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  <front>
    <journal-meta><journal-id journal-id-type="publisher">ESSD</journal-id><journal-title-group>
    <journal-title>Earth System Science Data</journal-title>
    <abbrev-journal-title abbrev-type="publisher">ESSD</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Earth Syst. Sci. Data</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1866-3516</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/essd-13-281-2021</article-id><title-group><article-title>A daily, 250 m and real-time gross primary productivity product (2000–present) covering the<?xmltex \hack{\break}?> contiguous United States</article-title><alt-title>SLOPE GPP product</alt-title>
      </title-group><?xmltex \runningtitle{SLOPE GPP product}?><?xmltex \runningauthor{C.~Jiang et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1 aff2 aff3">
          <name><surname>Jiang</surname><given-names>Chongya</given-names></name>
          <email>chongya.jiang@email.com</email>
        <ext-link>https://orcid.org/0000-0002-1660-7320</ext-link></contrib>
        <contrib contrib-type="author" corresp="yes" rid="aff1 aff2 aff3 aff4">
          <name><surname>Guan</surname><given-names>Kaiyu</given-names></name>
          <email>kaiyuguan@gmail.com</email>
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1 aff2 aff3">
          <name><surname>Wu</surname><given-names>Genghong</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1 aff3 aff4">
          <name><surname>Peng</surname><given-names>Bin</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1 aff2 aff4">
          <name><surname>Wang</surname><given-names>Sheng</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-3385-3109</ext-link></contrib>
        <aff id="aff1"><label>1</label><institution>Agroecosystem Sustainability Center, Institute for Sustainability, Energy, and Environment,<?xmltex \hack{\break}?> University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>College of Agricultural, Consumer &amp; Environmental Sciences,
University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>DOE Center for Advanced Bioenergy and Bioproducts Innovation,
University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>National Center for Supercomputing Applications, University of Illinois
at Urbana-Champaign,<?xmltex \hack{\break}?> Urbana, IL 61801, USA</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Chongya Jiang (chongya.jiang@email.com) and Kaiyu Guan
(kaiyuguan@gmail.com)</corresp></author-notes><pub-date><day>9</day><month>February</month><year>2021</year></pub-date>
      
      <volume>13</volume>
      <issue>2</issue>
      <fpage>281</fpage><lpage>298</lpage>
      <history>
        <date date-type="received"><day>14</day><month>February</month><year>2020</year></date>
           <date date-type="rev-request"><day>25</day><month>May</month><year>2020</year></date>
           <date date-type="rev-recd"><day>4</day><month>November</month><year>2020</year></date>
           <date date-type="accepted"><day>11</day><month>November</month><year>2020</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2021 </copyright-statement>
        <copyright-year>2021</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://essd.copernicus.org/articles/.html">This article is available from https://essd.copernicus.org/articles/.html</self-uri><self-uri xlink:href="https://essd.copernicus.org/articles/.pdf">The full text article is available as a PDF file from https://essd.copernicus.org/articles/.pdf</self-uri>
      <abstract><title>Abstract</title>
    <p id="d1e145">Gross primary productivity (GPP) quantifies the amount of
carbon dioxide (CO<inline-formula><mml:math id="M1" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>) fixed by plants through photosynthesis. Although
as a key quantity of terrestrial ecosystems, there is a lack of
high-spatial-and-temporal-resolution, real-time and observation-based GPP
products. To address this critical gap, here we leverage a state-of-the-art
vegetation index, near-infrared reflectance of vegetation (NIR<inline-formula><mml:math id="M2" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>), along
with accurate photosynthetically active radiation (PAR), to produce a
SatelLite Only Photosynthesis Estimation (SLOPE) GPP product for the
contiguous United States (CONUS). Compared to existing GPP products, the
proposed SLOPE product is advanced in its spatial resolution (250 m versus
<inline-formula><mml:math id="M3" display="inline"><mml:mrow><mml:mi mathvariant="italic">&gt;</mml:mi><mml:mn mathvariant="normal">500</mml:mn></mml:mrow></mml:math></inline-formula> m), temporal resolution (daily versus 8 d), instantaneity
(latency of 1 d versus <inline-formula><mml:math id="M4" display="inline"><mml:mrow><mml:mi mathvariant="italic">&gt;</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:math></inline-formula> weeks) and quantitative
uncertainty (on a per-pixel and daily basis versus no uncertainty
information available). These characteristics are achieved because of
several technical innovations employed in this study: (1) SLOPE couples
machine learning models with MODIS atmosphere and land products to
accurately estimate PAR. (2) SLOPE couples highly efficient and pragmatic
gap-filling and filtering algorithms with surface reflectance acquired by
both Terra and Aqua MODIS satellites to derive a soil-adjusted NIR<inline-formula><mml:math id="M5" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>
(SANIR<inline-formula><mml:math id="M6" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>) dataset. (3) SLOPE couples a temporal pattern recognition
approach with a long-term Cropland Data Layer (CDL) product to predict dynamic
C4 crop fraction. Through developing a parsimonious model with only two
slope parameters, the proposed SLOPE product explains 85 % of the spatial
and temporal variations in GPP acquired from 49 AmeriFlux eddy-covariance
sites (324 site years), with a root-mean-square error (RMSE) of
1.63 gC m<inline-formula><mml:math id="M7" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M8" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. The median <inline-formula><mml:math id="M9" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> over C3 and C4 crop sites reaches 0.87
and 0.94, respectively, indicating great potentials for monitoring crops, in
particular bioenergy crops, at the field level. With such a satisfactory
performance and its distinct characteristics in spatiotemporal resolution
and instantaneity, the proposed SLOPE GPP product is promising for
biological and environmental research, carbon cycle research, and a broad
range of real-time applications at the regional scale. The archived dataset
is available at <ext-link xlink:href="https://doi.org/10.3334/ORNLDAAC/1786" ext-link-type="DOI">10.3334/ORNLDAAC/1786</ext-link> (download
page: <uri>https://daac.ornl.gov/daacdata/cms/SLOPE_GPP_CONUS/data/</uri>, last access: 20 January 2021) (Jiang and Guan, 2020), and
the real-time dataset is available upon request.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<?pagebreak page282?><sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d1e255">Gross primary productivity (GPP) quantifies the amount of carbon dioxide
(CO<inline-formula><mml:math id="M10" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>) fixed by plants through photosynthesis
(Beer et al., 2010; Jung et al., 2017). Because
GPP is the largest carbon flux and influences other ecosystem processes such
as respiration and transpiration, monitoring GPP is crucial for
understanding the global carbon budget and terrestrial-ecosystem dynamics
(Bonan,
2019; Friedlingstein et al., 2019). In addition, biomass accumulation driven
by GPP is the basis for food, feed, wood and fiber production, and therefore
monitoring GPP is crucial for human welfare and development
(Guan et al., 2016; Ryu et
al., 2019).</p>
      <p id="d1e267">Over the past 2 decades, a number of GPP products with different spatial
and temporal characteristics have been derived using remote sensing
approaches (Xiao et al., 2019).
However, since GPP cannot be directly observed at large scales, different
models have been developed and used in generating GPP products.
Process-based models use a series of nonlinear equations to represent the
atmosphere–vegetation–soil system and associated fluxes. For example, a
publicly available global GPP product using process-based models is the
Breathing Earth System Simulator (BESS) (Jiang and Ryu,
2016). Machine-learning models upscale site-observed GPP to a larger scale
by establishing non-parametric relationships between the ground truth and
gridded explanatory variables. The FLUXCOM GPP product is a typical example
of this approach (Jung et al., 2019).
Semi-empirical approaches utilize equations with a concise physiological
meaning (e.g., light use efficiency) that are parameterized with several
empirical constraint functions. The MOD17 (MODIS GPP/NPP – net primary production – Project) GPP product
(Running et al., 2004), the Vegetation Photosynthesis
Model (VPM) GPP product
(Zhang et al., 2017) and
the Global LAnd Surface Satellite (GLASS) GPP product
(Yuan et al.,
2010) belong to this category.</p>
      <p id="d1e270">With differing principles, assumptions and complexity, existing remote
sensing GPP models heavily rely upon inputs with large uncertainties. First,
climate forcing, such as temperature, humidity, precipitation and wind
speed, is commonly used in these GPP models. However, these meteorological
data are not observed but derived from reanalysis approaches and usually
have coarse spatial resolution (e.g., <inline-formula><mml:math id="M11" display="inline"><mml:mrow><mml:mi mathvariant="italic">&gt;</mml:mi><mml:mn mathvariant="normal">10</mml:mn></mml:mrow></mml:math></inline-formula> km) and large time lags
(e.g., weeks). Second, plant functional types (PFTs) are used to define
different parameterization schemes in those models. To date, satellite land
cover products are usually characterized by considerably large time lags
(<inline-formula><mml:math id="M12" display="inline"><mml:mrow><mml:mi mathvariant="italic">&gt;</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> year), relatively low accuracy (<inline-formula><mml:math id="M13" display="inline"><mml:mrow><mml:mo>≤</mml:mo><mml:mn mathvariant="normal">70</mml:mn></mml:mrow></mml:math></inline-formula> %)
(Yang et al., 2017) and more uncertainties with
regards to year-to-year variations
(Cai
et al., 2014; Li et al., 2018). Third, high-level remote sensing land
products such as the leaf area index (LAI), fraction of absorbed
photosynthetically active radiation (FPAR), clumping index (CI), land
surface temperature (LST) and soil moisture (SM) are used by some models.
These variables are not directly observed but retrieved by complicated
algorithms, and their accuracy still needs significant improvement to meet
requirements of Earth system models (GCOS, 2011).</p>
      <p id="d1e303">Alternative approaches which heavily rely on reliable satellite observations
with low dependence on uncertain model structure or parameterization and model
inputs are highly required. Solar-induced fluorescence (SIF) emerged in
recent years and may provide a new opportunity for GPP estimation
(Guanter et al., 2014). Linear relationships
have been found between SIF and GPP at various ecosystems
(Liu
et al., 2017; Magney et al., 2019; Yang et al., 2015). However, satellite
SIF data generally have coarse resolution, large spatial gaps, short
temporal coverage and limited quality
(Bacour et al., 2019; Zhang
et al., 2018) and are therefore not suitable for many applications.</p>
      <p id="d1e307">Near-infrared reflectance of vegetation (NIR<inline-formula><mml:math id="M14" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula>), defined as the
product of the normalized difference vegetation index (NDVI) and observed NIR
reflectance (NIR<inline-formula><mml:math id="M15" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">Ref</mml:mi></mml:msub></mml:math></inline-formula>) (Eq. 1), has recently been presented as a proxy
of GPP (Badgley et al., 2017). A global monthly
<inline-formula><mml:math id="M16" display="inline"><mml:mrow><mml:mn mathvariant="normal">0.5</mml:mn><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> GPP dataset has been produced from satellite data using the
linear relationship between NIR<inline-formula><mml:math id="M17" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> and GPP
(Badgley et al., 2019), explaining
68 % GPP variations observed by the FLUXNET network. Several field studies
have recently found that taking incoming radiation into account further
improves the NIR<inline-formula><mml:math id="M18" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>–GPP relationship (Dechant
et al., 2020; Wu et al., 2020). Because MODIS provides long-term and
real-time (2000–present) observations of red (Red<inline-formula><mml:math id="M19" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">Ref</mml:mi></mml:msub></mml:math></inline-formula>) and NIR
(NIR<inline-formula><mml:math id="M20" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">Ref</mml:mi></mml:msub></mml:math></inline-formula>) reflectance and atmospheric conditions with high spatial (250 m for reflectance and 1 km for atmosphere) and temporal (daily) resolutions,
now there is an unprecedented opportunity to generate an observation-based
GPP product.
          <disp-formula id="Ch1.E1" content-type="numbered"><label>1</label><mml:math id="M21" display="block"><mml:mrow><?xmltex \hack{\hbox\bgroup\fontsize{9.5}{9.5}\selectfont$\displaystyle}?><mml:msub><mml:mi mathvariant="normal">NIR</mml:mi><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:mi mathvariant="normal">NDVI</mml:mi><mml:mo>×</mml:mo><mml:msub><mml:mi mathvariant="normal">NIR</mml:mi><mml:mi mathvariant="normal">Ref</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi mathvariant="normal">NIR</mml:mi><mml:mi mathvariant="normal">Ref</mml:mi></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="normal">Red</mml:mi><mml:mi mathvariant="normal">Ref</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi mathvariant="normal">NIR</mml:mi><mml:mi mathvariant="normal">Ref</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="normal">Red</mml:mi><mml:mi mathvariant="normal">Ref</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>×</mml:mo><mml:msub><mml:mi mathvariant="normal">NIR</mml:mi><mml:mi mathvariant="normal">Ref</mml:mi></mml:msub><?xmltex \hack{$\egroup}?></mml:mrow></mml:math></disp-formula></p>
      <p id="d1e452">Leveraging the concept of NIR<inline-formula><mml:math id="M22" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>, here we present a new GPP model and the
resultant daily, 250 m and real-time GPP product (2000–present) covering
the contiguous United States (CONUS) (Jiang and Guan, 2020).
The product is named SatelLite Only Photosynthesis Estimation (SLOPE)
because (1) the model only uses satellite data and (2) the model only has
two slope parameters. Detailed model design, multi-source satellite data
processing and comprehensive evaluation procedures are elucidated below.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Production of the SLOPE product</title>
      <p id="d1e472">The method we used to estimate GPP using the novel vegetation index
NIR<inline-formula><mml:math id="M23" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> follows the concept of light use efficiency (LUE)
(Monteith,
1972; Monteith and Moss, 1977):
          <disp-formula id="Ch1.E2" content-type="numbered"><label>2</label><mml:math id="M24" display="block"><mml:mrow><mml:mi mathvariant="normal">GPP</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="normal">PAR</mml:mi><mml:mo>×</mml:mo><mml:mi mathvariant="normal">FPAR</mml:mi><mml:mo>×</mml:mo><mml:mi mathvariant="normal">LUE</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula></p>
      <?pagebreak page283?><p id="d1e510">Since NIR<inline-formula><mml:math id="M25" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> has been found strongly correlated to FPAR
(Badgley et al., 2017) and moderately correlated to LUE
(Dechant et al., 2019), it is possible to simplify Eq. (2)
as
          <disp-formula id="Ch1.E3" content-type="numbered"><label>3</label><mml:math id="M26" display="block"><mml:mrow><mml:mi mathvariant="normal">GPP</mml:mi><mml:mo>≈</mml:mo><mml:mi mathvariant="normal">PAR</mml:mi><mml:mo>×</mml:mo><mml:mfenced close=")" open="("><mml:mrow><mml:mi>a</mml:mi><mml:mo>×</mml:mo><mml:msub><mml:mi mathvariant="normal">NIR</mml:mi><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:mi>b</mml:mi></mml:mrow></mml:mfenced><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
        where <inline-formula><mml:math id="M27" display="inline"><mml:mi>a</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M28" display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula> are the slope and intercept, which can be fitted from ground GPP
observations. Both PAR (photosynthetically active radiation) and NIR<inline-formula><mml:math id="M29" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> can be easily derived from
satellite observations with high spatial and temporal resolutions in real
time, avoiding complicated but uncertain algorithm or parameterization to
quantify FPAR and LUE in Eq. (2). This linear relationship is likely to
converge within C3 species (Badgley et
al., 2019) but differs between C3 and C4 species (Wu et al.,
2019). Accordingly, land cover data with considerably large time lags and
relatively low accuracy may not be necessary for the model parameterization.
Instead, an in-season C3–C4 species dataset is needed for the accurate
calibration of the linear relationship.</p>
      <p id="d1e591">Defining the ratio of GPP to PAR as the incident PAR use efficiency (iPUE)
gives
          <disp-formula id="Ch1.E4" content-type="numbered"><label>4</label><mml:math id="M30" display="block"><mml:mrow><mml:mi mathvariant="normal">iPUE</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="normal">GPP</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">PAR</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="normal">FPAR</mml:mi><mml:mo>×</mml:mo><mml:mi mathvariant="normal">LUE</mml:mi><mml:mo>≈</mml:mo><mml:mi>a</mml:mi><mml:mo>×</mml:mo><mml:msub><mml:mi mathvariant="normal">NIR</mml:mi><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:mi>b</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula></p>
      <p id="d1e640">Here iPUE is a confounding factor of canopy structure and leaf physiology,
representing the capacity of plants to use incoming radiation for
photosynthesis. When vegetation is absent, iPUE is zero and NIR<inline-formula><mml:math id="M31" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> is
expected to be zero too. However, this is not true in reality, as
<inline-formula><mml:math id="M32" display="inline"><mml:mrow><mml:mi mathvariant="italic">&gt;</mml:mi><mml:mn mathvariant="normal">99.9</mml:mn></mml:mrow></mml:math></inline-formula> % soils have positive NIR<inline-formula><mml:math id="M33" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> values according to
a global soil spectral library (Jiang and Fang, 2019), and the
correction of NIR<inline-formula><mml:math id="M34" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> for soil is needed for better performance at low
vegetation cover (Zeng et al.,
2019). To address this issue, we will propose a spatially explicit correction
for NIR<inline-formula><mml:math id="M35" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> to derive a soil-adjusted index SANIR<inline-formula><mml:math id="M36" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> (see details
in Sect. 2.2). Since SANIR<inline-formula><mml:math id="M37" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:math></inline-formula> when iPUE <inline-formula><mml:math id="M38" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0, Eq. (4) becomes
          <disp-formula id="Ch1.E5" content-type="numbered"><label>5</label><mml:math id="M39" display="block"><mml:mrow><mml:mi mathvariant="normal">iPUE</mml:mi><mml:mo>≈</mml:mo><mml:mi>c</mml:mi><mml:mo>×</mml:mo><mml:msub><mml:mi mathvariant="normal">SANIR</mml:mi><mml:mi mathvariant="normal">V</mml:mi></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
        where <inline-formula><mml:math id="M40" display="inline"><mml:mi>c</mml:mi></mml:math></inline-formula> is the slope coefficient.</p>
      <p id="d1e769">Considering the presence of mixed pixels of C3 and C4 species with the 250 m
pixels, Eq. (5) can be rewritten as
          <disp-formula id="Ch1.E6" content-type="numbered"><label>6</label><mml:math id="M41" display="block"><mml:mrow><mml:mi mathvariant="normal">iPUE</mml:mi><mml:mo>≈</mml:mo><mml:mfenced close="]" open="["><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub><mml:mo>×</mml:mo><mml:msub><mml:mi>f</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msub><mml:mo>×</mml:mo><mml:mfenced close=")" open="("><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi>f</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:mfenced></mml:mrow></mml:mfenced><mml:mo>×</mml:mo><mml:msub><mml:mi mathvariant="normal">SANIR</mml:mi><mml:mi mathvariant="normal">V</mml:mi></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
        where <inline-formula><mml:math id="M42" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M43" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> are the coefficients for C4 and C3 species,
respectively, and <inline-formula><mml:math id="M44" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is the fraction of C4 species in vegetation.
Therefore, the SLOPE GPP model is
          <disp-formula id="Ch1.E7" content-type="numbered"><label>7</label><mml:math id="M45" display="block"><mml:mrow><?xmltex \hack{\hbox\bgroup\fontsize{9.5}{9.5}\selectfont$\displaystyle}?><mml:mi mathvariant="normal">GPP</mml:mi><mml:mo>≈</mml:mo><mml:mfenced open="[" close="]"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub><mml:mo>×</mml:mo><mml:msub><mml:mi>f</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msub><mml:mo>×</mml:mo><mml:mfenced open="(" close=")"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi>f</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:mfenced></mml:mrow></mml:mfenced><mml:mo>×</mml:mo><mml:mi mathvariant="normal">PAR</mml:mi><mml:mo>×</mml:mo><mml:msub><mml:mi mathvariant="normal">SANIR</mml:mi><mml:mi mathvariant="normal">V</mml:mi></mml:msub><?xmltex \hack{$\egroup}?><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula></p>
      <p id="d1e949">In the SLOPE model (Eq. 7), PAR, SANIR<inline-formula><mml:math id="M46" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> and <inline-formula><mml:math id="M47" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> are remote
sensing inputs, whereas <inline-formula><mml:math id="M48" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M49" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> are model parameters to be
calibrated using ground-truth GPP data (Fig. 1). In the following sections,
we will elaborate on the derivation of PAR, SANIR<inline-formula><mml:math id="M50" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> and <inline-formula><mml:math id="M51" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, along
with their quantitative uncertainties, and the model calibration for
parameters <inline-formula><mml:math id="M52" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M53" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>. With the uncertainty of each term (<inline-formula><mml:math id="M54" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M55" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M56" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>f</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M57" display="inline"><mml:mi mathvariant="normal">Δ</mml:mi></mml:math></inline-formula>PAR and <inline-formula><mml:math id="M58" display="inline"><mml:mi mathvariant="normal">Δ</mml:mi></mml:math></inline-formula>SANIR<inline-formula><mml:math id="M59" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>), the uncertainty of GPP can be estimated in a
spatiotemporally explicit manner by
          <disp-formula id="Ch1.E8" content-type="numbered"><label>8</label><mml:math id="M60" display="block"><mml:mrow><?xmltex \hack{\hbox\bgroup\fontsize{8.9}{8.9}\selectfont$\displaystyle}?><mml:mtable rowspacing="0.2ex" class="split" columnspacing="1em" displaystyle="true" columnalign="right left"><mml:mtr><mml:mtd><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="normal">GPP</mml:mi></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mo>=</mml:mo><mml:mfenced open="(" close=")"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub><mml:mo>×</mml:mo><mml:mi mathvariant="normal">PAR</mml:mi><mml:mo>×</mml:mo><mml:msub><mml:mi mathvariant="normal">SANIR</mml:mi><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:mrow></mml:mfenced><mml:mo>×</mml:mo><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mo>+</mml:mo><mml:mfenced open="[" close="]"><mml:mrow><mml:mfenced close=")" open="("><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi>f</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:mfenced><mml:mo>×</mml:mo><mml:mi mathvariant="normal">PAR</mml:mi><mml:mo>×</mml:mo><mml:msub><mml:mi mathvariant="normal">SANIR</mml:mi><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:mrow></mml:mfenced><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mo>+</mml:mo><mml:mfenced close="]" open="["><mml:mrow><mml:mfenced open="(" close=")"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:mfenced><mml:mo>×</mml:mo><mml:mi mathvariant="normal">PAR</mml:mi><mml:mo>×</mml:mo><mml:msub><mml:mi mathvariant="normal">SANIR</mml:mi><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:mrow></mml:mfenced><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>f</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mo>+</mml:mo><mml:mfenced open="{" close="}"><mml:mrow><mml:mfenced open="[" close="]"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub><mml:mo>×</mml:mo><mml:msub><mml:mi>f</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msub><mml:mo>×</mml:mo><mml:mfenced open="(" close=")"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi>f</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:mfenced></mml:mrow></mml:mfenced><mml:mo>×</mml:mo><mml:msub><mml:mi mathvariant="normal">SANIR</mml:mi><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:mrow></mml:mfenced><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="normal">PAR</mml:mi></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mo>+</mml:mo><mml:mfenced close="}" open="{"><mml:mrow><mml:mfenced close="]" open="["><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub><mml:mo>×</mml:mo><mml:msub><mml:mi>f</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msub><mml:mo>×</mml:mo><mml:mfenced close=")" open="("><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi>f</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:mfenced></mml:mrow></mml:mfenced><mml:mo>×</mml:mo><mml:mi mathvariant="normal">PAR</mml:mi></mml:mrow></mml:mfenced><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="normal">SANIR</mml:mi><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:mrow></mml:mtd></mml:mtr></mml:mtable><?xmltex \hack{$\egroup}?><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula></p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><?xmltex \currentcnt{1}?><?xmltex \def\figurename{Figure}?><label>Figure 1</label><caption><p id="d1e1405">Framework to produce the SLOPE GPP product. The box with dashed
lines is the legend.</p></caption>
        <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://essd.copernicus.org/articles/13/281/2021/essd-13-281-2021-f01.png"/>

      </fig>

<sec id="Ch1.S2.SS1">
  <label>2.1</label><title>Derivation of PAR</title>
      <p id="d1e1421">SLOPE adopts several machine learning approaches to compute PAR using
forcing data mainly from Terra and Aqua MODIS Atmosphere and Land products
(data solely from morning satellite Terra, afternoon satellite Aqua and
combination of the two satellites are called MOD, MYD and MCD, respectively,
hereinafter). The list of inputs includes aerosol optical depth (AOD) at 3 km resolution from the MOD04_3K (MODIS/Terra Aerosol 5Min L2 Swath 3km) and MYD04_3K (MODIS/Aqua Aerosol 5Min L2 Swath 3km) products (Remer et al., 2013), total column water vapor (TWV) at 1 km resolution from the MOD05_L2 (MODIS/Terra Total Precipitable Water Vapor 5-Min L2 Swath 1km and 5km) and MYD05_L2 (MODIS/Aqua Total Precipitable Water Vapor 5-Min L2 Swath 1km and 5km) products (Chang et al., 2015), cloud optical thickness (COT) at 1 km resolution from the MOD06_L2 (MODIS/Terra Clouds 5-Min L2 Swath 1km and 5km) and MYD06_L2 (MODIS/Aqua Clouds 5-Min L2 Swath 1km and 5km) products (Baum et al., 2012), total column ozone burden (TO3) at 5 km resolution from the MOD07_L2 (MODIS/Terra Temperature and Water Vapor Profiles 5-Min L2 Swath 5km) and MYD07_L2 (MODIS/Aqua Temperature and Water Vapor Profiles 5-Min L2 Swath 5km) products (Borbas et al., 2015), white-sky land surface shortwave albedo (ALB) at 500 m resolution from the MCD43A3 (MODIS/Terra+Aqua Albedo Daily L3 Global 500m SIN Grid) product (Román et al., 2009), and altitude (ALT) at 30 m resolution from the Shuttle Radar Topography Mission Global 1 arc second (SRTMGL1) product (Kobrick and Crippen, 2017).</p>
      <p id="d1e1424">MODIS atmosphere products are swath data, and swaths vary day by day. To maintain consistency and facilitate further usage, all data are reprojected using the nearest neighbor resampling approach to the Conus Albers projection on the North American Datum of 1983 (NAD83) (European Petroleum Survey Group – EPSG:6350) with 1 km spatial resolution. For
swath data, an overlap area exists between two paths. In this case, data with
smaller sensor view zenith angles provided by MOD/MYD03_L2
products are chosen.<?pagebreak page284?> MODIS land products and SRTMGL1 are tile data with
finer resolution than 1 km. They are reprojected to the EPSG 6350 spatial
reference by aggregating all fine-resolution pixels within each 1 km grid.</p>
      <p id="d1e1427"><?xmltex \hack{\newpage}?>Data gaps exist in all MODIS products, and a gap-filling measure is required. For MODIS
atmosphere products, gaps in MOD and MYD are first filled by data in the MYD and MOD
counterpart on the same day, followed by a multi-year average on that day.
Since the multi-year average of COT is always non-zero, directly using it
for a gap-filling measure always implies a cloudy condition. Therefore, a CLARA-2 (cLoud, Albedo and surface Radiation) cloud
mask at 0.05<inline-formula><mml:math id="M61" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> acquired from NOAA AVHRR (Advanced Very High Resolution Radiometer) data is employed
(Karlsson et al., 2017). Only MODIS data gaps for
AVHRR cloudy pixels are filled by a multi-year average of COT, whereas MODIS
COT data gaps for AVHRR clear pixels are set to 0. For the MODIS land
product, i.e., ALB, a temporally moving window with a 7 d radius is
utilized for a specific day, and a Gaussian filter is applied to the time
series data within the moving window on a per-pixel basis. The filtered
values are used to fill gaps on that specific day.</p>
      <p id="d1e1440">Machine learning approaches are used to upscale the ground truth to satellite data.
The ground truth is from the Surface Radiation Budget (SURFRAD) Network
(Augustine et al., 2000), including seven
long-term continuous sites across the CONUS. Daily-mean shortwave radiation
(SWR) and PAR on the surface are calculated from site observations at 1–3 min intervals from 2000 through 2018. Daily-mean top-of-atmosphere SWR (SWR<inline-formula><mml:math id="M62" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">TOA</mml:mi></mml:msub></mml:math></inline-formula>) is calculated using latitude and day-of-year (DOY)
information (Allen et al., 1998). Subsequently, atmospheric
transmittance (<inline-formula><mml:math id="M63" display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mi mathvariant="normal">SWR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) and proportion of PAR in SW (<inline-formula><mml:math id="M64" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mi mathvariant="normal">PAR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) are
calculated as SWR <inline-formula><mml:math id="M65" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> SWR<inline-formula><mml:math id="M66" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">TOA</mml:mi></mml:msub></mml:math></inline-formula> and PAR <inline-formula><mml:math id="M67" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> SWR.</p>
      <?pagebreak page285?><p id="d1e1499">Models are built to estimate <inline-formula><mml:math id="M68" display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mi mathvariant="normal">SWR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> first, followed by <inline-formula><mml:math id="M69" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mi mathvariant="normal">PAR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. MOD data
representing atmospheric conditions in the morning and MYD for the afternoon
are used separately for the estimation, and the two estimates are averaged
to account for discrepancies between the morning and afternoon. Clear and cloudy
conditions are also treated separately in modeling considering the
absence or presence of non-zero COT data. For the estimation of <inline-formula><mml:math id="M70" display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mi mathvariant="normal">SWR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, ALB,
ALT and SWR<inline-formula><mml:math id="M71" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">TOA</mml:mi></mml:msub></mml:math></inline-formula> are used in addition to atmosphere data, whereas for
<inline-formula><mml:math id="M72" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mi mathvariant="normal">PAR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, ALB, ALT and the estimated <inline-formula><mml:math id="M73" display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mi mathvariant="normal">SWR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> are used. A summary of model
inputs is listed in Table 1.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><?xmltex \currentcnt{1}?><?xmltex \def\figurename{Table}?><label>Table 1</label><caption><p id="d1e1570">Summary of machine learning model inputs for the estimation of
<inline-formula><mml:math id="M74" display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mi mathvariant="normal">SWR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M75" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mi mathvariant="normal">PAR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. Daily estimations from MOD and MYD atmosphere data
are averaged.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="9">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="center"/>
     <oasis:colspec colnum="3" colname="col3" align="center" colsep="1"/>
     <oasis:colspec colnum="4" colname="col4" align="center"/>
     <oasis:colspec colnum="5" colname="col5" align="center" colsep="1"/>
     <oasis:colspec colnum="6" colname="col6" align="center"/>
     <oasis:colspec colnum="7" colname="col7" align="center" colsep="1"/>
     <oasis:colspec colnum="8" colname="col8" align="center"/>
     <oasis:colspec colnum="9" colname="col9" align="center"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1">Inputs</oasis:entry>
         <oasis:entry rowsep="1" namest="col2" nameend="col5" colsep="1">For daily <inline-formula><mml:math id="M76" display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mi mathvariant="normal">SWR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> estimation </oasis:entry>
         <oasis:entry rowsep="1" namest="col6" nameend="col9">For daily <inline-formula><mml:math id="M77" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mi mathvariant="normal">PAR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> estimation </oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry rowsep="1" namest="col2" nameend="col3" colsep="1">MOD  </oasis:entry>
         <oasis:entry rowsep="1" namest="col4" nameend="col5" colsep="1">MYD </oasis:entry>
         <oasis:entry rowsep="1" namest="col6" nameend="col7" colsep="1">MOD  </oasis:entry>
         <oasis:entry rowsep="1" namest="col8" nameend="col9">MYD </oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Clear</oasis:entry>
         <oasis:entry colname="col3">Cloudy</oasis:entry>
         <oasis:entry colname="col4">Clear</oasis:entry>
         <oasis:entry colname="col5">Cloudy</oasis:entry>
         <oasis:entry colname="col6">Clear</oasis:entry>
         <oasis:entry colname="col7">Cloudy</oasis:entry>
         <oasis:entry colname="col8">Clear</oasis:entry>
         <oasis:entry colname="col9">Cloudy</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">log(COT)</oasis:entry>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M78" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M79" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M80" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"/>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M81" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">log(AOD)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M82" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M83" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M84" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M85" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M86" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M87" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M88" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M89" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">TWV</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M90" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M91" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M92" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M93" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M94" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M95" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M96" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M97" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">TO3</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M98" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M99" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M100" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M101" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M102" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M103" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M104" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M105" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">ALB</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M106" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M107" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M108" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M109" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M110" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M111" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M112" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M113" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">ALT</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M114" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M115" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M116" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M117" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M118" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M119" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M120" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M121" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">SWR<inline-formula><mml:math id="M122" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">TOA</mml:mi></mml:msub></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M123" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M124" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M125" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M126" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7"/>
         <oasis:entry colname="col8"/>
         <oasis:entry colname="col9"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M127" display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mi mathvariant="normal">SWR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3"/>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"/>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M128" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M129" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M130" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M131" display="inline"><mml:mo>√</mml:mo></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d1e2221">Four different machine learning approaches are employed to estimate
<inline-formula><mml:math id="M132" display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mi mathvariant="normal">SWR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M133" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mi mathvariant="normal">PAR</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. They are the least absolute shrinkage and selection
operator (LASSO) (Tibshirani, 1996), multivariate
adaptive regression splines (MARS) (Friedman, 1991),
<inline-formula><mml:math id="M134" display="inline"><mml:mi>k</mml:mi></mml:math></inline-formula>-nearest neighbor regression (KNN) (Goldberger et al., 2005),
and random forest regression (RF) (Liaw and Wiener, 2002). We used
scikit-learn, a free software machine learning library for the Python
programming language to build the models. All the four algorithms were
automatically optimized by tuning their hyperparameters using
5-fold cross validation on their training dataset. All inputs and outputs
are the same for the four approaches. Four different PAR estimations are
then obtained by Eq. (9), and their ensemble mean and standard deviation are
considered as the final estimation and uncertainty, respectively.
            <disp-formula id="Ch1.E9" content-type="numbered"><label>9</label><mml:math id="M135" display="block"><mml:mrow><mml:mi mathvariant="normal">PAR</mml:mi><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="normal">SWR</mml:mi><mml:mi mathvariant="normal">TOA</mml:mi></mml:msub><mml:mo>×</mml:mo><mml:msub><mml:mi>t</mml:mi><mml:mi mathvariant="normal">SWR</mml:mi></mml:msub><mml:mo>×</mml:mo><mml:msub><mml:mi>p</mml:mi><mml:mi mathvariant="normal">PAR</mml:mi></mml:msub></mml:mrow></mml:math></disp-formula></p>
</sec>
<sec id="Ch1.S2.SS2">
  <label>2.2</label><?xmltex \opttitle{Derivation of SANIR${}_{\mathrm{V}}$}?><title>Derivation of SANIR<inline-formula><mml:math id="M136" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula></title>
      <p id="d1e2298">SLOPE derives NIR<inline-formula><mml:math id="M137" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> (Eq. 1) from MODIS band 1 (red) and band 2
(NIR) surface reflectance (SR) at 250 m resolution from MOD/MYD09GQ products
(Vermote et al., 2002). Only pixels with
quality control (QC) information defined as “corrected product produced at ideal
quality all bands” were used. Since cloud and cloud shadows substantially
reduce NIR<inline-formula><mml:math id="M138" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> values, SLOPE adopts three strategies to mitigate the
cloud contamination.</p>
      <p id="d1e2329">First, the cloud mask is applied. MOD–MYD COT data processed in Sect. 2.1
are resampled to the same spatial reference with MOD–MYD SR data and used to
mask out cloudy pixels. At this point, a morphological dilation operation is
used to enlarge the cloud mask to account for cloud edges. However, since
COT data have a coarser resolution (1 km) than SR data (250 m), there are
still partial clouds and cloud shadows left after this step.</p>
      <p id="d1e2332">Second, MOD and MYD data are combined. Ideally, on a specific day, MOD and
MYD NIR<inline-formula><mml:math id="M139" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> should be identical if they are obtained under the same
conditions. However, the remaining cloud contamination and sun-target-sensor
geometry could cause differences between morning and afternoon observations.
Considering that the vegetation index is more sensitive to cloud contamination than the
sensor view zenith angle, a simple criterion is applied to combine MOD and
MYD observations. If the difference between MOD and MYD NIR<inline-formula><mml:math id="M140" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> is
greater than or equal to a predefined threshold (0.1 in this study), then
the smaller one is likely cloud contaminated, and the larger one is used.
Otherwise, the average value of the two is used. However, in many cases,
both MOD and MYD data are contaminated, and the sensor view zenith angle may
cause unexpected day-to-day variations.</p>
      <p id="d1e2364">Third, a temporal filter is applied. The filter is based on the assumption
that NIR<inline-formula><mml:math id="M141" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> should change smoothly within a short time period.
Accordingly, a temporally moving window with a 7 d radius is utilized for
a specific day. The mean and standard deviation are calculated from the
NIR<inline-formula><mml:math id="M142" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> time series on a per-pixel basis. Values outside the range of
mean <inline-formula><mml:math id="M143" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1.5</mml:mn></mml:mrow></mml:math></inline-formula> standard deviations are considered as outliers and dropped.
Subsequently, the mean of the first 3 d and that of the last 7 d are
calculated, respectively. If the NIR<inline-formula><mml:math id="M144" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> value of the target day is
20 % smaller or larger than both the first 3 d mean and the last 3 d
mean, then that NIR<inline-formula><mml:math id="M145" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> value is considered as an outlier and dropped.</p>
      <p id="d1e2433">After the removal of outliers, a large amount of data gaps exist, and
a gap-filling measure is required. Similar to ALB in Sect. 2.1, a temporally moving
window with a 7 d radius is utilized for a specific day, and a Gaussian
filter is applied and used to fill gaps on that day. The rest of the data gaps
are filled with the multi-year average of NIR<inline-formula><mml:math id="M146" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula>. Considering extreme
cases for which no data are available on a specific day over all years, the multi-year
average of <inline-formula><mml:math id="M147" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:math></inline-formula> d is used for the final gap-filling measure.</p>
      <p id="d1e2460">To minimize the effects of variations in soil brightness on NIR<inline-formula><mml:math id="M148" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula>,
soil background NIR<inline-formula><mml:math id="M149" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> (NIR<inline-formula><mml:math id="M150" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Soil</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula>) is identified from multi-year
average NIR<inline-formula><mml:math id="M151" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> time series. For a specific pixel, soil background
NIR<inline-formula><mml:math id="M152" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> (NIR<inline-formula><mml:math id="M153" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Soil</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula>) is supposed to be (1) smaller than seasonal mean
NIR<inline-formula><mml:math id="M154" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula>, which includes the vegetated period, and (2) smaller than 0.2
indicated by a global soil spectral library (Jiang and Fang,
2019). Therefore, NIR<inline-formula><mml:math id="M155" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Soil</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> is supposed to within a range of [0,
min(mean(NIR<inline-formula><mml:math id="M156" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula>), 0.2)]. The mode of daily NIR<inline-formula><mml:math id="M157" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> averaged over 2000–2019 within this value range is considered as
NIR<inline-formula><mml:math id="M158" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Soil</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula>. An example is given in Fig. S5. Theoretically,
NIR<inline-formula><mml:math id="M159" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Soil</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> for evergreen species cannot be obtained from time series
NIR<inline-formula><mml:math id="M160" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> because of the persistent vegetation cover. Pixels with a
NIR<inline-formula><mml:math id="M161" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Soil</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> value larger than 0.1 and seasonal coefficient of variation
(CV) of NIR<inline-formula><mml:math id="M162" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> smaller than 33 % are empirically considered as
evergreen species, and their NIR<inline-formula><mml:math id="M163" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Soil</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> values are set to 0.</p>
      <p id="d1e2679">Finally, SANIR<inline-formula><mml:math id="M164" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> is defined as
            <disp-formula id="Ch1.E10" content-type="numbered"><label>10</label><mml:math id="M165" display="block"><mml:mrow><mml:msub><mml:mi mathvariant="normal">SANIR</mml:mi><mml:mi mathvariant="normal">V</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi mathvariant="normal">NIR</mml:mi><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="normal">NIR</mml:mi><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Soil</mml:mi></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi mathvariant="normal">NIR</mml:mi><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Peak</mml:mi></mml:mrow></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="normal">NIR</mml:mi><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Soil</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>×</mml:mo><mml:msub><mml:mi mathvariant="normal">NIR</mml:mi><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Peak</mml:mi></mml:mrow></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where NIR<inline-formula><mml:math id="M166" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Peak</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> is the maximum value of the multi-year average
NIR<inline-formula><mml:math id="M167" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> time series on a per-pixel basis. SANIR<inline-formula><mml:math id="M168" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> does not change
NIR<inline-formula><mml:math id="M169" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Peak</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> but changes more for low NIR<inline-formula><mml:math id="M170" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> values.
SANIR<inline-formula><mml:math id="M171" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula> is set to 0 when NIR<inline-formula><mml:math id="M172" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Ref</mml:mi></mml:mrow></mml:msub><mml:mo>≤</mml:mo></mml:mrow></mml:math></inline-formula> NIR<inline-formula><mml:math id="M173" display="inline"><mml:msub><mml:mi/><mml:mrow><mml:mi mathvariant="normal">V</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">Soil</mml:mi></mml:mrow></mml:msub></mml:math></inline-formula>. In
general, SANIR<inline-formula><mml:math id="M174" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> is supposed to be smooth within a short time period;
therefore, the standard deviation within the <inline-formula><mml:math id="M175" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>3 d temporal window
is calculated as uncertainty.</p>
</sec>
<?pagebreak page286?><sec id="Ch1.S2.SS3">
  <label>2.3</label><title>Derivation of the C4 fraction</title>
      <p id="d1e2903">A National Land Cover Database (NLCD) along with a crop-specific land cover
product Cropland Data Layer (CDL) are used to derive the fraction cover of
C4 crop in vegetation (<inline-formula><mml:math id="M176" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>). NLCD is a comprehensive land cover database
produced by the United States Geological Survey (USGS). It provides several
main thematic classes such as urban, agriculture and forest with high
accuracy (Homer et al., 2004). The 30 m nationwide NLCD data are available for 2001, 2004, 2006, 2008, 2011, 2013
and 2016. CDL is an agriculture-oriented product produced by the United
States Department of Agriculture (USDA). It provides <inline-formula><mml:math id="M177" display="inline"><mml:mrow><mml:mi mathvariant="italic">&gt;</mml:mi><mml:mn mathvariant="normal">100</mml:mn></mml:mrow></mml:math></inline-formula> crop
cover types and leverages other land cover types from NLCD
(Boryan et al., 2011). Across the
CONUS CDL data are available at a 30 m spatial resolution and in a yearly
temporal frequency from 2008 through 2019, whereas in some areas annual data
are available back to the 1990s.</p>
      <p id="d1e2930">The fraction of C4 crop in vegetated areas is first derived using existing
CDL data. NLCD land cover types are categorized into vegetated areas and
non-vegetated areas with 30 m resolution. The fraction of vegetated areas in
total area is subsequently calculated for each 250 m pixel. Similarly, CDL
crop types are categorized into C4-planted areas and non-C4 areas with 30 m
resolution. The fraction of C4 crops in total area is subsequently calculated
for each 250 m pixel. The ratio of the fraction of C4 crops in total area to the
fraction of vegetated areas in total area is calculated to derive the fraction
of C4 crops in vegetated areas at 250 m resolution. Since NLCD data are not
available for every year, an assumption is made that 1 year of NLCD data can
represent adjacent years. Specifically, NLCD 2001 is used for 2000–2002;
NLCD 2004 is used for 2003 and 2004; NLCD 2006 is used for 2005 and 2006;
NLCD 2008 is used for 2007–2009; NLCD 2011 is used for 2010 and 2011;
NLCD 2013 is used for 2012–2014; and NLCD 2016 is used for 2015–2019.</p>
      <p id="d1e2933">To predict the fraction of C4 crop in vegetation for region years for which no
CDL data are available, crop rotation patterns are identified from historical
data. Assuming that C4 crops are planted following three rotation
strategies: C4–non-C4, C4–C4–non-C4 and non-C4–non-C4–C4 and assigning 1
to C4 and 0 to non-C4, a total of eight possible time series during the
period of 2008–2019 when nationwide CDL data are available are listed in
Table 2. On a per-pixel basis, the time series of the fraction of C4 crop in
vegetation areas during 2008–2019 is compared with the eight predefined
rotation patterns. The Pearson coefficient <inline-formula><mml:math id="M178" display="inline"><mml:mi>r</mml:mi></mml:math></inline-formula> is calculated between actual time
series and each of the eight patterns, and the pattern yielding the largest
<inline-formula><mml:math id="M179" display="inline"><mml:mi>r</mml:mi></mml:math></inline-formula> is the identified rotation pattern. Once the pattern is identified,
the fraction of C4 crop in vegetated areas in any unknown year can be inferred.
If 1 year is inferred as C4, then the multi-year average of the C4 fraction
over C4-dominated years is used. Otherwise, the multi-year average over
C3-dominated years is used. If the largest <inline-formula><mml:math id="M180" display="inline"><mml:mi>r</mml:mi></mml:math></inline-formula> is smaller than 0.497, i.e., <inline-formula><mml:math id="M181" display="inline"><mml:mrow><mml:mi>p</mml:mi><mml:mi mathvariant="italic">&gt;</mml:mi><mml:mn mathvariant="normal">0.1</mml:mn></mml:mrow></mml:math></inline-formula> for 12 years, then it is considered as no significant
pattern, and the multi-year average over all years is used. The RMSE between the
predicted and reference CDL C4 fraction is calculated as uncertainty. To
account for the land cover change, the predicted C4 crop fraction is set to
0 in years when NLCD data are not classified as cropland. It is worth
mentioning that C4 grassland and shrubland are not considered in this study,
as no nationwide high-resolution distribution data are available.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T2" specific-use="star"><?xmltex \currentcnt{2}?><?xmltex \def\figurename{Table}?><label>Table 2</label><caption><p id="d1e2973">Predefined C4-planting patterns from 2008 through 2019. If the C4 crop
dominates in a specific year, 1 is assigned. Otherwise, 0 is assigned.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="9">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="center"/>
     <oasis:colspec colnum="3" colname="col3" align="center"/>
     <oasis:colspec colnum="4" colname="col4" align="center"/>
     <oasis:colspec colnum="5" colname="col5" align="center"/>
     <oasis:colspec colnum="6" colname="col6" align="center"/>
     <oasis:colspec colnum="7" colname="col7" align="center"/>
     <oasis:colspec colnum="8" colname="col8" align="center"/>
     <oasis:colspec colnum="9" colname="col9" align="center"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Year</oasis:entry>
         <oasis:entry colname="col2">Pattern 1</oasis:entry>
         <oasis:entry colname="col3">Pattern 2</oasis:entry>
         <oasis:entry colname="col4">Pattern 3</oasis:entry>
         <oasis:entry colname="col5">Pattern 4</oasis:entry>
         <oasis:entry colname="col6">Pattern 5</oasis:entry>
         <oasis:entry colname="col7">Pattern 6</oasis:entry>
         <oasis:entry colname="col8">Pattern 7</oasis:entry>
         <oasis:entry colname="col9">Pattern 8</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">2008</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">0</oasis:entry>
         <oasis:entry colname="col4">1</oasis:entry>
         <oasis:entry colname="col5">1</oasis:entry>
         <oasis:entry colname="col6">0</oasis:entry>
         <oasis:entry colname="col7">0</oasis:entry>
         <oasis:entry colname="col8">0</oasis:entry>
         <oasis:entry colname="col9">1</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2009</oasis:entry>
         <oasis:entry colname="col2">0</oasis:entry>
         <oasis:entry colname="col3">1</oasis:entry>
         <oasis:entry colname="col4">1</oasis:entry>
         <oasis:entry colname="col5">0</oasis:entry>
         <oasis:entry colname="col6">1</oasis:entry>
         <oasis:entry colname="col7">0</oasis:entry>
         <oasis:entry colname="col8">1</oasis:entry>
         <oasis:entry colname="col9">0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2010</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">0</oasis:entry>
         <oasis:entry colname="col4">0</oasis:entry>
         <oasis:entry colname="col5">1</oasis:entry>
         <oasis:entry colname="col6">1</oasis:entry>
         <oasis:entry colname="col7">1</oasis:entry>
         <oasis:entry colname="col8">0</oasis:entry>
         <oasis:entry colname="col9">0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2011</oasis:entry>
         <oasis:entry colname="col2">0</oasis:entry>
         <oasis:entry colname="col3">1</oasis:entry>
         <oasis:entry colname="col4">1</oasis:entry>
         <oasis:entry colname="col5">1</oasis:entry>
         <oasis:entry colname="col6">0</oasis:entry>
         <oasis:entry colname="col7">0</oasis:entry>
         <oasis:entry colname="col8">0</oasis:entry>
         <oasis:entry colname="col9">1</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2012</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">0</oasis:entry>
         <oasis:entry colname="col4">1</oasis:entry>
         <oasis:entry colname="col5">0</oasis:entry>
         <oasis:entry colname="col6">1</oasis:entry>
         <oasis:entry colname="col7">0</oasis:entry>
         <oasis:entry colname="col8">1</oasis:entry>
         <oasis:entry colname="col9">0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2013</oasis:entry>
         <oasis:entry colname="col2">0</oasis:entry>
         <oasis:entry colname="col3">1</oasis:entry>
         <oasis:entry colname="col4">0</oasis:entry>
         <oasis:entry colname="col5">1</oasis:entry>
         <oasis:entry colname="col6">1</oasis:entry>
         <oasis:entry colname="col7">1</oasis:entry>
         <oasis:entry colname="col8">0</oasis:entry>
         <oasis:entry colname="col9">0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2014</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">0</oasis:entry>
         <oasis:entry colname="col4">1</oasis:entry>
         <oasis:entry colname="col5">1</oasis:entry>
         <oasis:entry colname="col6">0</oasis:entry>
         <oasis:entry colname="col7">0</oasis:entry>
         <oasis:entry colname="col8">0</oasis:entry>
         <oasis:entry colname="col9">1</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2015</oasis:entry>
         <oasis:entry colname="col2">0</oasis:entry>
         <oasis:entry colname="col3">1</oasis:entry>
         <oasis:entry colname="col4">1</oasis:entry>
         <oasis:entry colname="col5">0</oasis:entry>
         <oasis:entry colname="col6">1</oasis:entry>
         <oasis:entry colname="col7">0</oasis:entry>
         <oasis:entry colname="col8">1</oasis:entry>
         <oasis:entry colname="col9">0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2016</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">0</oasis:entry>
         <oasis:entry colname="col4">0</oasis:entry>
         <oasis:entry colname="col5">1</oasis:entry>
         <oasis:entry colname="col6">1</oasis:entry>
         <oasis:entry colname="col7">1</oasis:entry>
         <oasis:entry colname="col8">0</oasis:entry>
         <oasis:entry colname="col9">0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2017</oasis:entry>
         <oasis:entry colname="col2">0</oasis:entry>
         <oasis:entry colname="col3">1</oasis:entry>
         <oasis:entry colname="col4">1</oasis:entry>
         <oasis:entry colname="col5">1</oasis:entry>
         <oasis:entry colname="col6">0</oasis:entry>
         <oasis:entry colname="col7">0</oasis:entry>
         <oasis:entry colname="col8">0</oasis:entry>
         <oasis:entry colname="col9">1</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2018</oasis:entry>
         <oasis:entry colname="col2">1</oasis:entry>
         <oasis:entry colname="col3">0</oasis:entry>
         <oasis:entry colname="col4">1</oasis:entry>
         <oasis:entry colname="col5">0</oasis:entry>
         <oasis:entry colname="col6">1</oasis:entry>
         <oasis:entry colname="col7">0</oasis:entry>
         <oasis:entry colname="col8">1</oasis:entry>
         <oasis:entry colname="col9">0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2019</oasis:entry>
         <oasis:entry colname="col2">0</oasis:entry>
         <oasis:entry colname="col3">1</oasis:entry>
         <oasis:entry colname="col4">0</oasis:entry>
         <oasis:entry colname="col5">1</oasis:entry>
         <oasis:entry colname="col6">1</oasis:entry>
         <oasis:entry colname="col7">1</oasis:entry>
         <oasis:entry colname="col8">0</oasis:entry>
         <oasis:entry colname="col9">0</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

</sec>
<sec id="Ch1.S2.SS4">
  <label>2.4</label><title>Calibration for iPUE coefficients</title>
      <p id="d1e3420">SLOPE was calibrated using the GPP data derived from AmeriFlux site
observations. The AmeriFlux network is a community of sites that use
eddy-covariance technology to measure landscape-level carbon, water and
energy fluxes across the Americas
(Baldocchi et al., 2001).
A total of 48 sites (324 site years) were involved in this study (Table S3).
All of the 43 sites in the FLUXNET2015 Tier 1 dataset (variable name:
GPP_DT_VUT_MEAN; quality
control: NEE_VUT_REF_QC) in the
CONUS were used because this dataset was produced by a<?pagebreak page287?> standardized data
processing pipeline with strict data quality control protocols and is
commonly considered the ground truth. Additionally, seven sites were from the
AmeriFlux level 4 dataset (variable name: GPP_or_MDS; quality control: NEE_or_fMDSsqc). This dataset was generated more than 10 years ago, and only
AmeriFlux Core Sites that are not covered by FLUXNET2015 were used for data
quality consideration. For both datasets, only days with the best quality
control flags were used in the SLOPE modeling and evaluation procedures.</p>
      <p id="d1e3423">We used Eq. (5) to conduct model calibration. Although SLOPE considers the iPUE–SANIR<inline-formula><mml:math id="M182" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> relationship for C3 and C4 species, we also
tested other configurations for comparison purposes. Configuration 1
(“all”) is defined as follows: all data were used together to fit a universal iPUE coefficient
<inline-formula><mml:math id="M183" display="inline"><mml:mi>c</mml:mi></mml:math></inline-formula>. Configuration 2 (“C3–C4”) is defined as follows: data were separated for C3 and C4 species to
fit <inline-formula><mml:math id="M184" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M185" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, respectively. It is worth mentioning that only C4
crops (six sites) were considered as C4 species, whereas C4 grass and shrubs
(three sites: US-SRG, Santa Rita Grassland; US-SRM, Santa Rita Mesquite; and US-Wkg, Walnut Gulch Kendall Grasslands) were still categorized into C3 species
because of the lack of nationwide and high-resolution C4 grass and shrub data.
Configuration 3 (“PFTs”) is defined as follows: data were separated for different PFTs,
evergreen needleleaf forest (ENF; 14 sites), deciduous broadleaf forest and
mixed forest (DBF and MF; 8 sites), shrubland and woody savannah (SHR and WSA; 5 sites), grassland (GRA; 8 sites), wetland (WET; 5 sites), C3 cropland
(10 sites) and C4 cropland (6 sites), to fit PFT-specific iPUE coefficients.
The RMSE between SANIR<inline-formula><mml:math id="M186" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>-derived and AmeriFlux iPUE for C3 and C4 are
calculated as uncertainties of <inline-formula><mml:math id="M187" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M188" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, respectively.</p>
</sec>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Evaluation of the SLOPE product</title>
<sec id="Ch1.S3.SS1">
  <label>3.1</label><title>Performance of PAR</title>
      <p id="d1e3524">SLOPE PAR demonstrates distinctive and detailed spatial variations in the
CONUS because of the large spatial variations of atmospheric conditions
(Fig. 2a). As an example, on 10 July 2020, large areas in New Jersey,
Wisconsin, Oklahoma, South Dakota and Montana display significantly lower
values than other areas, due to dominant impacts of clouds (Fig. S1). Aerosol
optical depth (Fig. S2), total water vapor (Fig. S3) and total ozone burden
(Fig. S4) also influence the amount of clear-sky PAR to some degree. For
example, the southeastern part of the CONUS shows more aerosol and thus lower
PAR values than other cloud-free areas. In addition to the total amount of
PAR, SLOPE PAR also reveals variations in the ratio of PAR to SWR (Fig. S5).
Despite a relatively small range (0.40–0.46), it is negatively
correlated with cloud optical thickness and total ozone burden and
positively correlates with total water vapor. PAR uncertainties caused by
the difference of the four machine learning algorithms are generally small
(<inline-formula><mml:math id="M189" display="inline"><mml:mrow><mml:mi mathvariant="italic">&lt;</mml:mi><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula> %; Fig. 2b). Higher uncertainties are mainly distributed in
cloudy and desert areas.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2" specific-use="star"><?xmltex \currentcnt{2}?><?xmltex \def\figurename{Figure}?><label>Figure 2</label><caption><p id="d1e3539">Spatial distribution of 1 km resolution <bold>(a)</bold> PAR (MJ m<inline-formula><mml:math id="M190" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M191" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) and <bold>(b)</bold> PAR uncertainty (MJ m<inline-formula><mml:math id="M192" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M193" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) on 10 July  2020.</p></caption>
          <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://essd.copernicus.org/articles/13/281/2021/essd-13-281-2021-f02.png"/>

        </fig>

      <p id="d1e3603">To evaluate SLOPE PAR, we used two different site observation datasets
which are independent of the PAR derivation procedure. The first dataset is
SURFRAD (Table S1). While SURFRAD data from 2000 through 2018 were used for
model training, we used data in 2019 for evaluation. The second dataset is
FLUXNET2015 (Table S2). A total of 41 sites providing PAR data were used for
the evaluation. For both datasets, only days with the best quality control
flags were used.</p>
      <p id="d1e3607">Evaluation results show that SLOPE PAR is in a highly aligned agreement with
the ground truth independent from the training procedure (Fig. 3). Across the
seven SURFRAD sites in 2019 and the 41 AmeriFlux sites from 2000 to 2014,
SLOPE PAR achieves an overall coefficient of determination (<inline-formula><mml:math id="M194" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>) of
0.91 and root-mean-square error (RMSE) values of 1.09 and
1.19 MJ m<inline-formula><mml:math id="M195" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M196" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, respectively. In addition, the<?pagebreak page288?> performance is reasonably stable
under different sky conditions, indicated by similar <inline-formula><mml:math id="M197" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> and RMSE values from
low to high atmospheric transmittance (Fig. S6).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><?xmltex \currentcnt{3}?><?xmltex \def\figurename{Figure}?><label>Figure 3</label><caption><p id="d1e3658">Comparison between site-observed PAR and SLOPE PAR. <bold>(a)</bold> Comparison
across seven SURFRAD sites in 2019. <bold>(b)</bold>  Comparison across 41 AmeriFlux sites
from 2000 to 2014. All site data are independent of the training procedure.</p></caption>
          <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://essd.copernicus.org/articles/13/281/2021/essd-13-281-2021-f03.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS2">
  <label>3.2</label><?xmltex \opttitle{Performance of SANIR${}_{\mathrm{V}}$}?><title>Performance of SANIR<inline-formula><mml:math id="M198" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula></title>
      <p id="d1e3690">SLOPE SANIR<inline-formula><mml:math id="M199" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> demonstrates detailed and distinctive spatial variations
in the CONUS (Fig. 4a). In the peak growing season, remarkably high
SANIR<inline-formula><mml:math id="M200" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> values (<inline-formula><mml:math id="M201" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 0.5) from the Corn Belt in the central
US are observed. This area is one of the most productive areas on Earth,
producing more than 30 % of global corn and soybean
(Green et al., 2018). Forested areas in
the eastern and western US are characterized by relatively high values (0.3–0.4) and medium values (0.2–0.3), respectively. Low values (<inline-formula><mml:math id="M202" display="inline"><mml:mrow><mml:mi mathvariant="italic">&lt;</mml:mi><mml:mn mathvariant="normal">0.2</mml:mn></mml:mrow></mml:math></inline-formula>) are mainly observed in grasslands and shrublands in the western US.
Uncertainty is associated with SANIR<inline-formula><mml:math id="M203" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> data on the pixel basis (Fig. 4b). In general, areas with higher SANIR<inline-formula><mml:math id="M204" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> values also have higher
uncertainties. However, this pattern is altered by atmospheric conditions,
where areas with higher cloud optical thickness (Fig. S1), aerosol optical
depth (Fig. S2) and water vapor (Fig. S3) values tend to have larger
uncertainties.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4" specific-use="star"><?xmltex \currentcnt{4}?><?xmltex \def\figurename{Figure}?><label>Figure 4</label><caption><p id="d1e3749">Spatial distribution of 250 m resolution <bold>(a)</bold>  SANIR<inline-formula><mml:math id="M205" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> and <bold>(b)</bold>
SANIR<inline-formula><mml:math id="M206" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> uncertainty across the CONUS on 10 July 2020.</p></caption>
          <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://essd.copernicus.org/articles/13/281/2021/essd-13-281-2021-f04.png"/>

        </fig>

      <p id="d1e3782">Figure 5 demonstrates that SLOPE SANIR<inline-formula><mml:math id="M207" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> is able to capture spatial and
temporal variations at a small scale (e.g., within a county). An overall drop
in SANIR<inline-formula><mml:math id="M208" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> due to an extreme event damage can be observed within a short
time period, thanks to the high temporal resolution (daily) of the SLOPE
product. In addition, differences between plots possibly indicating
different varieties, planting density and management can also be observed,
thanks to the high spatial resolution (250 m) of the SLOPE product.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5" specific-use="star"><?xmltex \currentcnt{5}?><?xmltex \def\figurename{Figure}?><label>Figure 5</label><caption><p id="d1e3806">SANIR<inline-formula><mml:math id="M209" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> in a <inline-formula><mml:math id="M210" display="inline"><mml:mrow><mml:mn mathvariant="normal">50</mml:mn><mml:mo>×</mml:mo><mml:mn mathvariant="normal">75</mml:mn></mml:mrow></mml:math></inline-formula> km<inline-formula><mml:math id="M211" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> area at Cedar Rapids,
Iowa (red marker in Fig. 4a), on <bold>(a)</bold> 9  Aug  2020 and <bold>(b)</bold>  13 Aug  2020. A
severe derecho took place from 10–11 August 2020. The maps are shown with
the sinusoidal projection.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://essd.copernicus.org/articles/13/281/2021/essd-13-281-2021-f05.png"/>

        </fig>

      <p id="d1e3851">SLOPE SANIR<inline-formula><mml:math id="M212" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> shows significantly different seasonality for different
PFTs (Fig. 6). The evergreen needleleaf forest site US-Blo (Blodgett Forest) is characterized
by a relatively stable SANIR<inline-formula><mml:math id="M213" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> seasonal cycle in 2019 (Fig. 6a),
indicated by a CV of 14.9 % only. The deciduous broadleaf forest site
US-Ha1 (Harvard Forest EMS Tower) has a large seasonal variation with a CV of 108.6 % (Fig. 6b). The
SANIR<inline-formula><mml:math id="M214" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> value suddenly rises from 0 to 0.3 in May, reaches 0.4 in June
and July and gradually decreases back to 0 in October. The hot desert open
shrubland site US-Whs (Walnut Gulch Lucky Hills Shrub) has an overall low SANIR<inline-formula><mml:math id="M215" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> value (Fig. 6c), with a
peak value observed in early October. The grassland site US-AR1 (ARM USDA UNL OSU Woodward Switchgrass 1) shows a
distinct double-peak (in June and September) seasonal pattern (Fig. 6d),
which is caused by the precipitation seasonality there. The wetland site
US-Myb (Mayberry Wetland) is characterized by a long growing season and a flat peak from April
to November (Fig. 6e). The cropland site US-Bo1 (Bondville) has corn planted in 2019,
and it shows the highest SANIR<inline-formula><mml:math id="M216" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> peak up to 0.5 among all the shown six
sites (Fig. 6f). It is worth mentioning that compared to the two raw
satellite-observed NIR<inline-formula><mml:math id="M217" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> values provided by MOD09GQ and MYD09GQ products,
respectively, SLOPE SANIR<inline-formula><mml:math id="M218" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> successfully removes the soil impact in the
non-growing season as the values equal to or close to 0. In addition,
SLOPE SANIR<inline-formula><mml:math id="M219" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> is gap-free and much less contaminated by noises.
Furthermore, spatiotemporally explicit uncertainty is associated with each
SANIR<inline-formula><mml:math id="M220" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> value.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6" specific-use="star"><?xmltex \currentcnt{6}?><?xmltex \def\figurename{Figure}?><label>Figure 6</label><caption><p id="d1e3938">Comparison between SANIR<inline-formula><mml:math id="M221" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> and raw NIR<inline-formula><mml:math id="M222" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> derived from
MOD09GQ and MYD09GQ products at six AmeriFlux sites (Table S3) in 2019. <bold>(a)</bold>
US-Blo (evergreen needleleaf forest, ENF). <bold>(b)</bold>  US-Ha1 (deciduous broadleaf
forest, DBF). <bold>(c)</bold>  US-Whs (open shrubland, OSH). <bold>(d)</bold>  US-AR1 (grassland, GRA).
<bold>(e)</bold>  US-Myb (wetland, WET). <bold>(f)</bold>  US-Bo1 (cropland, CRO). Shaded areas indicate
uncertainties of SANIR<inline-formula><mml:math id="M223" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>.</p></caption>
          <?xmltex \igopts{width=455.244094pt}?><graphic xlink:href="https://essd.copernicus.org/articles/13/281/2021/essd-13-281-2021-f06.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS3">
  <label>3.3</label><title>Performance of the C4 fraction</title>
      <p id="d1e4001">SLOPE predicts a reasonable fraction of the C4 crop in vegetation in the CONUS
(Fig. 7a). Most of the C4 crops are located in the Corn Belt, especially in
Indiana, Illinois, Iowa and Nebraska. A direct comparison between the predicted
C4 crop fraction (Fig. 8a) and independent reference CDL data (Fig. 8b)
indicates that the SLOPE prediction is able to reconstruct the spatial
patterns of the fraction of C4 crop in vegetation at 250 m resolution. It is
worth mentioning that the uncertainty metric RMSE is sensitive to extreme
values, and it is different from the misclassification rate (0.4 does not mean
40 %). For a pure pixel of a corn–soybean rotation field, the RMSE equals 0.39 if 3 out of 20 years are misclassified, i.e., misclassification rate of 0.15. A further investigation with regard to interannual dynamics shows
that the<?pagebreak page289?> SLOPE predictions can even perform better than CDL reference data
(Fig. 9), benchmarked with the ground truth collected in the field. At this
point, the CDL land cover could be prone to uncertainties in both satellite
observation and classification algorithm, and classification is conducted
year by year without an interannual consideration
(Lark et al., 2017). SLOPE employs a
rotation model to match decadal time series of CDL data, during which
procedure noises in CDL data are suppressed. The features for which SLOPE is able
to reconstruct spatial and interannual patterns of CDL data enable
producing GPP in years when CDL data are unavailable (e.g., 2020 and years
before 2008 for most regions). It is worth mentioning that uncertainty is
also associated with each pixel (Fig. 7b).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7" specific-use="star"><?xmltex \currentcnt{7}?><?xmltex \def\figurename{Figure}?><label>Figure 7</label><caption><p id="d1e4006">Spatial distribution of 250 m resolution <bold>(a)</bold> predicted fraction of
C4 crop in vegetation in 2000 and <bold>(b)</bold> C4 crop fraction uncertainty across
the CONUS.</p></caption>
          <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://essd.copernicus.org/articles/13/281/2021/essd-13-281-2021-f07.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F8" specific-use="star"><?xmltex \currentcnt{8}?><?xmltex \def\figurename{Figure}?><label>Figure 8</label><caption><p id="d1e4023">C4 crop fraction of <bold>(a)</bold> SLOPE predicted and <bold>(b)</bold> CDL reference data
in a <inline-formula><mml:math id="M224" display="inline"><mml:mrow><mml:mn mathvariant="normal">50</mml:mn><mml:mo>×</mml:mo><mml:mn mathvariant="normal">75</mml:mn></mml:mrow></mml:math></inline-formula> km<inline-formula><mml:math id="M225" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> area in Keith County, Nebraska (red
marker in Fig. 7a), in 2000. Only CDL data during 2008–2019 are used in
the modeling procedure, and therefore <bold>(b)</bold> is independent of <bold>(a)</bold>. The maps
are shown with the sinusoidal projection.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://essd.copernicus.org/articles/13/281/2021/essd-13-281-2021-f08.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F9" specific-use="star"><?xmltex \currentcnt{9}?><?xmltex \def\figurename{Figure}?><label>Figure 9</label><caption><p id="d1e4069">Comparison of fraction of C4 crop in vegetation between the field-collected ground truth, 250 m resolution CDL data and 250 m resolution SLOPE
predictions at six AmeriFlux sites (Table S3) in the US Corn Belt from
2000 to 2020. <bold>(a)</bold> US-Ne1 (uncertainty: 0.17; Mead – irrigated continuous maize site). <bold>(b)</bold> US-Ne2 (uncertainty:
0.40; Mead – irrigated maize–soybean rotation site). <bold>(c)</bold> US-Ne3 (uncertainty: 0.18; Mead – rainfed maize–soybean rotation site). <bold>(d)</bold> US-Bo1 (uncertainty: 0; Bondville). <bold>(e)</bold>
US-Ro1 (uncertainty: 0.16; Rosemount – G21). Uncertainty is the RMSE between the predicted
and the CDL reference.</p></caption>
          <?xmltex \igopts{width=455.244094pt}?><graphic xlink:href="https://essd.copernicus.org/articles/13/281/2021/essd-13-281-2021-f09.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS4">
  <label>3.4</label><title>Performance of GPP</title>
      <p id="d1e4101">SLOPE SANIR<inline-formula><mml:math id="M226" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> shows a strong linear correlation with iPUE (Fig. 10).
When data from all 49 sites (324 site years) are used together, the
SANIR<inline-formula><mml:math id="M227" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>–iPUE relationship has an overall <inline-formula><mml:math id="M228" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> value
of 0.73 (Fig. 10a). This is composed of an <inline-formula><mml:math id="M229" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> value of 0.92 from C4 species
(Fig. 10b) and 0.70 from C3 species (Fig. 10c). C3 species can be further
decomposed into six PFTs (Fig. 10d–i), among which cropland has the
highest <inline-formula><mml:math id="M230" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> value up to 0.80 (Fig. 10i), whereas evergreen needleleaf
forest has the lowest value of 0.46 (Fig. 10d). This relatively weak iPUE–SANIR<inline-formula><mml:math id="M231" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> relationship is expected because evergreen needleleaf
forest tends to allocate resources for leaf construction and maintenance at
large timescales and does not have much flexibility to change canopy
structure and leaf color as a response to varying environment at small timescales (Badgley et
al., 2019; Chabot and Hicks, 1982). Previous studies found that changes in
the xanthophyll cycle instead of chlorophyll concentration or absorbed PAR
explained the seasonal variation of photosynthetic capacity in evergreen
needleleaf forest (Gamon et
al., 2016; Magney et al., 2019). Therefore, SIF was suggested by some
studies as a better proxy of photosynthetic capacity in this<?pagebreak page290?> ecosystem
(Smith
et al., 2018; Turner et al., 2020), though satellite SIF has coarser spatial
resolution, shorter temporal coverage, larger temporal latency and
a lower signal-to-noise ratio than SANIR<inline-formula><mml:math id="M232" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>. In addition, the relatively weak
iPUE–SANIR<inline-formula><mml:math id="M233" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> relationship is also partly because of the small
value ranges in both SANIR<inline-formula><mml:math id="M234" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> and iPUE.</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F10" specific-use="star"><?xmltex \currentcnt{10}?><?xmltex \def\figurename{Figure}?><label>Figure 10</label><caption><p id="d1e4194">Comparison between SANIR<inline-formula><mml:math id="M235" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> and iPUE over different subsets.
The slope value of the SANIR<inline-formula><mml:math id="M236" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>–iPUE relationship is the
model parameter <inline-formula><mml:math id="M237" display="inline"><mml:mi>c</mml:mi></mml:math></inline-formula> (Eq. 5). Panel <bold>(a)</bold> is used by the model configuration 1
(all). Panels <bold>(b)</bold> and <bold>(c)</bold> are used by the model configuration 2 (C3–C4),
which is actually used by SLOPE. Panels <bold>(b)</bold> and <bold>(d)</bold>–<bold>(i)</bold> are used by the model
configuration 3 (PFTs).</p></caption>
          <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://essd.copernicus.org/articles/13/281/2021/essd-13-281-2021-f10.png"/>

        </fig>

      <p id="d1e4247">The overall slope is 3.82 gC MJ<inline-formula><mml:math id="M238" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for all data (Fig. 10a). A distinct
difference is found between C4 (5.18; Fig. 10b) and C3 (3.54; Fig. 10c)
species, suggesting the importance of separating C4 from C3 species in
modeling. The slope values vary to a limited degree within C3 species (Fig. 10d–i), ranging from 3.26 gC MJ<inline-formula><mml:math id="M239" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (cropland; Fig. 10i) to 3.80 gC MJ<inline-formula><mml:math id="M240" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (evergreen needleleaf forest; Fig. 10d), indicating the
insignificance of separating different PFTs. It is worth mentioning that the
SANIR<inline-formula><mml:math id="M241" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>–iPUE relationship has a zero intercept because
of the successful removal of the soil impact.</p>
      <p id="d1e4296">A 100-time-repeated 5-fold cross validation reveals the robustness of the
SANIR<inline-formula><mml:math id="M242" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>–iPUE relationships (Fig. 11). Here the repeated
cross validation means the whole GPP dataset from all 49 sites (324 site
years) is randomly split into five folds, four folds for training and one fold for
testing, and the process is repeated 100 times yielding 500 training–testing
splits in total. In all subsets, the uncertainties of the iPUE coefficient
<inline-formula><mml:math id="M243" display="inline"><mml:mi>c</mml:mi></mml:math></inline-formula> (the slope of the SANIR<inline-formula><mml:math id="M244" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>–iPUE relationship) are less
than 1 % (Fig. 11a). When using the three different model configurations,
the model performances in simulating the whole training–testing datasets
also show little variation (Fig. 11b), in general <inline-formula><mml:math id="M245" display="inline"><mml:mrow><mml:mi mathvariant="italic">&lt;</mml:mi><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula> % and
<inline-formula><mml:math id="M246" display="inline"><mml:mrow><mml:mi mathvariant="italic">&lt;</mml:mi><mml:mn mathvariant="normal">1.5</mml:mn></mml:mrow></mml:math></inline-formula> % for the training and testing datasets, respectively.
Moreover, the <inline-formula><mml:math id="M247" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> values between training and testing datasets, and
between C3–C4 and PFT-based configurations are almost identical
(<inline-formula><mml:math id="M248" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 0.76). These results suggest using <inline-formula><mml:math id="M249" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">5.18</mml:mn></mml:mrow></mml:math></inline-formula> (Fig. 10b) and <inline-formula><mml:math id="M250" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mrow><mml:mi mathvariant="normal">C</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">3.54</mml:mn></mml:mrow></mml:math></inline-formula> (Fig. 10c) in SLOPE is reasonable. The 95 %
confidential intervals of <inline-formula><mml:math id="M251" display="inline"><mml:mi>c</mml:mi></mml:math></inline-formula> for C4 and C3 species (Fig. 11a) are used as
their uncertainties in SLOPE.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F11" specific-use="star"><?xmltex \currentcnt{11}?><?xmltex \def\figurename{Figure}?><label>Figure 11</label><caption><p id="d1e4408">Statistics of the SANIR<inline-formula><mml:math id="M252" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>–iPUE relationship
from cross validation. <bold>(a)</bold> Slopes of the SANIR<inline-formula><mml:math id="M253" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>–iPUE
relationship over different subsets. <bold>(b)</bold> <inline-formula><mml:math id="M254" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> between AmeriFlux GPP and
estimated GPP using different model configurations for the training and
testing datasets, respectively. Error bars in both subplots indicate 95 %
confidential intervals over 500 experiments.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://essd.copernicus.org/articles/13/281/2021/essd-13-281-2021-f11.png"/>

        </fig>

      <p id="d1e4452">SLOPE GPP demonstrates detailed and distinctive spatial variations in the
CONUS (Fig. 12a). The Corn Belt is the most productive area, largely
contributed by the C4 crop corn whose GPP could reach up to 30 gC m<inline-formula><mml:math id="M255" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M256" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (Fig. 13a). Forested areas in the eastern US show medium GPP
values, followed by forests and croplands in the western US. Grasslands and
shrublands in the central and western US<?pagebreak page291?> generally show low productivity. On
this example day, the <inline-formula><mml:math id="M257" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> of spatial patterns between GPP and
SANIR<inline-formula><mml:math id="M258" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>, GPP and C4 fraction, and GPP and PAR across the CONUS are 0.89,
0.34 and 0.01, respectively. SANIR<inline-formula><mml:math id="M259" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>, an integrated vegetation index
containing information of both FPAR and LUE (Eq. 4), explains the majority
of GPP spatial variation. C4 fraction mainly contributes to the distribution
and magnitude of the peak in GPP spatial variation. Although PAR does not
influence the nationwide GPP spatial variation, it regulates GPP values at
local scale. For example, northeastern Nebraska shows smaller GPP values
than southeastern Nebraska in spite of a similar SANIR<inline-formula><mml:math id="M260" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> (Fig. 4a) and C4
fraction (Fig. 7a) because of smaller PAR values (Fig. 2a). At a small scale
(e.g., within a county), the 250 m resolution (<inline-formula><mml:math id="M261" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 0.06 km<inline-formula><mml:math id="M262" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>
per pixel) SLOPE GPP is close to revealing field-level heterogeneity,
considering that the mean and median crop field sizes in the CONUS are 0.19
and 0.28 km<inline-formula><mml:math id="M263" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>, respectively
(Yan and
Roy, 2016). For example, Fig. 13a shows large contrast in GPP, but Fig. 13b
is more homogeneous. This is because corn reaches peak growing season in
early July when soybean canopy is still open and sparse. SLOPE GPP with its
pixel size much smaller than field area is therefore able to show GPP
difference between corn and soybean. In late August, corn turns yellow, while
soybean is still green and active, and therefore they have similar GPP
values considering corn is C4, while soybean is C3. We suggest that the 250 m resolution makes a big difference compared to existing global GPP products whose
spatial resolutions are at least 500 m (<inline-formula><mml:math id="M264" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 0.25 km<inline-formula><mml:math id="M265" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> per
pixel). Quantitative uncertainty is provided for each SLOPE GPP estimate
(Eq. 8). The spatial pattern shows that the Corn Belt has the largest
uncertainty (Fig. 12b; e.g., 5 gC m<inline-formula><mml:math id="M266" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M267" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) due to the considerable
contribution from the uncertainty of the C4 fraction (Fig. 7b).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F12" specific-use="star"><?xmltex \currentcnt{12}?><?xmltex \def\figurename{Figure}?><label>Figure 12</label><caption><p id="d1e4586">Spatial distribution of 250 m resolution <bold>(a)</bold> GPP (gC m<inline-formula><mml:math id="M268" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M269" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) and <bold>(b)</bold> GPP uncertainty (gC m<inline-formula><mml:math id="M270" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M271" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) across the CONUS on
10 July 2020.</p></caption>
          <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://essd.copernicus.org/articles/13/281/2021/essd-13-281-2021-f12.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F13" specific-use="star"><?xmltex \currentcnt{13}?><?xmltex \def\figurename{Figure}?><label>Figure 13</label><caption><p id="d1e4653">GPP (gC m<inline-formula><mml:math id="M272" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M273" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) in a 50 <inline-formula><mml:math id="M274" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 75 km<inline-formula><mml:math id="M275" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> area in
Champaign County, Illinois (red marker in Fig. 12a), on <bold>(a)</bold> 10 July 2020
and <bold>(b)</bold> 20 August 2020. The maps are shown with the sinusoidal projection.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://essd.copernicus.org/articles/13/281/2021/essd-13-281-2021-f13.png"/>

        </fig>

      <?pagebreak page292?><p id="d1e4709">SLOPE GPP agrees fairly well with the ground truth from the AmeriFlux sites (Fig. 14).
Across all of the 49 sites (328 site years; Fig. 14a), SLOPE GPP achieves an
overall <inline-formula><mml:math id="M276" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> value of 0.85, RMSE of 1.63 gC m<inline-formula><mml:math id="M277" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M278" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> and relative
error of 37.8 %. For individual sites (Fig. 14b), the median <inline-formula><mml:math id="M279" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> and
RMSE values are 0.80 and 1.69 gC m<inline-formula><mml:math id="M280" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M281" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, respectively. C4 cropland
generally shows the highest median <inline-formula><mml:math id="M282" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> value (0.94), followed by
deciduous broadleaf forest and mixed forest (0.88) and C3 cropland (0.87).
The lowest median <inline-formula><mml:math id="M283" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> value (0.69) is observed for evergreen needleleaf
forest. With regard to RMSE, smaller median values are found in grassland
(1.09 gC m<inline-formula><mml:math id="M284" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M285" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>), shrubland and woody savannah (1.48 gC m<inline-formula><mml:math id="M286" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M287" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>), and deciduous broadleaf forest and mixed forest (1.48 gC m<inline-formula><mml:math id="M288" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M289" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>), whereas C3 (2.15 gC m<inline-formula><mml:math id="M290" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M291" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) and C4 (2.01 gC m<inline-formula><mml:math id="M292" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M293" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) cropland tend to have larger RMSE values.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F14" specific-use="star"><?xmltex \currentcnt{14}?><?xmltex \def\figurename{Figure}?><label>Figure 14</label><caption><p id="d1e4929">Performance of the SLOPE GPP. <bold>(a)</bold> Comparison between AmeriFlux
GPP and SLOPE GPP across all sites. <bold>(b)</bold> <inline-formula><mml:math id="M294" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> and RMSE of individual
sites. Sites with a C3–C4 rotation are separated into C3 CRO and C4 CRO.</p></caption>
          <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://essd.copernicus.org/articles/13/281/2021/essd-13-281-2021-f14.png"/>

        </fig>

      <p id="d1e4955">SLOPE GPP generally captures seasonal and interannual variations of
AmeriFlux GPP for different PFTs (Fig. 15). At the evergreen needleleaf
forest site US-Blo (Fig. 15a), the GPP seasonal cycle is mainly driven by
PAR, as the iPUE indicated by SANIR<inline-formula><mml:math id="M295" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> is fairly stable (Fig. 6a). At the
deciduous broadleaf forest site US-Ha1 (Fig. 15b), the start of the season and
the end of the season agree well between AmeriFlux GPP and SLOPE GPP. At the
open-shrubland site US-Whs (Fig. 15c), the quick rise and drop of GPP in
response to the start and end of the wet season are clearly observed in
SLOPE GPP. Even the double-peak pattern in 2011 can be observed in SLOPE
GPP. At the grassland site US-AR1 (Fig. 15d), the impact of a severe drought
in the southern Great Plains in 2011 is distinct in SLOPE GPP, as the GPP
values in 2011 are only about half of those in 2010 and 2012. At the
cropland site US-Bo1 (Fig. 15f), the rotation-caused year-to-year variation
is distinct, indicated by higher values in odd-numbered years with C4 crop
corn planted and lower values in even-numbered years with C3 crop soybean planted
(Fig. 9d). The lowest GPP peak is observed in 2012 when a severe
drought attacked the central US.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F15" specific-use="star"><?xmltex \currentcnt{15}?><?xmltex \def\figurename{Figure}?><label>Figure 15</label><caption><p id="d1e4969">Comparison between AmeriFlux (black dots) and SLOPE (red curves)
daily GPP at six AmeriFlux sites (Table S3) from 2000 to 2019. <bold>(a)</bold> US-Blo
(evergreen needleleaf forest, ENF). <bold>(b)</bold> US-Ha1 (deciduous broadleaf forest,
DBF). <bold>(c)</bold> US-Whs (open shrubland, OSH). <bold>(d)</bold> US-AR1 (grassland, GRA). <bold>(e)</bold>
US-Myb (wetland, WET). <bold>(f)</bold> US-Bo1 (cropland, CRO). Shaded areas indicate
uncertainties of SLOPE GPP.</p></caption>
          <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://essd.copernicus.org/articles/13/281/2021/essd-13-281-2021-f15.png"/>

        </fig>

</sec>
</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Data availability and data format</title>
      <p id="d1e5006">The archived daily 250 m resolution SLOPE GPP data product from 2000 to 2019
is distributed under a Creative Commons Attribution 4.0 License. It is
publicly available at NASA's Oak Ridge National Laboratory Distributed
Active Archive Center (ORNL DAAC) with a DOI of <ext-link xlink:href="https://doi.org/10.3334/ORNLDAAC/1786" ext-link-type="DOI">10.3334/ORNLDAAC/1786</ext-link> (download page: <uri>https://daac.ornl.gov/daacdata/cms/SLOPE_GPP_CONUS/data/</uri>, last access: 20 January 2021) (Jiang and Guan, 2020). Data from 2020 are
available from the authors upon request. All data are projected in the
standard MODIS Land Integerized Sinusoidal tile map projection and are
stored in GeoTIFF format files with a data type of signed 16 bit integer.
Each processing tile has a size of 4800 pixels by 4800 pixels, representing
a land region of approximately 1200 km by 1200 km . In addition to the GPP
product, SLOPE PAR, SANIR<inline-formula><mml:math id="M296" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> and C4 fraction, along with their
uncertainties, are also released. These datasets are also stored in the same
spatial projection and file format with the GPP dataset. PAR (resampled from
1 km to 250 m to be consistent with GPP) and SANIR<inline-formula><mml:math id="M297" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> are provided on a
daily basis, whereas C4 fraction is provided on an annual basis. A README
file is provided along with the SLOPE product, which instructs the usage of
the data.</p>
</sec>
<sec id="Ch1.S5" sec-type="conclusions">
  <label>5</label><title>Conclusions</title>
      <?pagebreak page294?><p id="d1e5042">This study produces a long-term and real-time (2000–present) GPP product
with daily and 250 m spatial and temporal resolutions. The product is based
on a remote-sensing-only (SLOPE) model, which uses accurate PAR, soil-adjusted
NIR<inline-formula><mml:math id="M298" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula> and dynamic C4 fractions as inputs. Evaluation against AmeriFlux
ground-truth GPP shows that the SLOPE GPP product has a reasonable accuracy,
with an overall <inline-formula><mml:math id="M299" display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> of 0.85 and RMSE of 1.63 gC m<inline-formula><mml:math id="M300" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> d<inline-formula><mml:math id="M301" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. To
demonstrate the real-time capacity of the SLOPE GPP product, the latest GPP
data on 2 November 2020, 2 d prior to the revision of this paper, is
shown in Fig. S7. The spatiotemporal resolution and instantaneity of the
SLOPE GPP product are higher than existing global GPP products, such as
MOD17, VPM, GLASS, FLUXCOM and BESS. We expect this novel GPP product can
significantly contribute to various researchers and stakeholders in fields
related to the regional carbon cycle, land surface processes, ecosystem
monitoring and management, and agriculture. The approaches used in this
study, in particular, the derivation of SANIR<inline-formula><mml:math id="M302" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>, can also be applied to
any other satellite platform with the two most classical bands: red and
NIR, for example, SaTellite dAta IntegRation (STAIR) from Landsat–MODIS fusion
data, which has daily, 30 m spatiotemporal resolution and can be applied at a
large scale (Jiang et al., 2020; Luo et al., 2018); commercial Planet Labs data with a daily
interval and spatial resolution up to 3m
(Houborg and McCabe, 2016; Kimm et al., 2020); and the Advanced Very High Resolution
Radiometer (AVHRR) with a temporal coverage as far back as 1982
(Franch
et al., 2017; Jiang et al., 2017). However, caution should be used in the
interpretation of GPP seasonal trajectory in evergreen needleleaf forests
because of the relatively poor relationship between SANIR<inline-formula><mml:math id="M303" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">V</mml:mi></mml:msub></mml:math></inline-formula>–iPUE and GPP
magnitude in southwestern US grasslands because of the ignorance of the fraction
of C4 grasslands. Finally, although the SLOPE product has been generated
from 2000 to present, caution should also be used in the interpretation of the
long-term trend because the SLOPE model, as many other LUE models, does not
explicitly consider the CO<inline-formula><mml:math id="M304" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> fertilization effects on vegetation
productivity.</p>
</sec>

      
      </body>
    <back><app-group>
        <supplementary-material position="anchor"><p id="d1e5116">The supplement related to this article is available online at: <inline-supplementary-material xlink:href="https://doi.org/10.5194/essd-13-281-2021-supplement" xlink:title="pdf">https://doi.org/10.5194/essd-13-281-2021-supplement</inline-supplementary-material>.</p></supplementary-material>
        </app-group><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d1e5127">CJ and KG designed the project and the workflow. CJ and GW developed
the SLOPE model. CJ processed the data and generated the GPP product.
CJ, BP and SW interpreted the results and refined the experiments.
CJ wrote the paper, and KG, GW, BP and SW all contributed to
the improvement of the paper.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d1e5133">The authors declare that they have no conflict of interest.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e5139">Chongya Jiang, Kaiyu Guan, Genghong Wu and Sheng Wang are funded by the DOE Center for<?pagebreak page295?> Advanced
Bioenergy and Bioproducts Innovation (U.S. Department of Energy, Office of
Science, Office of Biological and Environmental Research under award no. DE-SC0018420). Any opinions, findings and conclusions or recommendations
expressed in this publication are those of the author(s) and do not
necessarily reflect the views of the U.S. Department of Energy. Kaiyu Guan and
Bin Peng are funded by NASA awards (nos. NNX16AI56G and 80NSSC18K0170). Kaiyu Guan is also
funded by an NSF CAREER award (no. 1847334). Chongya Jiang and Kaiyu Guan also acknowledge the
support from Blue Waters Professorship from the National Center for
Supercomputing Applications of UIUC. This research is part of the Blue
Waters sustained-petascale computing project, which is supported by the
National Science Foundation (award nos. OCI-0725070 and ACI-1238993) and the
state of Illinois. Blue Waters is a joint effort of the University of
Illinois at Urbana-Champaign and its National Center for Supercomputing
Applications. We thank NASA for freely sharing the MODIS products.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d1e5144">This research has been supported by the U.S. Department of Energy (grant no. DE-SC0018420), the National Aeronautics and Space Administration (grant nos. NNX16AI56G and 80NSSC18K0170) and the National Science Foundation (grant no. 1847334).</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d1e5150">This paper was edited by Jens Klump and reviewed by three anonymous referees.</p>
  </notes><ref-list>
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    <!--<article-title-html>A daily, 250&thinsp;m and real-time gross primary productivity product (2000–present) covering the contiguous United States</article-title-html>
<abstract-html><p>Gross primary productivity (GPP) quantifies the amount of
carbon dioxide (CO<sub>2</sub>) fixed by plants through photosynthesis. Although
as a key quantity of terrestrial ecosystems, there is a lack of
high-spatial-and-temporal-resolution, real-time and observation-based GPP
products. To address this critical gap, here we leverage a state-of-the-art
vegetation index, near-infrared reflectance of vegetation (NIR<sub>V</sub>), along
with accurate photosynthetically active radiation (PAR), to produce a
SatelLite Only Photosynthesis Estimation (SLOPE) GPP product for the
contiguous United States (CONUS). Compared to existing GPP products, the
proposed SLOPE product is advanced in its spatial resolution (250&thinsp;m versus
<i>&gt;</i>500&thinsp;m), temporal resolution (daily versus 8&thinsp;d), instantaneity
(latency of 1&thinsp;d versus <i>&gt;</i>2 weeks) and quantitative
uncertainty (on a per-pixel and daily basis versus no uncertainty
information available). These characteristics are achieved because of
several technical innovations employed in this study: (1) SLOPE couples
machine learning models with MODIS atmosphere and land products to
accurately estimate PAR. (2) SLOPE couples highly efficient and pragmatic
gap-filling and filtering algorithms with surface reflectance acquired by
both Terra and Aqua MODIS satellites to derive a soil-adjusted NIR<sub>V</sub>
(SANIR<sub>V</sub>) dataset. (3) SLOPE couples a temporal pattern recognition
approach with a long-term Cropland Data Layer (CDL) product to predict dynamic
C4 crop fraction. Through developing a parsimonious model with only two
slope parameters, the proposed SLOPE product explains 85&thinsp;% of the spatial
and temporal variations in GPP acquired from 49 AmeriFlux eddy-covariance
sites (324 site years), with a root-mean-square error (RMSE) of
1.63&thinsp;gC&thinsp;m<sup>−2</sup>&thinsp;d<sup>−1</sup>. The median <i>R</i><sup>2</sup> over C3 and C4 crop sites reaches 0.87
and 0.94, respectively, indicating great potentials for monitoring crops, in
particular bioenergy crops, at the field level. With such a satisfactory
performance and its distinct characteristics in spatiotemporal resolution
and instantaneity, the proposed SLOPE GPP product is promising for
biological and environmental research, carbon cycle research, and a broad
range of real-time applications at the regional scale. The archived dataset
is available at <a href="https://doi.org/10.3334/ORNLDAAC/1786" target="_blank">https://doi.org/10.3334/ORNLDAAC/1786</a> (download
page: <a href="https://daac.ornl.gov/daacdata/cms/SLOPE_GPP_CONUS/data/" target="_blank"/>, last access: 20 January 2021) (Jiang and Guan, 2020), and
the real-time dataset is available upon request.</p></abstract-html>
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