formula><mml:math id="M95" display="inline"><mml:mo>|</mml:mo></mml:math></inline-formula>VZA<inline-formula><mml:math id="M96" display="inline"><mml:mo>|</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M97" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 35 ° (dashed green line), for <bold>(a)</bold> DJF 2016 and <bold>(b)</bold> JJA 2016. Zonal averages reflect all land pixels. Pixels over the Sahara region (15–32° N, 16° W–52° E) were filtered to limit distortion of observations over desert areas and focus primarily on vegetated regions. The SIF values are plotted by latitude at 2° resolution. </p></caption>
          <graphic xlink:href="https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026-f09.png"/>

        </fig>

</sec>
<sec id="Ch1.S4.SS3">
  <label>4.3</label><title>Isolating sensor-specific differences</title>
      <p id="d2e2010">To further evaluate the divergence between GOME-2A and GOME-2B SIF, we perform two co-sampling experiments (see Sect. S2.3). In Experiment 1, GOME-2A and GOME-2B pixels are spatially and temporally collocated. Matching pixel pairs had a maximum 50 km distance between their centers, at least 60 % spatial overlap of the smaller GOME-2A pixel with the GOME-2B pixel, and observation times less than 50 min apart. Experiment 2 applies the same constraints, with an additional requirement that both observations are within the same viewing geometry range of [<inline-formula><mml:math id="M98" display="inline"><mml:mo lspace="0mm">-</mml:mo></mml:math></inline-formula>35, <inline-formula><mml:math id="M99" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>35°]. These constraints help to isolate instrument-specific biases from those arising from sampling mismatches. Due to the limited spatial overlap of GOME-2A and GOME-2B ground pixels, sampling in Experiment 2 is practically limited to the Northern latitudes.</p>
      <p id="d2e2027">Figure <xref ref-type="fig" rid="F10"/> shows GOME-2A and GOME-2B SIF data, sampled to both experiments accordingly, and averaged over JJA 2014–2017. GOME-2A and GOME-2B SIF are better aligned for Experiment 2 (1.9 % bias) than for Experiment 1 (5.6 % bias) – as expected. This is confirmed by the empirical cumulative distribution functions (ECDFs) (bottom plots in Fig. <xref ref-type="fig" rid="F10"/>). ECDFs visualise the cumulative distribution of each dataset, enabling clear detection of systematic shifts between datasets. When only spatially and temporally co-sampled, Exp. 1, GOME-2B SIF values at the 90th percentile are 7.1 % higher than the corresponding GOME-2A value. Including co-sampling of viewing angles, Exp. 2, reduces the bias of GOME-2B SIF to GOME-2A SIF to 2.1 %.</p>

      <fig id="F10" specific-use="star"><label>Figure 10</label><caption><p id="d2e2036"><bold>(a, c)</bold> GOME-2A and <bold>(b, d)</bold> GOME-2B sampled according to Experiments 1 and 2, averaged over June–August (JJA) from 2014 to 2017 on a 0.5<inline-formula><mml:math id="M100" display="inline"><mml:mi mathvariant="italic">°</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M101" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 0.5° grid. SIF values are shown for grid cells with valid and sufficient observations (exceeding the 10th percentile of data counts) in both datasets and experiments. The mean SIF is shown as <inline-formula><mml:math id="M102" display="inline"><mml:mover accent="true"><mml:mi>x</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula>. The two bottom panels show the ECDF plots of GOME-2A and GOME-2B SIF according to <bold>(e)</bold> Experiment 1 and <bold>(f)</bold> Experiment 2. The dotted line indicates the 90th percentile, with the text indicating the corresponding SIF values.</p></caption>
          <graphic xlink:href="https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026-f10.png"/>

        </fig>

      <p id="d2e2082">Despite the reduced structural bias in Experiment 2, the correlation between GOME-2A and GOME-2B SIF is lower (<inline-formula><mml:math id="M103" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.92</mml:mn></mml:mrow></mml:math></inline-formula>) than in Experiment 1 (<inline-formula><mml:math id="M104" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.97</mml:mn></mml:mrow></mml:math></inline-formula>) (shown in Fig. S13). However, the SIF averages corresponding to Experiment 1 are based on nearly three times as many observations per grid cell as those in Experiment 2. This discrepancy in data density between the two experiments might reduce the comparability of their results. To enable a more balanced comparison, we constructed a reduced version of Experiment 1. The additional test involved averaging Experiment 1 data over a randomly selected subset of days from the JJA 2014–2017 period to match the data density of Experiment 2 better. The comparison between this reduced Experiment 1 and Experiment 2 was performed using only grid cells with valid and sufficient observations in both experiments. The divergence between GOME-2A and GOME-2B SIF remained similar to that of Fig. <xref ref-type="fig" rid="F10"/>, but the correlation between GOME-2A and GOME-2B SIF for Experiment 2 (<inline-formula><mml:math id="M105" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.96</mml:mn></mml:mrow></mml:math></inline-formula>) now exceeds that of Experiment 1 (<inline-formula><mml:math id="M106" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.95</mml:mn></mml:mrow></mml:math></inline-formula>) (shown in Fig. S16). These results confirm that the co-sampling requirements as set in Experiment 2 result in the best agreement among GOME-2A and GOME-2B SIF. The details on this additional test are in Sect. S2.3.1.</p>
      <p id="d2e2135">GOME-2A and GOME-2B SIF show strong coherence in terms of spatial distribution. However, our results indicate the importance of similar sampling to reduce systematic biases between the two datasets. Particularly, discrepancies in viewing geometry sampling have been shown to distort the coherence between inter-sensor SIF datasets. When both datasets are sampled similarly, GOME-2A and GOME-2B SIF agree to within 2 %. A slight discrepancy is expected, as they are separate sensors with minor differences in instrumental characteristics (Table <xref ref-type="table" rid="T1"/>). These results provide confidence in the consistency of GOME-2A SIF (pre-July 2013) and GOME-2B SIF (from July 2013 onwards), when both sensors operated with the same 1920 km swath and viewing zenith angle ranges (VZA <inline-formula><mml:math id="M107" display="inline"><mml:mo>∈</mml:mo></mml:math></inline-formula> [<inline-formula><mml:math id="M108" display="inline"><mml:mo lspace="0mm">-</mml:mo></mml:math></inline-formula>52, <inline-formula><mml:math id="M109" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>52°]).</p>
</sec>
</sec>
<sec id="Ch1.S5">
  <label>5</label><title>Long-term time series analysis</title>
      <p id="d2e2171">This section evaluates the combined 2007–2023 GOME-2 SIF record over time. It uses GOME-2A data from January 2007 to June 2013 and GOME-2B data from July 2013 onwards. We focus on SIF observations from the GOME-2A instrument under its nominal swath configuration to ensure similar viewing angle ranges within both datasets, limiting the bias between GOME-2A and GOME-2B SIF and advancing their connection (as found in Sect. <xref ref-type="sec" rid="Ch1.S4.SS3"/>). The record's performance is evaluated in two ways. First, the coherence between GOME-2A and GOME-2B SIF is assessed in Sect. <xref ref-type="sec" rid="Ch1.S5.SS1"/> using statistical tests and analysis. In Sect. <xref ref-type="sec" rid="Ch1.S5.SS2"/>, the temporal consistency of the record is evaluated using independent datasets. Both analyses use monthly-averaged SIF across six vegetative regions. The monthly and spatial averaging mitigate the effects of variation in geometry on SIF.</p>
<sec id="Ch1.S5.SS1">
  <label>5.1</label><title>Temporal coherence of GOME-2A and GOME-2B SIF</title>
      <p id="d2e2187">Figure <xref ref-type="fig" rid="F11"/> shows the monthly regional averages of SIF from January 2007 to December 2023. For most regions, the transition from GOME-2A SIF (in blue) to GOME-2B SIF (in green) appears seamless. However, in the Amazon, a slight downward shift in GOME-2B SIF, relative to GOME-2A SIF, is noted. To test whether this shift is related to the instrument transition, we proceed with statistical and analytical tests.</p>

      <fig id="F11" specific-use="star"><label>Figure 11</label><caption><p id="d2e2194">Time series of monthly averaged Level-2 SIF values retrieved from GOME-2A (in blue) and GOME-2B (in green) over <bold>(a)</bold> Eastern Europe, <bold>(b)</bold> the United States Cornbelt, <bold>(c)</bold> Eastern China, <bold>(d)</bold> the Amazon, <bold>(e)</bold> the Congo Basin, and <bold>(f)</bold> the Pampas region. GOME-2B SIF observations during the instrument's commissioning phase are indicated by the dashed green line.</p></caption>
          <graphic xlink:href="https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026-f11.png"/>

        </fig>

      <p id="d2e2222">To statistically investigate whether a structural break occurs at the transition month <inline-formula><mml:math id="M110" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, July 2013, from GOME-2A to GOME-2B SIF data, we fit a simple model to the monthly SIF time series, which includes a linear trend (<inline-formula><mml:math id="M111" display="inline"><mml:mrow><mml:mi mathvariant="italic">α</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula>), seasonal component (<inline-formula><mml:math id="M112" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mi>t</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>), and a mean level shift term (<inline-formula><mml:math id="M113" display="inline"><mml:mrow><mml:mi mathvariant="italic">δ</mml:mi><mml:msub><mml:mi>U</mml:mi><mml:mi>t</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>): 

            <disp-formula id="Ch1.E4" content-type="numbered"><label>4</label><mml:math id="M114" display="block"><mml:mrow><mml:msub><mml:mi>y</mml:mi><mml:mi>t</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mi mathvariant="italic">μ</mml:mi><mml:mo>+</mml:mo><mml:mi mathvariant="italic">α</mml:mi><mml:mi>t</mml:mi><mml:mo>+</mml:mo><mml:msub><mml:mi>S</mml:mi><mml:mi>t</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:mi mathvariant="italic">δ</mml:mi><mml:msub><mml:mi>U</mml:mi><mml:mi>t</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mi>t</mml:mi></mml:msub></mml:mrow></mml:math></disp-formula>

          where <inline-formula><mml:math id="M115" display="inline"><mml:mrow><mml:msub><mml:mi>y</mml:mi><mml:mi>t</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> represents the regional SIF value at month <inline-formula><mml:math id="M116" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M117" display="inline"><mml:mi mathvariant="italic">μ</mml:mi></mml:math></inline-formula> the monthly mean and <inline-formula><mml:math id="M118" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mi>t</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> the residual of the observed and fitted SIF. This equation is adapted from <xref ref-type="bibr" rid="bib1.bibx44" id="text.50"/> and commonly used to model trends in environmental variables that include a sudden level shift <xref ref-type="bibr" rid="bib1.bibx37" id="paren.51"><named-content content-type="pre">e.g.</named-content></xref>. The seasonal component <inline-formula><mml:math id="M119" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mi>t</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> represents the annual cycle of SIF as a first-order harmonic:

            <disp-formula id="Ch1.E5" content-type="numbered"><label>5</label><mml:math id="M120" display="block"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mi>t</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="italic">β</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mi>sin⁡</mml:mi><mml:mo>(</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mi mathvariant="italic">π</mml:mi><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>-</mml:mo><mml:mi mathvariant="italic">ϕ</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mn mathvariant="normal">12</mml:mn></mml:mfrac></mml:mstyle><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="italic">β</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mi>cos⁡</mml:mi><mml:mo>(</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mi mathvariant="italic">π</mml:mi><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>-</mml:mo><mml:mi mathvariant="italic">ϕ</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mn mathvariant="normal">12</mml:mn></mml:mfrac></mml:mstyle><mml:mo>)</mml:mo></mml:mrow></mml:math></disp-formula>

          where <inline-formula><mml:math id="M121" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">β</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M122" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">β</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> control the amplitude, <inline-formula><mml:math id="M123" display="inline"><mml:mi mathvariant="italic">ϕ</mml:mi></mml:math></inline-formula> is the phase shift, and the angular frequency corresponds to annual periodicity.</p>
      <p id="d2e2480">Before fitting the full model, the phase shift <inline-formula><mml:math id="M124" display="inline"><mml:mi mathvariant="italic">ϕ</mml:mi></mml:math></inline-formula> is fixed through a pre-optimalisation step. We estimated its value by evaluating the model with 100 evenly spaced values of <inline-formula><mml:math id="M125" display="inline"><mml:mi mathvariant="italic">ϕ</mml:mi></mml:math></inline-formula>, ranging from 0 to 1, and selecting the value under which the model performs best. This ensures good alignment of the modelled SIF with the real seasonal timing and avoids non-linearity in the model.</p>
      <p id="d2e2497">The possible offset in GOME-2 SIF related to the moment when the time series shifts from GOME-2A to GOME-2B data in July 2013, or <inline-formula><mml:math id="M126" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, is accounted for by the step-change indicator <inline-formula><mml:math id="M127" display="inline"><mml:mrow><mml:msub><mml:mi>U</mml:mi><mml:mi>t</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> as:

            <disp-formula id="Ch1.E6" content-type="numbered"><label>6</label><mml:math id="M128" display="block"><mml:mrow><mml:msub><mml:mi>U</mml:mi><mml:mi>t</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mfenced open="{" close=""><mml:mtable columnspacing="1em" rowspacing="0.2ex" class="cases" columnalign="left left" framespacing="0em"><mml:mtr><mml:mtd><mml:mrow><mml:mn mathvariant="normal">0</mml:mn><mml:mo>,</mml:mo></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mtext>if </mml:mtext><mml:mi>t</mml:mi><mml:mo>&lt;</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>,</mml:mo></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mtext>if </mml:mtext><mml:mi>t</mml:mi><mml:mo>≥</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:mfenced></mml:mrow></mml:math></disp-formula>

          In this equation, <inline-formula><mml:math id="M129" display="inline"><mml:mrow><mml:msub><mml:mi>U</mml:mi><mml:mi>t</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is set to 0 during the GOME-2A period (January 2007–June 2013) and switches to 1 from July 2013 onwards during the GOME-2B period. Finally, Ordinary Least Squares (OLS) regression is used to fit the five remaining unknowns: <inline-formula><mml:math id="M130" display="inline"><mml:mi mathvariant="italic">μ</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M131" display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M132" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">β</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M133" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">β</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, and <inline-formula><mml:math id="M134" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>.</p>
      <p id="d2e2632">We use the fitted coefficient <inline-formula><mml:math id="M135" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> and its <inline-formula><mml:math id="M136" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula>-value to evaluate the existence and magnitude of any step change at transition <inline-formula><mml:math id="M137" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. Additionally, we apply both the Chow and the Likelihood Ratio (LR) test to evaluate the statistical significance of the potential break. The Chow test evaluates whether regression parameters differ before and after the breakpoint. It tests if the data structure is best described with one or two regressions by fitting the same model to (i) the full GOME-2 dataset, (ii) the data before <inline-formula><mml:math id="M138" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (GOME-2A), and (iii) the data after <inline-formula><mml:math id="M139" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (GOME-2B). The LR test complements this by comparing the regression results from the full model (including the <inline-formula><mml:math id="M140" display="inline"><mml:mrow><mml:mi mathvariant="italic">δ</mml:mi><mml:msub><mml:mi>U</mml:mi><mml:mi>t</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> term) with a reduced model that excludes the step-change term. A significant <inline-formula><mml:math id="M141" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula>-value from the LR test indicates that including the step-change term significantly improved the fit.</p>
      <p id="d2e2703">Table <xref ref-type="table" rid="T2"/> shows the fit and statistical test results for all cases. The modelled and observed SIF are strongly correlated (<inline-formula><mml:math id="M142" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>≥</mml:mo></mml:mrow></mml:math></inline-formula> 0.91), implying that the model in Eq. (<xref ref-type="disp-formula" rid="Ch1.E4"/>) effectively captures the seasonal patterns and long-term trends necessary to detect structural breaks. In most regions, the step change coefficient <inline-formula><mml:math id="M143" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> is insignificant, indicating no jump in SIF from <inline-formula><mml:math id="M144" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. However, significant step changes (<inline-formula><mml:math id="M145" display="inline"><mml:mrow><mml:mi>p</mml:mi><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">0.05</mml:mn></mml:mrow></mml:math></inline-formula>) are detected within the records across Eastern China and the Amazon. This bias is 0.13 <inline-formula><mml:math id="M146" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.04 mW m<sup>−2</sup> sr<sup>−1</sup> nm<sup>−1</sup> over Eastern China and <inline-formula><mml:math id="M150" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.10 <inline-formula><mml:math id="M151" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.03 mW m<sup>−2</sup> sr<sup>−1</sup> nm<sup>−1</sup> over the Amazon region, respectively reflecting 16.6 % and 8.9 % of monthly averaged SIF over 2007–2023.</p>

<table-wrap id="T2" specific-use="star"><label>Table 2</label><caption><p id="d2e2848">Results of the regression fit, Chow test, and Likelihood Ratio (LR) test. The given uncertainty in <inline-formula><mml:math id="M155" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> represents one standard deviation of the estimated coefficient. The column r provides the Pearson correlation between the model fit and the monthly SIF time series. Significance is indicated by “Y” (yes) when the coefficient or test is statistically significant at the 95 % confidence level with <inline-formula><mml:math id="M156" display="inline"><mml:mrow><mml:mi>p</mml:mi><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">0.05</mml:mn></mml:mrow></mml:math></inline-formula>. If the <inline-formula><mml:math id="M157" display="inline"><mml:mi>p</mml:mi></mml:math></inline-formula> value exceeds 0.05, “N” (no) is indicated. For clarity, “Y” is shown in bold. More detailed results of the regression fit is shown in Table S5, and the results of the Chow and LR test are summarised in Table S6. </p></caption><oasis:table frame="topbot"><oasis:tgroup cols="6">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="center" colsep="1"/>
     <oasis:colspec colnum="5" colname="col5" align="center"/>
     <oasis:colspec colnum="6" colname="col6" align="center"/>
     <oasis:thead>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry rowsep="1" namest="col2" nameend="col4" align="center" colsep="1">Regression fit </oasis:entry>

         <oasis:entry rowsep="1" namest="col5" nameend="col6" morerows="1">Breakpoint significance following </oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2" morerows="1"><inline-formula><mml:math id="M158" display="inline"><mml:mi>r</mml:mi></mml:math></inline-formula></oasis:entry>

         <oasis:entry rowsep="1" namest="col3" nameend="col4" align="center" colsep="1">coefficient <inline-formula><mml:math id="M159" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula></oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">Regions</oasis:entry>

         <oasis:entry colname="col3">Value/bias A–B</oasis:entry>

         <oasis:entry colname="col4">Significant?</oasis:entry>

         <oasis:entry colname="col5">Chow test</oasis:entry>

         <oasis:entry colname="col6">Likelihood Ratio</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3">[mW m<sup>−2</sup> sr<sup>−1</sup> nm<sup>−1</sup>]</oasis:entry>

         <oasis:entry colname="col4">(Y/N)</oasis:entry>

         <oasis:entry colname="col5">(Y/N)</oasis:entry>

         <oasis:entry colname="col6">test  (Y/N)</oasis:entry>

       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>

         <oasis:entry colname="col1">Eastern Europe</oasis:entry>

         <oasis:entry colname="col2"><inline-formula><mml:math id="M163" display="inline"><mml:mn mathvariant="normal">0.92</mml:mn></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col3"><inline-formula><mml:math id="M164" display="inline"><mml:mrow><mml:mn mathvariant="normal">9.66</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msup><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.05</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col4">N</oasis:entry>

         <oasis:entry colname="col5">N</oasis:entry>

         <oasis:entry colname="col6">N</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">Corn Belt, US</oasis:entry>

         <oasis:entry colname="col2"><inline-formula><mml:math id="M165" display="inline"><mml:mn mathvariant="normal">0.94</mml:mn></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col3"><inline-formula><mml:math id="M166" display="inline"><mml:mrow><mml:mn mathvariant="normal">0.06</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.06</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col4">N</oasis:entry>

         <oasis:entry colname="col5">N</oasis:entry>

         <oasis:entry colname="col6">N</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">Eastern China</oasis:entry>

         <oasis:entry colname="col2"><inline-formula><mml:math id="M167" display="inline"><mml:mn mathvariant="normal">0.94</mml:mn></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col3"><inline-formula><mml:math id="M168" display="inline"><mml:mrow><mml:mn mathvariant="normal">0.13</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.04</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col4"><bold>Y</bold></oasis:entry>

         <oasis:entry colname="col5">N</oasis:entry>

         <oasis:entry colname="col6"><bold>Y</bold></oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">Amazon</oasis:entry>

         <oasis:entry colname="col2"><inline-formula><mml:math id="M169" display="inline"><mml:mn mathvariant="normal">0.94</mml:mn></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col3"><inline-formula><mml:math id="M170" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.10</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.03</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col4"><bold>Y</bold></oasis:entry>

         <oasis:entry colname="col5">N</oasis:entry>

         <oasis:entry colname="col6"><bold>Y</bold></oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">Zambia</oasis:entry>

         <oasis:entry colname="col2"><inline-formula><mml:math id="M171" display="inline"><mml:mn mathvariant="normal">0.95</mml:mn></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col3"><inline-formula><mml:math id="M172" display="inline"><mml:mrow><mml:mn mathvariant="normal">0.03</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.03</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col4">N</oasis:entry>

         <oasis:entry colname="col5">N</oasis:entry>

         <oasis:entry colname="col6">N</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1">Pampas</oasis:entry>

         <oasis:entry colname="col2"><inline-formula><mml:math id="M173" display="inline"><mml:mn mathvariant="normal">0.91</mml:mn></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col3"><inline-formula><mml:math id="M174" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.03</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.04</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col4">N</oasis:entry>

         <oasis:entry colname="col5">N</oasis:entry>

         <oasis:entry colname="col6">N</oasis:entry>

       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d2e3250">To interpret the detected offset bias <inline-formula><mml:math id="M175" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula>, we evaluate its magnitude against the underlying uncertainty in SIF. Uncertainty in SIF retrieval can be distinguished into random errors and systematic errors. The first vary stochastically, arise from, for example, fit residual noise or sampling divergence, and decrease through averaging. Due to the spatial and temporal averaging applied here, random errors are small relative to the detected offsets. Systematic errors originate from algorithmic settings and persist despite averaging <xref ref-type="bibr" rid="bib1.bibx13" id="paren.52"/>. To obtain a first-order estimate of these systematic errors, independently of regional offsets, we performed sensitivity tests over the Congo Basin, a region previously used as a sensitivity testbed by <xref ref-type="bibr" rid="bib1.bibx2" id="text.53"/>. We perturbed the settings of four distinct retrieval steps: (i) the degradation correction, (ii) the PC's, (iii) the interpolation across the slit function (discussed in more detail in <xref ref-type="bibr" rid="bib1.bibx2" id="text.54"/>), and (iv) the latitude bias correction to assess their sensitivity. The largest sensitivity arises from the PCs used within the fitting model, particularly the number of PCs chosen to represent the atmospheric transmission. Varying the number of PC's from 10 to 6 led to a divergence of 0.47 mW m<sup>−2</sup> sr<sup>−1</sup> nm<sup>−1</sup> for GOME-2B SIF at 14 January 2017 over the Congo Basin. Combining the uncertainties from the four perturbed retrieval settings gives an illustrative value of 0.55 mW m<sup>−2</sup> sr<sup>−1</sup> nm<sup>−1</sup>. Retrieval sensitivities of comparable order are expected in other regions, including Eastern China and the Amazon. Details on these tests are provided in Sect. S5.</p>
      <p id="d2e3342">The offsets <inline-formula><mml:math id="M182" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> detected in Eastern China (<inline-formula><mml:math id="M183" display="inline"><mml:mo lspace="0mm">+</mml:mo></mml:math></inline-formula>0.13) and the Amazon (<inline-formula><mml:math id="M184" display="inline"><mml:mo lspace="0mm">-</mml:mo></mml:math></inline-formula>0.10) are smaller than the estimated systematic error of 0.55 mW m<sup>−2</sup> sr<sup>−1</sup> nm<sup>−1</sup>. This indicates that the offsets lie within the range of retrieval sensitivities, but they nevertheless represent a persistent inter-sensor difference. Additionally, the LR test confirms that the addition of an offset term enhances the model fit for these two regions (Table <xref ref-type="table" rid="T2"/>). On the other hand, the Chow test results suggest the regression parameters remain consistent over the full GOME-2 record. These results imply that, while there is confidence in a mean-level bias at <inline-formula><mml:math id="M188" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, the seasonal pattern and structure did not differ significantly before and after July 2013. Therefore, we add the found <inline-formula><mml:math id="M189" display="inline"><mml:mi mathvariant="italic">δ</mml:mi></mml:math></inline-formula> magnitudes as a correction term to the monthly regional SIF values during the GOME-2B period (from July 2013 onward) to align the records of GOME-2A and GOME-2B and support the use of both records as one consistent record. The corrected time series for Eastern China and the Amazon are shown and evaluated in Sect. <xref ref-type="sec" rid="Ch1.S5.SS2"/>. Both regions are characterised by higher atmospheric humidity. The enhanced retrieval sensitivity under such conditions may contribute to the observed intersensor difference. A full attribution of these remaining differences, however, is beyond the scope of this study and requires further investigation.</p>
      <p id="d2e3425">Finally, we verify the impact of the correction on the record's coherence by using an independent dataset as a reference. Specifically, we use FluxSat GPP data, which overlaps with the analysed period from January 2007 to December 2020 <xref ref-type="bibr" rid="bib1.bibx17" id="paren.55"/>. FluxSat GPP is a satellite-derived global product that uses geometry-adjusted, daily-scaled MODIS MCD43D reflectance data and a machine learning approach to upscale eddy-covariance flux measurements from FLUXNET 2015. Assuming that FluxSat GPP correlates with SIF similarly across both sensors, it serves as a common reference to reveal intersensor biases. Each dataset – GOME-2 SIF with/without intersensor offset correction, and FluxSat GPP – is standardised over January 2007–December 2020 to enable cross-evaluation of their temporal variability. The standardisation relates the temporal variability to the data's standard deviation. We then compare the average difference between GOME-2 SIF and FluxSat GPP before and from <inline-formula><mml:math id="M190" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (July 2013), using both uncorrected and GOME-2 SIF corrected for the detected intersensor offset. The period before <inline-formula><mml:math id="M191" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> covers January 2007 to June 2013, and the period from <inline-formula><mml:math id="M192" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> covers July 2013 to December 2020.</p>
      <p id="d2e3464">Figure <xref ref-type="fig" rid="F12"/> shows the improvement in temporal consistency between GOME-2 SIF and FluxSat GPP over Eastern China and the Amazon after applying the intersensor offset correction. Before the correction, or the alignment of GOME-2A and GOME-2B SIF, the mean difference in SIF and GPP shifts substantially around <inline-formula><mml:math id="M193" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. Since the datasets are standardised, this shift in SIF<inline-formula><mml:math id="M194" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>GPP directly reflects the divergence between GOME-2A (<inline-formula><mml:math id="M195" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, January 2007–June 2013) and GOME-2B SIF (<inline-formula><mml:math id="M196" display="inline"><mml:mo lspace="0mm">≥</mml:mo></mml:math></inline-formula>T<sub>0</sub>, July 2013–December 2020) as a fraction of the total variability over time. For example, the alignment of SIF from both sensors reduced their divergence from 27.7 % to 4.6 % of the total variability over the Amazon region – a reduction of 23.1 %. This confirms that the application of the intersensor offset correction enhanced the temporal consistency within the combined GOME-2 record. Note that remaining differences around <inline-formula><mml:math id="M198" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (July 2013) may also reflect changes in the SIF–GPP relationships due to changed environmental conditions over time.</p>

      <fig id="F12" specific-use="star"><label>Figure 12</label><caption><p id="d2e3530">Differences in standardised FluxSat GPP and standardised GOME-2 SIF over the period before <inline-formula><mml:math id="M199" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (January 2007 to June 2013) and after <inline-formula><mml:math id="M200" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (July 2013 to December 2020). Each monthly averaged dataset is standardised by subtracting its mean value (<inline-formula><mml:math id="M201" display="inline"><mml:mi mathvariant="italic">μ</mml:mi></mml:math></inline-formula>) from each value (<inline-formula><mml:math id="M202" display="inline"><mml:mrow><mml:msub><mml:mi>x</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>) and dividing it by its standard deviation (<inline-formula><mml:math id="M203" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula>); then <inline-formula><mml:math id="M204" display="inline"><mml:mrow><mml:mi>x</mml:mi><mml:mo>=</mml:mo><mml:mo>(</mml:mo><mml:msub><mml:mi>x</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>-</mml:mo><mml:mi mathvariant="italic">μ</mml:mi><mml:mo>)</mml:mo><mml:mo>/</mml:mo><mml:mi mathvariant="italic">σ</mml:mi></mml:mrow></mml:math></inline-formula>. <inline-formula><mml:math id="M205" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> represents the transition of GOME-2A to GOME-2B SIF in July 2013. The box plots on the right, plotted against a pink background, show the difference between the intersensor offset corrected GOME-2 SIF and FluxSat GPP. The black arrows indicate the difference between averaged SIF<inline-formula><mml:math id="M206" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>GPP before and after <inline-formula><mml:math id="M207" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, with the numbers indicating this difference as a percentage of total variability over the 2007–2020 period. The SIF<inline-formula><mml:math id="M208" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>GPP differences are shown over <bold>(a)</bold> Eastern China and <bold>(b)</bold> the Amazon.</p></caption>
          <graphic xlink:href="https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026-f12.png"/>

        </fig>

      <p id="d2e3658">Overall, the presented approach to detect and correct for intersensor biases seems effective in enhancing the record's coherence. The methodology shown in this section can be used as a framework to detect, assess, and correct for potential biases between GOME-2A and GOME-2B SIF time series.</p>
</sec>
<sec id="Ch1.S5.SS2">
  <label>5.2</label><title>Evaluation of GOME-2 SIF against independent datasets</title>
      <p id="d2e3669">To evaluate whether the combined GOME-2 SIF records consistently track vegetation activity, we compared them to independent satellite-based proxies for photosynthesis: FluxSat GPP <xref ref-type="bibr" rid="bib1.bibx17" id="paren.56"/> and TROPOMI SIF data obtained by <xref ref-type="bibr" rid="bib1.bibx22" id="text.57"/>. Since TROPOMI SIF data is available from early 2018, it is explicitly used for cross-evaluation against the GOME-2B SIF period. Both datasets are widely used to track inter-annual vegetation dynamics. True validation of SIF observation is restricted due to the lack of ground truth. Direct in situ validation is limited due to the mismatch in spatial resolution and the dependence of SIF values on observation time, viewing geometry, and the instrument's spectral characteristics <xref ref-type="bibr" rid="bib1.bibx27" id="paren.58"/>. Therefore, cross-comparison with established independent datasets provides the common practice <xref ref-type="bibr" rid="bib1.bibx16 bib1.bibx22 bib1.bibx21 bib1.bibx2" id="paren.59"><named-content content-type="pre">e.g.,</named-content></xref>. The correlations between GOME-2 SIF and independent data are shown in Sect. S4.</p>
      <p id="d2e3686">Figure <xref ref-type="fig" rid="F13"/> shows the regional monthly time series of GOME-2 SIF, TROPOMI SIF, and FluxSat GPP, with GOME-2 SIF corrected for intersensor offsets in Eastern China and the Amazon (Sect. <xref ref-type="sec" rid="Ch1.S5.SS1"/>). All datasets were standardised to enable comparison. Across all regions, GOME-2 SIF consistently follows the seasonal cycle of FluxSat GPP with high correlations of <inline-formula><mml:math id="M209" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>≥</mml:mo></mml:mrow></mml:math></inline-formula> 0.98 outside the Amazon and <inline-formula><mml:math id="M210" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.92</mml:mn></mml:mrow></mml:math></inline-formula> over the Amazon. The application of the intersensor offset correction showed a positive impact on these correlations with an increase from <inline-formula><mml:math id="M211" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 0.97 to <inline-formula><mml:math id="M212" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.98</mml:mn></mml:mrow></mml:math></inline-formula> over Eastern China and from <inline-formula><mml:math id="M213" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 0.91 to <inline-formula><mml:math id="M214" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> 0.92 over the Amazon (shown in Fig. S20). Although these improvements are modest, they nonetheless suggest that applying the bias correction enhances the temporal consistency.</p>

      <fig id="F13" specific-use="star"><label>Figure 13</label><caption><p id="d2e3760">Time series of standardized SIF retrieved from GOME-2 (solid blue), FluxSat GPP (dashed black) and TROPOMI SIF (dashed orange). Since the GOME-2 dataset covers the entire FluxSat GPP period, it is standardised based on the same timespan (January 2007–December 2020). This enhances the alignment of GOME-2 SIF and FluxSat GPP. The used FluxSat data reflects daily averaged GPP.</p></caption>
          <graphic xlink:href="https://essd.copernicus.org/articles/18/5643/2026/essd-18-5643-2026-f13.png"/>

        </fig>

      <p id="d2e3770">GOME-2 SIF also agreed strongly with TROPOMI SIF (January 2018 to December 2022), with <inline-formula><mml:math id="M215" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.86</mml:mn></mml:mrow></mml:math></inline-formula> over the Amazon and <inline-formula><mml:math id="M216" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>≥</mml:mo></mml:mrow></mml:math></inline-formula> 0.95 elsewhere. In Eastern China, GOME-2 SIF often reveals an early-season peak, which FluxSat GPP does not capture. This feature is also present in TROPOMI SIF (e.g., in 2022), suggesting that SIF is sensitive to subtle phenological features not reflected in reflectance-based GPP.</p>
      <p id="d2e3795">When evaluated separately, e.g. in Zambia, GOME-2A SIF generally demonstrates slightly higher correlations with FluxSat GPP (<inline-formula><mml:math id="M217" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.98</mml:mn></mml:mrow></mml:math></inline-formula>) than GOME-2B SIF (<inline-formula><mml:math id="M218" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.94</mml:mn></mml:mrow></mml:math></inline-formula>), resulting in an overall lower correlation for the combined record (<inline-formula><mml:math id="M219" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.96</mml:mn></mml:mrow></mml:math></inline-formula>). While these analyses are based on different periods and should therefore be interpreted with caution, they suggest enhanced robustness within the GOME-2A SIF record. This is consistent with larger uncertainty within GOME-2B SIF as compared to GOME-2A SIF (Fig. <xref ref-type="fig" rid="F6"/>). Nevertheless, GOME-2B SIF maintains strong correlations with both FluxSat GPP and TROPOMI SIF, indicating that the underlying signals remain sufficiently robust.</p>
      <p id="d2e3836">Overall, these results indicate that the combined GOME-2 SIF record does not exhibit temporal biases or inconsistencies, including false trends induced by instrumental artifacts. Together with the findings by <xref ref-type="bibr" rid="bib1.bibx2" id="text.60"/>, this confirms the effectiveness of the advanced degradation correction applied by SIFTER v3 to enable robust and temporally consistent SIF records from both GOME-2A and GOME-2B SIF. When small intersensor offsets are present, our framework in Sect. <xref ref-type="sec" rid="Ch1.S5.SS1"/> has proven effective in resolving these biases and enabling GOME-2A and GOME-2B to be treated as one long-term dataset for monitoring vegetation activity.</p>
</sec>
</sec>
<sec id="Ch1.S6">
  <label>6</label><title>Code and data availability</title>
      <p id="d2e3853">The GOME-2A SIF data used in this work are publicly available under data doi <ext-link xlink:href="https://doi.org/10.21944/gome2a-sifter-v3-solar-induced-fluorescence" ext-link-type="DOI">10.21944/gome2a-sifter-v3-solar-induced-fluorescence</ext-link> <xref ref-type="bibr" rid="bib1.bibx2" id="paren.61"/>. The GOME-2B SIF data obtained and used in this work can be accessed at <ext-link xlink:href="https://doi.org/10.21944/gome2b-sifter-v3-solar-induced-fluorescence" ext-link-type="DOI">10.21944/gome2b-sifter-v3-solar-induced-fluorescence</ext-link> <xref ref-type="bibr" rid="bib1.bibx3" id="paren.62"/>. The GOME-2 SIF data are provided by KNMI within the framework of the EUMETSAT Satellite Application Facility on Atmospheric Composition Monitoring (AC SAF). The code to detect and correct for intersensor offset biases within GOME-2 timeseries is available on request.</p>
</sec>
<sec id="Ch1.S7" sec-type="conclusions">
  <label>7</label><title>Conclusions and outlook</title>
      <p id="d2e3876">We presented a combined GOME-2 SIF dataset spanning from 2007 to 2023, which combines SIF observations retrieved from both GOME-2A and GOME-2B. The GOME-2A SIF record (2007–2017) was previously retrieved using the SIFTER v3 retrieval algorithm <xref ref-type="bibr" rid="bib1.bibx2" id="paren.63"/>. Here, we extended this dataset by applying the same algorithm to GOME-2B data from 2013 to 2023. SIFTER v3 incorporates an advanced correction that addresses time, wavelength, and scan-angle dependencies of reflectance degradation – resolving temporal inconsistency issues.</p>
      <p id="d2e3882">Although GOME-2A and GOME-2B are identical in sensor design, they are affected differently by instrumental artefacts. We showed that, if not properly corrected for, these differences can induce intersensor biases. During the overlapping tandem phase, seasonally averaged SIF values from both sensors agreed within 2.1 % when co-sampled across time, space, as well as viewing geometry. In contrast, failing to address differences in viewing zenith angle (VZA) sampling can introduce biases in GOME-2B SIF of up to 15 % over high SIF regions. This discrepancy mainly arises from intersensor differences in captured VZA ranges, due to the reduced swath mode of GOME-2A.</p>
      <p id="d2e3885">Statistical analysis revealed no significant step change at the transition from GOME-2A to GOME-2B in mid-2013 for most case studies; however, it detected small offsets in Eastern China and the Amazon. Applying an additive intersensor offset correction in these regions enhanced the temporal coherence of the GOME-2 record and increased its correlation with independent FluxSat GPP. In the Amazon, the correction reduced the absolute SIF <inline-formula><mml:math id="M220" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula> GPP difference across the sensor transition by more than 20 %. Finally, we demonstrated strong coherence between the GOME-2 SIF record and FluxSat GPP (<inline-formula><mml:math id="M221" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>≥</mml:mo></mml:mrow></mml:math></inline-formula> 0.92), as well as between GOME-2 SIF and TROPOMI SIF (<inline-formula><mml:math id="M222" display="inline"><mml:mrow><mml:mi>r</mml:mi><mml:mo>≥</mml:mo></mml:mrow></mml:math></inline-formula> 0.87) across regions with different biomes – supporting its use for long-term monitoring of vegetation activity. Our methodology provides a framework to detect and, when necessary, correct for intersensor-related offsets, enabling the use of GOME-2A and GOME-2B SIF as a one coherent record.</p>
      <p id="d2e3915">Beyond the use of GOME-2 SIF for long-term monitoring, this study offers practical guidance for harmonising multi-sensor datasets. First, achieving internal consistency within each record is essential before merging. Second, differences in viewing geometry sampling can substantially bias intersensor observations and should be addressed, particularly for wide-swath instruments. Finally, the presented framework could be applied to identify and correct for structural breaks in other multi-sensor records. These insights will be valuable for extending the GOME-2 record with GOME-2C observations and for preparing to combine future SIF observations from Sentinel-5 aboard the upcoming Metop Second Generation A series (Metop-SG-A) satellites, for which SIF retrievals are expected to be technically feasible.</p>
</sec>

      
      </body>
    <back><app-group>
        <supplementary-material position="anchor"><p id="d2e3918">The supplement related to this article is available online at <inline-supplementary-material xlink:href="https://doi.org/10.5194/essd-18-5643-2026-supplement" xlink:title="pdf">https://doi.org/10.5194/essd-18-5643-2026-supplement</inline-supplementary-material>.</p></supplementary-material>
        </app-group><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d2e3929">JCSA and KFB designed the study. JCSA applied the SIFTER v3 algorithm to GOME-2B observations and processed the GOME-2B SIF data, with LGT contributing to the application of the degradation correction and ONET supporting the collection of the level-1b input from EUMETSAT. JCSA performed the data analysis and generated all figures and illustrations, while KFB and LGT assisted with the interpretation of the results. The internship report by RL provided insights into the scan-angle dependency in GOME-2 SIF, which informed the design and interpretation of the analysis in this study. JCSA led the writing, and KFB contributed to the conceptualisation of the storyline and figures, providing input and revisions that improved the intellectual content of the manuscript. All authors reviewed the manuscript.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d2e3935">The contact author has declared that none of the authors has any competing interests.</p>
  </notes><notes notes-type="disclaimer"><title>Disclaimer</title>

      <p id="d2e3941">Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims made in the text, published maps, institutional affiliations, or any other geographical representation in this paper. The authors bear the ultimate responsibility for providing appropriate place names. Views expressed in the text are those of the authors and do not necessarily reflect the views of the publisher.</p>
  </notes><ack><title>Acknowledgements</title><p id="d2e3947">EUMETSAT is acknowledged for providing the GOME-2 level-1b data (both the R3 data and the NRT data that followed). We would like to thank the European Union’s Horizon 2020 Research and Innovation program under grant agreement no. 869367 (EU LANDMARC project) for providing the seed funding that facilitated the initial development of this research. We further acknowledge the use of the Caltech TROPOMI SIF data and FluxSat GPP data. We thank Mohammed Hajaldaw, whose internship report provided insights into the effect of the number of principal components on the SIF retrieval, which helped guide our systematic error sensitivity test. Finally, we thank Jos van Geffen for making the corresponding datasets publicly accessible.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d2e3952">This research has been supported by the European Organization for the Exploitation of Meteorological Satellites (grant no. ACSAF CDOP-4) and the EU Horizon 2020 (grant no. 869367).</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d2e3959">This paper was edited by Iolanda Ialongo and reviewed by two anonymous referees.</p>
  </notes><ref-list>
    <title>References</title>

      <ref id="bib1.bibx1"><label>Anema et al.(2024)Anema, Boersma, Stammes, Koren, Woodgate, Köhler, Frankenberg, and Stol</label><mixed-citation>Anema, J. C. S., Boersma, K. F., Stammes, P., Koren, G., Woodgate, W., Köhler, P., Frankenberg, C., and Stol, J.: Monitoring the impact of forest changes on carbon uptake with solar-induced fluorescence measurements from GOME-2A and TROPOMI for an Australian and Chinese case study, Biogeosciences, 21, 2297–2311, <ext-link xlink:href="https://doi.org/10.5194/bg-21-2297-2024" ext-link-type="DOI">10.5194/bg-21-2297-2024</ext-link>, 2024.</mixed-citation></ref>
      <ref id="bib1.bibx2"><label>Anema et al.(2025a)Anema, Boersma, Tilstra, and Tuinder</label><mixed-citation>Anema, J. C. S., Boersma, K. F., Tilstra, L. G., and Tuinder, O. N. E.: SIFTER Solar-Induced Vegetation Fluorescence Data from GOME-2A (Version 3.0), TEMIS [data set], <ext-link xlink:href="https://doi.org/10.21944/gome2a-sifter-v3-solar-induced-fluorescence" ext-link-type="DOI">10.21944/gome2a-sifter-v3-solar-induced-fluorescence</ext-link>, 2025a.</mixed-citation></ref>
      <ref id="bib1.bibx3"><label>Anema et al.(2025b)Anema, Boersma, Tilstra, and Tuinder</label><mixed-citation>Anema, J. C. S., Boersma, K. F., Tilstra, L. G., and Tuinder, O. N. E.: SIFTER Solar-Induced Vegetation Fluorescence Data from GOME-2B (Version 3.0),  TEMIS [data set], <ext-link xlink:href="https://doi.org/10.21944/gome2b-sifter-v3-solar-induced-fluorescence" ext-link-type="DOI">10.21944/gome2b-sifter-v3-solar-induced-fluorescence</ext-link>, 2025b.</mixed-citation></ref>
      <ref id="bib1.bibx4"><label>Anema et al.(2025c)Anema, Boersma, Tilstra, Tuinder, and Verstraeten</label><mixed-citation>Anema, J. C. S., Boersma, K. F., Tilstra, L. G., Tuinder, O. N. E., and Verstraeten, W. W.: Improved consistency in solar-induced fluorescence retrievals from GOME-2A with the SIFTER v3 algorithm, Atmos. Meas. Tech., 18, 1961–1979, <ext-link xlink:href="https://doi.org/10.5194/amt-18-1961-2025" ext-link-type="DOI">10.5194/amt-18-1961-2025</ext-link>, 2025c.</mixed-citation></ref>
      <ref id="bib1.bibx5"><label>Chen et al.(2021)Chen, Huang, and Wang</label><mixed-citation>Chen, S., Huang, Y., and Wang, G.: Detecting Drought-Induced GPP Spatiotemporal Variabilities with Sun-Induced Chlorophyll Fluorescence during the 2009/2010 Droughts in China, Ecol. Indic., 121, 107092, <ext-link xlink:href="https://doi.org/10.1016/j.ecolind.2020.107092" ext-link-type="DOI">10.1016/j.ecolind.2020.107092</ext-link>, 2021.</mixed-citation></ref>
      <ref id="bib1.bibx6"><label>Dechant et al.(2020)Dechant, Ryu, Badgley, Zeng, Berry, Zhang, Goulas, Li, Zhang, Kang, Li, and Moya</label><mixed-citation>Dechant, B., Ryu, Y., Badgley, G., Zeng, Y., Berry, J. A., Zhang, Y., Goulas, Y., Li, Z., Zhang, Q., Kang, M., Li, J., and Moya, I.: Canopy structure explains the relationship between photosynthesis and sun-induced chlorophyll fluorescence in crops, Remote Sens. Environ.,  241, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2020.111733" ext-link-type="DOI">10.1016/j.rse.2020.111733</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bibx7"><label>Doughty et al.(2022)Doughty, Kurosu, Parazoo, Köhler, Wang, Sun, and Frankenberg</label><mixed-citation>Doughty, R., Kurosu, T. P., Parazoo, N., Köhler, P., Wang, Y., Sun, Y., and Frankenberg, C.: Global GOSAT, OCO-2, and OCO-3 solar-induced chlorophyll fluorescence datasets, Earth Syst. Sci. Data, 14, 1513–1529, <ext-link xlink:href="https://doi.org/10.5194/essd-14-1513-2022" ext-link-type="DOI">10.5194/essd-14-1513-2022</ext-link>, 2022.</mixed-citation></ref>
      <ref id="bib1.bibx8"><label>EUMETSAT(2022)</label><mixed-citation>EUMETSAT: GOME-2 Metop-A and -B FDR Product Validation Report Reprocessing R3, EUM/OPS/DOC/21/1237264,  <uri>https://user.eumetsat.int/s3/eup-strapi-media/GOME_2_Metop_A_and_B_FDR_Product_Validation_Report_Reprocessing_R3_8a6a49db6c.pdf</uri> (last access: 21 May 2025), 2022.</mixed-citation></ref>
      <ref id="bib1.bibx9"><label>Fancourt et al.(2022)Fancourt, Ziv, Boersma, Tavares, Wang, and Galbraith</label><mixed-citation>Fancourt, M., Ziv, G., Boersma, K. F., Tavares, J., Wang, Y., and Galbraith, D.: Background Climate Conditions Regulated the Photosynthetic Response of Amazon Forests to the 2015/2016 El Nino-Southern Oscillation Event, Communications Earth &amp; Environment, 3, 209, <ext-link xlink:href="https://doi.org/10.1038/s43247-022-00533-3" ext-link-type="DOI">10.1038/s43247-022-00533-3</ext-link>, 2022.</mixed-citation></ref>
      <ref id="bib1.bibx10"><label>Gerlein-Safdi et al.(2020)Gerlein-Safdi, Keppel-Aleks, Wang, Frolking, and Mauzerall</label><mixed-citation>Gerlein-Safdi, C., Keppel-Aleks, G., Wang, F., Frolking, S., and Mauzerall, D. L.: Satellite Monitoring of Natural Reforestation Efforts in China's Drylands, One Earth, 2, 98–108, <ext-link xlink:href="https://doi.org/10.1016/j.oneear.2019.12.015" ext-link-type="DOI">10.1016/j.oneear.2019.12.015</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bibx11"><label>Grossi et al.(2015)Grossi, Valks, Loyola, Aberle, Slijkhuis, Wagner, Beirle, and Lang</label><mixed-citation>Grossi, M., Valks, P., Loyola, D., Aberle, B., Slijkhuis, S., Wagner, T., Beirle, S., and Lang, R.: Total column water vapour measurements from GOME-2 MetOp-A and MetOp-B, Atmos. Meas. Tech., 8, 1111–1133, <ext-link xlink:href="https://doi.org/10.5194/amt-8-1111-2015" ext-link-type="DOI">10.5194/amt-8-1111-2015</ext-link>, 2015.</mixed-citation></ref>
      <ref id="bib1.bibx12"><label>Guanter et al.(2021)Guanter, Bacour, Schneider, Aben, van Kempen, Maignan, Retscher, Köhler, Frankenberg, Joiner, and Zhang</label><mixed-citation>Guanter, L., Bacour, C., Schneider, A., Aben, I., van Kempen, T. A., Maignan, F., Retscher, C., Köhler, P., Frankenberg, C., Joiner, J., and Zhang, Y.: The TROPOSIF global sun-induced fluorescence dataset from the Sentinel-5P TROPOMI mission, Earth Syst. Sci. Data, 13, 5423–5440, <ext-link xlink:href="https://doi.org/10.5194/essd-13-5423-2021" ext-link-type="DOI">10.5194/essd-13-5423-2021</ext-link>, 2021.</mixed-citation></ref>
      <ref id="bib1.bibx13"><label>Jacob et al.(2016)Jacob, Turner, Maasakkers, Sheng, Sun, Liu, Chance, Aben, McKeever, and Frankenberg</label><mixed-citation>Jacob, D. J., Turner, A. J., Maasakkers, J. D., Sheng, J., Sun, K., Liu, X., Chance, K., Aben, I., McKeever, J., and Frankenberg, C.: Satellite observations of atmospheric methane and their value for quantifying methane emissions, Atmos. Chem. Phys., 16, 14371–14396, <ext-link xlink:href="https://doi.org/10.5194/acp-16-14371-2016" ext-link-type="DOI">10.5194/acp-16-14371-2016</ext-link>, 2016.</mixed-citation></ref>
      <ref id="bib1.bibx14"><label>Joiner et al.(2012)Joiner, Yoshida, Vasilkov, Middleton, Campbell, Yoshida, Kuze, and Corp</label><mixed-citation>Joiner, J., Yoshida, Y., Vasilkov, A. P., Middleton, E. M., Campbell, P. K. E., Yoshida, Y., Kuze, A., and Corp, L. A.: Filling-in of near-infrared solar lines by terrestrial fluorescence and other geophysical effects: simulations and space-based observations from SCIAMACHY and GOSAT, Atmos. Meas. Tech., 5, 809–829, <ext-link xlink:href="https://doi.org/10.5194/amt-5-809-2012" ext-link-type="DOI">10.5194/amt-5-809-2012</ext-link>, 2012.</mixed-citation></ref>
      <ref id="bib1.bibx15"><label>Joiner et al.(2013)Joiner, Guanter, Lindstrot, Voigt, Vasilkov, Middleton, Huemmrich, Yoshida, and Frankenberg</label><mixed-citation>Joiner, J., Guanter, L., Lindstrot, R., Voigt, M., Vasilkov, A. P., Middleton, E. M., Huemmrich, K. F., Yoshida, Y., and Frankenberg, C.: Global monitoring of terrestrial chlorophyll fluorescence from moderate-spectral-resolution near-infrared satellite measurements: methodology, simulations, and application to GOME-2, Atmos. Meas. Tech., 6, 2803–2823, <ext-link xlink:href="https://doi.org/10.5194/amt-6-2803-2013" ext-link-type="DOI">10.5194/amt-6-2803-2013</ext-link>, 2013.</mixed-citation></ref>
      <ref id="bib1.bibx16"><label>Joiner et al.(2016)Joiner, Yoshida, Guanter, and Middleton</label><mixed-citation>Joiner, J., Yoshida, Y., Guanter, L., and Middleton, E. M.: New methods for the retrieval of chlorophyll red fluorescence from hyperspectral satellite instruments: simulations and application to GOME-2 and SCIAMACHY, Atmos. Meas. Tech., 9, 3939–3967, <ext-link xlink:href="https://doi.org/10.5194/amt-9-3939-2016" ext-link-type="DOI">10.5194/amt-9-3939-2016</ext-link>, 2016.</mixed-citation></ref>
      <ref id="bib1.bibx17"><label>Joiner et al.(2018)Joiner, Yoshida, Zhang, Duveiller, Jung, Lyapustin, Wang, and Tucker</label><mixed-citation>Joiner, J., Yoshida, Y., Zhang, Y., Duveiller, G., Jung, M., Lyapustin, A., Wang, Y., and Tucker, C. J.: Estimation of Terrestrial Global Gross Primary Production (GPP) with Satellite Data-Driven Models and Eddy Covariance Flux Data, Remote Sens., 10, 1346, <ext-link xlink:href="https://doi.org/10.3390/rs10091346" ext-link-type="DOI">10.3390/rs10091346</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bibx18"><label>Joiner et al.(2020)Joiner, Yoshida, Köehler, Campbell, Frankenberg, van der Tol, Yang, Parazoo, Guanter, and Sun</label><mixed-citation>Joiner, J., Yoshida, Y., Köehler, P., Campbell, P., Frankenberg, C., van der Tol, C., Yang, P., Parazoo, N., Guanter, L., and Sun, Y.: Systematic Orbital Geometry-Dependent Variations in Satellite Solar-Induced Fluorescence (SIF) Retrievals, Remote Sens., 12, 2346, <ext-link xlink:href="https://doi.org/10.3390/rs12152346" ext-link-type="DOI">10.3390/rs12152346</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bibx19"><label>Khosravi et al.(2015)Khosravi, Vountas, Rozanov, Bracher, Wolanin, and Burrows</label><mixed-citation>Khosravi, N., Vountas, M., Rozanov, V. V., Bracher, A., Wolanin, A., and Burrows, J. P.: Retrieval of Terrestrial Plant Fluorescence Based on the In-Filling of Far-Red Fraunhofer Lines Using SCIAMACHY Observations, Frontiers in Environmental Science, 3, <ext-link xlink:href="https://doi.org/10.3389/fenvs.2015.00078" ext-link-type="DOI">10.3389/fenvs.2015.00078</ext-link>, 2015.</mixed-citation></ref>
      <ref id="bib1.bibx20"><label>Klaes et al.(2007)Klaes, Schlussel, Munro, Luntama, Engeln, Ackermann, and Schmetz</label><mixed-citation>Klaes, K. D., Schlussel, P., Munro, R., Luntama, J.-P., Engeln, A. V., Ackermann, J., and Schmetz, J.: An Introduction to the EUMETSAT Polar System, B. Am. Meteorol. Soc., <ext-link xlink:href="https://doi.org/10.1175/BAMS-88-7-1085" ext-link-type="DOI">10.1175/BAMS-88-7-1085</ext-link>, 1085–1096, 2007.</mixed-citation></ref>
      <ref id="bib1.bibx21"><label>Köhler et al.(2015)Köhler, Guanter, and Joiner</label><mixed-citation>Köhler, P., Guanter, L., and Joiner, J.: A linear method for the retrieval of sun-induced chlorophyll fluorescence from GOME-2 and SCIAMACHY data, Atmos. Meas. Tech., 8, 2589–2608, <ext-link xlink:href="https://doi.org/10.5194/amt-8-2589-2015" ext-link-type="DOI">10.5194/amt-8-2589-2015</ext-link>, 2015.</mixed-citation></ref>
      <ref id="bib1.bibx22"><label>Köhler et al.(2018)Köhler, Frankenberg, Magney, Guanter, Joiner, and Landgraf</label><mixed-citation>Köhler, P., Frankenberg, C., Magney, T. S., Guanter, L., Joiner, J., and Landgraf, J.: Global Retrievals of Solar-Induced Chlorophyll Fluorescence With TROPOMI: First Results and Intersensor Comparison to OCO-2, Geophys. Res. Lett., 45, 10456–10463, <ext-link xlink:href="https://doi.org/10.1029/2018GL079031" ext-link-type="DOI">10.1029/2018GL079031</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bibx23"><label>Koren et al.(2018)Koren, Van Schaik, Araújo, Boersma, Gärtner, Killaars, Kooreman, Kruijt, Van Der Laan-Luijkx, Von Randow, Smith, and Peters</label><mixed-citation>Koren, G., Van Schaik, E., Araújo, A. C., Boersma, K. F., Gärtner, A., Killaars, L., Kooreman, M. L., Kruijt, B., Van Der Laan-Luijkx, I. T., Von Randow, C., Smith, N. E., and Peters, W.: Widespread Reduction in Sun-Induced Fluorescence from the Amazon during the 2015/2016 El Niño, Philos. T. R. Soc. B, 373, 20170408, <ext-link xlink:href="https://doi.org/10.1098/rstb.2017.0408" ext-link-type="DOI">10.1098/rstb.2017.0408</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bibx24"><label>Li et al.(2018)Li, Ma, Wu, and Yang</label><mixed-citation>Li, Q., Ma, M., Wu, X., and Yang, H.: Snow Cover and Vegetation-Induced Decrease in Global Albedo From 2002 to 2016, J. Geophys. Res.-Atmos., 123, 124–138, <ext-link xlink:href="https://doi.org/10.1002/2017JD027010" ext-link-type="DOI">10.1002/2017JD027010</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bibx25"><label>Liu et al.(2021)Liu, You, Zhang, Chen, Zhang, Li, and Wu</label><mixed-citation>Liu, Y., You, C., Zhang, Y., Chen, S., Zhang, Z., Li, J., and Wu, Y.: Resistance and Resilience of Grasslands to Drought Detected by SIF in Inner Mongolia, China, Agr. Forest Meteorol., 308–309, 108567, <ext-link xlink:href="https://doi.org/10.1016/j.agrformet.2021.108567" ext-link-type="DOI">10.1016/j.agrformet.2021.108567</ext-link>, 2021.</mixed-citation></ref>
      <ref id="bib1.bibx26"><label>Magney et al.(2019)Magney, Bowling, Logan, Grossmann, Stutz, Blanken, Burns, Cheng, Garcia, Köhler, Lopez, Parazoo, Raczka, Schimel, and Frankenberg</label><mixed-citation>Magney, T. S., Bowling, D. R., Logan, B. A., Grossmann, K., Stutz, J., Blanken, P. D., Burns, S. P., Cheng, R., Garcia, M. A., Köhler, P., Lopez, S., Parazoo, N. C., Raczka, B., Schimel, D., and Frankenberg, C.: Mechanistic Evidence for Tracking the Seasonality of Photosynthesis with Solar-Induced Fluorescence, P. Natl. Acad. Sci. USA, 116, 11640–11645, <ext-link xlink:href="https://doi.org/10.1073/pnas.1900278116" ext-link-type="DOI">10.1073/pnas.1900278116</ext-link>, 2019.</mixed-citation></ref>
      <ref id="bib1.bibx27"><label>Mohammed et al.(2019)Mohammed, Colombo, Middleton, Rascher, Van Der Tol, Nedbal, Goulas, Pérez-Priego, Damm, Meroni, Joiner, Cogliati, Verhoef, Malenovský, Gastellu-Etchegorry, Miller, Guanter, Moreno, Moya, Berry, Frankenberg, and Zarco-Tejada</label><mixed-citation>Mohammed, G. H., Colombo, R., Middleton, E. M., Rascher, U., Van Der Tol, C., Nedbal, L., Goulas, Y., Pérez-Priego, O., Damm, A., Meroni, M., Joiner, J., Cogliati, S., Verhoef, W., Malenovský, Z., Gastellu-Etchegorry, J.-P., Miller, J. R., Guanter, L., Moreno, J., Moya, I., Berry, J. A., Frankenberg, C., and Zarco-Tejada, P. J.: Remote Sensing of Solar-Induced Chlorophyll Fluorescence (SIF) in Vegetation: 50 Years of Progress, Remote Sens. Environ., 231, 111177, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2019.04.030" ext-link-type="DOI">10.1016/j.rse.2019.04.030</ext-link>, 2019.</mixed-citation></ref>
      <ref id="bib1.bibx28"><label>Munro et al.(2016)Munro, Lang, Klaes, Poli, Retscher, Lindstrot, Huckle, Lacan, Grzegorski, Holdak, Kokhanovsky, Livschitz, and Eisinger</label><mixed-citation>Munro, R., Lang, R., Klaes, D., Poli, G., Retscher, C., Lindstrot, R., Huckle, R., Lacan, A., Grzegorski, M., Holdak, A., Kokhanovsky, A., Livschitz, J., and Eisinger, M.: The GOME-2 instrument on the Metop series of satellites: instrument design, calibration, and level 1 data processing – an overview, Atmos. Meas. Tech., 9, 1279–1301, <ext-link xlink:href="https://doi.org/10.5194/amt-9-1279-2016" ext-link-type="DOI">10.5194/amt-9-1279-2016</ext-link>, 2016.</mixed-citation></ref>
      <ref id="bib1.bibx29"><label>Noël et al.(2024)Noël, Buchwitz, Hilker, Reuter, Weimer, Bovensmann, Burrows, Bösch, and Lang</label><mixed-citation>Noël, S., Buchwitz, M., Hilker, M., Reuter, M., Weimer, M., Bovensmann, H., Burrows, J. P., Bösch, H., and Lang, R.: Greenhouse gas retrievals for the CO2M mission using the FOCAL method: first performance estimates, Atmos. Meas. Tech., 17, 2317–2334, <ext-link xlink:href="https://doi.org/10.5194/amt-17-2317-2024" ext-link-type="DOI">10.5194/amt-17-2317-2024</ext-link>, 2024.</mixed-citation></ref>
      <ref id="bib1.bibx30"><label>Parazoo et al.(2019)Parazoo, Frankenberg, Köhler, Joiner, Yoshida, Magney, Sun, and Yadav</label><mixed-citation>Parazoo, N. C., Frankenberg, C., Köhler, P., Joiner, J., Yoshida, Y., Magney, T., Sun, Y., and Yadav, V.: Towards a Harmonized Long-Term Spaceborne Record of Far-Red Solar-Induced Fluorescence, J. Geophys. Res.-Biogeo., 124, 2518–2539, <ext-link xlink:href="https://doi.org/10.1029/2019JG005289" ext-link-type="DOI">10.1029/2019JG005289</ext-link>, 2019.</mixed-citation></ref>
      <ref id="bib1.bibx31"><label>Peltoniemi et al.(2005)Peltoniemi, Kaasalainen, Näränen, Rautiainen, Stenberg, Smolander, Smolander, and Voipio</label><mixed-citation>Peltoniemi, J. I., Kaasalainen, S., Näränen, J., Rautiainen, M., Stenberg, P., Smolander, H., Smolander, S., and Voipio, P.: BRDF Measurement of Understory Vegetation in Pine Forests: Dwarf Shrubs, Lichen, and Moss, Remote Sens. Environ., 94, 343–354, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2004.10.009" ext-link-type="DOI">10.1016/j.rse.2004.10.009</ext-link>, 2005.</mixed-citation></ref>
      <ref id="bib1.bibx32"><label>Sanghavi et al.(2025)Sanghavi, Frankenberg, Nelson, O'Dell, Rosenberg, and Joiner</label><mixed-citation>Sanghavi, S., Frankenberg, C., Nelson, R. R., O'Dell, C. W., Rosenberg, R., and Joiner, J.: Impact of Raman Scattering on SIF Retrievals From Hyperspectral Satellite Observations, Geophys. Res. Lett., 52, e2024GL112777, <ext-link xlink:href="https://doi.org/10.1029/2024GL112777" ext-link-type="DOI">10.1029/2024GL112777</ext-link>, 2025.</mixed-citation></ref>
      <ref id="bib1.bibx33"><label>Sun et al.(2018)Sun, Frankenberg, Jung, Joiner, Guanter, Köhler, and Magney</label><mixed-citation>Sun, Y., Frankenberg, C., Jung, M., Joiner, J., Guanter, L., Köhler, P., and Magney, T.: Overview of Solar-Induced Chlorophyll Fluorescence (SIF) from the Orbiting Carbon Observatory-2: Retrieval, Cross-Mission Comparison, and Global Monitoring for GPP, Remote Sens. Environ., 209, 808–823, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2018.02.016" ext-link-type="DOI">10.1016/j.rse.2018.02.016</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bibx34"><label>Sun et al.(2023)Sun, Gu, Wen, van der Tol, Porcar-Castell, Joiner, Chang, Magney, Wang, Hu, Rascher, Zarco-Tejada, Barrett, Lai, Han, and Luo</label><mixed-citation>Sun, Y., Gu, L., Wen, J., van der Tol, C., Porcar-Castell, A., Joiner, J., Chang, C. Y., Magney, T., Wang, L., Hu, L., Rascher, U., Zarco-Tejada, P., Barrett, C. B., Lai, J., Han, J., and Luo, Z.: From Remotely Sensed Solar-induced Chlorophyll Fluorescence to Ecosystem Structure, Function, and Service: Part I – Harnessing Theory, Glob. Change Biol., 29, 2926–2952, <ext-link xlink:href="https://doi.org/10.1111/gcb.16634" ext-link-type="DOI">10.1111/gcb.16634</ext-link>, 2023.</mixed-citation></ref>
      <ref id="bib1.bibx35"><label>Tilstra et al.(2012)Tilstra, Tuinder, and Stammes</label><mixed-citation>Tilstra, L. G., Tuinder, O. N. E., and Stammes, P.: A New Method for In-Flight Degradation Correction of GOME-2 Earth Reflectance Measurements, with Application to the Absorbing Aerosol Index, Proceedings of the 2012 EUMETSAT Meteorological Satellite Conference,  <uri>https://www-cdn.eumetsat.int/files/2020-04/pdf_conf_p61_s3_03_tilstra_p.pdf</uri> (last access: 19 October 2024), 2012.</mixed-citation></ref>
      <ref id="bib1.bibx36"><label>Turner et al.(2021)Turner, Köhler, Magney, Frankenberg, Fung, and Cohen</label><mixed-citation>Turner, A. J., Köhler, P., Magney, T. S., Frankenberg, C., Fung, I., and Cohen, R. C.: Extreme events driving year-to-year differences in gross primary productivity across the US, Biogeosciences, 18, 6579–6588, <ext-link xlink:href="https://doi.org/10.5194/bg-18-6579-2021" ext-link-type="DOI">10.5194/bg-18-6579-2021</ext-link>, 2021.</mixed-citation></ref>
      <ref id="bib1.bibx37"><label>van der A et al.(2006)van der A, Peters, Eskes, Boersma, van Roozendael, De Smedt, and Kelder</label><mixed-citation>van der A, R. J., Peters, D. H. M. U., Eskes, H., Boersma, K. F., van Roozendael, M., De Smedt, I., and Kelder, H. M.: Detection of the Trend and Seasonal Variation in Tropospheric NO<sub>2</sub> over China, J. Geophys. Res.-Atmos., 111, 2005JD006594, <ext-link xlink:href="https://doi.org/10.1029/2005JD006594" ext-link-type="DOI">10.1029/2005JD006594</ext-link>, 2006.</mixed-citation></ref>
      <ref id="bib1.bibx38"><label>van Schaik et al.(2020)van Schaik, Kooreman, Stammes, Tilstra, Tuinder, Sanders, Verstraeten, Lang, Cacciari, Joiner, Peters, and Boersma</label><mixed-citation>van Schaik, E., Kooreman, M. L., Stammes, P., Tilstra, L. G., Tuinder, O. N. E., Sanders, A. F. J., Verstraeten, W. W., Lang, R., Cacciari, A., Joiner, J., Peters, W., and Boersma, K. F.: Improved SIFTER v2 algorithm for long-term GOME-2A satellite retrievals of fluorescence with a correction for instrument degradation, Atmos. Meas. Tech., 13, 4295–4315, <ext-link xlink:href="https://doi.org/10.5194/amt-13-4295-2020" ext-link-type="DOI">10.5194/amt-13-4295-2020</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bibx39"><label>van Wittenberghe et al.(2015)van Wittenberghe, Alonso, Verrelst, Moreno, and Samson</label><mixed-citation>van Wittenberghe, S., Alonso, L., Verrelst, J., Moreno, J., and Samson, R.: Bidirectional Sun-Induced Chlorophyll Fluorescence Emission Is Influenced by Leaf Structure and Light Scattering Properties – A Bottom-up Approach, Remote Sens. Environ., 158, 169–179, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2014.11.012" ext-link-type="DOI">10.1016/j.rse.2014.11.012</ext-link>, 2015.</mixed-citation></ref>
      <ref id="bib1.bibx40"><label>Vicent et al.(2016)Vicent, Sabater, Tenjo, Acarreta, Manzano, Rivera, Jurado, Franco, Alonso, Verrelst, and Moreno</label><mixed-citation>Vicent, J., Sabater, N., Tenjo, C., Acarreta, J. R., Manzano, M., Rivera, J. P., Jurado, P., Franco, R., Alonso, L., Verrelst, J., and Moreno, J.: FLEX End-to-End Mission Performance Simulator, IEEE T. Geosci. Remote, 54, 4215–4223, <ext-link xlink:href="https://doi.org/10.1109/TGRS.2016.2538300" ext-link-type="DOI">10.1109/TGRS.2016.2538300</ext-link>, 2016.</mixed-citation></ref>
      <ref id="bib1.bibx41"><label>Wang et al.(2019)Wang, Beringer, Hutley, Cleverly, Li, Liu, and Sun</label><mixed-citation>Wang, C., Beringer, J., Hutley, L. B., Cleverly, J., Li, J., Liu, Q., and Sun, Y.: Phenology Dynamics of Dryland Ecosystems Along the North Australian Tropical Transect Revealed by Satellite Solar-Induced Chlorophyll Fluorescence, Geophys. Res. Lett., 46, 5294–5302, <ext-link xlink:href="https://doi.org/10.1029/2019GL082716" ext-link-type="DOI">10.1029/2019GL082716</ext-link>, 2019.</mixed-citation></ref>
      <ref id="bib1.bibx42"><label>Wang and Stammes(2008)</label><mixed-citation>Wang, P., Stammes, P., van der A, R., Pinardi, G., and van Roozendael, M.: FRESCO<inline-formula><mml:math id="M224" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>: an improved O<sub>2</sub> A-band cloud retrieval algorithm for tropospheric trace gas retrievals, Atmos. Chem. Phys., 8, 6565–6576, <ext-link xlink:href="https://doi.org/10.5194/acp-8-6565-2008" ext-link-type="DOI">10.5194/acp-8-6565-2008</ext-link>, 2008.</mixed-citation></ref>
      <ref id="bib1.bibx43"><label>Wang et al.(2022)Wang, Zhang, Ju, Wu, Liu, He, and Peñuelas</label><mixed-citation>Wang, S., Zhang, Y., Ju, W., Wu, M., Liu, L., He, W., and Peñuelas, J.: Temporally Corrected Long-Term Satellite Solar-Induced Fluorescence Leads to Improved Estimation of Global Trends in Vegetation Photosynthesis during 1995–2018, ISPRS J. Photogramm., 194, 222–234, <ext-link xlink:href="https://doi.org/10.1016/j.isprsjprs.2022.10.018" ext-link-type="DOI">10.1016/j.isprsjprs.2022.10.018</ext-link>, 2022.</mixed-citation></ref>
      <ref id="bib1.bibx44"><label>Weatherhead et al.(1998)Weatherhead, Reinsel, Tiao, Meng, Choi, Cheang, Keller, DeLuisi, Wuebbles, Kerr, Miller, Oltmans, and Frederick</label><mixed-citation>Weatherhead, E. C., Reinsel, G. C., Tiao, G. C., Meng, X.-L., Choi, D., Cheang, W.-K., Keller, T., DeLuisi, J., Wuebbles, D. J., Kerr, J. B., Miller, A. J., Oltmans, S. J., and Frederick, J. E.: Factors Affecting the Detection of Trends: Statistical Considerations and Applications to Environmental Data, J. Geophys. Res.-Atmos., 103, 17149–17161, <ext-link xlink:href="https://doi.org/10.1029/98JD00995" ext-link-type="DOI">10.1029/98JD00995</ext-link>, 1998.</mixed-citation></ref>
      <ref id="bib1.bibx45"><label>Wen et al.(2020)Wen, Köhler, Duveiller, Parazoo, Magney, Hooker, Yu, Chang, and Sun</label><mixed-citation>Wen, J., Köhler, P., Duveiller, G., Parazoo, N., Magney, T., Hooker, G., Yu, L., Chang, C., and Sun, Y.: A Framework for Harmonizing Multiple Satellite Instruments to Generate a Long-Term Global High Spatial-Resolution Solar-Induced Chlorophyll Fluorescence (SIF), Remote Sens. Environ., 239, 111644, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2020.111644" ext-link-type="DOI">10.1016/j.rse.2020.111644</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bibx46"><label>Yang and van der Tol(2018)</label><mixed-citation>Yang, P. and van der Tol, C.: Linking Canopy Scattering of Far-Red Sun-Induced Chlorophyll Fluorescence with Reflectance, Remote Sens. Environ., 209, 456–467, <ext-link xlink:href="https://doi.org/10.1016/j.rse.2018.02.029" ext-link-type="DOI">10.1016/j.rse.2018.02.029</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bibx47"><label>Zhang et al.(2022)Zhang, Xiao, Tong, Zhang, Meng, Li, Liu, and Yu</label><mixed-citation>Zhang, J., Xiao, J., Tong, X., Zhang, J., Meng, P., Li, J., Liu, P., and Yu, P.: NIRv and SIF Better Estimate Phenology than NDVI and EVI: Effects of Spring and Autumn Phenology on Ecosystem Production of Planted Forests, Agr. Forest Meteorol., 315, 108819, <ext-link xlink:href="https://doi.org/10.1016/j.agrformet.2022.108819" ext-link-type="DOI">10.1016/j.agrformet.2022.108819</ext-link>, 2022. </mixed-citation></ref>
      <ref id="bib1.bibx48"><label>Zhang et al.(2018)Zhang, Joiner, Gentine, and Zhou</label><mixed-citation>Zhang, Y., Joiner, J., Gentine, P., and Zhou, S.: Reduced Solar-induced Chlorophyll Fluorescence from GOME-2 during Amazon Drought Caused by Dataset Artifacts, Glob. Change Biol., 24, 2229–2230, <ext-link xlink:href="https://doi.org/10.1111/gcb.14134" ext-link-type="DOI">10.1111/gcb.14134</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bibx49"><label>Zhang et al.(2023)Zhang, Fang, Smith, Wang, Gentine, Scott, Migliavacca, Jeong, Litvak, and Zhou</label><mixed-citation>Zhang, Y., Fang, J., Smith, W. K., Wang, X., Gentine, P., Scott, R. L., Migliavacca, M., Jeong, S., Litvak, M., and Zhou, S.: Satellite Solar-induced Chlorophyll Fluorescence Tracks Physiological Drought Stress Development during 2020 Southwest US Drought, Glob. Change Biol., 29, 3395–3408, <ext-link xlink:href="https://doi.org/10.1111/gcb.16683" ext-link-type="DOI">10.1111/gcb.16683</ext-link>, 2023.</mixed-citation></ref>
      <ref id="bib1.bibx50"><label>Zou et al.(2024)Zou, Du, Liu, and Liu</label><mixed-citation>Zou, C., Du, S., Liu, X., and Liu, L.: TCSIF: a temporally consistent global Global Ozone Monitoring Experiment-2A (GOME-2A) solar-induced chlorophyll fluorescence dataset with the correction of sensor degradation, Earth Syst. Sci. Data, 16, 2789–2809, <ext-link xlink:href="https://doi.org/10.5194/essd-16-2789-2024" ext-link-type="DOI">10.5194/essd-16-2789-2024</ext-link>, 2024.</mixed-citation></ref>

  </ref-list></back>
    <!--<article-title-html>Long-term solar-induced fluorescence data record from GOME-2A and GOME-2B (2007–2023) using the SIFTER v3 algorithm</article-title-html>
<abstract-html/>
<ref-html id="bib1.bib1"><label>Anema et al.(2024)Anema, Boersma, Stammes, Koren, Woodgate,
Köhler, Frankenberg, and Stol</label><mixed-citation>
      
Anema, J. C. S., Boersma, K. F., Stammes, P., Koren, G., Woodgate, W., Köhler, P., Frankenberg, C., and Stol, J.: Monitoring the impact of forest changes on carbon uptake with solar-induced fluorescence measurements from GOME-2A and TROPOMI for an Australian and Chinese case study, Biogeosciences, 21, 2297–2311, <a href="https://doi.org/10.5194/bg-21-2297-2024" target="_blank">https://doi.org/10.5194/bg-21-2297-2024</a>, 2024.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib2"><label>Anema et al.(2025a)Anema, Boersma, Tilstra, and
Tuinder</label><mixed-citation>
      
Anema, J. C. S., Boersma, K. F., Tilstra, L. G., and Tuinder, O. N. E.:
SIFTER Solar-Induced Vegetation Fluorescence Data from GOME-2A
(Version 3.0),
TEMIS [data set], <a href="https://doi.org/10.21944/gome2a-sifter-v3-solar-induced-fluorescence" target="_blank">https://doi.org/10.21944/gome2a-sifter-v3-solar-induced-fluorescence</a>,
2025a.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib3"><label>Anema et al.(2025b)Anema, Boersma, Tilstra, and
Tuinder</label><mixed-citation>
      
Anema, J. C. S., Boersma, K. F., Tilstra, L. G., and Tuinder, O. N. E.:
SIFTER Solar-Induced Vegetation Fluorescence Data from GOME-2B
(Version 3.0),  TEMIS [data set],
<a href="https://doi.org/10.21944/gome2b-sifter-v3-solar-induced-fluorescence" target="_blank">https://doi.org/10.21944/gome2b-sifter-v3-solar-induced-fluorescence</a>,
2025b.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib4"><label>Anema et al.(2025c)Anema, Boersma, Tilstra, Tuinder, and
Verstraeten</label><mixed-citation>
      
Anema, J. C. S., Boersma, K. F., Tilstra, L. G., Tuinder, O. N. E., and Verstraeten, W. W.: Improved consistency in solar-induced fluorescence retrievals from GOME-2A with the SIFTER v3 algorithm, Atmos. Meas. Tech., 18, 1961–1979, <a href="https://doi.org/10.5194/amt-18-1961-2025" target="_blank">https://doi.org/10.5194/amt-18-1961-2025</a>, 2025c.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib5"><label>Chen et al.(2021)Chen, Huang, and Wang</label><mixed-citation>
      
Chen, S., Huang, Y., and Wang, G.: Detecting Drought-Induced GPP
Spatiotemporal Variabilities with Sun-Induced Chlorophyll Fluorescence during
the 2009/2010 Droughts in China, Ecol. Indic., 121, 107092,
<a href="https://doi.org/10.1016/j.ecolind.2020.107092" target="_blank">https://doi.org/10.1016/j.ecolind.2020.107092</a>, 2021.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib6"><label>Dechant et al.(2020)Dechant, Ryu, Badgley, Zeng, Berry, Zhang,
Goulas, Li, Zhang, Kang, Li, and Moya</label><mixed-citation>
      
Dechant, B., Ryu, Y., Badgley, G., Zeng, Y., Berry, J. A., Zhang, Y., Goulas,
Y., Li, Z., Zhang, Q., Kang, M., Li, J., and Moya, I.: Canopy structure explains the relationship between photosynthesis and sun-induced chlorophyll fluorescence in crops, Remote Sens. Environ.,  241, <a href="https://doi.org/10.1016/j.rse.2020.111733" target="_blank">https://doi.org/10.1016/j.rse.2020.111733</a>, 2020.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib7"><label>Doughty et al.(2022)Doughty, Kurosu, Parazoo, Köhler, Wang, Sun,
and Frankenberg</label><mixed-citation>
      
Doughty, R., Kurosu, T. P., Parazoo, N., Köhler, P., Wang, Y., Sun, Y., and Frankenberg, C.: Global GOSAT, OCO-2, and OCO-3 solar-induced chlorophyll fluorescence datasets, Earth Syst. Sci. Data, 14, 1513–1529, <a href="https://doi.org/10.5194/essd-14-1513-2022" target="_blank">https://doi.org/10.5194/essd-14-1513-2022</a>, 2022.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib8"><label>EUMETSAT(2022)</label><mixed-citation>
      
EUMETSAT: GOME-2 Metop-A and -B FDR Product Validation Report
Reprocessing R3, EUM/OPS/DOC/21/1237264,  <a href="https://user.eumetsat.int/s3/eup-strapi-media/GOME_2_Metop_A_and_B_FDR_Product_Validation_Report_Reprocessing_R3_8a6a49db6c.pdf" target="_blank"/> (last access: 21 May 2025), 2022.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib9"><label>Fancourt et al.(2022)Fancourt, Ziv, Boersma, Tavares, Wang, and
Galbraith</label><mixed-citation>
      
Fancourt, M., Ziv, G., Boersma, K. F., Tavares, J., Wang, Y., and Galbraith,
D.: Background Climate Conditions Regulated the Photosynthetic Response of
Amazon Forests to the 2015/2016 El Nino-Southern Oscillation Event,
Communications Earth &amp; Environment, 3, 209,
<a href="https://doi.org/10.1038/s43247-022-00533-3" target="_blank">https://doi.org/10.1038/s43247-022-00533-3</a>, 2022.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib10"><label>Gerlein-Safdi et al.(2020)Gerlein-Safdi, Keppel-Aleks, Wang,
Frolking, and Mauzerall</label><mixed-citation>
      
Gerlein-Safdi, C., Keppel-Aleks, G., Wang, F., Frolking, S., and Mauzerall,
D. L.: Satellite Monitoring of Natural Reforestation Efforts in
China's Drylands, One Earth, 2, 98–108,
<a href="https://doi.org/10.1016/j.oneear.2019.12.015" target="_blank">https://doi.org/10.1016/j.oneear.2019.12.015</a>, 2020.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib11"><label>Grossi et al.(2015)Grossi, Valks, Loyola, Aberle, Slijkhuis, Wagner,
Beirle, and Lang</label><mixed-citation>
      
Grossi, M., Valks, P., Loyola, D., Aberle, B., Slijkhuis, S., Wagner, T., Beirle, S., and Lang, R.: Total column water vapour measurements from GOME-2 MetOp-A and MetOp-B, Atmos. Meas. Tech., 8, 1111–1133, <a href="https://doi.org/10.5194/amt-8-1111-2015" target="_blank">https://doi.org/10.5194/amt-8-1111-2015</a>, 2015.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib12"><label>Guanter et al.(2021)Guanter, Bacour, Schneider, Aben, van Kempen,
Maignan, Retscher, Köhler, Frankenberg, Joiner, and Zhang</label><mixed-citation>
      
Guanter, L., Bacour, C., Schneider, A., Aben, I., van Kempen, T. A., Maignan, F., Retscher, C., Köhler, P., Frankenberg, C., Joiner, J., and Zhang, Y.: The TROPOSIF global sun-induced fluorescence dataset from the Sentinel-5P TROPOMI mission, Earth Syst. Sci. Data, 13, 5423–5440, <a href="https://doi.org/10.5194/essd-13-5423-2021" target="_blank">https://doi.org/10.5194/essd-13-5423-2021</a>, 2021.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib13"><label>Jacob et al.(2016)Jacob, Turner, Maasakkers, Sheng, Sun, Liu, Chance,
Aben, McKeever, and Frankenberg</label><mixed-citation>
      
Jacob, D. J., Turner, A. J., Maasakkers, J. D., Sheng, J., Sun, K., Liu, X., Chance, K., Aben, I., McKeever, J., and Frankenberg, C.: Satellite observations of atmospheric methane and their value for quantifying methane emissions, Atmos. Chem. Phys., 16, 14371–14396, <a href="https://doi.org/10.5194/acp-16-14371-2016" target="_blank">https://doi.org/10.5194/acp-16-14371-2016</a>, 2016.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib14"><label>Joiner et al.(2012)Joiner, Yoshida, Vasilkov, Middleton, Campbell,
Yoshida, Kuze, and Corp</label><mixed-citation>
      
Joiner, J., Yoshida, Y., Vasilkov, A. P., Middleton, E. M., Campbell, P. K. E., Yoshida, Y., Kuze, A., and Corp, L. A.: Filling-in of near-infrared solar lines by terrestrial fluorescence and other geophysical effects: simulations and space-based observations from SCIAMACHY and GOSAT, Atmos. Meas. Tech., 5, 809–829, <a href="https://doi.org/10.5194/amt-5-809-2012" target="_blank">https://doi.org/10.5194/amt-5-809-2012</a>, 2012.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib15"><label>Joiner et al.(2013)Joiner, Guanter, Lindstrot, Voigt, Vasilkov,
Middleton, Huemmrich, Yoshida, and Frankenberg</label><mixed-citation>
      
Joiner, J., Guanter, L., Lindstrot, R., Voigt, M., Vasilkov, A. P., Middleton, E. M., Huemmrich, K. F., Yoshida, Y., and Frankenberg, C.: Global monitoring of terrestrial chlorophyll fluorescence from moderate-spectral-resolution near-infrared satellite measurements: methodology, simulations, and application to GOME-2, Atmos. Meas. Tech., 6, 2803–2823, <a href="https://doi.org/10.5194/amt-6-2803-2013" target="_blank">https://doi.org/10.5194/amt-6-2803-2013</a>, 2013.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib16"><label>Joiner et al.(2016)Joiner, Yoshida, Guanter, and
Middleton</label><mixed-citation>
      
Joiner, J., Yoshida, Y., Guanter, L., and Middleton, E. M.: New methods for the retrieval of chlorophyll red fluorescence from hyperspectral satellite instruments: simulations and application to GOME-2 and SCIAMACHY, Atmos. Meas. Tech., 9, 3939–3967, <a href="https://doi.org/10.5194/amt-9-3939-2016" target="_blank">https://doi.org/10.5194/amt-9-3939-2016</a>, 2016.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib17"><label>Joiner et al.(2018)Joiner, Yoshida, Zhang, Duveiller, Jung,
Lyapustin, Wang, and Tucker</label><mixed-citation>
      
Joiner, J., Yoshida, Y., Zhang, Y., Duveiller, G., Jung, M., Lyapustin, A.,
Wang, Y., and Tucker, C. J.: Estimation of Terrestrial Global Gross Primary
Production (GPP) with Satellite Data-Driven Models and Eddy
Covariance Flux Data, Remote Sens., 10, 1346, <a href="https://doi.org/10.3390/rs10091346" target="_blank">https://doi.org/10.3390/rs10091346</a>,
2018.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib18"><label>Joiner et al.(2020)Joiner, Yoshida, Köehler, Campbell,
Frankenberg, van der Tol, Yang, Parazoo, Guanter, and Sun</label><mixed-citation>
      
Joiner, J., Yoshida, Y., Köehler, P., Campbell, P., Frankenberg, C., van
der Tol, C., Yang, P., Parazoo, N., Guanter, L., and Sun, Y.: Systematic
Orbital Geometry-Dependent Variations in Satellite Solar-Induced
Fluorescence (SIF) Retrievals, Remote Sens., 12, 2346,
<a href="https://doi.org/10.3390/rs12152346" target="_blank">https://doi.org/10.3390/rs12152346</a>, 2020.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib19"><label>Khosravi et al.(2015)Khosravi, Vountas, Rozanov, Bracher, Wolanin,
and Burrows</label><mixed-citation>
      
Khosravi, N., Vountas, M., Rozanov, V. V., Bracher, A., Wolanin, A., and
Burrows, J. P.: Retrieval of Terrestrial Plant Fluorescence Based on the
In-Filling of Far-Red Fraunhofer Lines Using SCIAMACHY Observations,
Frontiers in Environmental Science, 3, <a href="https://doi.org/10.3389/fenvs.2015.00078" target="_blank">https://doi.org/10.3389/fenvs.2015.00078</a>, 2015.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib20"><label>Klaes et al.(2007)Klaes, Schlussel, Munro, Luntama, Engeln,
Ackermann, and Schmetz</label><mixed-citation>
      
Klaes, K. D., Schlussel, P., Munro, R., Luntama, J.-P., Engeln, A. V.,
Ackermann, J., and Schmetz, J.: An Introduction to the EUMETSAT Polar
System, B. Am. Meteorol. Soc., <a href="https://doi.org/10.1175/BAMS-88-7-1085" target="_blank">https://doi.org/10.1175/BAMS-88-7-1085</a>, 1085–1096,
2007.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib21"><label>Köhler et al.(2015)Köhler, Guanter, and Joiner</label><mixed-citation>
      
Köhler, P., Guanter, L., and Joiner, J.: A linear method for the retrieval of sun-induced chlorophyll fluorescence from GOME-2 and SCIAMACHY data, Atmos. Meas. Tech., 8, 2589–2608, <a href="https://doi.org/10.5194/amt-8-2589-2015" target="_blank">https://doi.org/10.5194/amt-8-2589-2015</a>, 2015.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib22"><label>Köhler et al.(2018)Köhler, Frankenberg, Magney, Guanter,
Joiner, and Landgraf</label><mixed-citation>
      
Köhler, P., Frankenberg, C., Magney, T. S., Guanter, L., Joiner, J., and
Landgraf, J.: Global Retrievals of Solar-Induced Chlorophyll
Fluorescence With TROPOMI: First Results and Intersensor Comparison
to OCO-2, Geophys. Res. Lett., 45, 10456–10463,
<a href="https://doi.org/10.1029/2018GL079031" target="_blank">https://doi.org/10.1029/2018GL079031</a>, 2018.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib23"><label>Koren et al.(2018)Koren, Van Schaik, Araújo, Boersma,
Gärtner, Killaars, Kooreman, Kruijt, Van Der Laan-Luijkx, Von Randow,
Smith, and Peters</label><mixed-citation>
      
Koren, G., Van Schaik, E., Araújo, A. C., Boersma, K. F., Gärtner, A.,
Killaars, L., Kooreman, M. L., Kruijt, B., Van Der Laan-Luijkx, I. T.,
Von Randow, C., Smith, N. E., and Peters, W.: Widespread Reduction in
Sun-Induced Fluorescence from the Amazon during the 2015/2016 El
Niño, Philos. T. R. Soc. B, 373, 20170408, <a href="https://doi.org/10.1098/rstb.2017.0408" target="_blank">https://doi.org/10.1098/rstb.2017.0408</a>, 2018.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib24"><label>Li et al.(2018)Li, Ma, Wu, and Yang</label><mixed-citation>
      
Li, Q., Ma, M., Wu, X., and Yang, H.: Snow Cover and
Vegetation-Induced Decrease in Global Albedo From 2002 to 2016,
J. Geophys. Res.-Atmos., 123, 124–138,
<a href="https://doi.org/10.1002/2017JD027010" target="_blank">https://doi.org/10.1002/2017JD027010</a>, 2018.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib25"><label>Liu et al.(2021)Liu, You, Zhang, Chen, Zhang, Li, and Wu</label><mixed-citation>
      
Liu, Y., You, C., Zhang, Y., Chen, S., Zhang, Z., Li, J., and Wu, Y.:
Resistance and Resilience of Grasslands to Drought Detected by SIF in
Inner Mongolia, China, Agr. Forest Meteorol., 308–309,
108567, <a href="https://doi.org/10.1016/j.agrformet.2021.108567" target="_blank">https://doi.org/10.1016/j.agrformet.2021.108567</a>, 2021.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib26"><label>Magney et al.(2019)Magney, Bowling, Logan, Grossmann, Stutz, Blanken,
Burns, Cheng, Garcia, Köhler, Lopez, Parazoo, Raczka, Schimel, and
Frankenberg</label><mixed-citation>
      
Magney, T. S., Bowling, D. R., Logan, B. A., Grossmann, K., Stutz, J., Blanken,
P. D., Burns, S. P., Cheng, R., Garcia, M. A., Köhler, P., Lopez, S.,
Parazoo, N. C., Raczka, B., Schimel, D., and Frankenberg, C.: Mechanistic
Evidence for Tracking the Seasonality of Photosynthesis with Solar-Induced
Fluorescence, P. Natl. Acad. Sci. USA, 116,
11640–11645, <a href="https://doi.org/10.1073/pnas.1900278116" target="_blank">https://doi.org/10.1073/pnas.1900278116</a>, 2019.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib27"><label>Mohammed et al.(2019)Mohammed, Colombo, Middleton, Rascher, Van
Der Tol, Nedbal, Goulas, Pérez-Priego, Damm, Meroni, Joiner, Cogliati,
Verhoef, Malenovský, Gastellu-Etchegorry, Miller, Guanter, Moreno,
Moya, Berry, Frankenberg, and Zarco-Tejada</label><mixed-citation>
      
Mohammed, G. H., Colombo, R., Middleton, E. M., Rascher, U., Van Der Tol, C.,
Nedbal, L., Goulas, Y., Pérez-Priego, O., Damm, A., Meroni, M., Joiner,
J., Cogliati, S., Verhoef, W., Malenovský, Z., Gastellu-Etchegorry,
J.-P., Miller, J. R., Guanter, L., Moreno, J., Moya, I., Berry, J. A.,
Frankenberg, C., and Zarco-Tejada, P. J.: Remote Sensing of Solar-Induced
Chlorophyll Fluorescence (SIF) in Vegetation: 50 Years of Progress,
Remote Sens. Environ., 231, 111177,
<a href="https://doi.org/10.1016/j.rse.2019.04.030" target="_blank">https://doi.org/10.1016/j.rse.2019.04.030</a>, 2019.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib28"><label>Munro et al.(2016)Munro, Lang, Klaes, Poli, Retscher, Lindstrot,
Huckle, Lacan, Grzegorski, Holdak, Kokhanovsky, Livschitz, and
Eisinger</label><mixed-citation>
      
Munro, R., Lang, R., Klaes, D., Poli, G., Retscher, C., Lindstrot, R., Huckle, R., Lacan, A., Grzegorski, M., Holdak, A., Kokhanovsky, A., Livschitz, J., and Eisinger, M.: The GOME-2 instrument on the Metop series of satellites: instrument design, calibration, and level 1 data processing – an overview, Atmos. Meas. Tech., 9, 1279–1301, <a href="https://doi.org/10.5194/amt-9-1279-2016" target="_blank">https://doi.org/10.5194/amt-9-1279-2016</a>, 2016.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib29"><label>Noël et al.(2024)Noël, Buchwitz, Hilker, Reuter, Weimer,
Bovensmann, Burrows, Bösch, and Lang</label><mixed-citation>
      
Noël, S., Buchwitz, M., Hilker, M., Reuter, M., Weimer, M., Bovensmann, H., Burrows, J. P., Bösch, H., and Lang, R.: Greenhouse gas retrievals for the CO2M mission using the FOCAL method: first performance estimates, Atmos. Meas. Tech., 17, 2317–2334, <a href="https://doi.org/10.5194/amt-17-2317-2024" target="_blank">https://doi.org/10.5194/amt-17-2317-2024</a>, 2024.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib30"><label>Parazoo et al.(2019)Parazoo, Frankenberg, Köhler, Joiner,
Yoshida, Magney, Sun, and Yadav</label><mixed-citation>
      
Parazoo, N. C., Frankenberg, C., Köhler, P., Joiner, J., Yoshida, Y.,
Magney, T., Sun, Y., and Yadav, V.: Towards a Harmonized Long-Term
Spaceborne Record of Far-Red Solar-Induced Fluorescence,
J. Geophys. Res.-Biogeo., 124, 2518–2539,
<a href="https://doi.org/10.1029/2019JG005289" target="_blank">https://doi.org/10.1029/2019JG005289</a>, 2019.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib31"><label>Peltoniemi et al.(2005)Peltoniemi, Kaasalainen, Näränen,
Rautiainen, Stenberg, Smolander, Smolander, and Voipio</label><mixed-citation>
      
Peltoniemi, J. I., Kaasalainen, S., Näränen, J., Rautiainen, M.,
Stenberg, P., Smolander, H., Smolander, S., and Voipio, P.: BRDF
Measurement of Understory Vegetation in Pine Forests: Dwarf Shrubs, Lichen,
and Moss, Remote Sens. Environ., 94, 343–354,
<a href="https://doi.org/10.1016/j.rse.2004.10.009" target="_blank">https://doi.org/10.1016/j.rse.2004.10.009</a>, 2005.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib32"><label>Sanghavi et al.(2025)Sanghavi, Frankenberg, Nelson, O'Dell,
Rosenberg, and Joiner</label><mixed-citation>
      
Sanghavi, S., Frankenberg, C., Nelson, R. R., O'Dell, C. W., Rosenberg, R., and
Joiner, J.: Impact of Raman Scattering on SIF Retrievals From
Hyperspectral Satellite Observations, Geophys. Res. Lett., 52,
e2024GL112777, <a href="https://doi.org/10.1029/2024GL112777" target="_blank">https://doi.org/10.1029/2024GL112777</a>, 2025.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib33"><label>Sun et al.(2018)Sun, Frankenberg, Jung, Joiner, Guanter, Köhler,
and Magney</label><mixed-citation>
      
Sun, Y., Frankenberg, C., Jung, M., Joiner, J., Guanter, L., Köhler, P.,
and Magney, T.: Overview of Solar-Induced Chlorophyll Fluorescence
(SIF) from the Orbiting Carbon Observatory-2: Retrieval,
Cross-Mission Comparison, and Global Monitoring for GPP, Remote Sens. Environ., 209, 808–823, <a href="https://doi.org/10.1016/j.rse.2018.02.016" target="_blank">https://doi.org/10.1016/j.rse.2018.02.016</a>, 2018.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib34"><label>Sun et al.(2023)Sun, Gu, Wen, van der Tol, Porcar-Castell, Joiner,
Chang, Magney, Wang, Hu, Rascher, Zarco-Tejada, Barrett, Lai, Han, and
Luo</label><mixed-citation>
      
Sun, Y., Gu, L., Wen, J., van der Tol, C., Porcar-Castell, A., Joiner, J.,
Chang, C. Y., Magney, T., Wang, L., Hu, L., Rascher, U., Zarco-Tejada, P.,
Barrett, C. B., Lai, J., Han, J., and Luo, Z.: From Remotely Sensed
Solar-induced Chlorophyll Fluorescence to Ecosystem Structure, Function, and
Service: Part I – Harnessing Theory, Glob. Change Biol., 29,
2926–2952, <a href="https://doi.org/10.1111/gcb.16634" target="_blank">https://doi.org/10.1111/gcb.16634</a>, 2023.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib35"><label>Tilstra et al.(2012)Tilstra, Tuinder, and Stammes</label><mixed-citation>
      
Tilstra, L. G., Tuinder, O. N. E., and Stammes, P.: A New Method for In-Flight
Degradation Correction of GOME-2 Earth Reflectance Measurements, with
Application to the Absorbing Aerosol Index, Proceedings of the 2012
EUMETSAT Meteorological Satellite Conference,  <a href="https://www-cdn.eumetsat.int/files/2020-04/pdf_conf_p61_s3_03_tilstra_p.pdf" target="_blank"/> (last access: 19 October 2024), 2012.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib36"><label>Turner et al.(2021)Turner, Köhler, Magney, Frankenberg, Fung, and
Cohen</label><mixed-citation>
      
Turner, A. J., Köhler, P., Magney, T. S., Frankenberg, C., Fung, I., and Cohen, R. C.: Extreme events driving year-to-year differences in gross primary productivity across the US, Biogeosciences, 18, 6579–6588, <a href="https://doi.org/10.5194/bg-18-6579-2021" target="_blank">https://doi.org/10.5194/bg-18-6579-2021</a>, 2021.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib37"><label>van der A et al.(2006)van der A, Peters, Eskes, Boersma, van
Roozendael, De Smedt, and Kelder</label><mixed-citation>
      
van der A, R. J., Peters, D. H. M. U., Eskes, H., Boersma, K. F., van
Roozendael, M., De Smedt, I., and Kelder, H. M.: Detection of the Trend and
Seasonal Variation in Tropospheric NO<sub>2</sub> over China,
J. Geophys. Res.-Atmos., 111, 2005JD006594,
<a href="https://doi.org/10.1029/2005JD006594" target="_blank">https://doi.org/10.1029/2005JD006594</a>, 2006.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib38"><label>van Schaik et al.(2020)van Schaik, Kooreman, Stammes, Tilstra,
Tuinder, Sanders, Verstraeten, Lang, Cacciari, Joiner, Peters, and
Boersma</label><mixed-citation>
      
van Schaik, E., Kooreman, M. L., Stammes, P., Tilstra, L. G., Tuinder, O. N. E., Sanders, A. F. J., Verstraeten, W. W., Lang, R., Cacciari, A., Joiner, J., Peters, W., and Boersma, K. F.: Improved SIFTER v2 algorithm for long-term GOME-2A satellite retrievals of fluorescence with a correction for instrument degradation, Atmos. Meas. Tech., 13, 4295–4315, <a href="https://doi.org/10.5194/amt-13-4295-2020" target="_blank">https://doi.org/10.5194/amt-13-4295-2020</a>, 2020.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib39"><label>van Wittenberghe et al.(2015)van Wittenberghe, Alonso, Verrelst,
Moreno, and Samson</label><mixed-citation>
      
van Wittenberghe, S., Alonso, L., Verrelst, J., Moreno, J., and Samson, R.:
Bidirectional Sun-Induced Chlorophyll Fluorescence Emission Is Influenced by
Leaf Structure and Light Scattering Properties – A Bottom-up Approach,
Remote Sens. Environ., 158, 169–179,
<a href="https://doi.org/10.1016/j.rse.2014.11.012" target="_blank">https://doi.org/10.1016/j.rse.2014.11.012</a>, 2015.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib40"><label>Vicent et al.(2016)Vicent, Sabater, Tenjo, Acarreta, Manzano, Rivera,
Jurado, Franco, Alonso, Verrelst, and Moreno</label><mixed-citation>
      
Vicent, J., Sabater, N., Tenjo, C., Acarreta, J. R., Manzano, M., Rivera,
J. P., Jurado, P., Franco, R., Alonso, L., Verrelst, J., and Moreno, J.:
FLEX End-to-End Mission Performance Simulator, IEEE T.
Geosci. Remote, 54, 4215–4223,
<a href="https://doi.org/10.1109/TGRS.2016.2538300" target="_blank">https://doi.org/10.1109/TGRS.2016.2538300</a>, 2016.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib41"><label>Wang et al.(2019)Wang, Beringer, Hutley, Cleverly, Li, Liu, and
Sun</label><mixed-citation>
      
Wang, C., Beringer, J., Hutley, L. B., Cleverly, J., Li, J., Liu, Q., and Sun,
Y.: Phenology Dynamics of Dryland Ecosystems Along the North
Australian Tropical Transect Revealed by Satellite Solar-Induced
Chlorophyll Fluorescence, Geophys. Res. Lett., 46, 5294–5302,
<a href="https://doi.org/10.1029/2019GL082716" target="_blank">https://doi.org/10.1029/2019GL082716</a>, 2019.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib42"><label>Wang and Stammes(2008)</label><mixed-citation>
      
Wang, P., Stammes, P., van der A, R., Pinardi, G., and van Roozendael, M.: FRESCO+: an improved O<sub>2</sub> A-band cloud retrieval algorithm for tropospheric trace gas retrievals, Atmos. Chem. Phys., 8, 6565–6576, <a href="https://doi.org/10.5194/acp-8-6565-2008" target="_blank">https://doi.org/10.5194/acp-8-6565-2008</a>, 2008.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib43"><label>Wang et al.(2022)Wang, Zhang, Ju, Wu, Liu, He, and
Peñuelas</label><mixed-citation>
      
Wang, S., Zhang, Y., Ju, W., Wu, M., Liu, L., He, W., and Peñuelas, J.:
Temporally Corrected Long-Term Satellite Solar-Induced Fluorescence Leads to
Improved Estimation of Global Trends in Vegetation Photosynthesis during
1995–2018, ISPRS J. Photogramm., 194,
222–234, <a href="https://doi.org/10.1016/j.isprsjprs.2022.10.018" target="_blank">https://doi.org/10.1016/j.isprsjprs.2022.10.018</a>, 2022.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib44"><label>Weatherhead et al.(1998)Weatherhead, Reinsel, Tiao, Meng, Choi,
Cheang, Keller, DeLuisi, Wuebbles, Kerr, Miller, Oltmans, and
Frederick</label><mixed-citation>
      
Weatherhead, E. C., Reinsel, G. C., Tiao, G. C., Meng, X.-L., Choi, D., Cheang,
W.-K., Keller, T., DeLuisi, J., Wuebbles, D. J., Kerr, J. B., Miller, A. J.,
Oltmans, S. J., and Frederick, J. E.: Factors Affecting the Detection of
Trends: Statistical Considerations and Applications to Environmental
Data, J. Geophys. Res.-Atmos., 103, 17149–17161,
<a href="https://doi.org/10.1029/98JD00995" target="_blank">https://doi.org/10.1029/98JD00995</a>, 1998.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib45"><label>Wen et al.(2020)Wen, Köhler, Duveiller, Parazoo, Magney, Hooker,
Yu, Chang, and Sun</label><mixed-citation>
      
Wen, J., Köhler, P., Duveiller, G., Parazoo, N., Magney, T., Hooker, G.,
Yu, L., Chang, C., and Sun, Y.: A Framework for Harmonizing Multiple
Satellite Instruments to Generate a Long-Term Global High Spatial-Resolution
Solar-Induced Chlorophyll Fluorescence (SIF), Remote Sens. Environ., 239, 111644, <a href="https://doi.org/10.1016/j.rse.2020.111644" target="_blank">https://doi.org/10.1016/j.rse.2020.111644</a>, 2020.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib46"><label>Yang and van der Tol(2018)</label><mixed-citation>
      
Yang, P. and van der Tol, C.: Linking Canopy Scattering of Far-Red
Sun-Induced Chlorophyll Fluorescence with Reflectance, Remote Sens. Environ., 209, 456–467, <a href="https://doi.org/10.1016/j.rse.2018.02.029" target="_blank">https://doi.org/10.1016/j.rse.2018.02.029</a>, 2018.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib47"><label>Zhang et al.(2022)Zhang, Xiao, Tong, Zhang, Meng, Li, Liu, and
Yu</label><mixed-citation>
      
Zhang, J., Xiao, J., Tong, X., Zhang, J., Meng, P., Li, J., Liu, P., and Yu,
P.: NIRv and SIF Better Estimate Phenology than NDVI and EVI:
Effects of Spring and Autumn Phenology on Ecosystem Production of Planted
Forests, Agr. Forest Meteorol., 315, 108819,
<a href="https://doi.org/10.1016/j.agrformet.2022.108819" target="_blank">https://doi.org/10.1016/j.agrformet.2022.108819</a>, 2022.


    </mixed-citation></ref-html>
<ref-html id="bib1.bib48"><label>Zhang et al.(2018)Zhang, Joiner, Gentine, and Zhou</label><mixed-citation>
      
Zhang, Y., Joiner, J., Gentine, P., and Zhou, S.: Reduced Solar-induced
Chlorophyll Fluorescence from GOME-2 during Amazon Drought
Caused by Dataset Artifacts, Glob. Change Biol., 24, 2229–2230,
<a href="https://doi.org/10.1111/gcb.14134" target="_blank">https://doi.org/10.1111/gcb.14134</a>, 2018.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib49"><label>Zhang et al.(2023)Zhang, Fang, Smith, Wang, Gentine, Scott,
Migliavacca, Jeong, Litvak, and Zhou</label><mixed-citation>
      
Zhang, Y., Fang, J., Smith, W. K., Wang, X., Gentine, P., Scott, R. L.,
Migliavacca, M., Jeong, S., Litvak, M., and Zhou, S.: Satellite Solar-induced
Chlorophyll Fluorescence Tracks Physiological Drought Stress Development
during 2020 Southwest US Drought, Glob. Change Biol., 29,
3395–3408, <a href="https://doi.org/10.1111/gcb.16683" target="_blank">https://doi.org/10.1111/gcb.16683</a>, 2023.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib50"><label>Zou et al.(2024)Zou, Du, Liu, and Liu</label><mixed-citation>
      
Zou, C., Du, S., Liu, X., and Liu, L.: TCSIF: a temporally consistent global Global Ozone Monitoring Experiment-2A (GOME-2A) solar-induced chlorophyll fluorescence dataset with the correction of sensor degradation, Earth Syst. Sci. Data, 16, 2789–2809, <a href="https://doi.org/10.5194/essd-16-2789-2024" target="_blank">https://doi.org/10.5194/essd-16-2789-2024</a>, 2024.

    </mixed-citation></ref-html>--></article>
